CN113201084A - 使用卤化双苯基苯氧基催化剂控制聚烯烃的分子量 - Google Patents
使用卤化双苯基苯氧基催化剂控制聚烯烃的分子量 Download PDFInfo
- Publication number
- CN113201084A CN113201084A CN202110385158.5A CN202110385158A CN113201084A CN 113201084 A CN113201084 A CN 113201084A CN 202110385158 A CN202110385158 A CN 202110385158A CN 113201084 A CN113201084 A CN 113201084A
- Authority
- CN
- China
- Prior art keywords
- independently
- alpha
- tert
- carbazol
- bis
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Crystallography & Structural Chemistry (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201361840624P | 2013-06-28 | 2013-06-28 | |
| US61/840,624 | 2013-06-28 | ||
| CN201480033642.XA CN105283474A (zh) | 2013-06-28 | 2014-06-26 | 使用卤化双苯基苯氧基催化剂控制聚烯烃的分子量 |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201480033642.XA Division CN105283474A (zh) | 2013-06-28 | 2014-06-26 | 使用卤化双苯基苯氧基催化剂控制聚烯烃的分子量 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN113201084A true CN113201084A (zh) | 2021-08-03 |
Family
ID=51211353
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202110385158.5A Pending CN113201084A (zh) | 2013-06-28 | 2014-06-26 | 使用卤化双苯基苯氧基催化剂控制聚烯烃的分子量 |
| CN201480033642.XA Pending CN105283474A (zh) | 2013-06-28 | 2014-06-26 | 使用卤化双苯基苯氧基催化剂控制聚烯烃的分子量 |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201480033642.XA Pending CN105283474A (zh) | 2013-06-28 | 2014-06-26 | 使用卤化双苯基苯氧基催化剂控制聚烯烃的分子量 |
Country Status (9)
| Country | Link |
|---|---|
| US (2) | US9605098B2 (enExample) |
| EP (2) | EP3013871B1 (enExample) |
| JP (2) | JP6441332B2 (enExample) |
| KR (1) | KR102218415B1 (enExample) |
| CN (2) | CN113201084A (enExample) |
| BR (1) | BR112015030912B1 (enExample) |
| ES (2) | ES3062088T3 (enExample) |
| SG (2) | SG11201510689SA (enExample) |
| WO (1) | WO2014210333A1 (enExample) |
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| KR20150100694A (ko) | 2012-12-27 | 2015-09-02 | 다우 글로벌 테크놀로지스 엘엘씨 | 올레핀 중합을 위한 촉매계 |
| KR20150103082A (ko) * | 2012-12-27 | 2015-09-09 | 다우 글로벌 테크놀로지스 엘엘씨 | 에틸렌계 중합체를 제조하기 위한 중합 방법 |
| WO2014105414A1 (en) | 2012-12-27 | 2014-07-03 | Dow Global Technologies Llc | A polymerization process for producing ethylene based polymers |
| CN113201084A (zh) * | 2013-06-28 | 2021-08-03 | 陶氏环球技术有限责任公司 | 使用卤化双苯基苯氧基催化剂控制聚烯烃的分子量 |
| JP6797694B6 (ja) | 2014-06-30 | 2021-01-20 | ダウ グローバル テクノロジーズ エルエルシー | オレフィン重合のためのプロセス |
| BR112017000855B1 (pt) * | 2014-07-24 | 2022-02-08 | Dow Global Technologies Llc | Processo para formar um polímero à base de etileno |
| CN107787336B (zh) | 2015-06-30 | 2021-05-28 | 陶氏环球技术有限责任公司 | 用于制备基于乙烯的聚合物的聚合方法 |
| KR102588244B1 (ko) | 2015-06-30 | 2023-10-12 | 다우 글로벌 테크놀로지스 엘엘씨 | 에틸렌계 폴리머를 제조하는 중합 방법 |
| CN108377649B (zh) | 2015-09-30 | 2021-04-23 | 陶氏环球技术有限责任公司 | 用于产生乙烯类聚合物的聚合方法 |
