CN1109009C - 脂族醇的制备方法 - Google Patents

脂族醇的制备方法 Download PDF

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Publication number
CN1109009C
CN1109009C CN98805932A CN98805932A CN1109009C CN 1109009 C CN1109009 C CN 1109009C CN 98805932 A CN98805932 A CN 98805932A CN 98805932 A CN98805932 A CN 98805932A CN 1109009 C CN1109009 C CN 1109009C
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CN
China
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acid
catalyzer
hydrogenation
described method
methyl
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Expired - Fee Related
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CN98805932A
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Chinese (zh)
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CN1259112A (zh
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R·菲斯切尔
R·平考斯
J·沃尔弗-多玲
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BASF SE
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BASF SE
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/147—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof
    • C07C29/149—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof with hydrogen or hydrogen-containing gases
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/656—Manganese, technetium or rhenium
    • B01J23/6567—Rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
  • Furan Compounds (AREA)
CN98805932A 1997-05-16 1998-05-12 脂族醇的制备方法 Expired - Fee Related CN1109009C (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19720657.3 1997-05-16
DE19720657A DE19720657A1 (de) 1997-05-16 1997-05-16 Verfahren zur Herstellung von aliphatischen Alkoholen

Publications (2)

Publication Number Publication Date
CN1259112A CN1259112A (zh) 2000-07-05
CN1109009C true CN1109009C (zh) 2003-05-21

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ID=7829721

Family Applications (1)

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CN98805932A Expired - Fee Related CN1109009C (zh) 1997-05-16 1998-05-12 脂族醇的制备方法

Country Status (7)

Country Link
US (1) US6204417B1 (enExample)
EP (1) EP0983219B1 (enExample)
JP (1) JP4138025B2 (enExample)
CN (1) CN1109009C (enExample)
DE (2) DE19720657A1 (enExample)
ES (1) ES2187029T3 (enExample)
WO (1) WO1998052891A1 (enExample)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100450984C (zh) * 2004-04-02 2009-01-14 花王株式会社 脂肪醇的制造方法

