CN110747626A - 一种疏水导电织物的制备方法及其所得材料和应用 - Google Patents
一种疏水导电织物的制备方法及其所得材料和应用 Download PDFInfo
- Publication number
- CN110747626A CN110747626A CN201911180098.2A CN201911180098A CN110747626A CN 110747626 A CN110747626 A CN 110747626A CN 201911180098 A CN201911180098 A CN 201911180098A CN 110747626 A CN110747626 A CN 110747626A
- Authority
- CN
- China
- Prior art keywords
- fabric
- soaking
- solution
- hydrophobic
- conductive fabric
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000004744 fabric Substances 0.000 title claims abstract description 104
- 230000002209 hydrophobic effect Effects 0.000 title claims abstract description 50
- 238000002360 preparation method Methods 0.000 title claims abstract description 23
- 239000000463 material Substances 0.000 title abstract description 13
- 238000002791 soaking Methods 0.000 claims abstract description 39
- 239000000178 monomer Substances 0.000 claims abstract description 30
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 29
- 229920001940 conductive polymer Polymers 0.000 claims abstract description 25
- 239000007864 aqueous solution Substances 0.000 claims abstract description 24
- 239000000758 substrate Substances 0.000 claims abstract description 22
- 238000000034 method Methods 0.000 claims abstract description 21
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 20
- 238000001035 drying Methods 0.000 claims abstract description 20
- 238000005406 washing Methods 0.000 claims abstract description 20
- 230000001590 oxidative effect Effects 0.000 claims abstract description 19
- 239000000243 solution Substances 0.000 claims abstract description 16
- 238000006116 polymerization reaction Methods 0.000 claims abstract description 14
- 238000011065 in-situ storage Methods 0.000 claims abstract description 13
- 239000007800 oxidant agent Substances 0.000 claims abstract description 13
- 239000007853 buffer solution Substances 0.000 claims abstract description 10
- 238000003756 stirring Methods 0.000 claims abstract description 10
- 239000012670 alkaline solution Substances 0.000 claims abstract description 6
- 238000004140 cleaning Methods 0.000 claims abstract description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 27
- KAESVJOAVNADME-UHFFFAOYSA-N Pyrrole Chemical compound C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 claims description 24
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 18
- 239000000835 fiber Substances 0.000 claims description 16
- 239000011259 mixed solution Substances 0.000 claims description 15
- YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 claims description 10
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 claims description 8
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 8
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 6
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 6
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 6
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 claims description 6
