CN113529414A - 一种复合纱线生产工艺 - Google Patents

一种复合纱线生产工艺 Download PDF

Info

Publication number
CN113529414A
CN113529414A CN202110854677.1A CN202110854677A CN113529414A CN 113529414 A CN113529414 A CN 113529414A CN 202110854677 A CN202110854677 A CN 202110854677A CN 113529414 A CN113529414 A CN 113529414A
Authority
CN
China
Prior art keywords
fiber
parts
antibacterial
composite yarn
production process
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202110854677.1A
Other languages
English (en)
Inventor
吕燕峰
严金楼
武升平
晏贞万
张明英
曹祝杰
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nantong Tongzhou District Xiangyang Weaving Co ltd
Original Assignee
Nantong Tongzhou District Xiangyang Weaving Co ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nantong Tongzhou District Xiangyang Weaving Co ltd filed Critical Nantong Tongzhou District Xiangyang Weaving Co ltd
Priority to CN202110854677.1A priority Critical patent/CN113529414A/zh
Publication of CN113529414A publication Critical patent/CN113529414A/zh
Pending legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/402—Amides imides, sulfamic acids
    • D—TEXTILES; PAPER
    • D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/02—Yarns or threads characterised by the material or by the materials from which they are made
    • D02G3/04—Blended or other yarns or threads containing components made from different materials
    • D—TEXTILES; PAPER
    • D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/22—Yarns or threads characterised by constructional features, e.g. blending, filament/fibre
    • D02G3/32—Elastic yarns or threads ; Production of plied or cored yarns, one of which is elastic
    • D02G3/328—Elastic yarns or threads ; Production of plied or cored yarns, one of which is elastic containing elastane
    • D—TEXTILES; PAPER
    • D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/44—Yarns or threads characterised by the purpose for which they are designed
    • D—TEXTILES; PAPER
    • D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/44—Yarns or threads characterised by the purpose for which they are designed
    • D02G3/449—Yarns or threads with antibacterial properties
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/38—Oxides or hydroxides of elements of Groups 1 or 11 of the Periodic Table
    • D06M11/42—Oxides or hydroxides of copper, silver or gold
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/44—Oxides or hydroxides of elements of Groups 2 or 12 of the Periodic Table; Zincates; Cadmates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/46—Oxides or hydroxides of elements of Groups 4 or 14 of the Periodic Table; Titanates; Zirconates; Stannates; Plumbates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/68—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with phosphorus or compounds thereof, e.g. with chlorophosphonic acid or salts thereof
    • D06M11/70—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with phosphorus or compounds thereof, e.g. with chlorophosphonic acid or salts thereof with oxides of phosphorus; with hypophosphorous, phosphorous or phosphoric acids or their salts
    • D06M11/71—Salts of phosphoric acids
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/73—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof
    • D06M11/76—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof with carbon oxides or carbonates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
    • D06M13/192—Polycarboxylic acids; Anhydrides, halides or salts thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/50—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with organometallic compounds; with organic compounds containing boron, silicon, selenium or tellurium atoms
    • D06M13/51—Compounds with at least one carbon-metal or carbon-boron, carbon-silicon, carbon-selenium, or carbon-tellurium bond
    • D06M13/513—Compounds with at least one carbon-metal or carbon-boron, carbon-silicon, carbon-selenium, or carbon-tellurium bond with at least one carbon-silicon bond
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02—Natural fibres, other than mineral fibres
    • D06M2101/04—Vegetal fibres
    • D06M2101/06—Vegetal fibres cellulosic
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02—Natural fibres, other than mineral fibres
    • D06M2101/10—Animal fibres
    • D06M2101/12—Keratin fibres or silk
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16—Synthetic fibres, other than mineral fibres
    • D06M2101/18—Synthetic fibres consisting of macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/26—Polymers or copolymers of unsaturated carboxylic acids or derivatives thereof
    • D06M2101/28—Acrylonitrile; Methacrylonitrile
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/20—Treatment influencing the crease behaviour, the wrinkle resistance, the crease recovery or the ironing ease
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2201/00—Cellulose-based fibres, e.g. vegetable fibres
    • D10B2201/01—Natural vegetable fibres
    • D10B2201/02—Cotton
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2201/00—Cellulose-based fibres, e.g. vegetable fibres
    • D10B2201/01—Natural vegetable fibres
    • D10B2201/10—Bamboo
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2211/00—Protein-based fibres, e.g. animal fibres
    • D10B2211/01—Natural animal fibres, e.g. keratin fibres
    • D10B2211/02—Wool
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2321/00—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D10B2321/10—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polymers of unsaturated nitriles, e.g. polyacrylonitrile, polyvinylidene cyanide
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/02—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/04—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyesters, e.g. polyethylene terephthalate [PET]
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/10—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyurethanes
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2401/00—Physical properties
    • D10B2401/06—Load-responsive characteristics
    • D10B2401/062—Load-responsive characteristics stiff, shape retention
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2401/00—Physical properties
    • D10B2401/13—Physical properties anti-allergenic or anti-bacterial

