CN111250171B - 一种腈纶基光催化材料的制备方法 - Google Patents
一种腈纶基光催化材料的制备方法 Download PDFInfo
- Publication number
- CN111250171B CN111250171B CN202010114672.0A CN202010114672A CN111250171B CN 111250171 B CN111250171 B CN 111250171B CN 202010114672 A CN202010114672 A CN 202010114672A CN 111250171 B CN111250171 B CN 111250171B
- Authority
- CN
- China
- Prior art keywords
- fiber
- acrylic fiber
- acrylic
- zif
- 20min
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 229920002972 Acrylic fiber Polymers 0.000 title claims abstract description 39
- 230000001699 photocatalysis Effects 0.000 title claims abstract description 33
- 239000000463 material Substances 0.000 title claims abstract description 31
- 238000002360 preparation method Methods 0.000 title claims abstract description 9
- 238000000034 method Methods 0.000 claims abstract description 19
- 238000011065 in-situ storage Methods 0.000 claims abstract description 9
- 239000000835 fiber Substances 0.000 claims abstract description 8
- 239000013154 zeolitic imidazolate framework-8 Substances 0.000 claims abstract 5
- MFLKDEMTKSVIBK-UHFFFAOYSA-N zinc;2-methylimidazol-3-ide Chemical compound [Zn+2].CC1=NC=C[N-]1.CC1=NC=C[N-]1 MFLKDEMTKSVIBK-UHFFFAOYSA-N 0.000 claims abstract 5
- 238000001035 drying Methods 0.000 claims description 15
- 238000006243 chemical reaction Methods 0.000 claims description 14
- 238000009210 therapy by ultrasound Methods 0.000 claims description 14
- 239000002657 fibrous material Substances 0.000 claims description 12
- 238000010438 heat treatment Methods 0.000 claims description 12
- 239000004744 fabric Substances 0.000 claims description 10
- 230000001590 oxidative effect Effects 0.000 claims description 8
- SLCITEBLLYNBTQ-UHFFFAOYSA-N CO.CC=1NC=CN1 Chemical compound CO.CC=1NC=CN1 SLCITEBLLYNBTQ-UHFFFAOYSA-N 0.000 claims description 7
- ZJLKZLGZJOXUSX-UHFFFAOYSA-N CO.O.O.O.O.O.O.[N+](=O)([O-])[O-].[Zn+2].[N+](=O)([O-])[O-] Chemical compound CO.O.O.O.O.O.O.[N+](=O)([O-])[O-].[Zn+2].[N+](=O)([O-])[O-] ZJLKZLGZJOXUSX-UHFFFAOYSA-N 0.000 claims description 7
- 239000003795 chemical substances by application Substances 0.000 claims description 7
- 238000001816 cooling Methods 0.000 claims description 7
- 238000009991 scouring Methods 0.000 claims description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 7
- 230000003647 oxidation Effects 0.000 claims description 6
- 238000007254 oxidation reaction Methods 0.000 claims description 6
- ONDPHDOFVYQSGI-UHFFFAOYSA-N zinc nitrate Chemical compound [Zn+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ONDPHDOFVYQSGI-UHFFFAOYSA-N 0.000 claims description 6
