CN113201083B - 一种掺硫c3n4/聚(1,4-二苯基丁二炔)/聚苯胺光催化材料制备方法及其应用 - Google Patents
一种掺硫c3n4/聚(1,4-二苯基丁二炔)/聚苯胺光催化材料制备方法及其应用 Download PDFInfo
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- CN113201083B CN113201083B CN202110500405.1A CN202110500405A CN113201083B CN 113201083 B CN113201083 B CN 113201083B CN 202110500405 A CN202110500405 A CN 202110500405A CN 113201083 B CN113201083 B CN 113201083B
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- 239000000463 material Substances 0.000 title claims abstract description 29
- 230000001699 photocatalysis Effects 0.000 title claims abstract description 29
- 229920000767 polyaniline Polymers 0.000 title claims abstract description 28
- 238000002360 preparation method Methods 0.000 title claims abstract description 10
- 239000002121 nanofiber Substances 0.000 claims abstract description 49
- 239000002131 composite material Substances 0.000 claims abstract description 24
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 claims abstract description 16
- GVPWHKZIJBODOX-UHFFFAOYSA-N dibenzyl disulfide Chemical compound C=1C=CC=CC=1CSSCC1=CC=CC=C1 GVPWHKZIJBODOX-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000000178 monomer Substances 0.000 claims abstract description 14
- 238000012712 reversible addition−fragmentation chain-transfer polymerization Methods 0.000 claims abstract description 14
- 239000002114 nanocomposite Substances 0.000 claims abstract description 13
- 238000000034 method Methods 0.000 claims abstract description 11
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000004202 carbamide Substances 0.000 claims abstract description 7
- 239000003999 initiator Substances 0.000 claims abstract 3
- 239000011247 coating layer Substances 0.000 claims abstract 2
- 238000003756 stirring Methods 0.000 claims description 25
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 24
- 239000000243 solution Substances 0.000 claims description 20
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 claims description 10
- AMQJEAYHLZJPGS-UHFFFAOYSA-N N-Pentanol Chemical compound CCCCCO AMQJEAYHLZJPGS-UHFFFAOYSA-N 0.000 claims description 10
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 10
- 239000002243 precursor Substances 0.000 claims description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 8
- 239000008367 deionised water Substances 0.000 claims description 7
- 229910021641 deionized water Inorganic materials 0.000 claims description 7
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 claims description 6
- 239000007864 aqueous solution Substances 0.000 claims description 6
- 238000001914 filtration Methods 0.000 claims description 6
- 239000010453 quartz Substances 0.000 claims description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 6
- BQZJOQXSCSZQPS-UHFFFAOYSA-N 2-methoxy-1,2-diphenylethanone Chemical compound C=1C=CC=CC=1C(OC)C(=O)C1=CC=CC=C1 BQZJOQXSCSZQPS-UHFFFAOYSA-N 0.000 claims description 5
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 claims description 5
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 claims description 5
- 229910052786 argon Inorganic materials 0.000 claims description 5
- 238000001035 drying Methods 0.000 claims description 5
- 239000011780 sodium chloride Substances 0.000 claims description 5
- 238000001132 ultrasonic dispersion Methods 0.000 claims description 5
- 238000005406 washing Methods 0.000 claims description 5
- 229910001870 ammonium persulfate Inorganic materials 0.000 claims description 3
- 230000001678 irradiating effect Effects 0.000 claims description 3
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 claims description 3
- 239000004094 surface-active agent Substances 0.000 claims 2
- 102000020897 Formins Human genes 0.000 claims 1
- 108091022623 Formins Proteins 0.000 claims 1
- 239000012300 argon atmosphere Substances 0.000 claims 1
- 229920001940 conductive polymer Polymers 0.000 claims 1
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- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 claims 1
- 239000007789 gas Substances 0.000 claims 1
- 238000010438 heat treatment Methods 0.000 claims 1
- 239000011259 mixed solution Substances 0.000 claims 1
- 239000000203 mixture Substances 0.000 claims 1
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 claims 1
- 238000009210 therapy by ultrasound Methods 0.000 claims 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract 3
- 229910052717 sulfur Inorganic materials 0.000 abstract 3
- 239000011593 sulfur Substances 0.000 abstract 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract 2
- 238000003837 high-temperature calcination Methods 0.000 abstract 2
- 229910052757 nitrogen Inorganic materials 0.000 abstract 1
- 238000010526 radical polymerization reaction Methods 0.000 description 8
- 238000006243 chemical reaction Methods 0.000 description 6
- 239000011941 photocatalyst Substances 0.000 description 4
- 230000008901 benefit Effects 0.000 description 3
- 239000003054 catalyst Substances 0.000 description 3