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Microbiology (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)

Abstract

本发明涉及一种复合纱线生产工艺，包括以下步骤：(1)称取阿米卡星和硅烷偶联剂加入搅拌机中，再加入去离子水，再继续搅拌10‑15min，再加入所述腈纶纤维反应得到抗菌腈纶纤维；(2)称取联苯四甲酸二酐和N‑乙酰基乙二胺放入容器中常温下反应放入竹纤维进行浸渍，反应得改性竹纤维；(3)得到纺丝液，将所述纺丝液进行静电纺丝，使产生的纤维附着在细支羊毛纱的表面即得抗菌发热复合纤维；(4)将抗菌腈纶纤维、聚酯纤维、氨纶纤维、棉纤维、锦纶纤维、改性竹纤维和抗菌发热复合纤维，依次通过开清棉、梳棉、并条、粗纱、细纱和络筒工序，得到复合纱线。本发明工艺制备的复合纱线具有韧性、抗皱性、耐洗性、抗皱性能和抗菌性能。

Description

一种复合纱线生产工艺
技术领域
本发明涉及纺织技术领域，具体涉及一种复合纱线生产工艺。
背景技术
18世纪中期，纺织机械的发明，使得纺织行业得到了空前的发展，单一功能的面料已经远远满足不了工业时代人民的消费需求。各种功能性的面料应运而生，如防水、防辐射、阻燃抗电弧等面料。面料的功能实现有很多种方式，直接从纺织原料中获得特征是最常用最直接的手段。在用多种功能性纤维制成功能性面料过程中，面料在除了获得这些功能的叠加，另外还获得了这些功能以外的新特征，这为面料提供了其他应用场景。另外各种功能纤维复合，也要考虑规避这些单纤维的缺点、到成本以及工艺的可行性。但目前制备功能复合纱线的技术相对较少，羊毛纤维具有优良的保暖性能、吸湿性能及力学性能，但易虫蛀不易保存；竹纤维具有天然抗菌、抑菌、除螨和防臭功能，而且吸湿性、放湿性、透气性好，穿着舒适，已广泛应用于抗菌织物领域，但是竹纤维湿断裂强度较低、易断裂，往往所得纱线具有韧性低、不耐洗、不抗皱的缺点。腈纶纱线是纺织用纱线原料，其具有优良的保暖性、染色性和仿毛性等特点。
因此，研究一种复合以上纤维，具有韧性、抗皱性和耐洗性，有利于与其他纤维混合纺纱时更好的相容，提高弹性、高柔软性、抗皱性能和抗菌性能、优良的抗菌防虫蛀及自发热性能的的复合纱线生产工艺是非常重要的。
发明内容
针对现有技术的不足，本发明提出一种复合纱线生产工艺，以解决上述背景技术中提出的问题。
本发明的技术方案是这样实现的：
一种复合纱线生产工艺，包括以下步骤：
(1)称取阿米卡星和硅烷偶联剂加入搅拌机中，搅拌速度100-200r/min，搅拌时间5-10min，再加入去离子水，再继续搅拌10-15min，再加入所述腈纶纤维，升温至65-80℃，继续搅拌反应1-2h，再进行超声处理2-3h，过滤取固体物，经去离子水洗涤2-4次，烘干，得到抗菌腈纶纤维；
(2)称取联苯四甲酸二酐和N-乙酰基乙二胺放入容器中常温下反应0.5-1h，再向容器中放入竹纤维进行浸渍，在温度250-280℃下，恒温5-6h，反应结束后降至室温，即得改性竹纤维；
(3)称取脱脂羊毛纤维，将其溶解、离心后，加入无机抗菌剂和纳米二氧化钛，搅拌均匀后得到纺丝液，将所述纺丝液进行静电纺丝，使产生的纤维附着在细支羊毛纱的表面即得抗菌发热复合纤维；
