FR3067354B1 - Copolymere fonctionnel d'ethylene et de 1,3-butadiene - Google Patents

Copolymere fonctionnel d'ethylene et de 1,3-butadiene Download PDF

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Publication number
FR3067354B1
FR3067354B1 FR1755107A FR1755107A FR3067354B1 FR 3067354 B1 FR3067354 B1 FR 3067354B1 FR 1755107 A FR1755107 A FR 1755107A FR 1755107 A FR1755107 A FR 1755107A FR 3067354 B1 FR3067354 B1 FR 3067354B1
Authority
FR
France
Prior art keywords
butadiene
ethylene
functional copolymer
units
copolymer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
FR1755107A
Other languages
English (en)
French (fr)
Other versions
FR3067354A1 (fr
Inventor
Julien Thuilliez
Vincent Lafaquiere
Leyla Pehlivan
Benoît MACQUERON
Christophe Boisson
Franck D'agosto
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Centre National de la Recherche Scientifique
Compagnie Generale des Etablissements Michelin SCA
École d'Ingénieurs en Chimie et Sciences du Numérique
Université Claude Bernard Lyon 1
Original Assignee
Centre National de la Recherche Scientifique
Compagnie Generale des Etablissements Michelin SCA
École d'Ingénieurs en Chimie et Sciences du Numérique
Université Claude Bernard Lyon 1
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Centre National de la Recherche Scientifique, Compagnie Generale des Etablissements Michelin SCA, École d'Ingénieurs en Chimie et Sciences du Numérique, Université Claude Bernard Lyon 1 filed Critical Centre National de la Recherche Scientifique
Priority to FR1755107A priority Critical patent/FR3067354B1/fr
Priority to EP18737662.9A priority patent/EP3635051B1/fr
Priority to PCT/FR2018/051305 priority patent/WO2018224774A1/fr
Priority to JP2019567297A priority patent/JP7307684B2/ja
Priority to CN201880037701.9A priority patent/CN110719934B/zh
Priority to US16/619,864 priority patent/US11155656B2/en
Publication of FR3067354A1 publication Critical patent/FR3067354A1/fr
Application granted granted Critical
Publication of FR3067354B1 publication Critical patent/FR3067354B1/fr
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F236/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F236/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F236/06—Butadiene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F236/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F236/08—Isoprene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/54—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with other compounds thereof
    • C08F4/545—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with other compounds thereof rare earths being present, e.g. triethylaluminium + neodymium octanoate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/42—Introducing metal atoms or metal-containing groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2800/00—Copolymer characterised by the proportions of the comonomers expressed
    • C08F2800/10—Copolymer characterised by the proportions of the comonomers expressed as molar percentages
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2810/00—Chemical modification of a polymer
    • C08F2810/40—Chemical modification of a polymer taking place solely at one end or both ends of the polymer backbone, i.e. not in the side or lateral chains

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Macromonomer-Based Addition Polymer (AREA)
FR1755107A 2017-06-08 2017-06-08 Copolymere fonctionnel d'ethylene et de 1,3-butadiene Expired - Fee Related FR3067354B1 (fr)

Priority Applications (6)

Application Number Priority Date Filing Date Title
FR1755107A FR3067354B1 (fr) 2017-06-08 2017-06-08 Copolymere fonctionnel d'ethylene et de 1,3-butadiene
EP18737662.9A EP3635051B1 (fr) 2017-06-08 2018-06-06 Copolymere fonctionnel d'ethylene et de 1,3-butadiene
PCT/FR2018/051305 WO2018224774A1 (fr) 2017-06-08 2018-06-06 Copolymere fonctionnel d'ethylene et de 1,3-butadiene
JP2019567297A JP7307684B2 (ja) 2017-06-08 2018-06-06 エチレンと１，３－ブタジエンとの官能性コポリマー
CN201880037701.9A CN110719934B (zh) 2017-06-08 2018-06-06 官能化乙烯和1,3-丁二烯共聚物
US16/619,864 US11155656B2 (en) 2017-06-08 2018-06-06 Functional ethylene and 1,3-butadiene copolymer

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR1755107A FR3067354B1 (fr) 2017-06-08 2017-06-08 Copolymere fonctionnel d'ethylene et de 1,3-butadiene
FR1755107 2017-06-08

Publications (2)

Publication Number Publication Date
FR3067354A1 FR3067354A1 (fr) 2018-12-14
FR3067354B1 true FR3067354B1 (fr) 2020-10-23

Family

ID=59974531

Family Applications (1)