- 239000004065 semiconductor Substances 0.000 description 3
- 230000003197 catalytic effect Effects 0.000 description 2
- 239000012986 chain transfer agent Substances 0.000 description 2
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- 101710141544 Allatotropin-related peptide Proteins 0.000 description 1
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- 230000004913 activation Effects 0.000 description 1
- 238000010560 atom transfer radical polymerization reaction Methods 0.000 description 1
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- 238000013329 compounding Methods 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 239000001978 cystine tryptic agar Substances 0.000 description 1
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- 238000007720 emulsion polymerization reaction Methods 0.000 description 1
- 239000012634 fragment Substances 0.000 description 1
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- 238000006062 fragmentation reaction Methods 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 229920000592 inorganic polymer Polymers 0.000 description 1
- 239000012212 insulator Substances 0.000 description 1
- 230000031700 light absorption Effects 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 238000001465 metallisation Methods 0.000 description 1
- 229920003240 metallophthalocyanine polymer Polymers 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 229910000510 noble metal Inorganic materials 0.000 description 1
- 229920000620 organic polymer Polymers 0.000 description 1
- JMANVNJQNLATNU-UHFFFAOYSA-N oxalonitrile Chemical compound N#CC#N JMANVNJQNLATNU-UHFFFAOYSA-N 0.000 description 1
- 238000007146 photocatalysis Methods 0.000 description 1
- 208000017983 photosensitivity disease Diseases 0.000 description 1
- 231100000434 photosensitization Toxicity 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000005215 recombination Methods 0.000 description 1
- 230000006798 recombination Effects 0.000 description 1
- 238000006479 redox reaction Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000006722 reduction reaction Methods 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
- 150000003564 thiocarbonyl compounds Chemical class 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2438/00—Living radical polymerisation
- C08F2438/01—Atom Transfer Radical Polymerization [ATRP] or reverse ATRP
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W10/00—Technologies for wastewater treatment
- Y02W10/30—Wastewater or sewage treatment systems using renewable energies
- Y02W10/37—Wastewater or sewage treatment systems using renewable energies using solar energy
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Catalysts (AREA)
Abstract
Description
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CN202110500405.1A CN113201083B (zh) | 2021-05-08 | 2021-05-08 | 一种掺硫c3n4/聚(1,4-二苯基丁二炔)/聚苯胺光催化材料制备方法及其应用 |
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CN113201083A CN113201083A (zh) | 2021-08-03 |
CN113201083B true CN113201083B (zh) | 2023-08-25 |
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Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106179499A (zh) * | 2016-07-13 | 2016-12-07 | 华东理工大学 | 一种g‑C3N4与聚合物PDPB复合光催化剂的制备及其应用 |
CN106669760A (zh) * | 2016-12-28 | 2017-05-17 | 广州中国科学院沈阳自动化研究所分所 | 一种硫掺杂氮化碳光催化剂及其制备方法、应用 |
CN109126868A (zh) * | 2018-08-01 | 2019-01-04 | 河南师范大学 | 一种用于降解土霉素废水的g-C3N4-PANI复合光催化材料的制备方法 |
WO2020251493A1 (en) * | 2019-06-11 | 2020-12-17 | Yildiz Teknik Universitesi | Production of polyaniline graphitic carbon nitride nano-composites with high electrical conductivity |
-
2021
- 2021-05-08 CN CN202110500405.1A patent/CN113201083B/zh active Active
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106179499A (zh) * | 2016-07-13 | 2016-12-07 | 华东理工大学 | 一种g‑C3N4与聚合物PDPB复合光催化剂的制备及其应用 |
CN106669760A (zh) * | 2016-12-28 | 2017-05-17 | 广州中国科学院沈阳自动化研究所分所 | 一种硫掺杂氮化碳光催化剂及其制备方法、应用 |
CN109126868A (zh) * | 2018-08-01 | 2019-01-04 | 河南师范大学 | 一种用于降解土霉素废水的g-C3N4-PANI复合光催化材料的制备方法 |
WO2020251493A1 (en) * | 2019-06-11 | 2020-12-17 | Yildiz Teknik Universitesi | Production of polyaniline graphitic carbon nitride nano-composites with high electrical conductivity |
Non-Patent Citations (1)
Title |
---|
Polyaniline-TiO2 composite photocatalysts for light-driven hexavalent chromium ions reduction;Xiaoming Deng 等;《Science Bulletin》;第65卷;105-112 * |
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Inventor after: Request for anonymity Inventor after: Wang Guoxiang Inventor after: Zeng Lelin Inventor after: Liang Enxiang Inventor before: Wang Guoxiang Inventor before: Zeng Lelin Inventor before: Liang Enxiang |
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CI03 | Correction of invention patent | ||
CI03 | Correction of invention patent |
Correction item: Inventor Correct: Sunshine and rosy clouds|Wang Guoxiang|Zeng Lelin|Liang Enxiang False: Request not to disclose name|Wang Guoxiang|Zeng Lelin|Liang Enxiang Number: 47-02 Volume: 39 |