(4)将抗菌腈纶纤维、聚酯纤维、氨纶纤维、棉纤维、锦纶纤维、改性竹纤维和抗菌发热复合纤维，依次通过开清棉、梳棉、并条、粗纱、细纱和络筒工序，得到复合纱线。
优选地，所述硅烷偶联剂为乙烯基三乙氧基硅烷。
优选地，所述步骤(1)按重量份数比为：阿米卡星10-20份、硅烷偶联剂3-7份、腈纶纤维150-250份、去离子水350-550份。
优选地，所述步骤(2)所述联苯四甲酸二酐与所述N-乙酰基乙二胺按摩尔比为：0.9:1～1.5:1。
优选地，所述步骤(3)的无机抗菌剂为氧化锌、氧化铜、磷酸二氢铵或碳酸锂。
优选地，所述步骤(3)的脱脂羊毛纤维、无机抗菌剂与纳米二氧化钛按质量比为25-35:2-4:5-6。
优选地，所述步骤(4)的按重量份数比为：抗菌腈纶纤维10-20份、聚酯纤维8-15份、氨纶纤维5-10份、棉纤维60-70份、锦纶纤维10-20份、改性竹纤维11-18份和抗菌发热复合纤维20-30份。
优选地，所述步骤(3)的脱脂羊毛纤维的离心的转速为7500-8500rad/min，离心的时长为3-5min。
优选地，所述步骤(1)的超声功率为100-200kHz。
优选地，所述步骤(4)的纺纱速度为360-480m/min。
本发明具有以下有益效果：
本发明采用加入阿卡米星对腈纶纤维进行抗菌处理对细菌具有较强的抑制作用，同时吸湿性得到较大的增强，提高了力学强度；本发明制备的腈纶纤维具有较强的吸附性以及结合能力；本发明采用改性后的竹纤维提高了韧性、抗皱性和耐洗性，有利于与其他纤维混合纺纱时更好的相容，提高弹性、高柔软性、抗皱性能和抗菌性能；本发明采用抗菌发热复合纤维具有了优良的抗菌防虫蛀及自发热性能。
具体实施方式
为了对本发明的技术特征、目的和有益效果有更加清楚的理解，现结合具体实施例对本发明的技术方案进行以下详细说明，应理解这些实例仅用于说明本发明而不用于限制本发明的范围。
下述实施例中所述试验方法，如无特殊说明，均为常规方法；所述试剂和材料，如无特殊说明，均可从商业途径获得。
实施例1
一种复合纱线生产工艺，包括以下步骤：
(1)称取阿米卡星和硅烷偶联剂加入搅拌机中，搅拌速度100r/min，搅拌时间10min，再加入去离子水，再继续搅拌10min，再加入所述腈纶纤维，升温至80℃，继续搅拌反应1h，再进行超声处理3h，超声功率为100kHz，过滤取固体物，经去离子水洗涤4次，烘干，得到抗菌腈纶纤维；所述硅烷偶联剂为乙烯基三乙氧基硅烷；按重量份数比为：阿米卡星10份、硅烷偶联剂7份、腈纶纤维150份、去离子水550份；
(2)称取联苯四甲酸二酐和N-乙酰基乙二胺放入容器中常温下反应0.5h，再向容器中放入竹纤维进行浸渍，在温度280℃下，恒温5h，反应结束后降至室温，即得改性竹纤维；所述联苯四甲酸二酐与所述N-乙酰基乙二胺按摩尔比为：1.5:1；
(3)称取脱脂羊毛纤维，将其溶解、离心后，离心的转速为7500rad/min，离心的时长为5min；加入无机抗菌剂和纳米二氧化钛，搅拌均匀后得到纺丝液，将所述纺丝液进行静电纺丝，使产生的纤维附着在细支羊毛纱的表面即得抗菌发热复合纤维；所述无机抗菌剂为氧化锌、氧化铜、磷酸二氢铵或碳酸锂；所述脱脂羊毛纤维、无机抗菌剂与纳米二氧化钛按质量比为25:2:5；