- UIIMBOGNXHQVGW-UHFFFAOYSA-M sodium bicarbonate Substances [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims description 6
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 claims description 6
- 239000000872 buffer Substances 0.000 claims description 5
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 claims description 5
- -1 polyethylene Polymers 0.000 claims description 5
- 229960004889 salicylic acid Drugs 0.000 claims description 5
- YTPLMLYBLZKORZ-UHFFFAOYSA-N Thiophene Chemical compound C=1C=CSC=1 YTPLMLYBLZKORZ-UHFFFAOYSA-N 0.000 claims description 4
- BNIILDVGGAEEIG-UHFFFAOYSA-L disodium hydrogen phosphate Chemical compound [Na+].[Na+].OP([O-])([O-])=O BNIILDVGGAEEIG-UHFFFAOYSA-L 0.000 claims description 4
- 229910000397 disodium phosphate Inorganic materials 0.000 claims description 4
- 238000005516 engineering process Methods 0.000 claims description 4
- 229920002239 polyacrylonitrile Polymers 0.000 claims description 4
- MABNMNVCOAICNO-UHFFFAOYSA-N selenophene Chemical compound C=1C=C[se]C=1 MABNMNVCOAICNO-UHFFFAOYSA-N 0.000 claims description 4
- 229910000030 sodium bicarbonate Inorganic materials 0.000 claims description 4
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 4
- 229910000162 sodium phosphate Inorganic materials 0.000 claims description 4
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 claims description 3
- 239000004743 Polypropylene Substances 0.000 claims description 3
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 3
- 229910001870 ammonium persulfate Inorganic materials 0.000 claims description 3
- 229920001155 polypropylene Polymers 0.000 claims description 3
- GKWLILHTTGWKLQ-UHFFFAOYSA-N 2,3-dihydrothieno[3,4-b][1,4]dioxine Chemical compound O1CCOC2=CSC=C21 GKWLILHTTGWKLQ-UHFFFAOYSA-N 0.000 claims description 2
- 229920003043 Cellulose fiber Polymers 0.000 claims description 2
- 239000004698 Polyethylene Substances 0.000 claims description 2
- 239000007983 Tris buffer Substances 0.000 claims description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 2
- NQXWGWZJXJUMQB-UHFFFAOYSA-K iron trichloride hexahydrate Chemical compound O.O.O.O.O.O.[Cl-].Cl[Fe+]Cl NQXWGWZJXJUMQB-UHFFFAOYSA-K 0.000 claims description 2
- SZQUEWJRBJDHSM-UHFFFAOYSA-N iron(3+);trinitrate;nonahydrate Chemical compound O.O.O.O.O.O.O.O.O.[Fe+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O SZQUEWJRBJDHSM-UHFFFAOYSA-N 0.000 claims description 2
- 229920000573 polyethylene Polymers 0.000 claims description 2
- TULWUZJYDBGXMY-UHFFFAOYSA-N tellurophene Chemical compound [Te]1C=CC=C1 TULWUZJYDBGXMY-UHFFFAOYSA-N 0.000 claims description 2
- 229930192474 thiophene Natural products 0.000 claims description 2
- 238000009832 plasma treatment Methods 0.000 abstract description 4
- 230000007547 defect Effects 0.000 abstract description 2
- 238000011031 large-scale manufacturing process Methods 0.000 abstract description 2
- 229920000742 Cotton Polymers 0.000 description 20