Families Citing this family (53)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB0210143D0 (en) 2002-05-02 2002-06-12 Davy Process Techn Ltd Process
DE10241292A1 (de) * 2002-09-04 2004-03-18 Basf Ag Verfahren zur Herstellung optisch aktiver 2-Amino-, 2-Hydroxy oder 2-Alkoxy-1-alkohole
US20080248540A1 (en) * 2007-04-03 2008-10-09 The Ohio State University Methods of producing butanol
KR101588052B1 (ko) * 2008-03-28 2016-01-25 에스케이이노베이션 주식회사 발효액으로부터 부티르산을 추출하고 부티르산을 바이오연료로 화학적으로 전환하는 방법
US8637714B2 (en) 2008-07-31 2014-01-28 Celanese International Corporation Process for producing ethanol over catalysts containing platinum and palladium
US8357519B2 (en) * 2008-11-19 2013-01-22 The Ohio State University Methods and processes for producing esters
CN102300635B (zh) * 2009-10-26 2014-10-29 国际人造丝公司 用于通过将乙酸加氢生产乙醇的包含在含硅载体上的铂-锡的催化剂
US8658843B2 (en) 2011-10-06 2014-02-25 Celanese International Corporation Hydrogenation catalysts prepared from polyoxometalate precursors and process for using same to produce ethanol while minimizing diethyl ether formation
WO2013056268A2 (en) 2011-10-06 2013-04-18 Celanese International Corporation Hydrogenation catalysts prepared from polyoxometalate precursors and process for using same to produce ethanol
US8703868B2 (en) 2011-11-28 2014-04-22 Celanese International Corporation Integrated process for producing polyvinyl alcohol or a copolymer thereof and ethanol
US8637715B2 (en) 2011-12-21 2014-01-28 Celanese International Corporation Catalysts comprising secondary noble metals and process for producing ethanol
US9233899B2 (en) 2011-12-22 2016-01-12 Celanese International Corporation Hydrogenation catalysts having an amorphous support
CN103282333A (zh) 2011-12-22 2013-09-04 国际人造丝公司 使用具有无定形载体的加氢催化剂的乙醇方法
US8575406B2 (en) 2011-12-22 2013-11-05 Celanese International Corporation Catalysts having promoter metals and process for producing ethanol
US9000234B2 (en) 2011-12-22 2015-04-07 Celanese International Corporation Calcination of modified support to prepare hydrogenation catalysts
US8455702B1 (en) 2011-12-29 2013-06-04 Celanese International Corporation Cobalt and tin catalysts for producing ethanol
US9079172B2 (en) 2012-03-13 2015-07-14 Celanese International Corporation Promoters for cobalt-tin catalysts for reducing alkanoic acids
US9333496B2 (en) 2012-02-29 2016-05-10 Celanese International Corporation Cobalt/tin catalyst for producing ethanol
WO2013103392A1 (en) 2012-01-06 2013-07-11 Celanese International Corporation Hydrogenation catalyst and process for producing ethanol using the catalyst
US8865609B2 (en) 2012-01-06 2014-10-21 Celanese International Corporation Hydrogenation catalysts
US9024086B2 (en) 2012-01-06 2015-05-05 Celanese International Corporation Hydrogenation catalysts with acidic sites
US8815768B2 (en) 2012-01-06 2014-08-26 Celanese International Corporation Processes for making catalysts with acidic precursors
US8981164B2 (en) 2012-01-06 2015-03-17 Celanese International Corporation Cobalt and tin hydrogenation catalysts
US8841230B2 (en) 2012-01-06 2014-09-23 Celanese International Corporation Processes for making catalysts with metal halide precursors
AU2012363796A1 (en) 2012-01-06 2014-07-03 Celanese International Corporation Cobalt-containing hydrogenation catalysts and processes for making same
US8980789B2 (en) 2012-01-06 2015-03-17 Celanese International Corporation Modified catalyst supports
WO2013103393A1 (en) 2012-01-06 2013-07-11 Celanese International Corporation Processes for making catalysts comprising precious metal and active metal modified support
US8802588B2 (en) 2012-01-23 2014-08-12 Celanese International Corporation Bismuth catalyst composition and process for manufacturing ethanol mixture
US20130197278A1 (en) 2012-01-27 2013-08-01 Celanese International Corporation Process For Manufacturing Ethanol Using A Metallic Catalyst Supported on Titania
US9050585B2 (en) 2012-02-10 2015-06-09 Celanese International Corporation Chemisorption of ethyl acetate during hydrogenation of acetic acid to ethanol
US8729317B2 (en) 2012-02-15 2014-05-20 Celanese International Corporation Ethanol manufacturing process over catalyst with cesium and support comprising tungsten or oxides thereof
US20130225876A1 (en) 2012-02-29 2013-08-29 Celanese International Corporation Hydrogenation Catalyst Using Multiple Impregnations of an Active Metal Solution
US9126194B2 (en) 2012-02-29 2015-09-08 Celanese International Corporation Catalyst having support containing tin and process for manufacturing ethanol
US8927786B2 (en) 2012-03-13 2015-01-06 Celanese International Corporation Ethanol manufacturing process over catalyst having improved radial crush strength
US8536383B1 (en) 2012-03-14 2013-09-17 Celanese International Corporation Rhodium/tin catalysts and processes for producing ethanol
US9073042B2 (en) 2012-03-14 2015-07-07 Celanese International Corporation Acetic acid hydrogenation over a group VIII metal calcined catalyst having a secondary promoter
US9108895B2 (en) 2012-10-26 2015-08-18 Eastman Chemical Company Promoted ruthenium catalyst for the improved hydrogenation of carboxylic acids to the corresponding alcohols
US8772553B2 (en) 2012-10-26 2014-07-08 Celanese International Corporation Hydrogenation reaction conditions for producing ethanol
EP2759598A1 (de) * 2013-01-24 2014-07-30 Evonik Industries AG Verfahren zur Herstellung von alpha, omega-Alkandiol
CN103449971B (zh) * 2013-08-07 2014-12-17 青岛俪徕精细化工有限公司 α,ω-长碳链正构二元醇的生产方法
US10150719B2 (en) 2013-08-23 2018-12-11 Archer-Daniels-Midland Company Production of 1,6-hexanediol from adipic acid
US9266095B2 (en) 2014-01-27 2016-02-23 Celanese International Corporation Hydrogenation catalysts with cobalt and alkaline-earth metal modified supports
US9353035B2 (en) 2014-04-28 2016-05-31 Celanese International Corporation Process for producing ethanol with zonal catalysts
US9073815B1 (en) 2014-04-28 2015-07-07 Celanese International Corporation Hydrogenation catalysts comprising a mixed oxide and processes for producing ethanol
US9382177B2 (en) 2014-04-28 2016-07-05 Celanese International Corporation Hydrogenation catalysts comprising a mixed oxide comprising a promoter metal
US9024088B1 (en) 2014-04-28 2015-05-05 Celanese International Corporation Hydrogenation catalysts comprising a mixed oxide comprising nickel
CN111974388B (zh) * 2014-05-23 2023-10-31 三菱化学株式会社 负载金属催化剂、负载金属催化剂的保存方法以及醇的制造方法
WO2016122465A1 (en) 2015-01-27 2016-08-04 Celanese International Corporation Process for producing ethanol using solid catalysts
US9670120B2 (en) 2015-01-27 2017-06-06 Celanese International Corporation Process for producing ethanol using a solid catalyst
US9540297B2 (en) 2015-04-27 2017-01-10 Celanese International Corporation Ruthenium-bismuth mixed oxide hydrogenation catalysts and processes for producing ethanol
WO2016175745A1 (en) 2015-04-27 2016-11-03 Celanese International Corporation Ruthenium-bismuth mixed oxide hydrogenation catalysts and processes for producing ethanol
WO2016175747A1 (en) 2015-04-27 2016-11-03 Celanese International Corporation Hydrogenation catalysts comprising a mixed oxide having bismuth and process for producing ethanol
US10414858B2 (en) 2016-04-19 2019-09-17 Regents Of The University Of Minnesota Methods of forming diol compounds

