CN112174749A - Liquid soil conditioner and preparation method thereof - Google Patents
Liquid soil conditioner and preparation method thereof Download PDFInfo
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- CN112174749A CN112174749A CN202011065289.7A CN202011065289A CN112174749A CN 112174749 A CN112174749 A CN 112174749A CN 202011065289 A CN202011065289 A CN 202011065289A CN 112174749 A CN112174749 A CN 112174749A
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05C—NITROGENOUS FERTILISERS
- C05C3/00—Fertilisers containing other salts of ammonia or ammonia itself, e.g. gas liquor
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/60—Biocides or preservatives, e.g. disinfectants, pesticides or herbicides; Pest repellants or attractants
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/80—Soil conditioners
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G5/00—Fertilisers characterised by their form
- C05G5/20—Liquid fertilisers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K17/00—Soil-conditioning materials or soil-stabilising materials
- C09K17/40—Soil-conditioning materials or soil-stabilising materials containing mixtures of inorganic and organic compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2101/00—Agricultural use
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2109/00—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE pH regulation
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Organic Chemistry (AREA)
- Pest Control & Pesticides (AREA)
- Soil Sciences (AREA)
- Plant Pathology (AREA)
- Inorganic Chemistry (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Soil Conditioners And Soil-Stabilizing Materials (AREA)
- Fertilizers (AREA)
Abstract
The invention relates to the technical field of soil conditioning, in particular to a liquid soil conditioner and a preparation method thereof. The product can improve the land, can increase the amount of various nutrients needed by the growth and development of crops to be supplemented in time when the crops grow, and has obvious effect after being used. The soil conditioner can improve and neutralize the pH value of the soil, can increase the soil aggregate structure, loosen the soil, improve the physical and chemical properties of the soil, prevent soil hardening, salinization and salinization, improve the quality of crops and increase the yield, systematically and orderly improve the soil, can make the soil well developed and healthily developed, and can be recycled.
Description
Technical Field
The invention relates to the technical field of soil conditioning, in particular to a liquid soil conditioner and a preparation method thereof.
Background
Aiming at the serious salinization and salinization of soil in northwest China, the crop has the conditions of blight, yellow leaf disease, small leaf disease, bitter pox disease, brown spot, rot, mosaic disease, water core disease, rot, fruit cracking, rusty spot and the like in the growth process, and the consequence is that the root system of the crop grows slowly, the leaf surface cannot generate photosynthesis, the quality of the variety is reduced, the yield is reduced, even the soil is hardened, the crop cannot be cultivated, the crop of farmers is damaged, and the income is reduced in successive years.
Disclosure of Invention
In order to overcome the defects in the prior art, the invention provides a liquid soil conditioner and a preparation method thereof. Most of the soil conditioners in the market aim at acid soil and cannot meet requirements of salinized land and saline-alkali land. The product is specially used for radically treating serious areas of soil salinization and salinization, including 12 provinces including Xinjiang, Qinghai, inner Mongolia, Gansu, Ningxia, Shanxi, Hebei, Henan and northeast provinces in the north of Qinling.
In order to solve the technical problems, the technical scheme adopted by the invention is as follows:
a liquid soil conditioner is composed of the following raw materials in percentage by weight: 30-38% of molasses liquid; 28-36% of wood vinegar; 32-36% of amino acid stock solution; trace elements: 1-2% of chelated zinc, 1-2% of chelated iron and 1-2% of sodium octaborate tetrahydrate; 1.2 to 1.5 percent of compound microorganism bacteria; copper sulfate, ammonium heptamolybdate and manganese sulfate in balance; the ratio of the copper sulfate to the ammonium heptamolybdate to the manganese sulfate is 2:1: 1.
Further, the composite microbial bacteria are at least one of phosphate solubilizing bacteria powder, potassium solubilizing bacteria powder or photosynthetic bacteria powder, the number of effective bacteria in the phosphate solubilizing bacteria is not less than 5 hundred million/gram, the number of effective bacteria in the potassium solubilizing bacteria is not less than 5 hundred million/gram, and the number of effective bacteria in the photosynthetic bacteria is not less than 5 hundred million/gram.
Further, the pyroligneous liquor comprises acetic acid, phenols and water, wherein the organic matter component acetic acid accounts for more than 10%.
Furthermore, the wood vinegar is prepared by stewing miscellaneous tree branches and twigs in a charcoal kiln to generate smoke so as to be condensed by natural air cooling, and the condensed liquid is used as the wood vinegar.
A preparation method of a liquid soil conditioner specifically comprises the following steps:
s1, adding the molasses liquid, the trace elements, copper sulfate, ammonium heptamolybdate and manganese sulfate into a reaction kettle, and heating to 60-75 ℃;
s2, adding the amino acid stock solution, fully reacting and chelating for 30-45 minutes, and cooling to 30-40 ℃;
and S3, adding wood vinegar and the compound microorganism bacteria, stirring for reacting for 40 minutes, cooling, filtering, inspecting and packaging.
Compared with the prior art, the invention has the beneficial effects that:
the invention provides a liquid soil conditioner and a preparation method thereof, and the soil conditioner contains molasses liquid and pyroligneous liquid, and is also specially added with amino acid, trace elements and compound microorganism bacteria which are urgently needed by soil. The product can improve the land, can increase the amount of various nutrients needed by the growth and development of crops to be supplemented in time when the crops grow, and has obvious effect after being used. The product is added with the molasses liquid in a reaction kettle, heated to 60-75 ℃, added with the amino acid for full reaction and chelation for 30-45 minutes, and then added with the wood vinegar liquid after being cooled to 30-40 ℃, which changes the key protection effect of adding the compound microorganism bacteria in the later stage of the product; the wood vinegar has the function of promoting the reproduction of beneficial microorganisms in soil. Achieves multiple purposes, not only achieves the conditioning of soil salinization and salinization, but also increases soil amino acid, trace elements and compound microorganism bacteria, improves various nutrients of soil and reduces the investment burden of farmers.
The soil conditioner product provided by the invention has strong pertinence, aims at alkaline soil in the northwest five provinces, utilizes organic matters of waste residues and waste liquid as female parents, and all raw materials are biological organic matters without chemical materials.
The product is a pollution-free and green product: most of the soil conditioners in the market are mineral soil conditioners, because the raw materials are natural minerals, the soil conditioners are not calcined at high temperature, and the crop roots cannot absorb the soil conditioners at all. The soil conditioner provided by the invention is completely pollution-free, pollution-free and free of biological hormone, and is a novel green production material for agriculture and forestry planting in China.
The soil conditioner provided by the invention can improve soil, neutralize the pH value of the soil, increase the granular structure of the soil, loosen the soil, improve the physical and chemical properties of the soil, prevent soil hardening, salinization and salinization, simultaneously improve the quality of crops, increase the yield, systematically and orderly improve the soil, ensure the good development and healthy development of the soil, and can be recycled.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
A liquid soil conditioner is composed of the following raw materials in percentage by weight: 30-38% of molasses liquid; 28-36% of wood vinegar; 32-36% of amino acid stock solution; trace elements: 1-2% of chelated zinc, 1-2% of chelated iron and 1-2% of sodium octaborate tetrahydrate; 1.2 to 1.5 percent of compound microorganism bacteria; copper sulfate, ammonium heptamolybdate and manganese sulfate in balance; the ratio of the copper sulfate to the ammonium heptamolybdate to the manganese sulfate is 2:1: 1.
In this embodiment, the composite microbial bacteria is at least one of phosphate solubilizing bacteria powder, potassium solubilizing bacteria powder or photosynthetic bacteria powder, the number of effective bacteria in the phosphate solubilizing bacteria is not less than 5 hundred million/g, the number of effective bacteria in the potassium solubilizing bacteria is not less than 5 hundred million/g, and the number of effective bacteria in the photosynthetic bacteria is not less than 5 hundred million/g.
In this embodiment, the pyroligneous acid component is acetic acid, phenols, and water, wherein the organic component acetic acid accounts for more than 10%. The wood vinegar is prepared by stewing miscellaneous tree branches and branches in a charcoal kiln to generate smoke so as to cool and condense the miscellaneous tree branches and the branches by natural gas, and the condensed liquid is used as wood vinegar.
A preparation method of a liquid soil conditioner specifically comprises the following steps:
s1, adding the molasses liquid, the trace elements, copper sulfate, ammonium heptamolybdate and manganese sulfate into a reaction kettle, and heating to 60-75 ℃;
s2, adding the amino acid stock solution, fully reacting and chelating for 30-45 minutes, and cooling to 30-40 ℃;
and S3, adding wood vinegar and the compound microorganism bacteria, stirring for reacting for 40 minutes, cooling, filtering, inspecting and packaging.
Guangxi Angel yeast in the sweet liquid producing area; compound microbe bacteria producing area Henan Yangshao organism.