- 238000012360 testing method Methods 0.000 description 17
- 229920000128 polypyrrole Polymers 0.000 description 9
- 238000001514 detection method Methods 0.000 description 8
- 239000000126 substance Substances 0.000 description 8
- 239000003990 capacitor Substances 0.000 description 7
- 238000010277 constant-current charging Methods 0.000 description 7
- 239000008367 deionised water Substances 0.000 description 7
- 229910021641 deionized water Inorganic materials 0.000 description 7
- 238000007599 discharging Methods 0.000 description 7
- 229920000767 polyaniline Polymers 0.000 description 7
- 238000001878 scanning electron micrograph Methods 0.000 description 6
- 230000003075 superhydrophobic effect Effects 0.000 description 6
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 description 5
- 238000009940 knitting Methods 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 4
- 229920000747 poly(lactic acid) Polymers 0.000 description 4
- 239000004626 polylactic acid Substances 0.000 description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 239000002585 base Substances 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 230000007797 corrosion Effects 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 3
- 239000002121 nanofiber Substances 0.000 description 3
- 239000004094 surface-active agent Substances 0.000 description 3
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 238000000137 annealing Methods 0.000 description 2
- 239000004020 conductor Substances 0.000 description 2
- 229910052731 fluorine Inorganic materials 0.000 description 2
- 239000011737 fluorine Substances 0.000 description 2
- VCJMYUPGQJHHFU-UHFFFAOYSA-N iron(3+);trinitrate Chemical compound [Fe+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O VCJMYUPGQJHHFU-UHFFFAOYSA-N 0.000 description 2
- 239000002086 nanomaterial Substances 0.000 description 2
- 230000002441 reversible effect Effects 0.000 description 2
- AJPJDKMHJJGVTQ-UHFFFAOYSA-M sodium dihydrogen phosphate Chemical compound [Na+].OP(O)([O-])=O AJPJDKMHJJGVTQ-UHFFFAOYSA-M 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 230000007704 transition Effects 0.000 description 2
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000011258 core-shell material Substances 0.000 description 1
- 238000005536 corrosion prevention Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 description 1
- 238000010041 electrostatic spinning Methods 0.000 description 1
- 238000004146 energy storage Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 125000001165 hydrophobic group Chemical group 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- FYFFGSSZFBZTAH-UHFFFAOYSA-N methylaminomethanetriol Chemical compound CNC(O)(O)O FYFFGSSZFBZTAH-UHFFFAOYSA-N 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000002114 nanocomposite Substances 0.000 description 1
- 239000002105 nanoparticle Substances 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920001195 polyisoprene Polymers 0.000 description 1