(4)按重量份数比为：抗菌腈纶纤维10份、聚酯纤维15份、氨纶纤维5份、棉纤维70份、锦纶纤维10份、改性竹纤维18份和抗菌发热复合纤维20份；将抗菌腈纶纤维、聚酯纤维、氨纶纤维、棉纤维、锦纶纤维、改性竹纤维和抗菌发热复合纤维，依次通过开清棉、梳棉、并条、粗纱、细纱和络筒工序，纺纱速度为480m/min；得到复合纱线。
实施例2
一种复合纱线生产工艺，包括以下步骤：
(1)称取阿米卡星和硅烷偶联剂加入搅拌机中，搅拌速度150r/min，搅拌时间8min，再加入去离子水，再继续搅拌12min，再加入所述腈纶纤维，升温至70℃，继续搅拌反应1.5h，再进行超声处理2.5h，超声功率为150kHz，过滤取固体物，经去离子水洗涤3次，烘干，得到抗菌腈纶纤维；所述硅烷偶联剂为乙烯基三乙氧基硅烷；按重量份数比为：阿米卡星15份、硅烷偶联剂5份、腈纶纤维200份、去离子水400份；
(2)称取联苯四甲酸二酐和N-乙酰基乙二胺放入容器中常温下反应0.5h，再向容器中放入竹纤维进行浸渍，在温度270℃下，恒温5.5h，反应结束后降至室温，即得改性竹纤维；所述联苯四甲酸二酐与所述N-乙酰基乙二胺按摩尔比为：1.2:1；
(3)称取脱脂羊毛纤维，将其溶解、离心后，离心的转速为8000rad/min，离心的时长为4min；加入无机抗菌剂和纳米二氧化钛，搅拌均匀后得到纺丝液，将所述纺丝液进行静电纺丝，使产生的纤维附着在细支羊毛纱的表面即得抗菌发热复合纤维；所述无机抗菌剂为氧化锌、氧化铜、磷酸二氢铵或碳酸锂；所述脱脂羊毛纤维、无机抗菌剂与纳米二氧化钛按质量比为30:3:5；
(4)按重量份数比为：抗菌腈纶纤维15份、聚酯纤维12份、氨纶纤维8份、棉纤维65份、锦纶纤维15份、改性竹纤维15份和抗菌发热复合纤维25份；将抗菌腈纶纤维、聚酯纤维、氨纶纤维、棉纤维、锦纶纤维、改性竹纤维和抗菌发热复合纤维，依次通过开清棉、梳棉、并条、粗纱、细纱和络筒工序，纺纱速度为420m/min；得到复合纱线。
实施例3
一种复合纱线生产工艺，包括以下步骤：
(1)称取阿米卡星和硅烷偶联剂加入搅拌机中，搅拌速度200r/min，搅拌时间5min，再加入去离子水，再继续搅拌15min，再加入所述腈纶纤维，升温至65℃，继续搅拌反应2h，再进行超声处理2h，超声功率为200kHz，过滤取固体物，经去离子水洗涤4次，烘干，得到抗菌腈纶纤维；所述硅烷偶联剂为乙烯基三乙氧基硅烷；按重量份数比为：阿米卡星20份、硅烷偶联剂3份、腈纶纤维250份、去离子水350份；
(2)称取联苯四甲酸二酐和N-乙酰基乙二胺放入容器中常温下反应1h，再向容器中放入竹纤维进行浸渍，在温度250℃下，恒温6h，反应结束后降至室温，即得改性竹纤维；所述联苯四甲酸二酐与所述N-乙酰基乙二胺按摩尔比为：0.9:1；
(3)称取脱脂羊毛纤维，将其溶解、离心后，离心的转速为8500rad/min，离心的时长为3min；加入无机抗菌剂和纳米二氧化钛，搅拌均匀后得到纺丝液，将所述纺丝液进行静电纺丝，使产生的纤维附着在细支羊毛纱的表面即得抗菌发热复合纤维；所述无机抗菌剂为氧化锌、氧化铜、磷酸二氢铵或碳酸锂；所述脱脂羊毛纤维、无机抗菌剂与纳米二氧化钛按质量比为35:4:6；
