CN112469682A - 一种获得无铅压电材料的方法、相应无铅压电材料 - Google Patents

一种获得无铅压电材料的方法、相应无铅压电材料 Download PDF

Info

Publication number
CN112469682A
CN112469682A CN201980027113.1A CN201980027113A CN112469682A CN 112469682 A CN112469682 A CN 112469682A CN 201980027113 A CN201980027113 A CN 201980027113A CN 112469682 A CN112469682 A CN 112469682A
Authority
CN
China
Prior art keywords
lead
phase
free piezoelectric
phase boundary
piezoelectric material
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201980027113.1A
Other languages
English (en)
Other versions
CN112469682B (zh
Inventor
任晓兵
任帅
郝彦双
方敏侠
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Xian Jiaotong University
National Institute for Materials Science
Original Assignee
Xian Jiaotong University
National Institute for Materials Science
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Xian Jiaotong University, National Institute for Materials Science filed Critical Xian Jiaotong University
Publication of CN112469682A publication Critical patent/CN112469682A/zh
Application granted granted Critical
Publication of CN112469682B publication Critical patent/CN112469682B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10N—ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10N30/00—Piezoelectric or electrostrictive devices
    • H10N30/80—Constructional details
    • H10N30/85—Piezoelectric or electrostrictive active materials
    • H10N30/853—Ceramic compositions
    • H10N30/8542—Alkali metal based oxides, e.g. lithium, sodium or potassium niobates
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
    • C04B35/46—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on titanium oxides or titanates
    • C04B35/462—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on titanium oxides or titanates based on titanates
    • C04B35/465—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on titanium oxides or titanates based on titanates based on alkaline earth metal titanates
    • C04B35/468—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on titanium oxides or titanates based on titanates based on alkaline earth metal titanates based on barium titanates
    • C04B35/4682—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on titanium oxides or titanates based on titanates based on alkaline earth metal titanates based on barium titanates based on BaTiO3 perovskite phase
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
    • C04B35/495—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on vanadium, niobium, tantalum, molybdenum or tungsten oxides or solid solutions thereof with other oxides, e.g. vanadates, niobates, tantalates, molybdates or tungstates
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/64—Burning or sintering processes
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10N—ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10N30/00—Piezoelectric or electrostrictive devices
    • H10N30/01—Manufacture or treatment
    • H10N30/09—Forming piezoelectric or electrostrictive materials
    • H10N30/093—Forming inorganic materials
    • H10N30/097—Forming inorganic materials by sintering
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10N—ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10N30/00—Piezoelectric or electrostrictive devices
    • H10N30/20—Piezoelectric or electrostrictive devices with electrical input and mechanical output, e.g. functioning as actuators or vibrators
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10N—ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10N30/00—Piezoelectric or electrostrictive devices
    • H10N30/30—Piezoelectric or electrostrictive devices with mechanical input and electrical output, e.g. functioning as generators or sensors
    • H10N30/302—Sensors
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10N—ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10N30/00—Piezoelectric or electrostrictive devices
    • H10N30/80—Constructional details
    • H10N30/85—Piezoelectric or electrostrictive active materials
    • H10N30/853—Ceramic compositions
    • H10N30/8536—Alkaline earth metal based oxides, e.g. barium titanates
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3201—Alkali metal oxides or oxide-forming salts thereof
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3201—Alkali metal oxides or oxide-forming salts thereof
    • C04B2235/3203—Lithium oxide or oxide-forming salts thereof
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3205—Alkaline earth oxides or oxide forming salts thereof, e.g. beryllium oxide
    • C04B2235/3206—Magnesium oxides or oxide-forming salts thereof
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3205—Alkaline earth oxides or oxide forming salts thereof, e.g. beryllium oxide
    • C04B2235/3208—Calcium oxide or oxide-forming salts thereof, e.g. lime
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3205—Alkaline earth oxides or oxide forming salts thereof, e.g. beryllium oxide
    • C04B2235/3213—Strontium oxides or oxide-forming salts thereof
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3205—Alkaline earth oxides or oxide forming salts thereof, e.g. beryllium oxide
    • C04B2235/3215—Barium oxides or oxide-forming salts thereof
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3231—Refractory metal oxides, their mixed metal oxides, or oxide-forming salts thereof
    • C04B2235/3244—Zirconium oxides, zirconates, hafnium oxides, hafnates, or oxide-forming salts thereof
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3231—Refractory metal oxides, their mixed metal oxides, or oxide-forming salts thereof
    • C04B2235/3244—Zirconium oxides, zirconates, hafnium oxides, hafnates, or oxide-forming salts thereof
    • C04B2235/3248—Zirconates or hafnates, e.g. zircon
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3231—Refractory metal oxides, their mixed metal oxides, or oxide-forming salts thereof
    • C04B2235/3251—Niobium oxides, niobates, tantalum oxides, tantalates, or oxide-forming salts thereof
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3231—Refractory metal oxides, their mixed metal oxides, or oxide-forming salts thereof
    • C04B2235/3251—Niobium oxides, niobates, tantalum oxides, tantalates, or oxide-forming salts thereof
    • C04B2235/3255—Niobates or tantalates, e.g. silver niobate
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3293—Tin oxides, stannates or oxide forming salts thereof, e.g. indium tin oxide [ITO]
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3294—Antimony oxides, antimonates, antimonites or oxide forming salts thereof, indium antimonate
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3298—Bismuth oxides, bismuthates or oxide forming salts thereof, e.g. zinc bismuthate
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/44—Metal salt constituents or additives chosen for the nature of the anions, e.g. hydrides or acetylacetonate
    • C04B2235/442—Carbonates
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/70—Aspects relating to sintered or melt-casted ceramic products
    • C04B2235/74—Physical characteristics
    • C04B2235/76—Crystal structural characteristics, e.g. symmetry
    • C04B2235/768—Perovskite structure ABO3