- 238000005406 washing Methods 0.000 claims description 5
- LXBGSDVWAMZHDD-UHFFFAOYSA-N 2-methyl-1h-imidazole Chemical compound CC1=NC=CN1 LXBGSDVWAMZHDD-UHFFFAOYSA-N 0.000 claims description 3
- 239000012535 impurity Substances 0.000 claims description 3
- 239000000975 dye Substances 0.000 abstract description 34
- 238000001179 sorption measurement Methods 0.000 abstract description 9
- 239000002351 wastewater Substances 0.000 abstract description 6
- 238000004043 dyeing Methods 0.000 abstract description 4
- 239000000126 substance Substances 0.000 abstract description 4
- 238000004065 wastewater treatment Methods 0.000 abstract description 4
- 230000008569 process Effects 0.000 abstract description 3
- 239000002253 acid Substances 0.000 abstract description 2
- 230000009286 beneficial effect Effects 0.000 abstract description 2
- 239000013078 crystal Substances 0.000 abstract 1
- 230000001788 irregular Effects 0.000 abstract 1
- 229920002521 macromolecule Polymers 0.000 abstract 1
- 238000007146 photocatalysis Methods 0.000 description 9
- 230000000694 effects Effects 0.000 description 7
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 5
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 4
- HGINCPLSRVDWNT-UHFFFAOYSA-N acrylaldehyde Natural products C=CC=O HGINCPLSRVDWNT-UHFFFAOYSA-N 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 238000013033 photocatalytic degradation reaction Methods 0.000 description 4
- 238000011160 research Methods 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 239000004753 textile Substances 0.000 description 4
- 229910052724 xenon Inorganic materials 0.000 description 4
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 229920006286 oxidized acrylic fiber Polymers 0.000 description 2
- 239000002957 persistent organic pollutant Substances 0.000 description 2
- 239000011941 photocatalyst Substances 0.000 description 2
- 229910010413 TiO 2 Inorganic materials 0.000 description 1
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- 239000003463 adsorbent Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- -1 high safety Substances 0.000 description 1
- 238000005286 illumination Methods 0.000 description 1
- JBFYUZGYRGXSFL-UHFFFAOYSA-N imidazolide Chemical compound C1=C[N-]C=N1 JBFYUZGYRGXSFL-UHFFFAOYSA-N 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000010842 industrial wastewater Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000012621 metal-organic framework Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical group [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/1691—Coordination polymers, e.g. metal-organic frameworks [MOF]