(4)按重量份数比为：抗菌腈纶纤维20份、聚酯纤维8份、氨纶纤维10份、棉纤维60份、锦纶纤维20份、改性竹纤维11份和抗菌发热复合纤维30份；将抗菌腈纶纤维、聚酯纤维、氨纶纤维、棉纤维、锦纶纤维、改性竹纤维和抗菌发热复合纤维，依次通过开清棉、梳棉、并条、粗纱、细纱和络筒工序，纺纱速度为360m/min；得到复合纱线。
实施例4
一种复合纱线生产工艺，包括以下步骤：
(1)称取阿米卡星和硅烷偶联剂加入搅拌机中，搅拌速度180r/min，搅拌时间6min，再加入去离子水，再继续搅拌14min，再加入所述腈纶纤维，升温至68℃，继续搅拌反应1.5h，再进行超声处理2.5h，超声功率为180kHz，过滤取固体物，经去离子水洗涤3次，烘干，得到抗菌腈纶纤维；所述硅烷偶联剂为乙烯基三乙氧基硅烷；按重量份数比为：阿米卡星12份、硅烷偶联剂5份、腈纶纤维220份、去离子水500份；
(2)称取联苯四甲酸二酐和N-乙酰基乙二胺放入容器中常温下反应1h，再向容器中放入竹纤维进行浸渍，在温度260℃下，恒温5.5h，反应结束后降至室温，即得改性竹纤维；所述联苯四甲酸二酐与所述N-乙酰基乙二胺按摩尔比为：1.1:1；
(3)称取脱脂羊毛纤维，将其溶解、离心后，离心的转速为8200rad/min，离心的时长为4min；加入无机抗菌剂和纳米二氧化钛，搅拌均匀后得到纺丝液，将所述纺丝液进行静电纺丝，使产生的纤维附着在细支羊毛纱的表面即得抗菌发热复合纤维；所述无机抗菌剂为氧化锌、氧化铜、磷酸二氢铵或碳酸锂；所述脱脂羊毛纤维、无机抗菌剂与纳米二氧化钛按质量比为28:3:5；
(4)按重量份数比为：抗菌腈纶纤维11份、聚酯纤维13份、氨纶纤维7份、棉纤维62份、锦纶纤维12份、改性竹纤维13份和抗菌发热复合纤维23份；将抗菌腈纶纤维、聚酯纤维、氨纶纤维、棉纤维、锦纶纤维、改性竹纤维和抗菌发热复合纤维，依次通过开清棉、梳棉、并条、粗纱、细纱和络筒工序，纺纱速度为410m/min；得到复合纱线。
对比例1
采用本发明实施例2的生产工艺制备复合纱线，唯一不同的是没有步骤(1)的制备过程，其余部分适应性去掉抗菌腈纶纤维。
对比例2
采用本发明实施例2的生产工艺制备的复合纱线，唯一不同的是没有步骤(2)的制备过程，其余部分适应性去掉改性竹纤维。
对比例3
采用本发明实施例2的生产工艺制备的复合纱线，唯一不同的是没有步骤(3)的制备过程，其余部分适应性去掉抗菌发热复合纤维。
将实施例1-4和对比例1-3制备得到的复合纱线的性能进行测试，测试结果见下表1所示。
表1实施例1-3和对比例1-2制备的复合纱线的性能。
Figure BDA0003183706020000061
Figure BDA0003183706020000071
由表1可知，本发明实施例1-4的复合纱线的相比对比例1-2的复合纱线具有较好的抑菌性、抗皱性能和韧性。
以上实施例对本发明的产品及方法进行了详细介绍，本文中应用了具体例对本发明的主要步骤及实施方式进行了阐述，上述实施例只是帮助理解本发明的方法及核心原理。对于本领域的技术人员，依据本发明的核心原理，在具体实施中会对各条件和参数根据需要而变动，综上所述，本说明书不应理解为对本发明的限制。

