CN1136241C - 利用双中心催化剂得到的聚乙烯 - Google Patents

利用双中心催化剂得到的聚乙烯 Download PDF

Info

Publication number
CN1136241C
CN1136241C CNB998028142A CN99802814A CN1136241C CN 1136241 C CN1136241 C CN 1136241C CN B998028142 A CNB998028142 A CN B998028142A CN 99802814 A CN99802814 A CN 99802814A CN 1136241 C CN1136241 C CN 1136241C
Authority
CN
China
Prior art keywords
catalyst
polyethylene
polyethylene according
polymer
polymerization
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CNB998028142A
Other languages
English (en)
Chinese (zh)
Other versions
CN1290274A (zh
Inventor
A
A·夫莱斯塔德
��������ķ������
V·阿尔姆奇斯特
�ɵ�ɭ
E·奥蒙德森
T·德伦
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Borealis Polymers Oy
Original Assignee
Borealis Polymers Oy
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Borealis Polymers Oy filed Critical Borealis Polymers Oy
Publication of CN1290274A publication Critical patent/CN1290274A/zh
Application granted granted Critical
Publication of CN1136241C publication Critical patent/CN1136241C/zh
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Images

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/69—Chromium, molybdenum, tungsten or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/63912—Component covered by group C08F4/62 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/63916—Component covered by group C08F4/62 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/6392—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/63922—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/63925—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually non-bridged
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65925—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually non-bridged

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Peptides Or Proteins (AREA)
  • Polymerisation Methods In General (AREA)
CNB998028142A 1998-02-09 1999-02-09 利用双中心催化剂得到的聚乙烯 Expired - Fee Related CN1136241C (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
NO19980552 1998-02-09
NO980552A NO980552D0 (no) 1998-02-09 1998-02-09 Katalysatorbestandel og katalysator for (ko)polymerisering av etylen, og fremgangsmåte for fremstilling av slik

Publications (2)

Publication Number Publication Date
CN1290274A CN1290274A (zh) 2001-04-04
CN1136241C true CN1136241C (zh) 2004-01-28

Family

ID=19901654

Family Applications (2)

Application Number Title Priority Date Filing Date
CNB998028142A Expired - Fee Related CN1136241C (zh) 1998-02-09 1999-02-09 利用双中心催化剂得到的聚乙烯
CN998028177A Expired - Fee Related CN1132853C (zh) 1998-02-09 1999-02-09 供乙烯(共)聚合的催化剂及其制备方法

Family Applications After (1)

Application Number Title Priority Date Filing Date
CN998028177A Expired - Fee Related CN1132853C (zh) 1998-02-09 1999-02-09 供乙烯(共)聚合的催化剂及其制备方法

Country Status (14)

Country Link
US (2) US6780809B1 (https=)
EP (2) EP1045866B1 (https=)
JP (2) JP2002502895A (https=)
KR (1) KR20010040769A (https=)
CN (2) CN1136241C (https=)
AR (1) AR018078A1 (https=)
AT (1) ATE283866T1 (https=)
AU (2) AU738712B2 (https=)
BR (2) BR9907708A (https=)
CA (2) CA2320271C (https=)
DE (1) DE69922340T2 (https=)
ES (1) ES2234237T3 (https=)
NO (1) NO980552D0 (https=)
WO (2) WO1999040126A1 (https=)