Abstract

一种获得无铅压电材料的方法及相应的无铅压电材料，方法包括：通过掺杂将四方相T与正交相O之间的T/O相界调整至室温附近进而调整第一无铅压电材料的T/O相界：进一步通过掺杂，调整立方顺电相C与四方相T之间的C/T相界、以及正交相O与菱方相R之间的O/R相界，以使得C/T相界和O/R相界向T/O相界靠拢以调整C/T相界和O/R相界；获得第二无铅压电材料，在C/T相界和O/R相界向T/O相界靠拢的过程中，获得多种不同压电常数d33、不同居里温度Tc的第二无铅压电材料。

Description

PCT国内申请，说明书已公开。

Claims (60)

  1. PCT国内申请，权利要求书已公开。
CN201980027113.1A 2018-04-21 2019-04-22 一种获得无铅压电材料的方法、相应无铅压电材料 Active CN112469682B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
CN201810364324 2018-04-21
CN2018103643241 2018-04-21
PCT/CN2019/083695 WO2019201353A1 (zh) 2018-04-21 2019-04-22 一种获得无铅压电材料的方法、相应无铅压电材料

Publications (2)

Publication Number Publication Date
CN112469682A true CN112469682A (zh) 2021-03-09
CN112469682B CN112469682B (zh) 2023-01-03

Family

ID=68239729

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201980027113.1A Active CN112469682B (zh) 2018-04-21 2019-04-22 一种获得无铅压电材料的方法、相应无铅压电材料

Country Status (5)

Country Link
US (1) US20220037584A1 (zh)
EP (1) EP3786136A4 (zh)
JP (1) JP7462275B2 (zh)
CN (1) CN112469682B (zh)
WO (1) WO2019201353A1 (zh)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114409401A (zh) * 2022-01-21 2022-04-29 广东奥迪威传感科技股份有限公司 铌酸钾钠系压电陶瓷及其制备方法、电子设备

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111900246A (zh) * 2020-08-06 2020-11-06 清华大学 一种铌酸锂钠基无铅压电陶瓷的极化方法
CN111925209A (zh) * 2020-08-10 2020-11-13 国网河南省电力公司电力科学研究院 一种无铅声振压电换能材料及其制备方法
CN114988871B (zh) * 2022-05-16 2023-07-14 清华大学 温度稳定型铌酸钾钠基无铅压电陶瓷及其制备方法和应用
CN116283273A (zh) * 2022-12-07 2023-06-23 贵州大学 一种无铅压电陶瓷材料及其制备方法
CN116444270A (zh) * 2023-03-13 2023-07-18 国网智能电网研究院有限公司 一种高压电性能和高介电性能弛豫铁电陶瓷的制备方法
CN116768623A (zh) * 2023-06-13 2023-09-19 同济大学 具有温度稳定性的铌酸钾钠基织构压电陶瓷及其制备方法

Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101182203A (zh) * 2007-11-27 2008-05-21 山东大学 钛酸钡基压电陶瓷材料及其制备方法与应用
CN101376594A (zh) * 2007-08-30 2009-03-04 香港理工大学 铌锑酸钠钾系无铅压电陶瓷组合物
CN101798218A (zh) * 2010-03-18 2010-08-11 西安交通大学 一种锆钛酸钡和铌酸钾钠复合的无铅压电厚膜的制备方法
CN101863661A (zh) * 2010-06-04 2010-10-20 中国科学院上海硅酸盐研究所 织构化铌酸钾钠基无铅压电陶瓷的制备方法
CN101935215A (zh) * 2010-09-07 2011-01-05 聊城大学 具有良好温度稳定性的铌酸钾钠锂基无铅压电陶瓷复合物
CN103288450A (zh) * 2013-05-24 2013-09-11 四川大学 铌酸钾钠-锆钛酸铋钾/锂系无铅压电陶瓷
JP2013234100A (ja) * 2012-05-10 2013-11-21 Honda Electronic Co Ltd 圧電磁器組成物
CN103482977A (zh) * 2013-09-02 2014-01-01 四川大学 高压电常数铌锑酸钾钠-锆酸铋钠钾无铅压电陶瓷及制备方法
CN103613379A (zh) * 2013-11-04 2014-03-05 西安交通大学 一种高性能无铅压电陶瓷及其制备工艺
CN107098699A (zh) * 2017-03-28 2017-08-29 同济大学 宽烧结温区及宽组分调节的无铅压电织构陶瓷及制备方法

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6526833B1 (en) * 2000-03-13 2003-03-04 Massachusetts Institute Of Technology Rhombohedral-phase barium titanate as a piezoelectric transducer
JP4631246B2 (ja) 2002-03-20 2011-02-16 株式会社豊田中央研究所 圧電磁器組成物及びその製造方法並びに圧電素子及び誘電素子
JP2006236810A (ja) * 2005-02-25 2006-09-07 Ngk Insulators Ltd 発光装置
JP2007204336A (ja) * 2006-02-03 2007-08-16 Denso Corp 鉛フリー圧電セラミックス
JP4943043B2 (ja) * 2006-03-31 2012-05-30 富士フイルム株式会社 圧電セラミックスの製造方法
CN103601493B (zh) * 2013-10-15 2015-09-30 陕西科技大学 一种knn-ls无铅压电陶瓷及其制备方法
CN105732032A (zh) 2016-01-19 2016-07-06 上海交通大学 高致密度的铌锑酸钾钠锂-锆酸铋钠钙二元系无铅压电陶瓷及其制备方法
CN107098701B (zh) * 2017-04-27 2020-09-08 成都信息工程大学 铌酸钾钠锂-锆酸铋钠钾-钪酸铋三元系无铅压电陶瓷

Patent Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101376594A (zh) * 2007-08-30 2009-03-04 香港理工大学 铌锑酸钠钾系无铅压电陶瓷组合物
CN101182203A (zh) * 2007-11-27 2008-05-21 山东大学 钛酸钡基压电陶瓷材料及其制备方法与应用
CN101798218A (zh) * 2010-03-18 2010-08-11 西安交通大学 一种锆钛酸钡和铌酸钾钠复合的无铅压电厚膜的制备方法
CN101863661A (zh) * 2010-06-04 2010-10-20 中国科学院上海硅酸盐研究所 织构化铌酸钾钠基无铅压电陶瓷的制备方法
CN101935215A (zh) * 2010-09-07 2011-01-05 聊城大学 具有良好温度稳定性的铌酸钾钠锂基无铅压电陶瓷复合物
JP2013234100A (ja) * 2012-05-10 2013-11-21 Honda Electronic Co Ltd 圧電磁器組成物
CN103288450A (zh) * 2013-05-24 2013-09-11 四川大学 铌酸钾钠-锆钛酸铋钾/锂系无铅压电陶瓷
CN103482977A (zh) * 2013-09-02 2014-01-01 四川大学 高压电常数铌锑酸钾钠-锆酸铋钠钾无铅压电陶瓷及制备方法
CN103613379A (zh) * 2013-11-04 2014-03-05 西安交通大学 一种高性能无铅压电陶瓷及其制备工艺
CN107098699A (zh) * 2017-03-28 2017-08-29 同济大学 宽烧结温区及宽组分调节的无铅压电织构陶瓷及制备方法

Non-Patent Citations (5)

