CN112593313A - 一种氮、磷掺杂多孔中空碳纳米纤维的制备方法及应用 - Google Patents
一种氮、磷掺杂多孔中空碳纳米纤维的制备方法及应用 Download PDFInfo
- Publication number
- CN112593313A CN112593313A CN202011485079.3A CN202011485079A CN112593313A CN 112593313 A CN112593313 A CN 112593313A CN 202011485079 A CN202011485079 A CN 202011485079A CN 112593313 A CN112593313 A CN 112593313A
- Authority
- CN
- China
- Prior art keywords
- nitrogen
- phosphorus
- carbon nanofiber
- hollow carbon
- porous hollow
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 title claims abstract description 46
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 title claims abstract description 39
- 239000011574 phosphorus Substances 0.000 title claims abstract description 39
- 229910052698 phosphorus Inorganic materials 0.000 title claims abstract description 39
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 title claims abstract description 32
- 239000002134 carbon nanofiber Substances 0.000 title claims abstract description 30
- 229910052757 nitrogen Inorganic materials 0.000 title claims abstract description 23
- 238000002360 preparation method Methods 0.000 title claims description 7
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 12
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 claims description 9
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 claims description 9
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical class CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 8
- YUWBVKYVJWNVLE-UHFFFAOYSA-N [N].[P] Chemical compound [N].[P] YUWBVKYVJWNVLE-UHFFFAOYSA-N 0.000 claims description 8
- 239000007772 electrode material Substances 0.000 claims description 8
- 238000009987 spinning Methods 0.000 claims description 8
- 229920002239 polyacrylonitrile Polymers 0.000 claims description 7
- 230000003647 oxidation Effects 0.000 claims description 6
- 238000007254 oxidation reaction Methods 0.000 claims description 6
- 229920003229 poly(methyl methacrylate) Polymers 0.000 claims description 5
- 239000004926 polymethyl methacrylate Substances 0.000 claims description 5
- 239000002904 solvent Substances 0.000 claims description 5
- 239000012298 atmosphere Substances 0.000 claims description 4
- VHRYZQNGTZXDNX-UHFFFAOYSA-N methacryloyl chloride Chemical compound CC(=C)C(Cl)=O VHRYZQNGTZXDNX-UHFFFAOYSA-N 0.000 claims description 4
- 239000012299 nitrogen atmosphere Substances 0.000 claims description 4
- 239000002243 precursor Substances 0.000 claims description 4
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 3
- 238000001354 calcination Methods 0.000 claims description 3
- 238000010041 electrostatic spinning Methods 0.000 claims description 3
- 238000000034 method Methods 0.000 claims description 3
- 239000002121 nanofiber Substances 0.000 claims description 3
- YASRHLDAFCMIPB-UHFFFAOYSA-N (1-oxo-2,6,7-trioxa-1$l^{5}-phosphabicyclo[2.2.2]octan-4-yl)methanol Chemical compound C1OP2(=O)OCC1(CO)CO2 YASRHLDAFCMIPB-UHFFFAOYSA-N 0.000 claims description 2
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 claims 9
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 claims 4
- 230000004913 activation Effects 0.000 claims 1
- 238000010438 heat treatment Methods 0.000 claims 1
- 239000003999 initiator Substances 0.000 claims 1
- 239000000203 mixture Substances 0.000 claims 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract description 7
- 239000003990 capacitor Substances 0.000 abstract description 6
- 230000000694 effects Effects 0.000 abstract description 6
- DLGYNVMUCSTYDQ-UHFFFAOYSA-N azane;pyridine Chemical compound N.C1=CC=NC=C1 DLGYNVMUCSTYDQ-UHFFFAOYSA-N 0.000 abstract description 3
- 230000009286 beneficial effect Effects 0.000 abstract description 3
- 229920000049 Carbon (fiber) Polymers 0.000 abstract description 2
- 239000004917 carbon fiber Substances 0.000 abstract description 2
- 239000003792 electrolyte Substances 0.000 abstract description 2