- 229920005594 polymer fiber Polymers 0.000 description 1
- 239000012462 polypropylene substrate Substances 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 230000002940 repellent Effects 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 229920000428 triblock copolymer Polymers 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
Images
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/38—Oxides or hydroxides of elements of Groups 1 or 11 of the Periodic Table
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/68—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with phosphorus or compounds thereof, e.g. with chlorophosphonic acid or salts thereof
- D06M11/70—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with phosphorus or compounds thereof, e.g. with chlorophosphonic acid or salts thereof with oxides of phosphorus; with hypophosphorous, phosphorous or phosphoric acids or their salts
- D06M11/71—Salts of phosphoric acids
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/73—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof
- D06M11/76—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof with carbon oxides or carbonates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/61—Polyamines polyimines
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/18—Synthetic fibres consisting of macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/20—Polyalkenes, polymers or copolymers of compounds with alkenyl groups bonded to aromatic groups
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/18—Synthetic fibres consisting of macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/26—Polymers or copolymers of unsaturated carboxylic acids or derivatives thereof
- D06M2101/28—Acrylonitrile; Methacrylonitrile
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/10—Repellency against liquids
- D06M2200/12—Hydrophobic properties
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
本发明公开了一种疏水导电织物的制备方法及其所得材料和应用,该方法包括以下步骤:(1)将织物基材置于碱性溶液中浸泡,然后用水洗涤并干燥;(2)将步骤(1)干燥后的织物置于缓冲溶液中浸泡;(3)将步骤(2)中浸泡后的织物置于导电聚合物单体的水溶液中,搅拌,用pH调节剂调节溶液至酸性,再加入氧化剂使导电聚合物单体在织物表面进行原位聚合反应,最后经水洗、乙醇浸泡和干燥得到疏水导电织物。本发明制备方法简单、便于操作,省去了等离子体处理步骤,大大节约了制备成本,最终制得的疏水导电织物只需经过简单的清洗处理即可,克服了现有技术工艺繁琐的缺点,适合大规模生产,具有非常好的应用前景。
Description
技术领域
本发明涉及疏水导电材料的制备,尤其涉及一种疏水导电织物的制备方法及其所得材料和应用。
背景技术
导电聚合物具有良好的导电性、环境稳定性、储能性并且制备简单,在能源、传感器、电磁屏蔽、金属防腐等方面有着非常好的应用前景。在一些应用场景中,如防腐或防水性表面,疏水的导电高分子才能够满足所需的性能要求。影响固体表面润湿性的因素主要有:表面自由能和表面微观结构。当固体的表面自由能越小,越不易被一些液体润湿;材料的表面越粗糙,尤其是具有微米和纳米复合的结构,其疏水性越好。因此,降低材料的表面自由能和增加材料表面的微观粗糙度是提高材料表面疏水性的重要途径。
一些研究者通过使用表面活性剂改性或者含氟酸掺杂制备疏水性导电高分子。申请号为CN201210582862.0的中国专利公开了亲疏水可逆转换的聚苯胺纳米材料的制备方法,利用阴离子表面活性剂十二烷基苯磺酸钠的加入,使制得的聚苯胺纳米粒子、空心矩形管具有较好的疏水性,同时偶氮类化合物的掺杂使所制备的聚苯胺纳米材料具有一定的光学可控性,能够实现亲疏水的可逆转换。申请号为CN201610145871.1的中国专利公开了一种超疏水性聚苯胺耐腐蚀材料的制备方法,通过表面活性剂对聚苯胺进行修饰改性,利用表面活性剂的长链疏水基团使聚苯胺的浸润性由亲水变为超疏水。申请号为CN200510076659.6的中国专利公开了超疏水导电高分子纳米纤维及其制备方法和用途,利用静电纺丝法制得核壳结构的同轴导电高分子纳米纤维,其中“核”为直径80~300纳米的聚合物纤维,与之同轴的“壳”为80~200纳米厚的导电高分子层,通过用碱性溶液脱掺杂以及含氟有机磺酸溶液再掺杂,得到超疏水导电高分子纳米纤维。
