CN110719934B - 官能化乙烯和1,3-丁二烯共聚物 - Google Patents

官能化乙烯和1,3-丁二烯共聚物 Download PDF

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Publication number
CN110719934B
CN110719934B CN201880037701.9A CN201880037701A CN110719934B CN 110719934 B CN110719934 B CN 110719934B CN 201880037701 A CN201880037701 A CN 201880037701A CN 110719934 B CN110719934 B CN 110719934B
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group
copolymer
functional group
substituted
formula
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Chinese (zh)
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CN110719934A (zh
Inventor
J·蒂耶
V·拉法奎尔
L·佩赫利万
B·马克龙
C·布瓦松
F·达戈斯托
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Compagnie Generale des Etablissements Michelin SCA
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Compagnie Generale des Etablissements Michelin SCA
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F236/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F236/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F236/06—Butadiene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F236/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F236/08—Isoprene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/54—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with other compounds thereof
    • C08F4/545—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with other compounds thereof rare earths being present, e.g. triethylaluminium + neodymium octanoate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/42—Introducing metal atoms or metal-containing groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2800/00—Copolymer characterised by the proportions of the comonomers expressed
    • C08F2800/10—Copolymer characterised by the proportions of the comonomers expressed as molar percentages
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2810/00—Chemical modification of a polymer
    • C08F2810/40—Chemical modification of a polymer taking place solely at one end or both ends of the polymer backbone, i.e. not in the side or lateral chains

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Macromonomer-Based Addition Polymer (AREA)
CN201880037701.9A 2017-06-08 2018-06-06 官能化乙烯和1,3-丁二烯共聚物 Active CN110719934B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FR1755107A FR3067354B1 (fr) 2017-06-08 2017-06-08 Copolymere fonctionnel d'ethylene et de 1,3-butadiene
FR17/55107 2017-06-08
PCT/FR2018/051305 WO2018224774A1 (fr) 2017-06-08 2018-06-06 Copolymere fonctionnel d'ethylene et de 1,3-butadiene

Publications (2)

Publication Number Publication Date
CN110719934A CN110719934A (zh) 2020-01-21
CN110719934B true CN110719934B (zh) 2022-06-24

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CN201880037701.9A Active CN110719934B (zh) 2017-06-08 2018-06-06 官能化乙烯和1,3-丁二烯共聚物

Country Status (6)

Country Link
US (1) US11155656B2 (cg-RX-API-DMAC10.html)
EP (1) EP3635051B1 (cg-RX-API-DMAC10.html)
JP (1) JP7307684B2 (cg-RX-API-DMAC10.html)
CN (1) CN110719934B (cg-RX-API-DMAC10.html)
FR (1) FR3067354B1 (cg-RX-API-DMAC10.html)
WO (1) WO2018224774A1 (cg-RX-API-DMAC10.html)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR3090659A3 (fr) * 2018-12-21 2020-06-26 Michelin & Cie Bande de roulement pour pneumatique
FR3090654A3 (fr) * 2018-12-21 2020-06-26 Michelin & Cie Composition de caoutchouc
FR3100812B1 (fr) * 2019-09-18 2021-09-03 Michelin & Cie Copolymères d’éthylène et de 1,3-diène fonctionnels
FR3104585B1 (fr) * 2019-12-17 2021-12-03 Michelin & Cie Système catalytique à base d’un métallocène et d’un diorganomagnésien
FR3116535B1 (fr) * 2020-11-24 2022-11-25 Michelin & Cie Polymères téléchéliques à base d’éthylène et de 1,3-diène
US20260234300A1 (en) 2023-02-08 2026-08-13 ExxonMobil Technology and Engineering Company Catalysts for Copolymerizations
WO2024253829A1 (en) 2023-06-06 2024-12-12 ExxonMobil Technology and Engineering Company Solution catalyst systems and uses thereof
FR3168886A1 (fr) 2024-11-26 2026-05-29 Compagnie Generale Des Etablissements Michelin Polymère dibloc formé d’un bloc polystyrène et d’un bloc copolymère statistique d’un diène ramifié et de l‘éthylène et portant une fonction silanol ou alcoxysilane.

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6992147B1 (en) * 1999-11-12 2006-01-31 Bridgestone Corporation Modified polymers prepared with lanthanide-based catalysts
CN101309927A (zh) * 2005-11-09 2008-11-19 米其林技术公司 镧系元素的氢硼化茂金属配合物、包括所述配合物的催化体系、使用相同配合物的聚合方法和使用所述方法获得的乙烯-丁二烯共聚物

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2799468B1 (fr) 1999-10-12 2006-04-28 Michelin Soc Tech Systeme catalytique utilisable pour la copolymerisation de l'ethylene et d'un diene conjugue, procede de preparation de ce systeme catalytique et d'un copolymere d'ethylene et d'un diene conjugue
JP2004018697A (ja) * 2002-06-17 2004-01-22 Tosoh Corp エチレン−共役ジエン系共重合体の製造方法
CN100523023C (zh) 2002-10-16 2009-08-05 米其林技术公司 乙烯/丁二烯共聚物,用于合成其的催化体系和方法
FR2893029B1 (fr) 2005-11-09 2009-01-16 Michelin Soc Tech Complexe metallocene borohydrure d'un lanthanide, systeme catalytique l'incorporant, procede de polymerisation l'utilisant et copolymere ethylene/butadiene obtenu par ce procede
JP5217378B2 (ja) * 2007-11-16 2013-06-19 Jsr株式会社 変性共役ジエン系重合体の製造方法
JP5370076B2 (ja) * 2009-10-28 2013-12-18 宇部興産株式会社 共役ジエン重合体変性物及びその製造方法
CN103154059B (zh) * 2010-07-30 2014-12-24 株式会社普利司通 共轭二烯化合物与非共轭烯烃的共聚物、橡胶组合物、交联橡胶组合物和轮胎
FR2984904B1 (fr) * 2011-12-22 2014-01-03 Michelin Soc Tech Composition de caoutchouc
FR3044241A1 (fr) * 2015-12-01 2017-06-02 Michelin & Cie Systeme catalytique comprenant un metallocene de terre rare

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6992147B1 (en) * 1999-11-12 2006-01-31 Bridgestone Corporation Modified polymers prepared with lanthanide-based catalysts
CN101309927A (zh) * 2005-11-09 2008-11-19 米其林技术公司 镧系元素的氢硼化茂金属配合物、包括所述配合物的催化体系、使用相同配合物的聚合方法和使用所述方法获得的乙烯-丁二烯共聚物

Also Published As

Publication number Publication date
JP2020522597A (ja) 2020-07-30
WO2018224774A1 (fr) 2018-12-13
FR3067354B1 (fr) 2020-10-23
US20200140587A1 (en) 2020-05-07
JP7307684B2 (ja) 2023-07-12
CN110719934A (zh) 2020-01-21
FR3067354A1 (fr) 2018-12-14
EP3635051A1 (fr) 2020-04-15
US11155656B2 (en) 2021-10-26
EP3635051B1 (fr) 2021-11-17

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