- 229910002804 graphite Inorganic materials 0.000 abstract description 2
- 239000010439 graphite Substances 0.000 abstract description 2
- 239000011148 porous material Substances 0.000 abstract description 2
- KAESVJOAVNADME-UHFFFAOYSA-N Pyrrole Chemical compound C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 abstract 4
- 230000002708 enhancing effect Effects 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 description 3
- 238000004146 energy storage Methods 0.000 description 3
- 125000000524 functional group Chemical group 0.000 description 3
- AFINAILKDBCXMX-PBHICJAKSA-N (2s,3r)-2-amino-3-hydroxy-n-(4-octylphenyl)butanamide Chemical compound CCCCCCCCC1=CC=C(NC(=O)[C@@H](N)[C@@H](C)O)C=C1 AFINAILKDBCXMX-PBHICJAKSA-N 0.000 description 2
- 239000003575 carbonaceous material Substances 0.000 description 2
- 238000004821 distillation Methods 0.000 description 2
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 description 2
- 238000000746 purification Methods 0.000 description 2
- 238000001953 recrystallisation Methods 0.000 description 2
- GPKIXZRJUHCCKX-UHFFFAOYSA-N 2-[(5-methyl-2-propan-2-ylphenoxy)methyl]oxirane Chemical compound CC(C)C1=CC=C(C)C=C1OCC1OC1 GPKIXZRJUHCCKX-UHFFFAOYSA-N 0.000 description 1
- 239000004966 Carbon aerogel Substances 0.000 description 1
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 125000003342 alkenyl group Chemical group 0.000 description 1
- AAMATCKFMHVIDO-UHFFFAOYSA-N azane;1h-pyrrole Chemical compound N.C=1C=CNC=1 AAMATCKFMHVIDO-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 229920001940 conductive polymer Polymers 0.000 description 1
- 230000001276 controlling effect Effects 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000005530 etching Methods 0.000 description 1
- 229910021389 graphene Inorganic materials 0.000 description 1
- 125000005842 heteroatom Chemical group 0.000 description 1
- 238000003837 high-temperature calcination Methods 0.000 description 1
- 150000004679 hydroxides Chemical class 0.000 description 1
- 229910001416 lithium ion Inorganic materials 0.000 description 1
- -1 meanwhile Chemical group 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- BFDHFSHZJLFAMC-UHFFFAOYSA-L nickel(ii) hydroxide Chemical compound [OH-].[OH-].[Ni+2] BFDHFSHZJLFAMC-UHFFFAOYSA-L 0.000 description 1
- 125000002560 nitrile group Chemical group 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- 229920000767 polyaniline Polymers 0.000 description 1
- 229920000128 polypyrrole Polymers 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
Images
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F9/00—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments
- D01F9/08—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments of inorganic material
- D01F9/12—Carbon filaments; Apparatus specially adapted for the manufacture thereof
- D01F9/14—Carbon filaments; Apparatus specially adapted for the manufacture thereof by decomposition of organic filaments
- D01F9/20—Carbon filaments; Apparatus specially adapted for the manufacture thereof by decomposition of organic filaments from polyaddition, polycondensation or polymerisation products
- D01F9/21—Carbon filaments; Apparatus specially adapted for the manufacture thereof by decomposition of organic filaments from polyaddition, polycondensation or polymerisation products from macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D01F9/22—Carbon filaments; Apparatus specially adapted for the manufacture thereof by decomposition of organic filaments from polyaddition, polycondensation or polymerisation products from macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from polyacrylonitriles
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/42—Nitriles
- C08F220/44—Acrylonitrile
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/0007—Electro-spinning