Molasses is a by-product of sugar production, sugar that cannot be crystallized and re-extracted. The total sugar content is 48%, and the total sugar content comprises sucrose and various reducing sugars. The molasses liquid is an organic compound, white crystal with molecular weight of 342.3, has optical activity but no mutarota, and has a molecular formula as follows: c12H22O11. It is formed by dehydrating one molecule of glucose and one molecule of fructose, is easily soluble in water and difficult to dissolve in ethanol, and has sweet taste second to fructose. The sugar content is more than 45%, the brix is more than 65%, the sugar content is 42-45%, the solid content is 50%, the total sugar content is as follows: 53.89%, sucrose 31, 76%, invert sugar 19.12%. The purity was 60.78. Non-fermentable sugars: 4.3 percent. Non-fermentable sugars/whole sugars: 7.55 percent. Colloid: 8.12 percent. Acidity: 10.2 sulfated Ash: 10.26 percent. Total nitrogen amount: 0.475. phosphoric acid (P)205) Percent: 0.130. the cane molasses liquid and the cane molasses residues are mainly applied to the industries of edible alcohol, monosodium glutamate, yeast, caramel pigment, feed and the like, are widely used as raw materials, and are main raw materials of the product. The effects are three: firstly, humic acid and fulvic acid in the product are generated after the special screened strains are subjected to high-activity treatment in a biological fermentation mode, so that the content of biochemical fulvic acid is increased to about 90%, the development of crop root systems can be effectively promoted, the activity of enzymes in crops is enhanced, and the absorption of fertilizers is increased; secondly, it is rich in unknown biological factor [ UGF]The humic acid is characterized by being not possessed by other coal-derived humic acid and coal-derived fulvic acid, is composed of natural hormones, natural enzymes, composite small peptides, functional proteins and the like, can stimulate and promote the secretion of crop growth hormone, and has the stimulation effect similar to artificially synthesized hormones such as composite sodium nitrophenolate, naphthylacetic acid and the like on crops(ii) a And thirdly, the high-content organic matter (more than 30 percent) belongs to decomposed organic matter generated in the biological fermentation process, and is different from 'raw' organic matter on the market, so that the main raw material has more practical effects on the aspects of improving the soil environment, promoting the absorption of crops to chemical fertilizers and the like.
The wood vinegar is natural plant material extracted by biochemical high and new technology, and the main components of the product are acetic acid, phenols and water, wherein the organic matter component acetic acid accounts for more than 10%. The product has strong bactericidal and antibacterial functions at high concentration; can inhibit the propagation of mixed bacteria at low concentration, and has antibacterial and insect-proof effects. Wood vinegar can neutralize nitrogen and sulfur compounds and is used as deodorant; the wood vinegar contains a plurality of phenolic substances which can sterilize, disinfect and avoid pests and is used as a disinfectant and insect repellent. Has been widely used in organic agriculture cultivation in developed countries. Pyroligneous acid is also used in many applications. Firstly, the wood vinegar liquid is sprayed in the soil for improving the soil, so that the damping off of seeds can be prevented, and the wood vinegar liquid can also be used as a disinfectant of the soil. The bamboo vinegar liquid applied in the soil can effectively inhibit the propagation of microorganisms which hinder the growth of plants and can kill pests such as root nodule nematodes and the like. And secondly, the plant growth regulator wood vinegar can promote the growth of vegetables, fruit trees, flowers, rice, lawns and other plants. Thirdly, the wood vinegar can also be used for preparing fertilizers, inhibiting the growth of weeds, reducing the pesticide dosage, and insect pest repellents and the like.
The wood vinegar is prepared by stewing various miscellaneous tree branches, branches cut off from an orchard and the like in a charcoal kiln to generate smoke so that natural gas is condensed into liquid, and the wood vinegar is good in quality, but coniferous trees with high resin content, casuarina equisetifolia and waste furniture with paint cannot be used. The liquid obtained by condensation is crude wood vinegar, and can be used after being refined to remove undesirable components. The main component of wood vinegar is vinegar, and in addition, there are more than one hundred other components, so the effect is almost the same as that of vinegar, but the effect is different mainly due to the difference of added nutrients or natural pesticides. The main effects are as follows: (1) the vitality of the roots and the leaves of the crops is enhanced, the aging is slowed down, the acidity of the fruits is reduced, the storage time of the fruits is prolonged, and the flavor is improved. (2) Preventing and controlling some plant diseases and insect pests on soil and leaves and promoting the propagation of beneficial microorganisms in the soil.
Compounding trace elements: 16 elements necessary for plant growth and development are as follows: carbon, hydrogen, oxygen, nitrogen (N), phosphorus (P), sulfur (S), potassium (k), calcium (Ca), magnesium (Mg), iron (Fe), zinc (Zn), copper (Cu), molybdenum (Mo), boron (B), and chlorine (Rn). Nine elements such as carbon, hydrogen, oxygen, nitrogen, phosphorus, sulfur, potassium, calcium, magnesium and the like are called macroelements due to the fact that plants absorb more; the 7 elements of iron, manganese (Mn), zinc, copper, molybdenum, boron, chlorine, etc. are called trace elements because of their low absorption by plants. The composite trace elements are the general names of the above 7 elements. For crops, macroelements or microelements are important as well, but the macroelements or the microelements are not essential. Even if a trace element is absent, it may affect a physiological function and lead to a reduction in yield, although it is required in a small amount. Since crops are planted on the land for a long time and the products are continuously taken away, the fertility of the soil is necessarily gradually reduced, and the soil contains less and less nutrients. In order to help farmers to obtain high and stable yield in successive years, various nutrients required for the growth and development of crops must be supplemented in time.