另外,也有一些研究者通过改变基材的粗糙度从而得到疏水导电材料。申请号为CN200710037333.1的中国专利公开了全程疏水性聚吡咯膜的制备方法,将三嵌段共聚物聚苯乙烯-聚异戊二烯-聚乳酸或聚异戊二烯-聚苯乙烯-聚乳酸涂覆到导电玻璃表面得到导电基底,再将该基底置于低于0.1大气压、120~170℃条件下退火处理10~20小时,冷却后用碱性物质、甲醇和水的混合溶液进行腐蚀去除聚乳酸得到具有纳米孔洞的非平滑基底聚苯乙烯-聚异戊二烯或聚异戊二烯-聚苯乙烯膜,最后通过电化学聚合得到全程疏水性聚吡咯膜。这种方法需要长时间的退火处理并去除模板聚乳酸才能得到孔洞,过程较为复杂。
申请号为CN201110028140.6的中国专利公开了一种超疏水耐水洗性导电织物及制备方法,用表面存在裂纹、横截面为十字型的异型聚酯合成纤维与棉纤维混纺的织物作为基底,在经过等离子体处理后利用原位聚合法将导电聚合物与基底织物复合,得到超疏水导电织物。这种方法制备疏水性导电织物需要对基材先进行等离子体处理,大大增加了生产成本。
发明内容
发明目的:针对以上问题,本发明提出一种成本低、处理方法简单的疏水导电织物的制备方法。本发明的另一目的是提供由该方法制备得到的疏水导电织物。本发明还有一个目的是提供该疏水导电织物在可穿戴电子设备、超级电容器、电磁屏蔽、隐身技术、传感器或自清洁织物方面的应用。
技术方案:本发明所述的一种疏水导电织物的制备方法,包括以下步骤:
(1)将织物基材置于碱性溶液中浸泡,然后用水洗涤并干燥;
(2)将步骤(1)干燥后的织物置于缓冲溶液中浸泡;
(3)将步骤(2)中浸泡后的织物置于导电聚合物单体的水溶液中,搅拌,用pH调节剂调节溶液至酸性,再加入氧化剂使导电聚合物单体在织物表面进行原位聚合反应,最后经水洗、乙醇浸泡和干燥得到疏水导电织物。
其中,所述步骤(1)中织物基材的纱线由纤维相互缠绕扭曲而成,表面凹凸不平并留有空隙,所述纤维种类为聚乙烯、聚丙烯、纤维素纤维、聚丙烯腈或带有羧基的纤维,所述纤维为非圆形结构,进一步优选为扁平状结构。需要说明的是,为了形成表面凹凸不平的结构,需要选用针织物作为基材。
所述步骤(1)中的碱性溶液为KOH或NaOH溶液,浓度为1~6mol/L;浸泡温度为40~80℃,浸泡时间为0.2~2h。
所述步骤(2)中的缓冲溶液为Na2CO3/NaHCO3混合溶液、Na2HPO4/NaH2PO4混合溶液、乙二胺/盐酸混合溶液或三羟甲基氨基甲烷/盐酸混合溶液,其中缓冲对的摩尔比为0.2:1~1.5:1,浓度为0.5~3mol/L;浸泡温度为40~80℃,浸泡时间为10~60min。
所述步骤(3)中的导电聚合物单体为吡咯、苯胺、噻吩、3,4-乙撑二氧噻吩、硒吩或碲吩,其浓度为0.05~0.2mol/L。
所述步骤(3)中用pH调节剂调节溶液pH至1~4;所述pH调节剂为盐酸、硫酸、磷酸、乙酸、水杨酸或对甲苯磺酸,浓度为0.5~3mol/L。
需要说明的是,本发明的步骤(3)是先让缓冲溶液浸泡后的织物吸附导电聚合物单体,再加酸调节溶液pH,现有的制备方法通常是先将酸与导电聚合物单体混合,再用织物吸附单体。本发明先吸附后调节pH的目的是经过缓冲溶液浸泡后的织物带负电荷较多,能够充分吸附导电聚合物单体,随后调节pH至酸性值,为单体的聚合以及掺杂提供良好的反应环境。
所述步骤(3)中的氧化剂为过硫酸铵、六水合三氯化铁或九水硝酸铁,当然也可以选择其他常用的氧化剂,并不仅限于本发明。
本发明还提供了上述制备方法所制得的疏水导电织物。
本发明最后提供了所述疏水导电织物在制备可穿戴电子设备、超级电容器、电磁屏蔽、隐身技术、传感器或自清洁织物中的应用。
本发明先将织物基材进行碱处理以增加纤维表面的粗糙度,为导电聚合物单体提供更多的承载空间,从而更好的吸附导电聚合物单体;然后再将碱处理后的织物浸泡在缓冲溶液中,利用缓冲溶液中的阴离子基团作为中间桥梁,吸引更多的导电聚合物单体,使其在纤维表面发生原位化学氧化聚合,从而得到疏水导电织物。另外,由于所用织物的纱线是由大量扁平状纤维相互缠绕扭曲而成,表面凹凸不平并留有大量空隙,这种粗糙结构的基材被不规则颗粒状的导电聚合物附着后变得更加粗糙,从而表现出良好的疏水性。
有益效果:与现有技术相比,本发明制备方法简单、便于操作,省去了等离子体处理步骤,大大节约了制备成本,最终制得的疏水导电织物只需经过简单的清洗处理即可,克服了现有技术工艺繁琐的缺点,适合大规模生产,具有非常好的应用前景。
附图说明
图1是本发明实施例1针织棉基材的低倍SEM图;
图2是本发明实施例1针织棉基材的高倍SEM图;
图3是本发明实施例1疏水导电织物的SEM图;
图4是本发明实施例1疏水导电织物的静态接触角图。
具体实施方式
下面结合附图和实施例对本发明作进一步的说明。
实施例1
(1)取一块5cm×5cm的针织棉置于1mol/L的NaOH溶液中恒温(40℃)浸泡0.2h,随后用清水洗涤织物并自然干燥;
(2)将步骤(1)所得干燥后的织物置于0.5mol/L的Na2CO3/NaHCO3(摩尔比1:1)混合溶液中恒温(40℃)浸泡10min;
(3)将步骤(2)中浸泡后的织物转移至吡咯单体水溶液(0.1mol/L)中,充分搅拌后用1mol/L对甲苯磺酸调节水溶液的pH值至2,随后加入氧化剂三氯化铁水溶液(0.1mol/L)使吡咯单体在针织棉基材上进行原位化学氧化聚合,最后通过去离子水洗涤、乙醇浸泡和自然干燥得到疏水导电织物。
如图1所示,为针织棉基材的低倍SEM图,从图中可明显看出针织棉由大量扁平状纤维相互缠绕扭曲而成,表面凹凸不平并留有大量空隙,图2是高倍放大的针织棉SEM图。图3是疏水导电织物的SEM图,相比于图2,可看出经处理后的织物纤维表面有着导电聚合物颗粒,使纤维表面更粗糙。
经过检测,该导电织物承载的聚吡咯含量为2.5mg/cm2,电阻率为16.8Ωcm;5μL水滴在其上的接触角为135°(如图4所示),表现出较高的疏水特性;用两电极测试体系对以该电极组装的对称型超级电容器进行恒流充放电测试,1A/g电流密度时该电极的比容量为35F/g,具有良好的导电性。因此,通过本发明制备的具有较高疏水性、良好导电性的织物在可穿戴电子设备、超级电容器、电磁屏蔽、隐身技术、传感器以及自清洁织物等领域具有非常好的潜在应用价值。
实施例2
(1)取一块5cm×5cm的聚丙烯织物置于6mol/L的NaOH溶液中恒温(80℃)浸泡2h,随后用清水洗涤织物并自然干燥;
(2)将步骤(1)所得干燥后的织物置于3mol/L的Na2HPO4/NaH2PO4(摩尔比1:1)混合溶液中恒温(80℃)浸泡60min;
(3)将步骤(2)中浸泡后的织物转移至苯胺单体水溶液(0.1mol/L)中,充分搅拌后用2mol/L盐酸调节水溶液的pH值至1,随后加入氧化剂过硫酸铵水溶液(0.1mol/L)使苯胺单体在聚丙烯基材上进行原位化学氧化聚合,最后通过去离子水洗涤、乙醇浸泡和自然干燥得到疏水导电织物。