* Cited by examiner, † Cited by third party
Title
N. BENSEMMA等: "Investigation of the BaTiO3–BaMg1/3Nb2/3O3 system: Structural, dielectric, ferroelectric and electromechanical studies", 《JOURNAL OF MATERIALS SCIENCE》 *
ROOPAM GAUR等: "Piezoelectric properties of (K0.5Na0.5)1-xLix(Nb0.96Sb0.04)O3 ceramics prepared from nanocrystalline powders", 《CERAMICS INTERNATIONAL》 *
SHASHA FENG等: "Lead-free (K, Na)NbO3-Bi0.5K0.5ZrO3-BaZrO3 ternary system: Microstructure and electrical properties", 《JOURNAL OF ALLOYS AND COMPOUNDS》 *
YAO YONGGANG等: "Relationship between Phase Coexistence and Properties in Piezoelectric Materials", 《中国材料进展》 *
唐福生等: "(K0.5Na0.5)NbO3-LiNbO3无铅压电陶瓷的烧结特性和压电性能研究", 《无机材料学报》 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114409401A (zh) * 2022-01-21 2022-04-29 广东奥迪威传感科技股份有限公司 铌酸钾钠系压电陶瓷及其制备方法、电子设备

Also Published As

Publication number Publication date
EP3786136A4 (en) 2021-06-16
JP2021522144A (ja) 2021-08-30
EP3786136A1 (en) 2021-03-03
WO2019201353A1 (zh) 2019-10-24
JP7462275B2 (ja) 2024-04-05
US20220037584A1 (en) 2022-02-03
CN112469682B (zh) 2023-01-03

Similar Documents

Publication Publication Date Title
CN112469682B (zh) 一种获得无铅压电材料的方法、相应无铅压电材料
Liu et al. Ultrahigh energy density and improved discharged efficiency in bismuth sodium titanate based relaxor ferroelectrics with A-site vacancy
Wang et al. BiFeO3-BaTiO3: A new generation of lead-free electroceramics
Praveen et al. Effect of poling process on piezoelectric properties of sol–gel derived BZT–BCT ceramics
Hao et al. Structure evolution and electrostrictive properties in (Bi0. 5Na0. 5) 0.94 Ba0. 06TiO3–M2O5 (M= Nb, Ta, Sb) lead-free piezoceramics
Bai et al. Temperature-insensitive large strain response with a low hysteresis behavior in BNT-based ceramics
Wang et al. Characteristics of giant piezoelectricity around the rhombohedral-tetragonal phase boundary in (K, Na) NbO 3-based ceramics with different additives
Cen et al. A high temperature stable piezoelectric strain of KNN-based ceramics
Zeng et al. Relaxor phenomenon of (1-x)(Ba. 85Ca. 15)(Zr. 09Ti. 91) O3-xTa+ 0.6 wt% Li2CO3 ceramics with high piezoelectric constant and Curie temperature
Shang et al. Effect of configuration entropy on dielectric relaxor, ferroelectric properties of high-entropy (NaBiBa) x (SrCa)(1-3 x)/2TiO3 ceramics
KR102020605B1 (ko) 변형율이 높은 삼성분계 무연 압전 세라믹 조성물
Yan et al. Enhanced piezoelectric activity around orthorhombic-tetragonal phase boundary in multielement codoping BaTiO3
Liu et al. Effects of antiferroelectric substitution on the structure and ferroelectric properties of a complex perovskite solid solution
Zhou et al. Cooling rate-dependent microstructure and electrical properties of BCZT ceramics
Maqbool et al. Structure and temperature dependent electrical properties of lead-free Bi0. 5Na0. 5TiO3-SrZrO3 ceramics
Amu-Darko et al. Relaxor ferroelectric and dielectric properties of (1–x) Ba (Zr0. 1Ti0. 9) O3–xBa (Mg1/3Ta2/3) O3 ceramics
Karakaya et al. Enhanced room temperature energy storage density of Bi (Li1/3Ti2/3) O3 substituted Bi0. 5Na0. 5TiO3–BaTiO3 ceramics
Al-Aaraji et al. Progress In Lead Free-Relaxor Ferroelectrics For Energy Storage Applications.
Zhang et al. A new low-temperature firable 0.95 Pb (ZrxTi1-x) O3-0.05 Bi (Mn1/2Ti1/2) O3 ceramic for high-power applications
Jin et al. Dielectric and ferroelectric properties of CuO-doped lead magnesium niobate-based relaxor ferroelectric ceramics
Ge et al. Fe-doping as a universal phase boundary shifter for BCZT ceramics across the morphotropic phase boundary
KR100933718B1 (ko) Ｂｎｂｔ계 압전세라믹스 및 그의 제조방법
Palei et al. Effect of silver content on the phase transition and electrical properties of 0.95 [(K0. 5Na0. 5) NbO3]–0.05 LiSbO3 ceramics
Chen et al. Electric field induced irreversible change and asymmetric butterfly strain loops in Pb (Zr, Ti) O3-Pb (Ni1/3Nb2/3) O3-Bi (Zn1/2Ti1/2) O3 quaternary ceramics
KR102540032B1 (ko) 압전 세라믹 적층체

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant