CN110785444B - 通过连续聚合制备共轭二烯类聚合物的方法 - Google Patents

通过连续聚合制备共轭二烯类聚合物的方法 Download PDF

Info

Publication number
CN110785444B
CN110785444B CN201780092489.1A CN201780092489A CN110785444B CN 110785444 B CN110785444 B CN 110785444B CN 201780092489 A CN201780092489 A CN 201780092489A CN 110785444 B CN110785444 B CN 110785444B
Authority
CN
China
Prior art keywords
acid
reactor
conjugated diene
polymer
monomer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201780092489.1A
Other languages
English (en)
Chinese (zh)
Other versions
CN110785444A (zh
Inventor
俞锡俊
朴成浩
崔洙荣
安贞宪
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
LG Chem Ltd
Original Assignee
LG Chem Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by LG Chem Ltd filed Critical LG Chem Ltd
Publication of CN110785444A publication Critical patent/CN110785444A/zh
Application granted granted Critical
Publication of CN110785444B publication Critical patent/CN110785444B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F136/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F136/02—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F136/04—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F136/06—Butadiene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/001—Multistage polymerisation processes characterised by a change in reactor conditions without deactivating the intermediate polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/52—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from boron, aluminium, gallium, indium, thallium or rare earths
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F136/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F136/02—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F136/04—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F236/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/54—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with other compounds thereof
    • C08F4/545—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with other compounds thereof rare earths being present, e.g. triethylaluminium + neodymium octanoate

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)
  • Polymerization Catalysts (AREA)
CN201780092489.1A 2017-10-26 2017-12-26 通过连续聚合制备共轭二烯类聚合物的方法 Active CN110785444B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
KR10-2017-0140413 2017-10-26
KR1020170140413A KR102154046B1 (ko) 2017-10-26 2017-10-26 연속식 중합에 의한 공액디엔계 중합체의 제조방법
PCT/KR2017/015490 WO2019083092A1 (ko) 2017-10-26 2017-12-26 연속식 중합에 의한 공액디엔계 중합체의 제조방법

Publications (2)

Publication Number Publication Date
CN110785444A CN110785444A (zh) 2020-02-11
CN110785444B true CN110785444B (zh) 2022-09-06

Family

ID=66247493

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201780092489.1A Active CN110785444B (zh) 2017-10-26 2017-12-26 通过连续聚合制备共轭二烯类聚合物的方法

Country Status (6)

Country Link
US (1) US10982026B2 (https=)
EP (1) EP3702378B1 (https=)
JP (1) JP7015386B2 (https=)
KR (1) KR102154046B1 (https=)
CN (1) CN110785444B (https=)
WO (1) WO2019083092A1 (https=)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR102742692B1 (ko) * 2019-10-11 2024-12-16 주식회사 엘지화학 연속식 중합에 의한 변성 공액디엔계 중합체의 제조방법
KR102523121B1 (ko) * 2020-01-31 2023-04-19 주식회사 엘지화학 공액디엔계 중합체의 연속 제조 시스템
WO2022065902A1 (ko) * 2020-09-25 2022-03-31 주식회사 엘지화학 네오디뮴 촉매화 공액디엔계 중합체 및 이를 포함하는 고무 조성물
CN118696068A (zh) 2022-04-08 2024-09-24 阿朗新科德国有限责任公司 支化的改性二烯橡胶

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1026181A1 (en) * 1999-02-03 2000-08-09 JSR Corporation Method of producing conjugated diene polymer
KR20030072620A (ko) * 2001-02-07 2003-09-15 바이엘 악티엔게젤샤프트 엘라스토머의 연속 제조 방법
CN102124037A (zh) * 2008-06-20 2011-07-13 株式会社普利司通 制备顺式1，4-聚二烯用催化剂
KR20150028615A (ko) * 2013-09-06 2015-03-16 주식회사 엘지화학 플러깅이 감소된 부타디엔 고무의 제조방법 및 제조장치
WO2016080766A1 (ko) * 2014-11-20 2016-05-26 주식회사 엘지화학 공액 디엔계 중합체의 제조방법
KR20160060563A (ko) * 2014-11-20 2016-05-30 주식회사 엘지화학 공액 디엔계 중합체의 제조방법
WO2017069494A1 (ko) * 2015-10-22 2017-04-27 주식회사 엘지화학 폴리부타디엔의 제조 장치
KR20170053467A (ko) * 2015-11-06 2017-05-16 주식회사 엘지화학 부타디엔 고무의 연속제조방법 및 이를 이용한 부타디엔 고무의 연속제조장치

Family Cites Families (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4136244A (en) * 1974-12-23 1979-01-23 Compagnie Generale Des Etablissements Michelin Continuous solution polymerization process
FR2295972A1 (fr) * 1974-12-23 1976-07-23 Michelin & Cie Polymerisation ou copolymerisation en solution d'un ou plusieurs dienes conjugues avec eventuellement un ou plusieurs composes vinylaromatiques
US4843120A (en) * 1986-09-29 1989-06-27 The Goodyear Tire & Rubber Company Rubber composition
US5194491A (en) * 1989-05-30 1993-03-16 Mitsubishi Monsanto Chemical Company Process for producing rubber-modified styrene resin, and resin composition
EP0489660B1 (fr) 1990-12-06 1994-11-02 Roussel-Uclaf Utilisation de thiazolylalkoxy acrylates pour la fabrication de compositions insecticides et/ou acaricides
JP3175350B2 (ja) 1992-10-15 2001-06-11 ジェイエスアール株式会社 高ビニル結合を有するブタジエン系重合体の連続重合方法
WO1998007765A2 (de) * 1996-08-19 1998-02-26 Basf Aktiengesellschaft Verfahren zur anionischen polymerisation
US5955537A (en) * 1998-02-13 1999-09-21 The Goodyear Tire & Rubber Company Continuous polymerization process
US6372863B1 (en) * 1999-08-12 2002-04-16 The Goodyear Tire & Rubber Company Synthesis of styrene-butadiene rubber
US6930146B1 (en) * 2000-07-27 2005-08-16 Jsr Corporation 1,2-polybutadiene, thermoplastic elastomer composition and polymer composition
ES2456694T3 (es) * 2000-10-25 2014-04-23 Asahi Kasei Kabushiki Kaisha Polímero hidrogenado
US6627715B2 (en) * 2001-08-16 2003-09-30 The Goodyear Tire & Rubber Company Group IIa metal containing catalyst system
US6617406B2 (en) * 2001-08-30 2003-09-09 The Goodyear Tire & Rubber Company Synthesis of elastomeric high trans-1,4-polybutadiene
US7754831B2 (en) * 2002-12-25 2010-07-13 Mitsubishi Rayon Co., Ltd. Vinyl polymer, process for producing vinyl polymer, thermosetting coating composition, and coating material
US7064171B1 (en) * 2005-09-22 2006-06-20 The Goodyear Tire & Rubber Company Non-random styrene-butadiene rubber
EP2495266A1 (en) * 2011-03-04 2012-09-05 Styron Deutschland GmbH High styrene high vinyl styrene-butadiene rubber and methods for preparation thereof
KR101469268B1 (ko) 2011-12-28 2014-12-05 제일모직주식회사 공액 디엔으로부터 열가소성 수지를 연속적으로 제조하는 방법 및 그로부터 제조된 열가소성 수지
SG11201610196TA (en) * 2014-08-20 2017-03-30 Versalis Spa Process for the preparation of diene polymers or random vinyl arene-diene copolymers
KR101653574B1 (ko) * 2014-12-11 2016-09-08 주식회사 엘지화학 변성 공역디엔계 중합체, 이를 포함하는 변성 고무 조성물 및 변성 공역디엔계 중합체의 제조방법
US10508159B2 (en) 2014-12-24 2019-12-17 Lg Chem, Ltd. Method for preparing diene-based rubber latex and acrylonitrile-butadiene-styrene graft copolymer comprising the same
KR101745788B1 (ko) * 2015-01-05 2017-06-09 주식회사 엘지화학 변성 공역디엔계 중합체, 이를 포함하는 변성 고무 조성물 및 변성 공역디엔계 중합체의 제조방법
US10174193B2 (en) * 2015-06-19 2019-01-08 Lg Chem, Ltd. Method for preparing modified acrylonitrile-butadiene-styrene resin, and modified acrylonitrile-butadiene-styrene resin prepared thereby
KR102068651B1 (ko) 2015-12-23 2020-01-21 주식회사 엘지화학 공액디엔 고무질 중합체의 제조방법
KR101857392B1 (ko) * 2017-01-03 2018-06-19 주식회사 엘지화학 변성 공액디엔계 중합체 제조방법