经过检测,该导电织物承载的聚苯胺含量为1.8mg/cm2,电阻率为35.2Ωcm;5μL水滴在其上的接触角为133°,表现出较高的疏水特性;用两电极测试体系对以该电极组装的对称型超级电容器进行恒流充放电测试,1A/g电流密度时该电极的比容量为25F/g,具有良好的导电性。
实施例3
(1)取一块5cm×5cm的聚丙烯腈织物置于3mol/L的NaOH溶液中恒温(60℃)浸泡0.5h,随后用清水洗涤织物并自然干燥;
(2)将步骤(1)所得干燥后的织物置于2mol/L的Na2CO3/NaHCO3(摩尔比1:1)混合溶液中恒温(60℃)浸泡30min;
(3)将步骤(2)中浸泡后的织物转移至硒吩单体水溶液(0.05mol/L)中,充分搅拌后用3mol/L水杨酸调节水溶液的pH值至1,随后加入氧化剂硝酸铁水溶液(0.05mol/L)使硒吩单体在聚丙烯腈基材上进行原位化学氧化聚合,最后通过去离子水洗涤、乙醇浸泡和自然干燥得到疏水导电织物。
经过检测,该导电织物承载的聚硒吩含量为1.3mg/cm2,电阻率为113.3Ωcm,5μL水滴在其上的接触角为132°,表现出较高的疏水特性;用两电极测试体系对以该电极组装的对称型超级电容器进行恒流充放电测试,1A/g电流密度时该电极的比容量为8F/g,具有良好的导电性。
实施例4
(1)取一块5cm×5cm的针织棉置于2mol/L的NaOH溶液中恒温(50℃)浸泡0.5h,随后用清水洗涤织物并自然干燥;
(2)将步骤(1)所得干燥后的织物置于1mol/L的Na2HPO4/NaH2PO4(摩尔比1:1)混合溶液中恒温(70℃)浸泡10min;
(3)将步骤(2)中浸泡后的织物转移至吡咯单体水溶液(0.2mol/L)中,充分搅拌后用3mol/L水杨酸调节水溶液的pH值至1,随后加入氧化剂三氯化铁水溶液(0.3mol/L)使吡咯单体在针织棉基材上进行原位化学氧化聚合,最后通过去离子水洗涤、乙醇浸泡和自然干燥得到疏水导电织物;
经过检测,该导电织物承载的聚吡咯含量为3.5mg/cm2,电阻率为10.4Ωcm,5μL水滴在其上的接触角为141°,表现出较高的疏水特性;用两电极测试体系对以该电极组装的对称型超级电容器进行恒流充放电测试,1A/g电流密度时该电极的比容量为37F/g,具有良好的导电性。
实施例5
(1)取一块5cm×5cm的针织棉置于3mol/L的NaOH溶液中恒温(40℃)浸泡0.5h,随后用清水洗涤织物并自然干燥;
(2)将步骤(1)所得干燥后的织物置于1mol/L的乙二胺/盐酸(摩尔比1.5:1)混合溶液中恒温(70℃)浸泡10min;
(3)将步骤(2)中浸泡后的织物转移至吡咯单体水溶液(0.2mol/L)中,充分搅拌后用0.5mol/L硫酸调节水溶液的pH值至4,随后加入氧化剂三氯化铁水溶液(0.4mol/L)使吡咯单体在针织棉基材上进行原位化学氧化聚合,最后通过去离子水洗涤、乙醇浸泡和自然干燥得到疏水导电织物;
经过检测,该导电织物承载的聚吡咯含量为3.0mg/cm2,电阻率为13.8Ωcm,5μL水滴在其上的接触角为138°,表现出较高的疏水特性;用两电极测试体系对以该电极组装的对称型超级电容器进行恒流充放电测试,1A/g电流密度时该电极的比容量为33F/g,具有良好的导电性。
实施例6
(1)取一块5cm×5cm的针织棉置于1mol/L的NaOH溶液中恒温(60℃)浸泡1h,随后用清水洗涤织物并自然干燥;
(2)将步骤(1)所得干燥后的织物置于1mol/L的三羟甲基氨基甲烷/盐酸(摩尔比0.2:1)混合溶液中恒温(40℃)浸泡10min;
(3)将步骤(2)中浸泡后的织物转移至吡咯单体水溶液(0.2mol/L)中,充分搅拌后用0.5mol/L磷酸调节水溶液的pH值至3,随后加入氧化剂三氯化铁水溶液(0.4mol/L)使吡咯单体在针织棉基材上进行原位聚合,最后通过去离子水洗涤、乙醇浸泡和自然干燥得到疏水导电织物;
经过检测,该导电织物承载的聚吡咯含量为2.8mg/cm2,电阻率为18.5Ωcm,5μL水滴在其上的接触角为131°,表现出较高的疏水特性;用两电极测试体系对以该电极组装的对称型超级电容器进行恒流充放电测试,1A/g电流密度时该电极的比容量为21F/g,具有良好的导电性。
对比例1
疏水导电织物制备所涉及的条件同实施例4,与实施例4不同的是,对比例1的针织棉未在缓冲溶液中进行浸泡处理,具体制备过程为:
(1)取一块5cm×5cm的针织棉置于2mol/L的NaOH溶液中恒温(50℃)浸泡0.5h,随后用清水洗涤织物并自然干燥;
(2)将步骤(1)中所得织物转移至吡咯单体水溶液(0.2mol/L)中,充分搅拌后用3mol/L水杨酸调节水溶液的pH值至1,随后加入氧化剂三氯化铁水溶液(0.3mol/L)使吡咯单体在针织棉基材上进行原位化学氧化聚合,最后通过去离子水洗涤、乙醇浸泡和自然干燥得到疏水导电织物。
经过检测,该导电织物承载的聚吡咯含量为2.0mg/cm2,电阻率为27.9Ωcm,5μL水滴在其上的接触角为125°(小于实施例4中141°);用两电极测试体系对以该电极组装的对称型超级电容器进行恒流充放电测试,1A/g电流密度时该电极的比容量为24F/g。由于未经过缓冲溶液浸泡处理,相比于实施例4,对比例1最后原位聚合到织物上的聚吡咯减少,电导率下降。
对比例2
导电织物制备过程同实施例4,与实施例4不同的是,织物基材为机织棉。
经过检测,该导电织物承载的聚吡咯含量为1.8mg/cm2,电阻率为46.8Ωcm,5μL水滴在其上的接触角为0°(不具备疏水性),这是因为机织棉的纱线结构较规整,组成纱线的纤维排列较规律,不像针织棉纤维排列成凹凸不平的纱线;用两电极测试体系对以该电极组装的对称型超级电容器进行恒流充放电测试,1A/g电流密度时该电极的比容量为22F/g。由此可见,利用本发明的方法制备疏水导电织物,对织物基材的选取具有严格的要求,必须选择针织物,而非机织物。
Claims (10)
1.一种疏水导电织物的制备方法,其特征在于,包括以下步骤:
(1)将织物基材置于碱性溶液中浸泡,然后用水洗涤并干燥;
(2)将步骤(1)干燥后的织物置于缓冲溶液中浸泡;
(3)将步骤(2)中浸泡后的织物置于导电聚合物单体的水溶液中,搅拌,用pH调节剂调节溶液至酸性,再加入氧化剂使导电聚合物单体在织物表面进行原位聚合反应,最后经水洗、乙醇浸泡和干燥得到疏水导电织物。
2.根据权利要求1所述的疏水导电织物的制备方法,其特征在于,所述步骤(1)中织物基材的纱线由纤维相互缠绕扭曲而成,表面凹凸不平并留有空隙,所述纤维种类为聚乙烯、聚丙烯、纤维素纤维、聚丙烯腈或带有羧基的纤维。
3.根据权利要求2所述的疏水导电织物的制备方法,其特征在于,所述纤维为扁平状。
4.根据权利要求1所述的疏水导电织物的制备方法,其特征在于,所述步骤(1)中的碱性溶液为KOH或NaOH溶液,浓度为1~6mol/L;浸泡温度为40~80℃,浸泡时间为0.2~2h。
