CN113233934A - Attapulgite biological organosilicon fertilizer special for saline-alkali soil and preparation method thereof - Google Patents

Attapulgite biological organosilicon fertilizer special for saline-alkali soil and preparation method thereof Download PDF

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Publication number
CN113233934A
CN113233934A CN202110429606.7A CN202110429606A CN113233934A CN 113233934 A CN113233934 A CN 113233934A CN 202110429606 A CN202110429606 A CN 202110429606A CN 113233934 A CN113233934 A CN 113233934A
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China
Prior art keywords
attapulgite
saline
soil
percent
alkali soil
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CN202110429606.7A
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Chinese (zh)
Inventor
冯志珍
赵文娟
胡文友
张建虎
白亚妮
徐升运
秦涛
冯璞阳
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Gansu Huilin Industrial Development Co ltd
Bio-Agriculture Institute Of Shaanxi
Institute of Soil Science of CAS
Original Assignee
Gansu Huilin Industrial Development Co ltd
Bio-Agriculture Institute Of Shaanxi
Institute of Soil Science of CAS
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Priority to CN202110429606.7A priority Critical patent/CN113233934A/en
Publication of CN113233934A publication Critical patent/CN113233934A/en
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    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05DINORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
    • C05D5/00Fertilisers containing magnesium
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • C05G3/80Soil conditioners
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G5/00Fertilisers characterised by their form
    • C05G5/10Solid or semi-solid fertilisers, e.g. powders
    • C05G5/12Granules or flakes

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Organic Chemistry (AREA)
  • Pest Control & Pesticides (AREA)
  • Soil Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Fertilizers (AREA)

Abstract

The invention relates to the technical field of agricultural fertilizers, and discloses an attapulgite biological organic silicon fertilizer special for saline-alkali soil, which comprises the following components in percentage by weight: 25 to 45 percent of attapulgite, 30 to 50 percent of fulvic acid and 5 to 25 percent of bacillus mucilaginosus; also discloses a preparation method. The invention can be used as a fertilizer to provide nutrients, can also be used as a soil conditioner to improve saline-alkali soil, can realize the cyclic utilization of agricultural wastes, and can reduce the use of chemical fertilizers and pesticides; the invention provides a growth and reproduction place for the bacterial strain, increases the number of effective viable bacteria and prolongs the survival time of the bacterial strain; the bacillus mucilaginosus is utilized, the strain belongs to silicate bacteria, and can decompose insoluble substances such as phosphorus, potassium, silicon and the like in attapulgite, so that necessary nutrient elements are provided for plant growth, and the added fulvic acid is a high-molecular organic compound with a small molecular weight, is acidic, can effectively promote plant growth and adjust the pH value of soil.