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
- B01J35/39—Photocatalytic properties
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/28—Treatment of water, waste water, or sewage by sorption
- C02F1/285—Treatment of water, waste water, or sewage by sorption using synthetic organic sorbents
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/30—Treatment of water, waste water, or sewage by irradiation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
- B01J2531/0238—Complexes comprising multidentate ligands, i.e. more than 2 ionic or coordinative bonds from the central metal to the ligand, the latter having at least two donor atoms, e.g. N, O, S, P
- B01J2531/0241—Rigid ligands, e.g. extended sp2-carbon frameworks or geminal di- or trisubstitution
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/20—Complexes comprising metals of Group II (IIA or IIB) as the central metal
- B01J2531/26—Zinc
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/30—Organic compounds
- C02F2101/308—Dyes; Colorants; Fluorescent agents
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2305/00—Use of specific compounds during water treatment
- C02F2305/10—Photocatalysts
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W10/00—Technologies for wastewater treatment
- Y02W10/30—Wastewater or sewage treatment systems using renewable energies
- Y02W10/37—Wastewater or sewage treatment systems using renewable energies using solar energy
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Water Supply & Treatment (AREA)
- Hydrology & Water Resources (AREA)
- Environmental & Geological Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Inorganic Chemistry (AREA)
- Catalysts (AREA)
Abstract
本发明公开了一种腈纶基光催化材料的制备方法,将具有吸附和光催化性能的ZIF‑8原位生长在腈纶纤维上,再进一步氧化制得一种吸附性能好、能在可见光下催化分解染料的功能材料,用于印染废水的脱色。腈纶纤维的大分子呈不规则的螺旋形构象,且没有严格的晶区,分子中含酸性基团,有利于ZIF‑8在纤维上的生长。腈纶预氧化后,具有优良的热传导性,耐磨及化学稳定性,在废水处理过程中,使用寿命长。
Description
技术领域
本发明涉及功能纤维材料制备技术领域,具体为一种腈纶基光催化材料的制备方法。
背景技术
印染行业作为纺织工业重要的组成部分,是纺织品生产链中产品深加工、提升品质、功能和价值的重要环节,是高附加值服装面料、家用纺织品和产业用纺织品等产业的重要技术支撑。但印染废水因有机物含量高,色度大,水质变化大,成分复杂,属于难处理的工业废水之一。针对印染废水中由染料而引起的色度问题,通常依靠吸附或光催化技术等方法来去除。活性炭作为环境友好型吸附剂,原料充足且安全性高,耐酸碱、耐热、不溶于水和有机溶剂、易再生等优点,对水中溶解的染料分子有一定的吸附能力。但是由于活性炭的比表面积小,孔容小,微孔分布过宽和吸附选择性能差等缺点,加上其表面官能团及电化学性质的一些限制,使其对染料的吸附去除作用有限。光催化技术是目前研究较多的一中染料脱色技术。它利用光照下产生的能量,促使催化剂或氧化物发生能级跃迁,由此产生的自由基或空轨道具有强氧化性,可与废水中的有机污染物发生反应,可使有机污染物更彻底地降解,进而达到去除污染物的目的。常用的光催化剂有TiO2、Fe2O3、WO3、ZnO等。然而,这些光催化剂要在紫外光下才能发挥作用,在可见光下效率低,其实际应用也受到严重限制。