- D01D5/0015—Electro-spinning characterised by the initial state of the material
- D01D5/003—Electro-spinning characterised by the initial state of the material the material being a polymer solution or dispersion
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/28—Formation of filaments, threads, or the like while mixing different spinning solutions or melts during the spinning operation; Spinnerette packs therefor
- D01D5/30—Conjugate filaments; Spinnerette packs therefor
- D01D5/34—Core-skin structure; Spinnerette packs therefor
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
- D01F8/08—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyacrylonitrile as constituent
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
- D01F8/10—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one other macromolecular compound obtained by reactions only involving carbon-to-carbon unsaturated bonds as constituent
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/22—Electrodes
- H01G11/24—Electrodes characterised by structural features of the materials making up or comprised in the electrodes, e.g. form, surface area or porosity; characterised by the structural features of powders or particles used therefor
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/22—Electrodes
- H01G11/30—Electrodes characterised by their material
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/22—Electrodes
- H01G11/30—Electrodes characterised by their material
- H01G11/32—Carbon-based
- H01G11/36—Nanostructures, e.g. nanofibres, nanotubes or fullerenes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/84—Processes for the manufacture of hybrid or EDL capacitors, or components thereof
- H01G11/86—Processes for the manufacture of hybrid or EDL capacitors, or components thereof specially adapted for electrodes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/13—Energy storage using capacitors
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Power Engineering (AREA)
- Textile Engineering (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Mechanical Engineering (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Dispersion Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Nanotechnology (AREA)
- Medicinal Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Carbon And Carbon Compounds (AREA)
- Inorganic Fibers (AREA)
Abstract
Description
Claims (7)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202011485079.3A CN112593313B (zh) | 2020-12-16 | 2020-12-16 | 一种氮、磷掺杂多孔中空碳纳米纤维的制备方法及应用 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202011485079.3A CN112593313B (zh) | 2020-12-16 | 2020-12-16 | 一种氮、磷掺杂多孔中空碳纳米纤维的制备方法及应用 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN112593313A true CN112593313A (zh) | 2021-04-02 |
CN112593313B CN112593313B (zh) | 2022-11-11 |
Family
ID=75196264
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN202011485079.3A Active CN112593313B (zh) | 2020-12-16 | 2020-12-16 | 一种氮、磷掺杂多孔中空碳纳米纤维的制备方法及应用 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN112593313B (zh) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN113501511A (zh) * | 2021-06-15 | 2021-10-15 | 暨南大学 | 一种基于植酸调节氮掺杂碳结构的方法及其应用 |
CN113564752A (zh) * | 2021-07-05 | 2021-10-29 | 上海工程技术大学 | 内管壁负载氧化锡的中空多孔碳纳米纤维及其制备方法和应用 |
CN114843467A (zh) * | 2022-04-28 | 2022-08-02 | 华南师范大学 | 一种氮、磷共掺钒氧化物/碳自支撑电极材料及其制备方法和应用 |
CN115012072A (zh) * | 2022-07-18 | 2022-09-06 | 重庆锦添翼新能源科技有限公司 | 一种碳纳米纤维/石墨烯纳米片及其制备方法 |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104262398A (zh) * | 2014-09-23 | 2015-01-07 | 厦门大学 | 一种含活性双键的磷氮系阻燃剂及其制备方法与应用 |
CN106115653A (zh) * | 2016-06-22 | 2016-11-16 | 兰州理工大学 | 一种杂原子掺杂的多孔碳材料的制备方法 |
US20190055127A1 (en) * | 2016-12-07 | 2019-02-21 | Wenzhou University | Sheet-shaped nitrogen-phosphorus co-doped porous carbon material and method for preparation thereof and use thereof |
CN110336049A (zh) * | 2019-07-26 | 2019-10-15 | 东华大学 | 一种氮钴掺杂的中空碳纳米纤维及其制备方法和应用以及一种金属空气电池 |