5.根据权利要求1所述的疏水导电织物的制备方法,其特征在于,所述步骤(2)中的缓冲溶液为Na2CO3/NaHCO3混合溶液、Na2HPO4/NaH2PO4混合溶液、乙二胺/盐酸混合溶液或三羟甲基氨基甲烷/盐酸混合溶液,其中缓冲对的摩尔比为0.2:1~1.5:1,浓度为0.5~3mol/L;浸泡温度为40~80℃,浸泡时间为10~60min。
6.根据权利要求1所述的疏水导电织物的制备方法,其特征在于,所述步骤(3)中的导电聚合物单体为吡咯、苯胺、噻吩、3,4-乙撑二氧噻吩、硒吩或碲吩,其浓度为0.05~0.2mol/L。
7.根据权利要求1所述的疏水导电织物的制备方法,其特征在于,所述步骤(3)中用pH调节剂调节溶液pH至1~4;所述pH调节剂为盐酸、硫酸、磷酸、乙酸、水杨酸或对甲苯磺酸,浓度为0.5~3mol/L。
8.根据权利要求1所述的疏水导电织物的制备方法,其特征在于,所述步骤(3)中的氧化剂为过硫酸铵、六水合三氯化铁或九水硝酸铁。
9.权利要求1~8任一项所述制备方法所制得的疏水导电织物。
10.权利要求9所述的疏水导电织物在制备可穿戴电子设备、超级电容器、电磁屏蔽、隐身技术、传感器或自清洁织物中的应用。
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201911180098.2A CN110747626B (zh) | 2019-11-27 | 2019-11-27 | 一种疏水导电织物的制备方法及其所得材料和应用 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201911180098.2A CN110747626B (zh) | 2019-11-27 | 2019-11-27 | 一种疏水导电织物的制备方法及其所得材料和应用 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN110747626A true CN110747626A (zh) | 2020-02-04 |
CN110747626B CN110747626B (zh) | 2021-07-27 |
Family
ID=69284741
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201911180098.2A Active CN110747626B (zh) | 2019-11-27 | 2019-11-27 | 一种疏水导电织物的制备方法及其所得材料和应用 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN110747626B (zh) |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111198219A (zh) * | 2020-02-19 | 2020-05-26 | 苏州微湃医疗科技有限公司 | 一种用于汗液检测的可穿戴式生物传感器 |
CN112053859A (zh) * | 2020-08-29 | 2020-12-08 | 盐城工学院 | 一种基于织物的柔性平面微型超级电容器的制备方法 |
CN112127166A (zh) * | 2020-08-07 | 2020-12-25 | 浙江理工大学 | 原位聚合低电阻稳定传导疏水织物的制备方法 |
CN113417157A (zh) * | 2021-06-18 | 2021-09-21 | 广东省科学院微生物研究所(广东省微生物分析检测中心) | 一种超耐洗双功能可穿戴电子织物及其制备方法 |
CN115323784A (zh) * | 2022-01-27 | 2022-11-11 | 青岛大学 | 一种聚吡咯导电柔性纤维膜材料及其制备方法 |
CN116641229A (zh) * | 2023-06-06 | 2023-08-25 | 江苏瑞洋安泰新材料科技有限公司 | 一种导电超疏水织物及其制备方法 |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1254728A (zh) * | 1998-11-23 | 2000-05-31 | 电子科技大学 | 掺杂诱导沉积聚苯胺自组装超薄膜的制备方法 |
CN102943388A (zh) * | 2012-11-26 | 2013-02-27 | 西安工程大学 | 一种原位聚合反应制备抗静电涤纶织物的方法 |
CN103981693A (zh) * | 2014-06-03 | 2014-08-13 | 陕西科技大学 | 聚苯胺-碱芳纶复合导电纤维及其制备方法 |
CN106012101A (zh) * | 2016-06-29 | 2016-10-12 | 郭舒洋 | 一种高导电复合纤维的制备方法 |
CN107630390A (zh) * | 2017-09-27 | 2018-01-26 | 华南理工大学 | 一种木质素磺酸增强聚吡咯导电纸及其制备方法 |
CN108330684A (zh) * | 2018-02-07 | 2018-07-27 | 江南大学 | 一种多功能棉织物及其制备方法 |
-
2019
- 2019-11-27 CN CN201911180098.2A patent/CN110747626B/zh active Active
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1254728A (zh) * | 1998-11-23 | 2000-05-31 | 电子科技大学 | 掺杂诱导沉积聚苯胺自组装超薄膜的制备方法 |
CN102943388A (zh) * | 2012-11-26 | 2013-02-27 | 西安工程大学 | 一种原位聚合反应制备抗静电涤纶织物的方法 |
CN103981693A (zh) * | 2014-06-03 | 2014-08-13 | 陕西科技大学 | 聚苯胺-碱芳纶复合导电纤维及其制备方法 |
CN106012101A (zh) * | 2016-06-29 | 2016-10-12 | 郭舒洋 | 一种高导电复合纤维的制备方法 |
CN107630390A (zh) * | 2017-09-27 | 2018-01-26 | 华南理工大学 | 一种木质素磺酸增强聚吡咯导电纸及其制备方法 |
CN108330684A (zh) * | 2018-02-07 | 2018-07-27 | 江南大学 | 一种多功能棉织物及其制备方法 |
Non-Patent Citations (1)
Title |
---|
BO WANG 等: "A stretchable and hydrophobic polypyrrole/knitted cotton fabric electrode for all-solid-state supercapacitor with excellent strain capacitance", 《ELECTROCHIMICA ACTA》 * |
