CN111971822A - 用于锂离子电池的正极材料的生产方法 - Google Patents

用于锂离子电池的正极材料的生产方法 Download PDF

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Publication number
CN111971822A
CN111971822A CN201980022125.5A CN201980022125A CN111971822A CN 111971822 A CN111971822 A CN 111971822A CN 201980022125 A CN201980022125 A CN 201980022125A CN 111971822 A CN111971822 A CN 111971822A
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positive electrode
producing
metal
lithium
material according
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Chinese (zh)
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邹锋
刘洋
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Tesla Inc
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Springbauer International
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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/52—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
    • H01M4/525—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G53/00—Compounds of nickel
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G53/00—Compounds of nickel
    • C01G53/80—Compounds containing nickel, with or without oxygen or hydrogen, and containing one or more other elements
    • C01G53/82—Compounds containing nickel, with or without oxygen or hydrogen, and containing two or more other elements
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G53/00—Compounds of nickel
    • C01G53/40—Complex oxides containing nickel and at least one other metal element
    • C01G53/42—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/131—Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/485—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/50—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
    • H01M4/505—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/50—Solid solutions
    • C01P2002/52—Solid solutions containing elements as dopants
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/50—Solid solutions
    • C01P2002/52—Solid solutions containing elements as dopants
    • C01P2002/54—Solid solutions containing elements as dopants one element only
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
    • C01P2002/72—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by d-values or two theta-values, e.g. as X-ray diagram
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/01—Particle morphology depicted by an image
    • C01P2004/03—Particle morphology depicted by an image obtained by SEM
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/30—Particle morphology extending in three dimensions
    • C01P2004/32—Spheres
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/51—Particles with a specific particle size distribution
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/60—Particles characterised by their size
    • C01P2004/61—Micrometer sized, i.e. from 1-100 micrometer
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/11—Powder tap density
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/40—Electric properties
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M2004/026—Electrodes composed of, or comprising, active material characterised by the polarity
    • H01M2004/028—Positive electrodes
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

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  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)
  • Secondary Cells (AREA)
CN201980022125.5A 2018-04-04 2019-04-03 用于锂离子电池的正极材料的生产方法 Pending CN111971822A (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201862652516P 2018-04-04 2018-04-04
US62/652,516 2018-04-04
PCT/CA2019/050403 WO2019191837A1 (en) 2018-04-04 2019-04-03 Method to produce cathode materials for li-ion batteries

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CN111971822A true CN111971822A (zh) 2020-11-20

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US (2) US11909041B2 (https=)
EP (1) EP3776698A4 (https=)
JP (2) JP7480052B2 (https=)
KR (2) KR20240114783A (https=)
CN (1) CN111971822A (https=)
CA (1) CA3092269A1 (https=)
WO (1) WO2019191837A1 (https=)

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CA3225483A1 (en) 2021-07-16 2023-01-19 Thorsten BEIERLING Method for making precursors of cathode active materials for lithium ion batteries
FI4405303T3 (fi) 2021-09-21 2025-10-22 Basf Se Menetelmä litiumioniakkujen katodiaktiivisten materiaalien esiasteiden valmistamiseksi
KR102430686B1 (ko) * 2021-12-28 2022-08-10 (주)에코프로머티리얼즈 황산니켈의 습식제련 회수방법
US20230378461A1 (en) * 2022-05-23 2023-11-23 Rivian Ip Holdings, Llc Coating process for cathode materials for rechargeable batteries
CN115465899B (zh) * 2022-09-14 2023-09-15 陕西红马科技有限公司 一种多冠状多元素球形包覆型前驱体及其制备方法、化学包覆修饰产品及方法
EP4365137A1 (en) 2022-11-02 2024-05-08 Basf Se Process for making an oxide of manganese
WO2025045774A1 (en) 2023-08-31 2025-03-06 Basf Se Process for making precursors of cathode active materials for lithium-ion batteries
WO2025125012A1 (en) 2023-12-12 2025-06-19 Basf Se Process for making a coated cathode active material, and coated cathode active material
EP4707244A1 (en) 2024-09-05 2026-03-11 Basf Se Process for making precursors of cathode active materials for lithium-ion batteries

Citations (9)

* Cited by examiner, † Cited by third party
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US5264201A (en) * 1990-07-23 1993-11-23 Her Majesty The Queen In Right Of The Province Of British Columbia Lithiated nickel dioxide and secondary cells prepared therefrom
US5447707A (en) * 1992-06-15 1995-09-05 Inco Limited Process for producing nickel hydroxide
US5824283A (en) * 1997-04-28 1998-10-20 Inco Limited Process for producing nickel hydroxide from elemental nickel
CN1255106A (zh) * 1997-05-07 2000-05-31 富士化学工业株式会社 尖晶石型锂锰复合氧化物的新颖制造方法及蓄电池用的正极活性物质
US20040223905A1 (en) * 2003-05-06 2004-11-11 Inco Limited Low temperature lithiation of mixed hydroxides
US20120028128A1 (en) * 2009-03-18 2012-02-02 Santoku Corporation All-solid-state lithium battery
CN105027335A (zh) * 2013-01-30 2015-11-04 住友金属矿山株式会社 镍钴复合氢氧化物和其制造方法
CN106384813A (zh) * 2016-10-14 2017-02-08 中国科学院青岛生物能源与过程研究所 一种锂离子电池用正极材料的快速合成方法
CN107636866A (zh) * 2015-11-30 2018-01-26 株式会社Lg化学 二次电池用正极活性材料和包含其的二次电池

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5264201A (en) * 1990-07-23 1993-11-23 Her Majesty The Queen In Right Of The Province Of British Columbia Lithiated nickel dioxide and secondary cells prepared therefrom
US5447707A (en) * 1992-06-15 1995-09-05 Inco Limited Process for producing nickel hydroxide
US5824283A (en) * 1997-04-28 1998-10-20 Inco Limited Process for producing nickel hydroxide from elemental nickel
JPH10324524A (ja) * 1997-04-28 1998-12-08 Inco Ltd 元素状ニッケルから水酸化ニッケルを製造する方法
CN1255106A (zh) * 1997-05-07 2000-05-31 富士化学工业株式会社 尖晶石型锂锰复合氧化物的新颖制造方法及蓄电池用的正极活性物质
US20040223905A1 (en) * 2003-05-06 2004-11-11 Inco Limited Low temperature lithiation of mixed hydroxides
US20120028128A1 (en) * 2009-03-18 2012-02-02 Santoku Corporation All-solid-state lithium battery
CN105027335A (zh) * 2013-01-30 2015-11-04 住友金属矿山株式会社 镍钴复合氢氧化物和其制造方法
CN107636866A (zh) * 2015-11-30 2018-01-26 株式会社Lg化学 二次电池用正极活性材料和包含其的二次电池
CN106384813A (zh) * 2016-10-14 2017-02-08 中国科学院青岛生物能源与过程研究所 一种锂离子电池用正极材料的快速合成方法

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US11909041B2 (en) 2024-02-20
EP3776698A1 (en) 2021-02-17
KR20200138238A (ko) 2020-12-09
US20210013507A1 (en) 2021-01-14
WO2019191837A1 (en) 2019-10-10
JP2024105339A (ja) 2024-08-06
CA3092269A1 (en) 2019-10-10
US20240213469A1 (en) 2024-06-27
JP7830539B2 (ja) 2026-03-16
KR102686534B1 (ko) 2024-07-18
JP7480052B2 (ja) 2024-05-09
KR20240114783A (ko) 2024-07-24
EP3776698A4 (en) 2022-01-19
JP2021517707A (ja) 2021-07-26

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