Application Number Title Priority Date Filing Date
FR1755107A Expired - Fee Related FR3067354B1 (fr) 2017-06-08 2017-06-08 Copolymere fonctionnel d'ethylene et de 1,3-butadiene

Country Status (6)

Country Link
US (1) US11155656B2 (cg-RX-API-DMAC10.html)
EP (1) EP3635051B1 (cg-RX-API-DMAC10.html)
JP (1) JP7307684B2 (cg-RX-API-DMAC10.html)
CN (1) CN110719934B (cg-RX-API-DMAC10.html)
FR (1) FR3067354B1 (cg-RX-API-DMAC10.html)
WO (1) WO2018224774A1 (cg-RX-API-DMAC10.html)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR3090659A3 (fr) * 2018-12-21 2020-06-26 Michelin & Cie Bande de roulement pour pneumatique
FR3090654A3 (fr) * 2018-12-21 2020-06-26 Michelin & Cie Composition de caoutchouc
FR3100812B1 (fr) * 2019-09-18 2021-09-03 Michelin & Cie Copolymères d’éthylène et de 1,3-diène fonctionnels
FR3104585B1 (fr) * 2019-12-17 2021-12-03 Michelin & Cie Système catalytique à base d’un métallocène et d’un diorganomagnésien
FR3116535B1 (fr) * 2020-11-24 2022-11-25 Michelin & Cie Polymères téléchéliques à base d’éthylène et de 1,3-diène
US20260234300A1 (en) 2023-02-08 2026-08-13 ExxonMobil Technology and Engineering Company Catalysts for Copolymerizations
WO2024253829A1 (en) 2023-06-06 2024-12-12 ExxonMobil Technology and Engineering Company Solution catalyst systems and uses thereof
FR3168886A1 (fr) 2024-11-26 2026-05-29 Compagnie Generale Des Etablissements Michelin Polymère dibloc formé d’un bloc polystyrène et d’un bloc copolymère statistique d’un diène ramifié et de l‘éthylène et portant une fonction silanol ou alcoxysilane.

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2799468B1 (fr) 1999-10-12 2006-04-28 Michelin Soc Tech Systeme catalytique utilisable pour la copolymerisation de l'ethylene et d'un diene conjugue, procede de preparation de ce systeme catalytique et d'un copolymere d'ethylene et d'un diene conjugue
DE60041550D1 (de) * 1999-11-12 2009-03-26 Bridgestone Corp Modifizierte polymere hergestellt mit katalysator auf basys von lanthaniden
JP2004018697A (ja) * 2002-06-17 2004-01-22 Tosoh Corp エチレン−共役ジエン系共重合体の製造方法
CN100523023C (zh) 2002-10-16 2009-08-05 米其林技术公司 乙烯/丁二烯共聚物,用于合成其的催化体系和方法
FR2893029B1 (fr) 2005-11-09 2009-01-16 Michelin Soc Tech Complexe metallocene borohydrure d'un lanthanide, systeme catalytique l'incorporant, procede de polymerisation l'utilisant et copolymere ethylene/butadiene obtenu par ce procede
FR2893028B1 (fr) 2005-11-09 2008-02-15 Michelin Soc Tech Complexe metallocene borohydrure d'un lanthanide, systeme catalytique l'incorporant, procede de polymerisation l'utilisant et copolymere ethylene/butadiene obtenu par ce procede
JP5217378B2 (ja) * 2007-11-16 2013-06-19 Ｊｓｒ株式会社 変性共役ジエン系重合体の製造方法
JP5370076B2 (ja) * 2009-10-28 2013-12-18 宇部興産株式会社 共役ジエン重合体変性物及びその製造方法
CN103154059B (zh) * 2010-07-30 2014-12-24 株式会社普利司通 共轭二烯化合物与非共轭烯烃的共聚物、橡胶组合物、交联橡胶组合物和轮胎
FR2984904B1 (fr) * 2011-12-22 2014-01-03 Michelin Soc Tech Composition de caoutchouc
FR3044241A1 (fr) * 2015-12-01 2017-06-02 Michelin & Cie Systeme catalytique comprenant un metallocene de terre rare

Also Published As

Publication number Publication date
JP2020522597A (ja) 2020-07-30
WO2018224774A1 (fr) 2018-12-13
CN110719934B (zh) 2022-06-24
US20200140587A1 (en) 2020-05-07
JP7307684B2 (ja) 2023-07-12
CN110719934A (zh) 2020-01-21
FR3067354A1 (fr) 2018-12-14
EP3635051A1 (fr) 2020-04-15
US11155656B2 (en) 2021-10-26
EP3635051B1 (fr) 2021-11-17

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