Families Citing this family (34)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NO980552D0 (no) * 1998-02-09 1998-02-09 Borealis As Katalysatorbestandel og katalysator for (ko)polymerisering av etylen, og fremgangsmåte for fremstilling av slik
NO981631L (no) * 1998-04-08 1999-10-11 Borealis As Katalysator for polymerisasjon av etylen, og fremgangsmaate for fremstilling av denne
US6272384B1 (en) 1999-05-27 2001-08-07 Urologix, Inc. Microwave therapy apparatus
GB9919718D0 (en) * 1999-08-19 1999-10-20 Borealis As Process
US6433133B1 (en) * 1999-11-16 2002-08-13 Eastman Chemical Company Process for reducing the weight average molecular weight and melt index ratio of polyethylenes and polyethylene products
US6388017B1 (en) * 2000-05-24 2002-05-14 Phillips Petroleum Company Process for producing a polymer composition
EP1399491B1 (en) 2001-04-30 2006-08-23 W.R. Grace & Co.-Conn. Supported dual transition metal catalyst systems
US6943224B2 (en) 2001-04-30 2005-09-13 W. R. Grace & Co.-Conn. Process for preparing supported transition metal catalyst systems and catalyst systems prepared thereby
KR20050084349A (ko) * 2002-12-17 2005-08-26 비피 케미칼즈 리미티드 지지된 올레핀 중합 촉매
US7384885B2 (en) 2003-03-31 2008-06-10 Exxonmobil Chemical Patents Inc. Catalyst activation and resins therefrom
AU2003226161A1 (en) * 2003-03-31 2004-11-23 Exxonmobil Chemical Patents Inc. Utility conduit resin
US20040192865A1 (en) * 2003-03-31 2004-09-30 Roger Scott T. Resin for extruded pipe
US20040192864A1 (en) * 2003-03-31 2004-09-30 Exxonmobil Chemical Company Utility conduit resin
WO2004096868A1 (en) * 2003-03-31 2004-11-11 Exxonmobil Chemical Patents Inc. Resin for extruded pipe
DE102005019393A1 (de) 2005-04-25 2006-10-26 Basell Polyolefine Gmbh Polyethylenformmassen für Spritzgussanwendungen
DE102005019395A1 (de) * 2005-04-25 2006-10-26 Basell Polyolefine Gmbh Formmasse aus Polyethylen zur Folienherstellung und Verfahren zum Herstellen der Formmasse in Gegenwart eines Mischkatalysators
KR20090024671A (ko) 2006-04-07 2009-03-09 다우 글로벌 테크놀로지스 인크. 폴리올레핀 조성물, 그로부터 제조된 물품 및 그의 제조 방법
CA2605077C (en) * 2007-10-01 2014-07-08 Nova Chemicals Corporation A co-supported catalyst system
CA2605044C (en) * 2007-10-01 2014-12-02 Nova Chemicals Corporation Polymerization process using a mixed catalyst system
BRPI1012232A2 (pt) * 2009-02-27 2017-01-31 Chevron Phillips Chemical Co Lp película de polietileno com propriedades de barreira aperfeiçoadas e métodos para a sua produção
US8852748B2 (en) 2009-02-27 2014-10-07 Chevron Phillips Chemical Company Lp Polyethylene film having improved barrier properties and methods of making same
US7951881B2 (en) 2009-02-27 2011-05-31 Chevron Phillips Chemical Company Lp Polyethylene film having improved barrier properties and methods of making same
CA2713042C (en) 2010-08-11 2017-10-24 Nova Chemicals Corporation Method of controlling polymer architecture
WO2012067777A2 (en) * 2010-11-19 2012-05-24 Exxonmobil Chemical Patents Inc. Processes for making multimodal molecular weight distribution polyolefins
US8148470B1 (en) 2010-11-19 2012-04-03 Exxonmobil Chemical Patents Inc. Processes for making multimodal molecular weight distribution polyolefins
US8653208B2 (en) * 2012-05-18 2014-02-18 Union Carbide Chemicals & Plastics Technology Llc Process for preparing catalysts and catalysts made thereby
CA2783494C (en) 2012-07-23 2019-07-30 Nova Chemicals Corporation Adjusting polymer composition
CN104877052B (zh) * 2015-05-06 2018-04-13 无锡耀汇科技有限公司 一种聚乙烯树脂
CN104877051B (zh) * 2015-05-06 2018-04-13 无锡耀汇科技有限公司 一种聚烯烃催化剂
RU2736067C2 (ru) 2016-04-20 2020-11-11 ЮНИВЕЙШН ТЕКНОЛОДЖИЗ, ЭлЭлСи Модификатор индекса текучести полимера
CN110167975B (zh) 2017-01-11 2026-02-17 Sabic环球技术有限责任公司 用于乙烯聚合的氧化铬催化剂
WO2018130539A1 (en) * 2017-01-11 2018-07-19 Sabic Global Technologies B.V. Chromium oxide catalyst for ethylene polymerization
CN111902467B (zh) 2018-02-05 2022-11-11 埃克森美孚化学专利公司 通过添加超高分子量高密度聚乙烯增强的lldpe的加工性
JP2023539244A (ja) 2020-08-24 2023-09-13 セラニーズ・インターナショナル・コーポレーション 分子量分布の狭い高密度ポリエチレンから作製されるゲル押出物品