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1026181A1 (en) * 1999-02-03 2000-08-09 JSR Corporation Method of producing conjugated diene polymer
KR20030072620A (ko) * 2001-02-07 2003-09-15 바이엘 악티엔게젤샤프트 엘라스토머의 연속 제조 방법
CN102124037A (zh) * 2008-06-20 2011-07-13 株式会社普利司通 制备顺式1，4-聚二烯用催化剂
KR20150028615A (ko) * 2013-09-06 2015-03-16 주식회사 엘지화학 플러깅이 감소된 부타디엔 고무의 제조방법 및 제조장치
WO2016080766A1 (ko) * 2014-11-20 2016-05-26 주식회사 엘지화학 공액 디엔계 중합체의 제조방법
KR20160060563A (ko) * 2014-11-20 2016-05-30 주식회사 엘지화학 공액 디엔계 중합체의 제조방법
WO2017069494A1 (ko) * 2015-10-22 2017-04-27 주식회사 엘지화학 폴리부타디엔의 제조 장치
KR20170053467A (ko) * 2015-11-06 2017-05-16 주식회사 엘지화학 부타디엔 고무의 연속제조방법 및 이를 이용한 부타디엔 고무의 연속제조장치

Also Published As

Publication number Publication date
US20200123288A1 (en) 2020-04-23
EP3702378B1 (en) 2021-06-23
US10982026B2 (en) 2021-04-20
JP7015386B2 (ja) 2022-02-02
JP2020536999A (ja) 2020-12-17
CN110785444A (zh) 2020-02-11
WO2019083092A1 (ko) 2019-05-02
KR102154046B1 (ko) 2020-09-09
EP3702378A1 (en) 2020-09-02
KR20190046518A (ko) 2019-05-07
EP3702378A4 (en) 2020-09-09

Similar Documents

Publication Publication Date Title
CN110366568B (zh) 改性共轭二烯类聚合物的制备方法
EP3409718B1 (en) Modifier and modified conjugated diene-based polymer containing functional group derived therefrom
CN111133044B (zh) 改性共轭二烯类聚合物及其制备方法
CN111344315B (zh) 通过连续聚合制备共轭二烯类聚合物的方法
CN110785444B (zh) 通过连续聚合制备共轭二烯类聚合物的方法
EP3409717B1 (en) Modified conjugated diene-based polymer and method for preparing same
CN111164109A (zh) 用于使共轭二烯聚合的催化剂的制备方法、催化剂和使用其制备共轭二烯类聚合物的方法
KR20190046517A (ko) 공액디엔계 중합체의 제조방법
KR102213173B1 (ko) 연속식 중합에 의한 공액디엔계 중합체의 제조방법
KR102921288B1 (ko) 네오디뮴 촉매화 공액디엔계 중합체 및 이를 포함하는 고무 조성물
CN113728023A (zh) 改性剂、改性共轭二烯类聚合物及其制备方法
CN115038726B (zh) 钕催化的共轭二烯类聚合物和包含其的橡胶组合物
JP7462735B2 (ja) 変性共役ジエン系重合体の製造方法
JP7811657B2 (ja) 触媒組成物の製造方法および共役ジエン系重合体の製造方法
KR102742692B1 (ko) 연속식 중합에 의한 변성 공액디엔계 중합체의 제조방법
CN114502563B (zh) 含亚氨基的新型化合物、改性共轭二烯类聚合物、制备聚合物的方法和橡胶组合物
CN113348185B (zh) 改性共轭二烯类聚合物、其制备方法和包含该改性共轭二烯类聚合物的橡胶组合物
KR102757739B1 (ko) 변성 공액디엔계 중합체, 이의 제조방법 및 이를 포함하는 고무 조성물
CN118613510A (zh) 制备催化剂组合物的方法和制备共轭二烯类聚合物的方法
CN120752267A (zh) 共轭二烯类聚合物和橡胶组合物
CN120225574A (zh) 催化剂组合物的制备方法和共轭二烯类聚合物的制备方法

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant