JP7307684B2 - エチレンと１，３－ブタジエンとの官能性コポリマー - Google Patents

エチレンと１，３－ブタジエンとの官能性コポリマー Download PDF

Info

Publication number
JP7307684B2
JP7307684B2 JP2019567297A JP2019567297A JP7307684B2 JP 7307684 B2 JP7307684 B2 JP 7307684B2 JP 2019567297 A JP2019567297 A JP 2019567297A JP 2019567297 A JP2019567297 A JP 2019567297A JP 7307684 B2 JP7307684 B2 JP 7307684B2
Authority
JP
Japan
Prior art keywords
group
functional group
formula
copolymer
iii
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
JP2019567297A
Other languages
English (en)
Japanese (ja)
Other versions
JP2020522597A (ja
JP2020522597A5 (cg-RX-API-DMAC10.html
Inventor
ジュリアン テュイリエ
ヴィンセント ラファキエール
レイラ ペリヴァン
ブノワ マクロン
クリストフ ボワソン
フランク ダゴスト
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Compagnie Generale des Etablissements Michelin SCA
Original Assignee
Compagnie Generale des Etablissements Michelin SCA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Compagnie Generale des Etablissements Michelin SCA filed Critical Compagnie Generale des Etablissements Michelin SCA
Publication of JP2020522597A publication Critical patent/JP2020522597A/ja
Publication of JP2020522597A5 publication Critical patent/JP2020522597A5/ja
Application granted granted Critical
Publication of JP7307684B2 publication Critical patent/JP7307684B2/ja
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F236/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F236/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F236/06—Butadiene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F236/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F236/08—Isoprene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/54—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with other compounds thereof
    • C08F4/545—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with other compounds thereof rare earths being present, e.g. triethylaluminium + neodymium octanoate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/42—Introducing metal atoms or metal-containing groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2800/00—Copolymer characterised by the proportions of the comonomers expressed
    • C08F2800/10—Copolymer characterised by the proportions of the comonomers expressed as molar percentages
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2810/00—Chemical modification of a polymer
    • C08F2810/40—Chemical modification of a polymer taking place solely at one end or both ends of the polymer backbone, i.e. not in the side or lateral chains

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Macromonomer-Based Addition Polymer (AREA)
JP2019567297A 2017-06-08 2018-06-06 エチレンと１，３－ブタジエンとの官能性コポリマー Active JP7307684B2 (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FR1755107A FR3067354B1 (fr) 2017-06-08 2017-06-08 Copolymere fonctionnel d'ethylene et de 1,3-butadiene
FR17/55107 2017-06-08
PCT/FR2018/051305 WO2018224774A1 (fr) 2017-06-08 2018-06-06 Copolymere fonctionnel d'ethylene et de 1,3-butadiene

Publications (3)

Publication Number Publication Date
JP2020522597A JP2020522597A (ja) 2020-07-30
JP2020522597A5 JP2020522597A5 (cg-RX-API-DMAC10.html) 2021-07-26
JP7307684B2 true JP7307684B2 (ja) 2023-07-12

Family

ID=59974531

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2019567297A Active JP7307684B2 (ja) 2017-06-08 2018-06-06 エチレンと１，３－ブタジエンとの官能性コポリマー

Country Status (6)

Country Link
US (1) US11155656B2 (cg-RX-API-DMAC10.html)
EP (1) EP3635051B1 (cg-RX-API-DMAC10.html)
JP (1) JP7307684B2 (cg-RX-API-DMAC10.html)
CN (1) CN110719934B (cg-RX-API-DMAC10.html)
FR (1) FR3067354B1 (cg-RX-API-DMAC10.html)
WO (1) WO2018224774A1 (cg-RX-API-DMAC10.html)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR3090659A3 (fr) * 2018-12-21 2020-06-26 Michelin & Cie Bande de roulement pour pneumatique
FR3090654A3 (fr) * 2018-12-21 2020-06-26 Michelin & Cie Composition de caoutchouc
FR3100812B1 (fr) * 2019-09-18 2021-09-03 Michelin & Cie Copolymères d’éthylène et de 1,3-diène fonctionnels
FR3104585B1 (fr) * 2019-12-17 2021-12-03 Michelin & Cie Système catalytique à base d’un métallocène et d’un diorganomagnésien
FR3116535B1 (fr) * 2020-11-24 2022-11-25 Michelin & Cie Polymères téléchéliques à base d’éthylène et de 1,3-diène
US20260234300A1 (en) 2023-02-08 2026-08-13 ExxonMobil Technology and Engineering Company Catalysts for Copolymerizations
WO2024253829A1 (en) 2023-06-06 2024-12-12 ExxonMobil Technology and Engineering Company Solution catalyst systems and uses thereof
FR3168886A1 (fr) 2024-11-26 2026-05-29 Compagnie Generale Des Etablissements Michelin Polymère dibloc formé d’un bloc polystyrène et d’un bloc copolymère statistique d’un diène ramifié et de l‘éthylène et portant une fonction silanol ou alcoxysilane.

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2003514078A (ja) 1999-11-12 2003-04-15 株式会社ブリヂストン ランタニドを基にした触媒を用いて製造した変性重合体
JP2004018697A (ja) 2002-06-17 2004-01-22 Tosoh Corp エチレン−共役ジエン系共重合体の製造方法
JP2009515015A (ja) 2005-11-09 2009-04-09 ソシエテ ド テクノロジー ミシュラン ランタニドのホウ化水素メタロセン複合体、該複合体を含む触媒系、該触媒を使用する重合方法、および該方法を使用して得られたエチレン−ブタジエンコポリマー
JP2009120758A (ja) 2007-11-16 2009-06-04 Jsr Corp 変性共役ジエン系重合体の製造方法、変性共役ジエン系重合体、及びゴム組成物
JP2011093967A (ja) 2009-10-28 2011-05-12 Ube Industries Ltd 共役ジエン重合体変性物及びその製造方法
WO2012014455A1 (ja) 2010-07-30 2012-02-02 株式会社ブリヂストン 共役ジエン化合物と非共役オレフィンとの共重合体、ゴム組成物、架橋ゴム組成物、及びタイヤ
JP2018536759A (ja) 2015-12-01 2018-12-13 コンパニー ゼネラール デ エタブリッスマン ミシュラン 希土類メタロセンを含む触媒系

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2799468B1 (fr) 1999-10-12 2006-04-28 Michelin Soc Tech Systeme catalytique utilisable pour la copolymerisation de l'ethylene et d'un diene conjugue, procede de preparation de ce systeme catalytique et d'un copolymere d'ethylene et d'un diene conjugue
CN100523023C (zh) 2002-10-16 2009-08-05 米其林技术公司 乙烯/丁二烯共聚物,用于合成其的催化体系和方法
FR2893029B1 (fr) 2005-11-09 2009-01-16 Michelin Soc Tech Complexe metallocene borohydrure d'un lanthanide, systeme catalytique l'incorporant, procede de polymerisation l'utilisant et copolymere ethylene/butadiene obtenu par ce procede
FR2984904B1 (fr) * 2011-12-22 2014-01-03 Michelin Soc Tech Composition de caoutchouc

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2003514078A (ja) 1999-11-12 2003-04-15 株式会社ブリヂストン ランタニドを基にした触媒を用いて製造した変性重合体
JP2004018697A (ja) 2002-06-17 2004-01-22 Tosoh Corp エチレン−共役ジエン系共重合体の製造方法
JP2009515015A (ja) 2005-11-09 2009-04-09 ソシエテ ド テクノロジー ミシュラン ランタニドのホウ化水素メタロセン複合体、該複合体を含む触媒系、該触媒を使用する重合方法、および該方法を使用して得られたエチレン−ブタジエンコポリマー
JP2014088405A (ja) 2005-11-09 2014-05-15 Company General De Etablisman Michelin ランタニドのホウ化水素メタロセン複合体、該複合体を含む触媒系、該触媒を使用する重合方法、および該方法を使用して得られたエチレン−ブタジエンコポリマー
JP2009120758A (ja) 2007-11-16 2009-06-04 Jsr Corp 変性共役ジエン系重合体の製造方法、変性共役ジエン系重合体、及びゴム組成物
JP2011093967A (ja) 2009-10-28 2011-05-12 Ube Industries Ltd 共役ジエン重合体変性物及びその製造方法
WO2012014455A1 (ja) 2010-07-30 2012-02-02 株式会社ブリヂストン 共役ジエン化合物と非共役オレフィンとの共重合体、ゴム組成物、架橋ゴム組成物、及びタイヤ
JP2018536759A (ja) 2015-12-01 2018-12-13 コンパニー ゼネラール デ エタブリッスマン ミシュラン 希土類メタロセンを含む触媒系

Also Published As

Publication number Publication date
JP2020522597A (ja) 2020-07-30
WO2018224774A1 (fr) 2018-12-13
CN110719934B (zh) 2022-06-24
FR3067354B1 (fr) 2020-10-23
US20200140587A1 (en) 2020-05-07
CN110719934A (zh) 2020-01-21
FR3067354A1 (fr) 2018-12-14
EP3635051A1 (fr) 2020-04-15
US11155656B2 (en) 2021-10-26
EP3635051B1 (fr) 2021-11-17

Similar Documents

Publication Publication Date Title
JP7187492B2 (ja) ゴム組成物
US11155656B2 (en) Functional ethylene and 1,3-butadiene copolymer
JP7204684B2 (ja) １，３－ジエンとオレフィンとからなる官能性コポリマー
CN102449002B (zh) 用于共轭二烯聚合的催化体系、聚合方法和所得到的官能聚合物
CN114521198B (zh) 官能化的乙烯与1,3-二烯的共聚物
JP2009515015A (ja) ランタニドのホウ化水素メタロセン複合体、該複合体を含む触媒系、該触媒を使用する重合方法、および該方法を使用して得られたエチレン−ブタジエンコポリマー
JP6811250B2 (ja) ［ビス（トリヒドロカルビルシリル）アミノシリル］−官能化スチレンおよびその調製方法
WO2015199222A1 (ja) 水素化重合体の製造方法
CN112888580B (zh) 橡胶组合物
JP7354293B2 (ja) 共役ジエン系グラフト重合体からなる粘度指数向上剤、及び油組成物
JP7673055B2 (ja) エチレンと１，３－ジエンの官能性コポリマー
CN114829418A (zh) 用于催化体系的二有机镁化合物
US12570775B2 (en) Catalytic system based on a metallocene and a diorganomagnesium
CN117222677B (zh) 1,3-二烯与乙烯的官能共聚物或者1,3-二烯、乙烯与α-单烯烃的官能共聚物
EP0497954A1 (en) Silyl derivatives of eugenol
AU5406294A (en) Process for preparing epoxy-terminated polymers
JPH03106890A (ja) ２―アリルフェノールのシリル誘導体
KR20190037521A (ko) 중합체의 변성률 측정 방법

Legal Events

Date Code Title Description
A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20210528

A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20210528

A977 Report on retrieval

Free format text: JAPANESE INTERMEDIATE CODE: A971007

Effective date: 20220531

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20220608

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20220907

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20221226

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20230316

TRDD Decision of grant or rejection written
A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

Effective date: 20230601

A61 First payment of annual fees (during grant procedure)

Free format text: JAPANESE INTERMEDIATE CODE: A61

Effective date: 20230630

R150 Certificate of patent or registration of utility model

Ref document number: 7307684

Country of ref document: JP

Free format text: JAPANESE INTERMEDIATE CODE: R150

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250