Description

Attapulgite biological organosilicon fertilizer special for saline-alkali soil and preparation method thereof
Technical Field
The invention relates to the technical field of agricultural fertilizers, and particularly relates to an attapulgite bio-organic silicon fertilizer special for saline-alkali soil and a preparation method thereof.
Background
The soil salinization problem is widely existed in the world, and the problem is particularly serious in arid and semiarid regions. According to the incomplete statistics of the textbook organization and the grain and agriculture organization of the United nations, the area of the saline-alkali soil in the whole world reaches 9.5 multiplied by 108hm2And at 1.0-1.5X 10 per year6hm2Is increasing. The area of saline-alkali land in China is about 9.9 multiplied by 107hm2The land is mainly distributed in plains of 23 provinces, cities and autonomous regions of 5 large areas, and comprises coastal saline-alkali soil areas, Huang-Huai-Hai plain saline-alkali soil areas, northwest semi-arid saline-alkali soil areas, arid saline-alkali soil areas and northeast saline-alkali soil areas. The salinization of soil causes various ecological environment problems, such as water and soil loss, land desertification, forest and grassland resource reduction, biological diversity reduction, and the like, so that the need for seeking active and effective measures to prevent and improve the salinization soil is urgent.
Attapulgite (Attapulgite) is a natural one-dimensional nanoscale water-containing magnesium-aluminum-rich silicate clay mineral, and has a nanorod crystal structure, nanopores, a surface active group, a unique nanorod crystal morphology and a pore structure, so that the attapulgite clay mineral has excellent adsorption performance, colloid performance, carrier performance and reinforcing performance. The silicon element is one of the essential nutrient elements for the growth of crops, can improve the photosynthesis efficiency of the crops, enhance the root system activity, enhance the lodging resistance, the disease and insect resistance, improve the yield and improve the quality, and the insufficient silicon content in the soil is confirmed to be a key factor for limiting the yield of the crops. At present, silicate bacteria are widely applied to microbial fertilizers, and the bacteria can decompose insoluble substances such as phosphorus, potassium, silicon and the like in soil or minerals and have certain nitrogen fixation capacity. In conclusion, the inventor invents the attapulgite biological organosilicon fertilizer special for saline-alkali soil and the preparation method thereof.
Disclosure of Invention
Based on the problems, the invention provides the attapulgite bio-organic silicon fertilizer special for the saline-alkali soil and the preparation method thereof, the attapulgite bio-organic silicon fertilizer can be used as a fertilizer to provide nutrients, can also be used as a soil conditioner to improve the saline-alkali soil, can realize the cyclic utilization of agricultural wastes, and can reduce the use of chemical fertilizers and pesticides.
In order to solve the technical problems, the invention provides the following technical scheme:
an attapulgite biological organic silicon fertilizer special for saline-alkali soil comprises the following components in percentage by weight: 25 to 45 percent of attapulgite, 30 to 50 percent of fulvic acid and 5 to 25 percent of bacillus mucilaginosus.
Further, the fulvic acid is produced by co-fermenting a compound microbial inoculum and agricultural wastes, the fermentation process is a solid-semisolid fermentation process, and the agricultural wastes comprise the following components in percentage by weight: 20-35% of defective fruits or waste peel residues or vegetable wastes, 30-45% of straws and 40-55% of sheep manure; the bacterial strains in the composite microbial inoculum are bacillus subtilis, bacillus megaterium and bacillus amyloliquefaciens, and the strain content of the composite microbial inoculum is 108cfu/ml-109cfu/ml。
In order to solve the technical problems, the invention also provides a preparation method of the attapulgite bio-organic silicon fertilizer, which comprises the following steps:
s1: crushing attapulgite clay ore, and grinding with a grinding machine to obtain fine powder of 80-120 meshes;
s2: mixing the attapulgite, the fulvic acid and the bacillus mucilaginosus which are processed in the step S1 according to the weight ratio, adding the mixture into a stirrer, uniformly mixing, conveying the mixture into a granulator by using a conveyor belt, and spraying a proper amount of water into the granulator, wherein the water content is controlled to be 15-25%;
s3: and (4) drying the granules processed in the step (S2) in a dryer at the drying temperature of 70-100 ℃ until the water content is 8-15%, transporting the dried granules to a cooler, cooling to normal temperature, then obtaining finished granules by using an electric screening sieve, wherein the grain size of the finished granules is 1-3.5 mm, and feeding the finished granules into a packaging machine for metering and packaging.
Compared with the prior art, the invention has the beneficial effects that: the invention can be used as a fertilizer to provide nutrients, can also be used as a soil conditioner to improve soil, can realize the recycling of agricultural wastes, can reduce the use of chemical fertilizers and pesticides, has rich raw materials, low cost, convenient use, simple manufacturing process and low energy consumption, has no harm to human bodies in the production process, no pollution to the environment, has no harmful residues when being applied to farmlands, can effectively improve soil and recover soil fertility; the granular structure of the saline-alkali soil is adjusted by utilizing the unique rod crystal morphology and the pore structure of the attapulgite, the attapulgite is used as a microorganism carrier, a growth and propagation place is provided for strains, the number of effective viable bacteria is increased, and the survival time of the strains is prolonged; the bacillus mucilaginosus is utilized, the strain belongs to silicate bacteria, and can decompose insoluble substances such as phosphorus, potassium, silicon and the like in attapulgite, so that necessary nutrient elements are provided for plant growth, and the added fulvic acid is a high-molecular organic compound with a small molecular weight, is acidic, can effectively promote plant growth and adjust the pH value of soil.
Detailed Description
In order to make the objects, technical solutions and advantages of the present invention more apparent, the present invention is further described in detail below with reference to examples, and the exemplary embodiments and descriptions thereof are only used for explaining the present invention and are not used as limitations of the present invention.
Example (b):
the present embodiment provides aThe attapulgite biological organic silicon fertilizer special for the saline-alkali soil comprises the following components in percentage by weight: 25 to 45 percent of attapulgite, 30 to 50 percent of fulvic acid and 5 to 25 percent of bacillus mucilaginosus. The fulvic acid is sold in the market, is produced by co-fermenting a compound microbial inoculum and agricultural wastes, has high organic matter content, is prepared by a solid-semisolid fermentation process, and consists of the following components in percentage by weight: 20-35% of defective fruits or waste peel residues or vegetable wastes, 30-45% of straws and 40-55% of sheep manure; the bacterial strains in the composite microbial inoculum are bacillus subtilis, bacillus megaterium and bacillus amyloliquefaciens, and the strain content of the composite microbial inoculum is 108cfu/ml-109cfu/ml. The bacillus subtilis, bacillus megaterium and bacillus amyloliquefaciens are inoculated into an LB culture medium or a beef extract peptone liquid culture medium according to a conventional culture method, the inoculation amount is 1-3% by volume, the fermentation temperature is 28-32 ℃, and the concentration reaches 10 after fermentation for 48 hours8cfu/ml-109cfu/ml of bacillus liquid.
The preparation method of the attapulgite biological organosilicon fertilizer comprises the following steps:
s1: crushing attapulgite clay ore, and grinding with a grinding machine to obtain fine powder of 80-120 meshes;
s2: mixing the attapulgite, the fulvic acid and the bacillus mucilaginosus which are processed in the step S1 according to the weight ratio, adding the mixture into a stirrer, uniformly mixing, conveying the mixture into a granulator by using a conveyor belt, and spraying a proper amount of water into the granulator, wherein the water content is controlled to be 15-25%;
s3: and (4) drying the granules processed in the step (S2) in a dryer at the drying temperature of 70-100 ℃ until the water content is 8-15%, transporting the dried granules to a cooler, cooling to normal temperature, then obtaining finished granules by using an electric screening sieve, wherein the grain size of the finished granules is 1-3.5 mm, and feeding the finished granules into a packaging machine for metering and packaging.
The embodiment aims to solve the problem of difficult crop growth in saline-alkali soil and overcome the defect that silicon element in attapulgite is difficult to be absorbed and utilized by plants. The attapulgite biological organosilicon fertilizer is specially used for saline-alkali soil, and the main components of the attapulgite biological organosilicon fertilizer are attapulgite, fulvic acid, silicate bacteria and organic substances.
The attapulgite is a pure natural nanoscale porous nonmetallic mineral, and the porous crystal structure of the attapulgite not only can improve the physical structure of saline-alkali soil, but also can be used as an excellent carrier for microbial adsorption and propagation, and can provide necessary trace elements for the saline-alkali soil. The attapulgite can improve the physical properties of saline-alkali soil, such as conditioning aggregate structure, increasing soil permeability and adjusting soil pH value, is used as a main raw material of the invention, and is added with fulvic acid and silicate bacteria, namely bacillus mucilaginosus, and activated to prepare the organic silicon fertilizer.
The fulvic acid is a high molecular organic compound with small molecular weight of humic acid, contains various active functional groups, has strong biological activity, is easy to be absorbed by plants, is acidic, can improve the activity of attapulgite, increases the water absorption expansion rate of the attapulgite, stimulates the growth and development of the plants, improves the immunity of the plants, resists cold and diseases, can improve the fertility condition of soil nutrients by fruit and vegetable wastes, straws and livestock and poultry manure, provides carbon and nitrogen sources required by microbial growth, and is an ideal material for improving salinized soil by matching the attapulgite. The fulvic acid is produced by taking agricultural and sideline product processing waste, agricultural straws, livestock and poultry manure and the like as raw materials and carrying out compound fermentation by using a compound microbial inoculum, and the fulvic acid mainly comprises fulvic acid, amino acid, organic matters and nucleic acid, and is matched with other biological essential elements and nutritional ingredients, so that the immunity and the stress resistance of plants can be obviously improved, and the soil salinization degree can be improved.
The silicate bacteria can decompose silicon in the attapulgite and provide sufficient silicon element for crops. The bacillus mucilaginosus belongs to silicate bacteria, has strong strain activity, high temperature resistance, acid and alkali resistance, fast propagation and strong applicability, can decompose insoluble silicon and other medium and trace elements in attapulgite, and provides necessary nutrient elements for plants.
The attapulgite biological organosilicon fertilizer of the embodiment is applied to Gansu Zhangye saline-alkali soil, and the result shows that: when the application amount of the attapulgite biological organosilicon fertilizer is 4 thm-2、8t hm-2And 12 thm-2The yield of the corn planted in the saline-alkali soil is 11453kg hm-2、15476kg hm-2And 16161kg hm-2Highest ratio control (11291kg hm)-2) The yield is increased by 30.1 percent. The physical structure and fertility indexes of soil in a test area show that the average weight diameter of soil aggregates in the test area treated by the attapulgite bio-organic silicon fertilizer is up to 4.70mm, which is increased by 17.9% compared with a control (3.86 mm); the cation exchange capacity of the soil reaches 35.63cmol +/kg at most, and is increased by 8.9 percent compared with a control (32.45cmol +/kg); the pH value of the soil is reduced to 8.54 which is 7.1 percent lower than that of a control (9.19); the organic matter content of the soil reaches 10.98g kg at most, which is increased by 41.0 percent compared with the control (6.48g kg).
The attapulgite biological organic silicon fertilizer can adjust the pH value of soil, improve the content of organic matters in the soil and improve the micro-ecological environment of the soil by increasing the stability of soil aggregates and the cation exchange capacity, thereby improving the saline-alkali soil, improving the soil quality and increasing the corn yield.
The attapulgite bio-organic silicon fertilizer is implemented according to the agricultural industry standard NY 884-.
The attapulgite bio-organic silicon fertilizer has the advantages of rich raw material resources, low cost, simple manufacturing process, low energy consumption and no need of special conditions; the production process is harmless to human bodies, has no pollution to the environment, has low cost of farmland application, good effect and no harmful residues, and can effectively improve soil and recover soil fertility; the fertilizer is convenient to use, has no special requirements as the use method of the traditional fertilizer, can improve the nutrient utilization rate, reduce the application amount of the fertilizer, effectively stimulate the growth of plants, improve the yield and the quality of crops, has good comprehensive effect, is a win-win measure which gives consideration to the resource utilization of wastes and the research and development of novel environment-friendly fertilizers, and has far-reaching significance for further perfecting the existing ecological cycle agricultural mode in agricultural application.
The above is an embodiment of the present invention. The embodiments and specific parameters in the embodiments are only for the purpose of clearly illustrating the process of verifying the invention and are not intended to limit the scope of the invention, which is defined by the claims, and all the equivalent structural changes made by applying the content of the specification of the invention should be covered by the scope of the invention.

Claims (3)

1. The attapulgite biological organic silicon fertilizer special for saline-alkali soil is characterized by comprising the following components in percentage by weight: 25 to 45 percent of attapulgite, 30 to 50 percent of fulvic acid and 5 to 25 percent of bacillus mucilaginosus.
2. The attapulgite bio-organic silicon fertilizer special for saline-alkali soil according to claim 1, wherein the fulvic acid is produced by co-fermentation of a complex microbial inoculum and agricultural wastes, the fermentation process is a solid-semisolid fermentation process, and the agricultural wastes comprise the following components in percentage by weight: 20-35% of defective fruits or waste peel residues or vegetable wastes, 30-45% of straws and 40-55% of sheep manure; the bacterial strains in the composite microbial inoculum are bacillus subtilis, bacillus megaterium and bacillus amyloliquefaciens, and the strain content of the composite microbial inoculum is 108cfu/ml-109cfu/ml。
3. A method for preparing attapulgite bio-organosilicon fertilizer according to claim 1 or 2, characterized by comprising the following steps:
s1: crushing attapulgite clay ore, and grinding with a grinding machine to obtain fine powder of 80-120 meshes;
s2: mixing the attapulgite, the fulvic acid and the bacillus mucilaginosus which are processed in the step S1 according to the weight ratio, adding the mixture into a stirrer, uniformly mixing, conveying the mixture into a granulator by using a conveyor belt, and spraying a proper amount of water into the granulator, wherein the water content is controlled to be 15-25%;
s3: and (4) drying the granules processed in the step (S2) in a dryer at the drying temperature of 70-100 ℃ until the water content is 8-15%, transporting the dried granules to a cooler, cooling to normal temperature, then obtaining finished granules by using an electric screening sieve, wherein the grain size of the finished granules is 1-3.5 mm, and feeding the finished granules into a packaging machine for metering and packaging.
CN202110429606.7A 2021-04-21 2021-04-21 Attapulgite biological organosilicon fertilizer special for saline-alkali soil and preparation method thereof Pending CN113233934A (en)

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102174583A (en) * 2011-02-22 2011-09-07 福州大学 Method for producing biological humic acid by mixed fermentation
CN102206102A (en) * 2011-03-11 2011-10-05 四川省兰月农化科技开发有限责任公司 Production method for fulvic acid with rice straws
CN106278711A (en) * 2016-07-31 2017-01-04 王兆荣 A kind of attapulgite bacterial manure

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102174583A (en) * 2011-02-22 2011-09-07 福州大学 Method for producing biological humic acid by mixed fermentation
CN102206102A (en) * 2011-03-11 2011-10-05 四川省兰月农化科技开发有限责任公司 Production method for fulvic acid with rice straws
CN106278711A (en) * 2016-07-31 2017-01-04 王兆荣 A kind of attapulgite bacterial manure

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