沸石咪唑酯骨架材料(ZIF-8)具有分子筛结构和微孔结构,是一种典型的金属骨架材料(MOFs),因其热稳定性和化学稳定性好,其吸附和光催化性能近年来被广泛研究,但粉末状ZIF-8在废水处理中面临着回收再利用困难的问题,将其负载在纤维上,可有效解决这问题,但纤维本身的性能既影响ZIF-8的负载量,也会影响其使用寿命。
发明内容
本发明的目的在于提供一种腈纶基光催化材料的制备方法,以解决上述背景技术中提出的问题。
为实现上述目的,本发明提供如下技术方案:一种腈纶基光催化材料的制备方法,包括以下步骤:
A、腈纶纤维预处理:将纤维材料进行除杂预处理;
B、腈纶纤维上原位生长ZIF-8:采用原位生长法将ZIF-8负载到预处理的纤维上;
C、氧化:将负载ZIF-8的腈纶纤维进行氧化处理。
优选的,所述步骤A具体方法为:将腈纶纤维用0.5-1g/L精练剂RUCOGEN WBL按浴比10:1在50-60℃处理10-15min,水洗后烘干。
优选的,所述步骤B具体方法为:将步骤A预处理的腈纶纤维置于0.05-0.15M的六水合硝酸锌甲醇溶液中,在50-60℃超声10-20min,加入0.2-0.4M 2-甲基咪唑甲醇溶液,其中硝酸锌溶液与2-甲基咪唑溶液的体积比为1:1,在50-60℃超声10-20min,升温至70-80℃反应3-4h,反应结束后将纤维材料取出,烘干。
优选的,所述步骤C具体方法为:将步骤B得到的纤维材料置于马弗炉内,在有氧气氛下,升温至200-250℃,氧化40-60min,冷却后即得光催化材料。
优选的,所述腈纶为腈纶纱线或针织物。
优选的,水洗后烘干温度为70-80℃,时间为10-20min。
优选的,烘干温度为80-100℃,时间为12-20min。
与现有技术相比,本发明的有益效果是:
(1)本发明所提供的技术方案将金属骨架ZIF-8原位负载在腈纶上,再氧化制成一种光催化材料,该方法工艺简单,充分利用腈纶纤维的优异性能及ZIF-8对染料的吸附性能和光催化性能,使得光催化材料能有效吸附、降解有机染料,实现废水的脱色。
(2)将ZIF-8负载在腈纶纤维上,既可以解决粉末状ZIF-8在废水处理中难回收再利用的困难,又有利于ZIF-8在纤维上的生长,可以获得更高的脱色效果,而且氧化后的腈纶纤维,化学稳定性更好,应用前景广阔。
附图说明
图1为本发明流程图。
具体实施方式
下面将结合本发明实施例中的附图,对本发明实施例中的技术方案进行清楚、完整地描述,显然,所描述的实施例仅仅是本发明一部分实施例,而不是全部的实施例。基于本发明中的实施例,本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其他实施例,都属于本发明保护的范围。
请参阅图1,本发明提供一种技术方案:一种腈纶基光催化材料的制备方法,包括以下步骤:
A、腈纶纤维预处理:将纤维材料进行除杂预处理;
B、腈纶纤维上原位生长ZIF-8:采用原位生长法将ZIF-8负载到预处理的纤维上;
C、氧化:将负载ZIF-8的腈纶纤维进行氧化处理。
本发明中,步骤A具体方法为:将腈纶纤维用0.5-1g/L精练剂RUCOGEN WBL按浴比10:1在50-60℃处理10-15min,水洗后烘干,水洗后烘干温度为70-80℃,时间为10-20min。
本发明中,步骤B具体方法为:将步骤A预处理的腈纶纤维置于0.05-0.15M的六水合硝酸锌甲醇溶液中,在50-60℃超声10-20min,加入0.2-0.4M 2-甲基咪唑甲醇溶液,其中硝酸锌溶液与2-甲基咪唑溶液的体积比为1:1,在50-60℃超声10-20min,升温至70-80℃反应3-4h,反应结束后将纤维材料取出,烘干,烘干温度为80-100℃,时间为12-20min。
本发明中,步骤C具体方法为:将步骤B得到的纤维材料置于马弗炉内,在有氧气氛下,升温至200-250℃,氧化40-60min,冷却后即得光催化材料。
其中,腈纶为腈纶纱线或针织物。
实施例1:
将腈纶开司米用0.5g/L精练剂RUCOGEN WBL按浴比10:1在50℃处理10min,水洗后烘干。将0.5g经过预处理的腈纶开司米置于100mL浓度为0.05M的六水合硝酸锌甲醇溶液中,在50℃超声10min,加入100mL 0.2M 2-甲基咪唑甲醇溶液中,在50℃超声10min,升温至70℃反应3h,反应结束后将纤维材料取出,烘干。然后置于马弗炉内,在有氧气氛下,升温至200℃,氧化40min,冷却得光催化材料。
为了考察所制备的材料对染料的脱色效果,选择活性黑KN-B染料为研究对象,测定光催化对染料的脱色性能,测试条件为0.25g光催化材料,在1000W氙灯照射下,对50mL质量浓度为20mg/L的活性黑KN-B染料溶液在室温下进行光催化降解3h,测得染料的脱色率达到85%,重复使用3次后对染料的脱色率可达60%。
实施例2:
将腈纶开司米用0.5g/L精练剂RUCOGEN WBL按浴比10:1在50℃处理10min,水洗后烘干。将0.5g经过预处理的腈纶开司米置于100mL浓度为0.1M的六水合硝酸锌甲醇溶液中,在50℃超声10min,加入100mL 0.3M 2-甲基咪唑甲醇溶液中,在50℃超声20min,升温至80℃反应4h,反应结束后将纤维材料取出,烘干。然后置于马弗炉内,在有氧气氛下,升温至200℃,氧化60min,冷却得光催化材料。
为了考察所制备的材料对染料的脱色效果,选择活性黑KN-B染料为研究对象,测定光催化对染料的脱色性能,测试条件为0.25g光催化材料,在1000W氙灯照射下,对50mL质量浓度为20mg/L的活性黑KN-B染料溶液在室温下进行光催化降解3h,测得染料的脱色率达到88%,重复使用3次后对染料的脱色率可达64%。
实施例3:
将腈纶针织物用1g/L精练剂RUCOGEN WBL按浴比10:1在60℃处理15min,水洗后烘干。将0.5g经过预处理的腈纶织物置于150mL浓度为0.1M的六水合硝酸锌甲醇溶液中,在60℃超声10min,加入150mL 0.3M 2-甲基咪唑甲醇溶液中,在60℃超声10min,升温至70℃反应4h,反应结束后将织物取出,烘干。然后置于马弗炉内,在有氧气氛下,升温至250℃,氧化50min,冷却得光催化材料。
为了考察所制备的材料对染料的脱色效果,选择活性黑KN-B染料为研究对象,测定光催化对染料的脱色性能,测试条件为0.25g光催化材料,在1000W氙灯照射下,对50mL质量浓度为20mg/L的活性黑KN-B染料溶液在室温下进行光催化降解3h,测得染料的脱色率达到90%,重复使用3次后对染料的脱色率可达64%。
实施例4:
将腈纶针织物用1g/L精练剂RUCOGEN WBL按浴比10:1在60℃处理15min,水洗后烘干。将0.5g经过预处理的腈纶织物置于150mL浓度为0.15M的六水合硝酸锌甲醇溶液中,在60℃超声20min,加入150mL 0.4M 2-甲基咪唑甲醇溶液中,在60℃超声20min,升温至80℃反应4h,反应结束后将织物取出,烘干。然后置于马弗炉内,在有氧气氛下,升温至250℃,氧化60min,冷却得光催化材料。
为了考察所制备的材料对染料的脱色效果,选择活性黑KN-B染料为研究对象,测定光催化对染料的脱色性能,测试条件为0.25g光催化材料,在1000W氙灯照射下,对50mL质量浓度为20mg/L的活性黑KN-B染料溶液在室温下进行光催化降解3h,测得染料的脱色率达到95%,重复使用3次后对染料的脱色率可达67%。
综上所述,本发明所提供的技术方案将金属骨架ZIF-8原位负载在腈纶上,再氧化制成一种光催化材料,该方法工艺简单,充分利用腈纶纤维的优异性能及ZIF-8对染料的吸附性能和光催化性能,使得光催化材料能有效吸附、降解有机染料,实现废水的脱色;将ZIF-8负载在腈纶纤维上,既可以解决粉末状ZIF-8在废水处理中难回收再利用的困难,又有利于ZIF-8在纤维上的生长,可以获得更高的脱色效果,而且氧化后的腈纶纤维,化学稳定性更好,应用前景广阔。
尽管已经示出和描述了本发明的实施例,对于本领域的普通技术人员而言,可以理解在不脱离本发明的原理和精神的情况下可以对这些实施例进行多种变化、修改、替换和变型,本发明的范围由所附权利要求及其等同物限定。
Claims (1)
1.一种腈纶基光催化材料的制备方法,其特征在于:包括以下步骤:
A、腈纶纤维预处理:将纤维材料进行除杂预处理;
B、腈纶纤维上原位生长ZIF-8:采用原位生长法将ZIF-8负载到预处理的纤维上;
C、氧化:将负载ZIF-8的腈纶纤维进行氧化处理;
所述步骤A具体方法为:将腈纶纤维用0.5-1g/L精练剂RUCOGEN WBL按浴比10:1在50-60℃处理10-15min,水洗后烘干;
所述步骤B具体方法为:将步骤A预处理的腈纶纤维置于0.05-0.15M的六水合硝酸锌甲醇溶液中,在50-60℃超声10-20min,加入0.2-0.4M 2-甲基咪唑甲醇溶液,其中硝酸锌溶液与2-甲基咪唑溶液的体积比为1:1,在50-60℃超声10-20min,升温至70-80℃反应3-4h,反应结束后将纤维材料取出,烘干;
所述步骤C具体方法为:将步骤B得到的纤维材料置于马弗炉内,在有氧气氛下,升温至200-250℃,氧化40-60min,冷却后即得光催化材料;
所述腈纶为腈纶纱线或针织物;
水洗后烘干温度为70-80℃,时间为10-20min;
烘干温度为80-100℃,时间为12-20min。
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202010114672.0A CN111250171B (zh) | 2020-02-25 | 2020-02-25 | 一种腈纶基光催化材料的制备方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202010114672.0A CN111250171B (zh) | 2020-02-25 | 2020-02-25 | 一种腈纶基光催化材料的制备方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN111250171A CN111250171A (zh) | 2020-06-09 |
CN111250171B true CN111250171B (zh) | 2022-12-09 |
Family
ID=70942952
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN202010114672.0A Active CN111250171B (zh) | 2020-02-25 | 2020-02-25 | 一种腈纶基光催化材料的制备方法 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN111250171B (zh) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111905816A (zh) * | 2020-07-08 | 2020-11-10 | 武汉纺织大学 | 一种zif-8功能织物及其制备方法 |
CN113231029B (zh) * | 2021-05-28 | 2023-06-16 | 南通大学 | 一种具有高效脱色性能的活性炭纤维功能材料的制备方法 |
CN113713776A (zh) * | 2021-09-10 | 2021-11-30 | 天津工业大学 | 一种负载zif-67的羊毛织物的制备方法及其在印染废水中的应用 |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109499545A (zh) * | 2019-01-09 | 2019-03-22 | 长春工业大学 | 用于水相有机染料吸附的zif-8/碳纤维复合材料的制备方法 |
-
2020
- 2020-02-25 CN CN202010114672.0A patent/CN111250171B/zh active Active
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109499545A (zh) * | 2019-01-09 | 2019-03-22 | 长春工业大学 | 用于水相有机染料吸附的zif-8/碳纤维复合材料的制备方法 |
Non-Patent Citations (2)
Title |
---|
"Fabrication of zeolitic imidazolate framework-8 functional polyacrylonitrile nanofibrous mats for dye removal";Yifei Zhan et al.;《Journal of Polymer Research》;20190522;第26卷;摘要和第2页 * |
"腈纶的氧化处理及其耐酸和耐有机溶剂性能研究";季涛等;《产业用纺织品》;20061231(第2期);前言和第1.1-1.3节、2.1.3节 * |
Also Published As
Publication number | Publication date |
---|---|
CN111250171A (zh) | 2020-06-09 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN111250171B (zh) | 一种腈纶基光催化材料的制备方法 | |
Han et al. | Copper–iron bimetal modified PAN fiber complexes as novel heterogeneous Fenton catalysts for degradation of organic dye under visible light irradiation | |
CN107824210B (zh) | 一种氮掺杂介孔碳包裹的二氧化钛复合光催化剂及其制备方法和应用 | |
CN113333011B (zh) | 一种复合催化剂及其制备方法和应用 | |
CN111604082A (zh) | 一种载铁生物炭的制备方法、产品及其应用 | |
CN111617805B (zh) | 光Fenton催化剂、其制备方法、其应用及水处理剂 | |
CN111254707B (zh) | 一种负载Fe-MOF的活性炭纤维材料的制备方法 | |
CN110330091B (zh) | 基于光芬顿催化的磁性生物质功能炭纤维及其制备方法和应用 | |
CN110004705B (zh) | 一种具有高效光催化功能复合石墨烯的纤维织物制备方法 | |
CN105749893A (zh) | 一种表面负载纳米二氧化钛的改性活性炭纤维丝的制备方法 | |
CN111068715B (zh) | Ag/Bi2O3/CuBi2O4纳米纤维复合光催化剂的制备方法 | |
CN111558371B (zh) | 一种基于陶瓷基与碳基混合体作为载体的催化剂制备方法及配套的平板式臭氧氧化反应器 | |
CN105771947A (zh) | 一种石墨烯-纳米二氧化钛复合整理织物催化剂及其制备方法 | |
CN110368990B (zh) | 一种Cu系多金属氧酸盐-功能化氧化石墨烯纳米材料的制备方法及其应用 | |
CN115121240A (zh) | 一种多孔二氧化钛复合材料及其制备方法和应用 | |
CN103551204A (zh) | 一种多级层次孔结构的Fenton-like催化剂及其应用 | |
Zhai et al. | Lignin‐Derived Carbon Nanofibers Loaded with TiO2 Enables Efficient Photocatalysis | |
CN106824160A (zh) | 活性碳纤维膜负载ZnO光催化剂的制备方法 | |
CN111957320B (zh) | 一种催化降解水中污染物的负载催化剂过滤纤维及其制备与应用 | |
CN111318289B (zh) | 一种Bi-Bi5+/BiOBr自掺杂光催化剂及其制备方法 | |
CN110270347B (zh) | 一种基于等离子体处理的负载铁酸钙/硅酸银棉织物的制备方法 | |
CN114768825B (zh) | 一种工业废水催化氧化催化剂的制备方法 | |
CN114950572B (zh) | 一种室温下高效去除甲醛的负载型催化剂及其制备方法和应用 | |
CN110026192A (zh) | 一种用于印染废水降解的Cu/TiO2复合镀光催化剂的制备方法 | |
CN112742484B (zh) | 一种磷酸银光催化剂在棉织物表面负载的方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
GR01 | Patent grant | ||
GR01 | Patent grant | ||
TR01 | Transfer of patent right | ||
TR01 | Transfer of patent right |
Effective date of registration: 20231226 Address after: 226600 Group 2, Changfen Village, Duntou Town, Hai'an City, Nantong City, Jiangsu Province Patentee after: NANTONG JINYU SPINNING PLASTIC CO.,LTD. Address before: 226019 Jiangsu Province, Nantong City Chongchuan District sik Road No. 9 Patentee before: NANTONG University |