KR20200066750A (ko) * | 2018-11-29 | 2020-06-11 | 한국과학기술연구원 | 이종원소가 도핑된 탄소나노섬유 제조방법, 이에 따라 제조된 이종원소가 도핑된 탄소나노섬유 및 이를 이용한 탄소나노섬유-고분자 복합소재 |
-
2020
- 2020-12-16 CN CN202011485079.3A patent/CN112593313B/zh active Active
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104262398A (zh) * | 2014-09-23 | 2015-01-07 | 厦门大学 | 一种含活性双键的磷氮系阻燃剂及其制备方法与应用 |
CN106115653A (zh) * | 2016-06-22 | 2016-11-16 | 兰州理工大学 | 一种杂原子掺杂的多孔碳材料的制备方法 |
US20190055127A1 (en) * | 2016-12-07 | 2019-02-21 | Wenzhou University | Sheet-shaped nitrogen-phosphorus co-doped porous carbon material and method for preparation thereof and use thereof |
KR20200066750A (ko) * | 2018-11-29 | 2020-06-11 | 한국과학기술연구원 | 이종원소가 도핑된 탄소나노섬유 제조방법, 이에 따라 제조된 이종원소가 도핑된 탄소나노섬유 및 이를 이용한 탄소나노섬유-고분자 복합소재 |
CN110336049A (zh) * | 2019-07-26 | 2019-10-15 | 东华大学 | 一种氮钴掺杂的中空碳纳米纤维及其制备方法和应用以及一种金属空气电池 |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN113501511A (zh) * | 2021-06-15 | 2021-10-15 | 暨南大学 | 一种基于植酸调节氮掺杂碳结构的方法及其应用 |
CN113564752A (zh) * | 2021-07-05 | 2021-10-29 | 上海工程技术大学 | 内管壁负载氧化锡的中空多孔碳纳米纤维及其制备方法和应用 |
CN114843467A (zh) * | 2022-04-28 | 2022-08-02 | 华南师范大学 | 一种氮、磷共掺钒氧化物/碳自支撑电极材料及其制备方法和应用 |
CN115012072A (zh) * | 2022-07-18 | 2022-09-06 | 重庆锦添翼新能源科技有限公司 | 一种碳纳米纤维/石墨烯纳米片及其制备方法 |
CN115012072B (zh) * | 2022-07-18 | 2023-12-19 | 重庆锦添翼新能源科技有限公司 | 一种碳纳米纤维/石墨烯纳米片及其制备方法 |
Also Published As
Publication number | Publication date |
---|---|
CN112593313B (zh) | 2022-11-11 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN112593313B (zh) | 一种氮、磷掺杂多孔中空碳纳米纤维的制备方法及应用 | |
CN103594254B (zh) | 一种二氧化锰/介孔碳纳米分级复合电极材料的制备方法 | |
CN107611434B (zh) | 一种柔性自支撑多孔碳纳米纤维电极的制备方法及其应用 | |
CN108010747B (zh) | 一种超级电容器用氮硫双掺杂活性炭的制备方法 | |
WO2012146046A1 (zh) | 一种聚酰亚胺电容电池及其制作方法 | |
CN103896246A (zh) | 杂原子掺杂的多孔碳纳米管的制备方法及其应用 | |
US11691881B2 (en) | Carbonized amino acid modified lignin and preparation method therefor | |
CN109192523B (zh) | 一种Ni(OH)2/多层石墨烯复合材料的制备方法 | |
CN112864365A (zh) | 一种氮-硫共掺杂多孔碳负载氧化锌的负极材料及制法 | |
CN109592674B (zh) | 一种石墨烯负极材料及其制备方法 | |
CN109928384A (zh) | 一种氮掺杂多孔碳材料的制备方法 | |
CN111640921A (zh) | 一种钒类化合物电极材料的制备方法及其在水系锌离子电池中的应用 | |
CN111834130A (zh) | 塌陷碳基纳米笼电极材料及其制备方法 | |
CN105719843B (zh) | 一种氮化钼/氮化钛纳米管阵列复合材料及其制备方法和应用 | |
CN110589823A (zh) | 一种柚子皮多孔碳材料及其制备方法与应用 | |
CN107680826B (zh) | 一种用于超级电容器的分层多孔活性炭电极材料的制备方法 | |
CN112960699A (zh) | 一种杂原子掺杂多孔碳负载花球状Fe3O4的电极材料及制法 | |
CN111573748A (zh) | 一种N,P-共掺杂多孔碳-NiS2的超级电容器电极材料及其制法 | |
CN113593924B (zh) | 一种氮化碳-石墨烯复合材料及其制备方法和应用 | |
CN113394030A (zh) | 一种镍基电极材料及其制备方法和应用 | |
CN112735858A (zh) | 一种用于超级电容器的氮硫共掺杂的层状多孔碳杂化材料的制备方法 | |
CN111554517A (zh) | 一种氮掺杂多孔碳包覆纳米NiCo2O4的电极活性材料及其制法 | |
CN116313540B (zh) | 一种电容器用电极材料及其制备方法 | |
CN109755040A (zh) | 利用葵花籽壳制备高压水系超级电容器电极材料的方法 | |
CN112599362B (zh) | 一种孔隙分布均匀的氮硫掺杂介孔碳电极材料的制法和应用 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
TA01 | Transfer of patent application right | ||
TA01 | Transfer of patent application right |
Effective date of registration: 20221010 Address after: 314500 2001, room 3, Victoria Park, 1410 triumph of Wutong street, Tongxiang, Jiaxing, Zhejiang. Applicant after: Jiaxing beichuang Network Technology Co.,Ltd. Address before: 110000 Shenyang Dadong District entrepreneurship and innovation incubation base, 142 Wanghua middle street, Dadong District, Shenyang City, Liaoning Province Applicant before: Shan Bailing |
|
TA01 | Transfer of patent application right | ||
TA01 | Transfer of patent application right |
Effective date of registration: 20221024 Address after: Room 311, Floor 3, Building 4, High tech Incubation Park, No. 8, Nanxin Road, Leshan Hi tech Zone, Leshan City, Sichuan Province, 614000 Applicant after: Leshan Zhongke Zhengguang Agroforestry Technology Co.,Ltd. Address before: 314500 2001, room 3, Victoria Park, 1410 triumph of Wutong street, Tongxiang, Jiaxing, Zhejiang. Applicant before: Jiaxing beichuang Network Technology Co.,Ltd. |
|
GR01 | Patent grant | ||
GR01 | Patent grant |