Claims (10)

1.一种复合纱线生产工艺，其特征在于：包括以下步骤：
(1)称取阿米卡星和硅烷偶联剂加入搅拌机中，搅拌速度100-200r/min，搅拌时间5-10min，再加入去离子水，再继续搅拌10-15min，再加入所述腈纶纤维，升温至65-80℃，继续搅拌反应1-2h，再进行超声处理2-3h，过滤取固体物，经去离子水洗涤2-4次，烘干，得到抗菌腈纶纤维；
(2)称取联苯四甲酸二酐和N-乙酰基乙二胺放入容器中常温下反应0.5-1h，再向容器中放入竹纤维进行浸渍，在温度250-280℃下，恒温5-6h，反应结束后降至室温，即得改性竹纤维；
(3)称取脱脂羊毛纤维，将其溶解、离心后，加入无机抗菌剂和纳米二氧化钛，搅拌均匀后得到纺丝液，将所述纺丝液进行静电纺丝，使产生的纤维附着在细支羊毛纱的表面即得抗菌发热复合纤维；
(4)将抗菌腈纶纤维、聚酯纤维、氨纶纤维、棉纤维、锦纶纤维、改性竹纤维和抗菌发热复合纤维，依次通过开清棉、梳棉、并条、粗纱、细纱和络筒工序，得到复合纱线。
2.根据权利要求1所述的一种复合纱线生产工艺，其特征在于：所述硅烷偶联剂为乙烯基三乙氧基硅烷。
3.根据权利要求1所述的一种复合纱线生产工艺，其特征在于：所述步骤(1)按重量份数比为：阿米卡星10-20份、硅烷偶联剂3-7份、腈纶纤维150-250份、去离子水350-550份。
4.根据权利要求1所述的一种复合纱线生产工艺，其特征在于：所述步骤(2)所述联苯四甲酸二酐与所述N-乙酰基乙二胺按摩尔比为：0.9:1～1.5:1。
5.根据权利要求1所述的一种复合纱线生产工艺，其特征在于：所述步骤(3)的无机抗菌剂为氧化锌、氧化铜、磷酸二氢铵或碳酸锂。
6.根据权利要求1所述的一种复合纱线生产工艺，其特征在于：所述步骤(3)的脱脂羊毛纤维、无机抗菌剂与纳米二氧化钛按质量比为25-35:2-4:5-6。
7.根据权利要求1所述的一种复合纱线生产工艺，其特征在于：所述步骤(4)的按重量份数比为：抗菌腈纶纤维10-20份、聚酯纤维8-15份、氨纶纤维5-10份、棉纤维60-70份、锦纶纤维10-20份、改性竹纤维11-18份和抗菌发热复合纤维20-30份。
8.根据权利要求1所述的一种复合纱线生产工艺，其特征在于：所述步骤(3)的脱脂羊毛纤维的离心的转速为7500-8500rad/min，离心的时长为3-5min。
9.根据权利要求1所述的一种复合纱线生产工艺，其特征在于：所述步骤(1)的超声功率为100-200kHz。
10.根据权利要求1所述的一种复合纱线生产工艺，其特征在于：所述步骤(4)的纺纱速度为360-480m/min。
CN202110854677.1A 2021-07-28 2021-07-28 一种复合纱线生产工艺 Pending CN113529414A (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202110854677.1A CN113529414A (zh) 2021-07-28 2021-07-28 一种复合纱线生产工艺

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202110854677.1A CN113529414A (zh) 2021-07-28 2021-07-28 一种复合纱线生产工艺

Publications (1)

Publication Number Publication Date
CN113529414A true CN113529414A (zh) 2021-10-22

Family

ID=78121134

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202110854677.1A Pending CN113529414A (zh) 2021-07-28 2021-07-28 一种复合纱线生产工艺

Country Status (1)

Country Link
CN (1) CN113529414A (zh)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113862854A (zh) * 2021-11-04 2021-12-31 江苏金銮纺织科技股份有限公司 一种抗菌纳米纤维纱线的生产工艺
CN118029038A (zh) * 2024-02-02 2024-05-14 广东启悦未来科技股份有限公司 一种柔软亲肤蕾丝面料及其制备方法