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4214106A (en) * 1977-04-07 1980-07-22 Hoechst Aktiengesellschaft Process for the preparation of ethylene glycol
US5149680A (en) * 1987-03-31 1992-09-22 The British Petroleum Company P.L.C. Platinum group metal alloy catalysts for hydrogenation of carboxylic acids and their anhydrides to alcohols and/or esters

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE878345C (de) * 1940-02-07 1953-06-01 Degussa Katalysator fuer die Oxydation von Ammoniak
US3578583A (en) * 1968-09-10 1971-05-11 Chevron Res Reforming process with promoted low platinum content catalyst
IE34345B1 (en) * 1969-07-03 1975-04-16 Universal Oil Prod Co Hydrocarbon conversion process and catalyst therefor
FR2102666A5 (enExample) * 1970-08-14 1972-04-07 Raffinage Cie Francaise
DE2519817A1 (de) 1975-05-03 1976-11-11 Hoechst Ag Verfahren zur herstellung von butandiol-(1.4)
DE2715667A1 (de) 1977-04-07 1978-10-12 Hoechst Ag Verfahren zur herstellung von butandiol-(1.4)
US4108478A (en) * 1977-07-05 1978-08-22 Fenix & Scisson, Inc. Means to prevent relative rotation of threaded together pin and box tool joints
US4338221A (en) * 1981-02-11 1982-07-06 Uop Inc. Catalyst for the reduction of unsaturated organic acids
US4398039A (en) * 1981-05-18 1983-08-09 The Standard Oil Company Hydrogenation of carboxylic acids
GB8707595D0 (en) * 1987-03-31 1987-05-07 British Petroleum Co Plc Chemical process
JPH01310738A (ja) * 1988-06-10 1989-12-14 Toyota Motor Corp 排ガス浄化用触媒
DD297888A7 (de) * 1989-12-06 1992-01-30 Leuna-Werke Ag,De Reformierkatalysator fuer die umwandlung von benzinkohlenwasserstoffen
US5254518A (en) * 1992-07-22 1993-10-19 Exxon Research & Engineering Company Group IVB oxide addition to noble metal on rare earth modified silica alumina as hydrocarbon conversion catalyst

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4214106A (en) * 1977-04-07 1980-07-22 Hoechst Aktiengesellschaft Process for the preparation of ethylene glycol
US5149680A (en) * 1987-03-31 1992-09-22 The British Petroleum Company P.L.C. Platinum group metal alloy catalysts for hydrogenation of carboxylic acids and their anhydrides to alcohols and/or esters

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100450984C (zh) * 2004-04-02 2009-01-14 花王株式会社 脂肪醇的制造方法

Also Published As

Publication number Publication date
ES2187029T3 (es) 2003-05-16
US6204417B1 (en) 2001-03-20
EP0983219A2 (de) 2000-03-08
EP0983219B1 (de) 2002-11-06
DE19720657A1 (de) 1998-11-19
WO1998052891A1 (de) 1998-11-26
JP2001526670A (ja) 2001-12-18
JP4138025B2 (ja) 2008-08-20
CN1259112A (zh) 2000-07-05
DE59806195D1 (de) 2002-12-12

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Granted publication date: 20030521

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