The amino acid is a compound in which a hydrogen atom on a carbon atom of a carboxylic acid is substituted with an amino group, and the amino acid molecule contains both amino and carboxyl functional groups. Amino acids, like hydroxy acids, can be classified as α -, β -, γ -, w-amino acids according to the position of the amino group attached to the carbon chain, but the amino acids obtained after proteolysis are all α -amino acids, and only twenty, which are the basic units constituting proteins. Amino acids are the basic substances that constitute proteins required for animal nutrition. Is an organic compound containing a basic amino group and an acidic carboxyl group. The amino group attached to the alpha-carbon is an alpha-amino acid. The majority of the amino acids that make up a protein are alpha-amino acids. The nutrition proportion of the soil is balanced, the using amount of the fertilizer is reduced, and the soil is prevented from hardening.
A compound microbial preparation is a microbial preparation prepared from two or more than two microbial strains which are not antagonistic to each other. The microbial inoculum generally has the excellent characteristics of complete species, reasonable compatibility, strong functionality, high economic benefit and the like. The product adopts three concentrated bacillus subtilis strains as main strains, matches bacillus licheniformis, trichoderma harzianum and bacillus polymyxa as main compound microbial inoculum, and is a compound microbial inoculum which is produced by specially adding mineral potassium fulvate and micromolecular amino acid through full fermentation. The composite microbial bacteria are at least one of phosphate solubilizing bacteria powder, potassium solubilizing bacteria powder or photosynthetic bacteria powder, the number of effective bacteria in the phosphate solubilizing bacteria is not less than 5 hundred million/gram, the number of effective bacteria in the potassium solubilizing bacteria is not less than 5 hundred million/gram, and the number of effective bacteria in the photosynthetic bacteria is not less than 5 hundred million/gram.
Although only the preferred embodiments of the present invention have been described in detail, the present invention is not limited to the above embodiments, and various changes can be made without departing from the spirit of the present invention within the knowledge of those skilled in the art, and all changes are encompassed in the scope of the present invention.
Claims (5)
1. The liquid soil conditioner is characterized by comprising the following raw materials in percentage by mass: 30-38% of molasses liquid; 28-36% of wood vinegar; 32-36% of amino acid stock solution; trace elements: 1-2% of chelated zinc, 1-2% of chelated iron and 1-2% of sodium octaborate tetrahydrate; 1.2 to 1.5 percent of compound microorganism bacteria; copper sulfate, ammonium heptamolybdate and manganese sulfate in balance; the ratio of the copper sulfate to the ammonium heptamolybdate to the manganese sulfate is 2:1: 1.
2. A liquid soil conditioner according to claim 1 wherein: the composite microbial bacteria are at least one of phosphate solubilizing bacteria powder, potassium solubilizing bacteria powder or photosynthetic bacteria powder, the number of effective bacteria in the phosphate solubilizing bacteria is not less than 5 hundred million/gram, the number of effective bacteria in the potassium solubilizing bacteria is not less than 5 hundred million/gram, and the number of effective bacteria in the photosynthetic bacteria is not less than 5 hundred million/gram.
3. A liquid soil conditioner according to claim 1 wherein: the pyroligneous liquor comprises acetic acid, phenols and water, wherein the organic matter component acetic acid accounts for more than 10%.
4. A liquid soil conditioner according to claim 1 or 3, wherein: the wood vinegar is prepared by stewing miscellaneous tree branches and branches in a charcoal kiln to generate smoke so as to cool and condense the miscellaneous tree branches and the branches by natural gas, and the condensed liquid is used as wood vinegar.
5. The preparation method of the liquid soil conditioner is characterized by comprising the following steps:
s1, adding the molasses liquid, the trace elements, copper sulfate, ammonium heptamolybdate and manganese sulfate into a reaction kettle, and heating to 60-75 ℃;
s2, adding the amino acid stock solution, fully reacting and chelating for 30-45 minutes, and cooling to 30-40 ℃;
and S3, adding wood vinegar and the compound microorganism bacteria, stirring for reacting for 40 minutes, cooling, filtering, inspecting and packaging.
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| CN202011065289.7A CN112174749A (en) | 2020-09-30 | 2020-09-30 | Liquid soil conditioner and preparation method thereof |
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| CN202011065289.7A CN112174749A (en) | 2020-09-30 | 2020-09-30 | Liquid soil conditioner and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN113632612A (en) * | 2021-09-10 | 2021-11-12 | 西安秦衡生态农业科技有限公司 | Method for quickly and efficiently improving saline-alkali soil |
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Application publication date: 20210105 |
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