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106061731A (zh) * 2015-02-13 2016-10-26 零点零有限责任公司 纺织方法和产品
WO2017107879A1 (zh) * 2015-12-21 2017-06-29 常熟市卫丰针纺织有限公司 一种竹纤维和锦纶混纺面料
CN111826764A (zh) * 2020-07-28 2020-10-27 吴忠德悦纺织科技有限公司 一种改性多组份复合纱线的制备方法
CN112391843A (zh) * 2020-10-16 2021-02-23 北京航天凯恩化工科技有限公司 一种改性竹纤维、抗菌抗皱复合纱线及其制备方法
CN113106589A (zh) * 2021-04-15 2021-07-13 苏州大学 一种抗菌防虫蛀的发热复合纱线及其制备方法

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106061731A (zh) * 2015-02-13 2016-10-26 零点零有限责任公司 纺织方法和产品
WO2017107879A1 (zh) * 2015-12-21 2017-06-29 常熟市卫丰针纺织有限公司 一种竹纤维和锦纶混纺面料
CN111826764A (zh) * 2020-07-28 2020-10-27 吴忠德悦纺织科技有限公司 一种改性多组份复合纱线的制备方法
CN112391843A (zh) * 2020-10-16 2021-02-23 北京航天凯恩化工科技有限公司 一种改性竹纤维、抗菌抗皱复合纱线及其制备方法
CN113106589A (zh) * 2021-04-15 2021-07-13 苏州大学 一种抗菌防虫蛀的发热复合纱线及其制备方法

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113862854A (zh) * 2021-11-04 2021-12-31 江苏金銮纺织科技股份有限公司 一种抗菌纳米纤维纱线的生产工艺
CN118029038A (zh) * 2024-02-02 2024-05-14 广东启悦未来科技股份有限公司 一种柔软亲肤蕾丝面料及其制备方法

Similar Documents

Publication Publication Date Title
CN113529414A (zh) 一种复合纱线生产工艺
CN103255538B (zh) 一种防紫外抗菌面料及其制备工艺
CN103526374B (zh) 远红外莫代尔纤维家纺面料
CN103526414B (zh) 远红外牛奶蛋白纤维家纺面料
CN101144193B (zh) 一种直接制备多微孔涤纶短纤维的方法
CN113862852B (zh) 一种涤/棉/海岛纤维混纺包芯纱及其生产方法
CN110029445A (zh) 一种抗菌抑菌水刺无纺布
CN111910285A (zh) 一种石墨烯生物复合纤维及其制备方法和应用
CN114045673B (zh) 一种抗菌涤纶混纤弹性丝及其制备方法
CN101962912A (zh) 高吸湿吸水腈纶的制备方法
CN116254699B (zh) 一种基于双官能化氮化硼抗菌纺织品及其制备方法
CN115839027B (zh) 一种含有细旦涤纶长丝的吸湿透气化纤面料及其生产工艺
CN104153030B (zh) 一种有色玉米纤维织物的制造方法
CN104746195A (zh) 一种翡翠珍珠纤维、吸湿排汗纤维以及天丝混纺纱及其制备方法和应用
CN111058283A (zh) 一种抗菌腈纶纤维的制备方法及其应用
CN108754726A (zh) 一种吸湿性纱线的制备方法
CN108842270A (zh) 能对温度微调节的三维立体结构面料
CN106757602A (zh) 含量子能纤维的面料及其制备方法
CN111636191A (zh) 天丝纤维和银离子复合纤维面料及其制造方法
CN112064351A (zh) 一种保暖抗菌复合面料及其加工工艺
CN110484976A (zh) 一种纯苎麻纤维高支纺织面料的制备方法
CN107956014A (zh) 一种纺织丝线及其制备方法
CN110735320A (zh) 一种抗菌防螨防霉面料
CN115246259B (zh) 一种吸湿透气型保温羽绒复合面料及其制备方法
CN112323196A (zh) 一种竹纤维与真丝的面料

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
WD01 Invention patent application deemed withdrawn after publication
WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20211022