| ES2804554T3 (es) | 2015-09-30 | 2021-02-08 | Dow Global Technologies Llc | Procatalizador y proceso de polimerización usando el mismo |
| SG11201900653RA (en) | 2016-07-29 | 2019-02-27 | Dow Global Technologies Llc | Silyl-bridged bis-biphenyl-phenoxy catalysts for olefin polymerization |
| SG11201908307XA (en) * | 2017-03-15 | 2019-10-30 | Dow Global Technologies Llc | Catalyst system for multi-block copolymer formation |
| KR102533900B1 (ko) | 2017-03-31 | 2023-05-18 | 다우 글로벌 테크놀로지스 엘엘씨 | 올레핀 중합을 위한 게르마늄-브릿지된 비스-바이페닐-페녹시 촉매 |
| US11401354B2 (en) | 2017-03-31 | 2022-08-02 | Dow Global Technologies Llc | Bis-biphenyl-phenoxy catalysts for olefin polymerization |
| KR102590976B1 (ko) | 2017-09-29 | 2023-10-19 | 다우 글로벌 테크놀로지스 엘엘씨 | 개선된 용해도를 위한 금속 상에 메틸렌트리알킬규소 리간드를 갖는 비스-페닐-페녹시 폴리올레핀 촉매 |
| JP7208981B2 (ja) | 2017-09-29 | 2023-01-19 | ダウ グローバル テクノロジーズ エルエルシー | 溶解度を改善するために金属上にアルコキシ－またはアミド－配位子を有するビス－フェニル－フェノキシポリオレフィン触媒 |
| US11066489B2 (en) | 2017-09-29 | 2021-07-20 | Dow Global Technologies Llc | Bis-phenyl-phenoxy polyolefin catalysts having two methylenetrialkylsilicon ligands on the metal for improved solubility |
| KR102100142B1 (ko) * | 2017-12-21 | 2020-04-14 | 사빅 에스케이 넥슬렌 컴퍼니 피티이 엘티디 | 금속-리간드 착체, 이를 포함하는 에틸렌계 중합용 촉매 조성물 및 이를 이용한 에틸렌계 중합체의 제조방법 |
| SG11202008656PA (en) * | 2018-03-30 | 2020-10-29 | Dow Global Technologies Llc | Olefin polymerization activators |
| EP3774942A1 (en) * | 2018-03-30 | 2021-02-17 | Dow Global Technologies LLC | Olefin polymerization activators |
| JP7460602B2 (ja) | 2018-08-30 | 2024-04-02 | ダウ グローバル テクノロジーズ エルエルシー | ２つのアントラセニル配位子を有するビス－フェニル－フェノキシポリオレフィンプロ触媒 |
| EP3924395A4 (en) * | 2019-02-12 | 2022-06-22 | ExxonMobil Chemical Patents Inc. | BIS(ARYL-PHENOLATE) LEWIS-BASED CATALYSTS AND METHODS THEREOF |
| CN114616255B (zh) * | 2019-11-04 | 2024-09-13 | 陶氏环球技术有限责任公司 | 联苯酚聚合催化剂 |
| WO2021091959A1 (en) | 2019-11-04 | 2021-05-14 | Dow Global Technologies Llc | Titanium biphenylphenol polymerization catalysts |
| EP4055070B9 (en) | 2019-11-04 | 2024-07-31 | Dow Global Technologies LLC | Bimodal catalyst systems |
| WO2021127150A1 (en) | 2019-12-19 | 2021-06-24 | Dow Global Technologies Llc | Gas-phase biphenylphenol polymerization catalysts |
| KR102975594B1 (ko) | 2020-01-31 | 2026-06-16 | 다우 글로벌 테크놀로지스 엘엘씨 | Iii족 및 란타나이드 비스-페닐-페녹시 금속-리간드 착물 |
| EP4097152B1 (en) | 2020-01-31 | 2025-09-03 | Dow Global Technologies LLC | Polymerization processes that include group iii and lanthanide bis-phenyl-phenoxy metal-ligand complexes and chain transfer agents |
| WO2021191724A1 (en) | 2020-03-24 | 2021-09-30 | Nova Chemicals (International) S.A. | Polymerization catalyst having a tetradentate ligand |
| EP4185593A4 (en) * | 2020-12-28 | 2024-08-21 | SABIC SK Nexlene Company Pte. Ltd. | METAL LIGAND COMPLEX, CATALYST COMPOSITION FOR PRODUCING ETHYLENE-BASED POLYMER THEREOF, AND METHOD FOR PRODUCING ETHYLENE-BASED POLYMER THEREOF |
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| WO2022173915A1 (en) * | 2021-02-15 | 2022-08-18 | Dow Global Technologies Llc | Method for making a poly(ethylene-co-1-alkene) copolymer with reverse comonomer distribution |
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| KR20150103082A (ko) | 2012-12-27 | 2015-09-09 | 다우 글로벌 테크놀로지스 엘엘씨 | 에틸렌계 중합체를 제조하기 위한 중합 방법 |
| KR20150100694A (ko) | 2012-12-27 | 2015-09-02 | 다우 글로벌 테크놀로지스 엘엘씨 | 올레핀 중합을 위한 촉매계 |
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| CN113201084A (zh) * | 2013-06-28 | 2021-08-03 | 陶氏环球技术有限责任公司 | 使用卤化双苯基苯氧基催化剂控制聚烯烃的分子量 |
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-
2014
- 2014-06-26 CN CN202110385158.5A patent/CN113201084A/zh active Pending
- 2014-06-26 JP JP2016524204A patent/JP6441332B2/ja active Active
- 2014-06-26 KR KR1020167001548A patent/KR102218415B1/ko active Active
- 2014-06-26 BR BR112015030912-7A patent/BR112015030912B1/pt active IP Right Grant
- 2014-06-26 SG SG11201510689SA patent/SG11201510689SA/en unknown
- 2014-06-26 ES ES21183736T patent/ES3062088T3/es active Active
- 2014-06-26 CN CN201480033642.XA patent/CN105283474A/zh active Pending
- 2014-06-26 WO PCT/US2014/044374 patent/WO2014210333A1/en not_active Ceased
- 2014-06-26 EP EP14741484.1A patent/EP3013871B1/en active Active
- 2014-06-26 SG SG10201802443VA patent/SG10201802443VA/en unknown
- 2014-06-26 US US14/781,419 patent/US9605098B2/en active Active
- 2014-06-26 ES ES14741484T patent/ES2934177T3/es active Active
- 2014-06-26 EP EP21183736.4A patent/EP3925989B1/en active Active
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2017
- 2017-02-15 US US15/433,198 patent/US10144791B2/en active Active
-
2018
- 2018-11-21 JP JP2018217837A patent/JP6813556B2/ja active Active
Also Published As
| Publication number | Publication date |
|---|---|
| SG11201510689SA (en) | 2016-01-28 |
| ES3062088T3 (en) | 2026-04-08 |
| EP3925989A1 (en) | 2021-12-22 |
| JP2019049003A (ja) | 2019-03-28 |
| WO2014210333A1 (en) | 2014-12-31 |
| ES2934177T3 (es) | 2023-02-17 |
| EP3013871A1 (en) | 2016-05-04 |
| US9605098B2 (en) | 2017-03-28 |
| BR112015030912A8 (pt) | 2020-01-28 |
| BR112015030912B1 (pt) | 2021-08-03 |
| SG10201802443VA (en) | 2018-05-30 |
| US20170158790A1 (en) | 2017-06-08 |
| US20160108156A1 (en) | 2016-04-21 |
| US10144791B2 (en) | 2018-12-04 |
| JP2016524024A (ja) | 2016-08-12 |
| BR112015030912A2 (pt) | 2017-07-25 |
| CN105283474A (zh) | 2016-01-27 |
| EP3013871B1 (en) | 2022-10-19 |
| KR20160037890A (ko) | 2016-04-06 |
| KR102218415B1 (ko) | 2021-02-22 |
| JP6441332B2 (ja) | 2018-12-19 |
| JP6813556B2 (ja) | 2021-01-13 |
| EP3925989B1 (en) | 2026-01-07 |
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