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB8333032D0 (en) * 1983-12-10 1984-01-18 Bp Chem Int Ltd Orientated polyolefins
DE68913226T2 (de) 1988-04-26 1994-09-29 Showa Denko Kk Verfahren zur Herstellung von Ethylenpolymeren.
CN1131953A (zh) 1993-08-06 1996-09-25 埃克森化学专利公司 聚合催化剂及其制备和用途
US5614456A (en) * 1993-11-15 1997-03-25 Mobil Oil Corporation Catalyst for bimodal molecular weight distribution ethylene polymers and copolymers
BE1009186A3 (fr) * 1995-03-13 1996-12-03 Solvay Solide catalytique pour la (co)polymerisation d'ethylene, procede pour sa preparation, systeme catalytique pour la (co)polymerisation d'ethylene et procede de (co)polymerisation d'ethylene.
CA2227248A1 (en) * 1995-08-22 1997-03-06 Basf Aktiengesellschaft Polymers of ethylene having a high environmental stress crack resistance
DE19716239A1 (de) * 1997-04-18 1998-10-22 Basf Ag Verfahren zur Polymerisation von alpha-Olefinen in der Gasphase
GB9712663D0 (en) * 1997-06-16 1997-08-20 Borealis As Process
NO980552D0 (no) * 1998-02-09 1998-02-09 Borealis As Katalysatorbestandel og katalysator for (ko)polymerisering av etylen, og fremgangsmåte for fremstilling av slik
US6013596A (en) * 1998-05-18 2000-01-11 Arco Chemical Technology, L.P. Double metal cyanide catalysts containing cyclic, bidentate complexing agents
DE69925853T2 (de) * 1998-06-16 2006-05-18 Borealis Technology Oy Olefin polymerizations verfahren
ATE242275T1 (de) * 1998-12-16 2003-06-15 Borealis Tech Oy Mehrstufenverfahren zur darstellung von polyolefinen mit hoher schmelzfestigkeit
WO2000050466A1 (en) * 1999-02-22 2000-08-31 Borealis Technology Oy Olefin polymerisation process

Also Published As

Publication number Publication date
AU2443199A (en) 1999-08-23
CN1132853C (zh) 2003-12-31
CA2320271A1 (en) 1999-08-12
US6780809B1 (en) 2004-08-24
CN1290272A (zh) 2001-04-04
AU738712B2 (en) 2001-09-27
DE69922340T2 (de) 2005-11-10
AR018078A1 (es) 2001-10-31
BR9907708A (pt) 2000-11-14
CA2320436C (en) 2007-08-14
BR9907702A (pt) 2000-11-14
JP2002502895A (ja) 2002-01-29
EP1053264A1 (en) 2000-11-22
CA2320436A1 (en) 1999-08-12
CA2320271C (en) 2007-07-17
KR20010040769A (ko) 2001-05-15
AU2443099A (en) 1999-08-23
US6541581B1 (en) 2003-04-01
AU740974B2 (en) 2001-11-15
JP2002502897A (ja) 2002-01-29
ES2234237T3 (es) 2005-06-16
NO980552D0 (no) 1998-02-09
CN1290274A (zh) 2001-04-04
DE69922340D1 (de) 2005-01-05
ATE283866T1 (de) 2004-12-15
EP1045866B1 (en) 2004-12-01
WO1999040126A1 (en) 1999-08-12
WO1999040131A1 (en) 1999-08-12
WO1999040126A9 (en) 1999-10-21
EP1045866A1 (en) 2000-10-25

Similar Documents

Publication Publication Date Title
CN1136241C (zh) 利用双中心催化剂得到的聚乙烯
CN1112371C (zh) 具有宽分子量分布的聚乙烯的制备方法及其使用的催化剂体系
US10618987B2 (en) Modified catalyst supports
US9115229B2 (en) Particulate metallocene-alumoxane catalyst
EP1268562B1 (en) Organometal catalyst compositions
US8445607B2 (en) Process for the preparation of a particulate bimodal polyethylene product
CN1135240C (zh) 具有高耐环境开裂性能的乙烯聚合物以及其制备中所用的催化剂
US9475893B2 (en) Modified catalyst supports
CN1152057C (zh) 用于乙烯聚合的催化剂体系
US8546496B2 (en) Process for preparing a bimodal polyethylene product in a single loop reactor

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
C17 Cessation of patent right
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20040128