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111198219A (zh) * | 2020-02-19 | 2020-05-26 | 苏州微湃医疗科技有限公司 | 一种用于汗液检测的可穿戴式生物传感器 |
CN111198219B (zh) * | 2020-02-19 | 2022-09-13 | 苏州微湃医疗科技有限公司 | 一种用于汗液检测的可穿戴式生物传感器 |
CN112127166A (zh) * | 2020-08-07 | 2020-12-25 | 浙江理工大学 | 原位聚合低电阻稳定传导疏水织物的制备方法 |
CN112053859A (zh) * | 2020-08-29 | 2020-12-08 | 盐城工学院 | 一种基于织物的柔性平面微型超级电容器的制备方法 |
CN112053859B (zh) * | 2020-08-29 | 2021-12-03 | 盐城工学院 | 一种基于织物的柔性平面微型超级电容器的制备方法 |
CN113417157A (zh) * | 2021-06-18 | 2021-09-21 | 广东省科学院微生物研究所(广东省微生物分析检测中心) | 一种超耐洗双功能可穿戴电子织物及其制备方法 |
CN115323784A (zh) * | 2022-01-27 | 2022-11-11 | 青岛大学 | 一种聚吡咯导电柔性纤维膜材料及其制备方法 |
CN116641229A (zh) * | 2023-06-06 | 2023-08-25 | 江苏瑞洋安泰新材料科技有限公司 | 一种导电超疏水织物及其制备方法 |
CN116641229B (zh) * | 2023-06-06 | 2023-11-03 | 江苏瑞洋安泰新材料科技有限公司 | 一种导电超疏水织物及其制备方法 |
Also Published As
Publication number | Publication date |
---|---|
CN110747626B (zh) | 2021-07-27 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN110747626B (zh) | 一种疏水导电织物的制备方法及其所得材料和应用 | |
CN108335919B (zh) | 一种金属有机框架/导电聚合物复合材料、其制备和应用 | |
Miao et al. | Electrospun polymer nanofiber membrane electrodes and an electrolyte for highly flexible and foldable all-solid-state supercapacitors | |
CN108103616B (zh) | 一种氮掺杂的木质素基碳纤维复合材料的制备方法 | |
CN101070672A (zh) | 一种超疏水导电纤维、织物及其制备方法和应用 | |
CN105702483B (zh) | 一种纸基聚吡咯复合膜及其制备方法 | |
WO2021114321A1 (zh) | 一种柔性导电纤维膜材料及其制备方法 | |
CN108841175B (zh) | 多孔活性碳/MnS/聚吡咯三元复合纳米纤维的制备方法及用途 | |
CN104916448A (zh) | 一种层次结构微纳多孔纤维电极材料及其制备方法 | |
CN102050947A (zh) | 聚苯胺纳米纤维的乳液聚合物及制备方法 | |
CN110556251B (zh) | 线型超级电容器用电极材料及其制备方法与超级电容器 | |
Liu et al. | High‐performance textile electrode enhanced by surface modifications of fiberglass cloth with polypyrrole tentacles for flexible supercapacitors | |
CN113690057B (zh) | 植酸电化学氧化-聚吡咯/碳纤维复合材料及其制备方法和应用 | |
CN110265229B (zh) | 纸纤维/本征态聚苯胺超级电容器复合电极材料制备方法 | |
Chen et al. | Recent advances in flexible supercapacitors | |
WO2017155185A1 (ko) | 코팅된 다공성 재료의 제조방법, 코팅된 다공성 재료 및 코팅된 다공성 재료를 포함하는 전극 | |
CN108666147B (zh) | 一种沉积导电高分子的复合间隔织物及其制备和应用 | |
Wang et al. | Porous polyvinyl chloride films as substrate for polyaniline-based flexible and robust free-standing electrodes for high performance supercapacitors | |
CN108389729B (zh) | 一种石墨烯织物电极或纱线电极的制备方法及在超级电容器中的应用 | |
Zhao et al. | Electrode Material of PVA/PANI/GO‐PANI Hybrid Hydrogels through Secondary Induced Assembly In Situ Polymerization Method for Flexible Supercapacitors | |
CN105322193B (zh) | 一种纳米碳纤维膜及其制备和在锂空气电池正极中的应用 | |
KR101751819B1 (ko) | 폴리아닐린 나노와이어를 포함하는 유연 섬유 투명 전극의 제조방법과 그에 따른 폴리아닐린 나노와이어를 포함하는 유연 섬유 투명 전극 | |
CN113490639B (zh) | 在多孔碳质基底的表面上和主体内生长碳纳米管的方法以及用于制备电极的用途 | |
Dong et al. | Whole-polymers electrode membrane based on the interfacial polymerization and intermacromolecular force between polyaniline and polyethersulfone for flexible supercapacitors | |
CN114512350A (zh) | 一种具有自支撑的柔性碳材料及其制备方法和应用 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
GR01 | Patent grant | ||
GR01 | Patent grant |