CN110983822A - 一种纱线涂料染色用涂料组合物 - Google Patents
一种纱线涂料染色用涂料组合物 Download PDFInfo
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Abstract
本发明公开了一种纱线涂料染色用涂料组合物,按照质量份数,其组成为:化合物(A)10~20份、化合物(B)5~10份、化合物(C)2~8份、化合物(D)2~5份、粘合剂0.2~1.2份、偶联剂0.05~0.5份、固色剂0.05~0.8份;本申请公开的纱线涂料染色用涂料组合物,其综合性能:固色率、耐摩擦、耐水洗和耐汗渍色牢度等方面完全满足印染需求。印染过程中,废水产生量少,减少环境污染。
Description
技术领域
属于染料领域,具体涉及一种纱线涂料染色用涂料组合物。
背景技术
涂料染色用涂料代替染料,依靠黏合剂及交联剂固着在织物上。与传统染色工艺相比,具有流程短、色谱广、成本低、能耗省、用水少、污水少等优点。新型涂料染色工艺的特点是,用湿摩擦牢度提高剂替代传统的黏合剂;采用纤维增深技术,使纤维带正电荷,无需高温焙烘,明显增强对涂料的吸附,从而提高涂料的上染率;涂料利用率比传统的黏合剂方法高20%~30%,使涂料染色、固着和柔软整理一步完成,改善了手感,解决了黏辊等问题。因此,采用新型涂料替代部分活性、还原染料,可以大大简化工艺,节能、节水、减少用料,基本达到零排放要求。
目前现有的染料综合性能,如固色率、耐摩擦、耐水洗和耐汗渍色牢度等方面总是不能同时完全满足印染要求,因此需要开发一种同时满足上述性能要求的涂料组合物。
发明内容
本发明所要解决的技术问题是:提供一种耐摩擦、耐水洗的纱线涂料染色用涂料组合物。
为解决上述技术问题,提供的技术方案是一种纱线涂料染色用涂料组合物,按照质量份数,其组成为:化合物(A)10~20份、化合物(B)5-10份、化合物(C)2~8份、化合物(D)2~5份;粘合剂0.2~1.2份,偶联剂0.05~0.5份,固色剂0.05~0.8份;
所述的化合物(A)的结构式为:
所述的化合物(B)的结构式为:
所述的化合物(C)的结构式为:
所述的化合物(D)的结构式为:
其中,n=2,X=Br;n=6,X=Cl;n=10,X=Cl。
所述的粘合剂为水性聚氨酯-丙烯酸酯粘合剂。
所述的固色剂为环氧氯丙烷与三甲胺的聚合物、1-2烯咪唑的季胺化聚合物、二甲基二烯丙基铵盐聚合物、2-异丁烯氧乙基三甲基胺偏硫酸聚合物中的一种或几种。
所述的偶联剂为铝-锆有机金属络合物偶联剂。
优选的,所述的纱线涂料染色用涂料组合物,其特征在于:按照质量份数,其组成为:化合物(A)10份、化合物(B)5份、化合物(C)4份、化合物(D)2份、粘合剂0.8份、偶联剂0.3份、固色剂0.3份。
优选的,所述的纱线涂料染色用涂料组合物,其特征在于:按照质量份数,其组成为:化合物(A)20份、化合物(B)8份、化合物(C)5份、化合物(D)3份、粘合剂0.3、偶联剂0.2、固色剂0.5份。
有益效果:本申请公开的纱线涂料染色用涂料组合物,其综合性能:固色率、耐摩擦、耐水洗和耐汗渍色牢度等方面完全满足印染需求。印染过程中,废水产生量少,减少污染。
具体实施方式
实施例1
一种纱线涂料染色用涂料组合物,按照质量份数,其组成为:按照质量份数,其组成为:化合物(A)10份、化合物(B)5份、化合物(C)4份、化合物(D)2份、水性聚氨酯-丙烯酸酯粘合剂0.8份、铝-锆有机金属络合物偶联剂0.3份、1-2烯咪唑的季胺化聚合物0.3份。
所述的化合物(A)的结构式为:
所述的化合物(B)的结构式为:
所述的化合物(C)的结构式为:
所述的化合物(D)的结构式为:
其中,其中,n=6,X=Cl。
实施例2
一种纱线涂料染色用涂料组合物,按照质量份数,其组成为:按照质量份数,其组成为:化合物(A)20份、化合物(B)8份、化合物(C)5份、化合物(D)3份、水性聚氨酯-丙烯酸酯粘合剂0.3、铝-锆有机金属络合物偶联剂0.2、2-异丁烯氧乙基三甲基胺偏硫酸聚合物0.5份。
所述的化合物(A)的结构式为:
所述的化合物(B)的结构式为:
所述的化合物(C)的结构式为:
所述的化合物(D)的结构式为:
其中,n=2,X=Br。
利用实施例1、实施例2纱线涂料染色用涂料组合物,对棉和羊毛混纺比50∶50纱线染色,染色浴比1∶10,助剂的选用、用量,染料和助剂的加入方式、时间、升温速率和保温时间严格按一浴两步法的常规染色工艺曲线操作。
Claims (6)
2.根据权利要求1所述的一种纱线涂料染色用涂料组合物,其特征在于:所述的粘合剂为水性聚氨酯-丙烯酸酯粘合剂。
3.根据权利要求1所述的一种纱线涂料染色用涂料组合物,其特征在于:所述的固色剂为环氧氯丙烷与三甲胺的聚合物、1-2烯咪唑的季胺化聚合物、二甲基二烯丙基铵盐聚合物、2-异丁烯氧乙基三甲基胺偏硫酸聚合物中的一种或几种。
4.根据权利要求1所述的一种纱线涂料染色用涂料组合物,其特征在于:所述的偶联剂为铝-锆有机金属络合物偶联剂。
5.根据权利要求1-4任一项所述的一种纱线涂料染色用涂料组合物,其特征在于:按照质量份数,其组成为:化合物(A)10份、化合物(B)5份、化合物(C)4份、化合物(D)2份、粘合剂0.8份、偶联剂0.3份、固色剂0.3份。
6.根据权利要求1-4任一项所述述的一种纱线涂料染色用涂料组合物,其特征在于:按照质量份数,其组成为:化合物(A)20份、化合物(B)8份、化合物(C)5份、化合物(D)3份、粘合剂0.3、偶联剂0.2、固色剂0.5份。
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