CN1103785C - 偏氟乙烯聚合方法 - Google Patents

偏氟乙烯聚合方法 Download PDF

Info

Publication number
CN1103785C
CN1103785C CN97114826A CN97114826A CN1103785C CN 1103785 C CN1103785 C CN 1103785C CN 97114826 A CN97114826 A CN 97114826A CN 97114826 A CN97114826 A CN 97114826A CN 1103785 C CN1103785 C CN 1103785C
Authority
CN
China
Prior art keywords
molecular weight
end group
polyoxyalkylene
perfluoro
fluoro
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
CN97114826A
Other languages
English (en)
Chinese (zh)
Other versions
CN1172122A (zh
Inventor
G·布里那蒂
P·拉扎里
V·阿尔色拉
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Solvay Specialty Polymers Italy SpA
Original Assignee
Ausimont SpA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ausimont SpA filed Critical Ausimont SpA
Publication of CN1172122A publication Critical patent/CN1172122A/zh
Application granted granted Critical
Publication of CN1103785C publication Critical patent/CN1103785C/zh
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F14/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F14/18—Monomers containing fluorine
    • C08F14/22—Vinylidene fluoride
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/12—Polymerisation in non-solvents
    • C08F2/16—Aqueous medium

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
CN97114826A 1996-07-01 1997-07-01 偏氟乙烯聚合方法 Expired - Lifetime CN1103785C (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
ITMI96A001342 1996-07-01
IT96MI001342A IT1295535B1 (it) 1996-07-01 1996-07-01 Processo di polimerizzazione di vinilidenfluoruro (vdf)

Publications (2)

Publication Number Publication Date
CN1172122A CN1172122A (zh) 1998-02-04
CN1103785C true CN1103785C (zh) 2003-03-26

Family

ID=11374511

Family Applications (1)

Application Number Title Priority Date Filing Date
CN97114826A Expired - Lifetime CN1103785C (zh) 1996-07-01 1997-07-01 偏氟乙烯聚合方法

Country Status (9)

Country Link
US (1) US7122608B1 (enExample)
EP (1) EP0816397B1 (enExample)
JP (1) JPH1060054A (enExample)
KR (1) KR100476078B1 (enExample)
CN (1) CN1103785C (enExample)
CA (1) CA2209324C (enExample)
DE (1) DE69704040T2 (enExample)
IT (1) IT1295535B1 (enExample)
RU (1) RU2184744C2 (enExample)

Families Citing this family (68)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ITMI981519A1 (it) * 1998-07-02 2000-01-02 Ausimont Spa Processodi polimerizzazione del tfe
IT1307756B1 (it) 1999-02-05 2001-11-19 Ausimont Spa Polimeri elettroliti per batterie ricaricabili al litio.
ITMI991516A1 (it) * 1999-07-09 2001-01-09 Ausimont Spa Sintesi dei copolimeri peralogenati termoprocesabili del clorotrifluoroetilene
US6677414B2 (en) 1999-12-30 2004-01-13 3M Innovative Properties Company Aqueous emulsion polymerization process for the manufacturing of fluoropolymers
US7279522B2 (en) 2001-09-05 2007-10-09 3M Innovative Properties Company Fluoropolymer dispersions containing no or little low molecular weight fluorinated surfactant
ATE338073T1 (de) 2002-05-22 2006-09-15 3M Innovative Properties Co Prozess zur reduzierung des gehaltes an fluorierten emulgatoren in wässrigen fluorpolymer-dispersionen
CN1662566B (zh) * 2002-06-21 2010-06-16 3M创新有限公司 极性端基量减少的含氟聚合物的制备方法
EP1452571B1 (en) 2003-02-28 2005-08-17 3M Innovative Properties Company Fluoropolymer dispersion containing no or little low molecular weight fluorinated surfactant
FR2852017B1 (fr) 2003-03-03 2005-04-22 Atofina Procede de fabrication de pvdf thermiquement stable
FR2852016B1 (fr) 2003-03-03 2006-07-07 Atofina Procede de fabrication de pvdf thermiquement stable
US6841616B2 (en) 2003-03-28 2005-01-11 Arkema Inc. Polymerization of halogen-containing monomers using siloxane surfactant
US6869997B2 (en) 2003-05-06 2005-03-22 Arkema, Inc. Polymerization of fluoromonomers using a 3-allyloxy-2-hydroxy-1-propanesulfonic acid salt as surfactant
EP1529785B1 (en) 2003-10-24 2011-03-16 3M Innovative Properties Company Aqueous dispersions of polytetrafluoroethylene particles
EP1533325B1 (en) 2003-11-17 2011-10-19 3M Innovative Properties Company Aqueous dispersions of polytetrafluoroethylene having a low amount of fluorinated surfactant
EP1561742B1 (en) 2004-02-05 2012-11-21 3M Innovative Properties Company Method of recovering fluorinated acid surfactants from adsorbent particles loaded therewith
EP1561729A1 (en) 2004-02-05 2005-08-10 3M Innovative Properties Company Removal of fluorinated surfactants from waste water
US7122610B2 (en) * 2004-04-27 2006-10-17 Arkema Inc. Method of producing thermoplastic fluoropolymers using alkyl sulfonate surfactants
EP1614731B1 (en) 2004-07-05 2008-08-27 3M Innovative Properties Company Primer coating of PTFE for metal substrates
JP2006036986A (ja) * 2004-07-28 2006-02-09 Asahi Glass Co Ltd 含フッ素ポリマーラテックス、その製造方法および含フッ素ポリマー
ITMI20050007A1 (it) 2005-01-05 2006-07-06 Solvay Solexis Spa Uso di dispersioni acquose di polimeri a base di vdf nella preparazione di vernici per rivestimenti di substrati architettonici
DE602005005317T2 (de) 2005-07-07 2009-03-12 Solvay Solexis S.P.A. Polymerisationsverfahren
EP1743921A1 (en) 2005-07-13 2007-01-17 Solvay Solexis S.p.A. Thermoplastic halopolymer composition
EP1743920A1 (en) 2005-07-13 2007-01-17 Solvay Solexis S.p.A. Thermoplastic fluoropolymer composition
US20080015304A1 (en) 2006-07-13 2008-01-17 Klaus Hintzer Aqueous emulsion polymerization process for producing fluoropolymers
US7795332B2 (en) 2005-07-15 2010-09-14 3M Innovative Properties Company Method of removing fluorinated carboxylic acid from aqueous liquid
GB0525978D0 (en) 2005-12-21 2006-02-01 3M Innovative Properties Co Fluorinated Surfactants For Making Fluoropolymers
GB0514398D0 (en) 2005-07-15 2005-08-17 3M Innovative Properties Co Aqueous emulsion polymerization of fluorinated monomers using a fluorinated surfactant
GB0523853D0 (en) 2005-11-24 2006-01-04 3M Innovative Properties Co Fluorinated surfactants for use in making a fluoropolymer
US7728087B2 (en) 2005-12-23 2010-06-01 3M Innovative Properties Company Fluoropolymer dispersion and method for making the same
US7754795B2 (en) 2006-05-25 2010-07-13 3M Innovative Properties Company Coating composition
US8119750B2 (en) 2006-07-13 2012-02-21 3M Innovative Properties Company Explosion taming surfactants for the production of perfluoropolymers
US7932333B2 (en) * 2006-11-09 2011-04-26 E.I. Du Pont De Nemours And Company Aqueous polymerization of fluorinated monomer using polymerization agent comprising high molecular weight fluoropolyether acid or salt and fluoropolyether acid or salt surfactant
JP5439186B2 (ja) * 2006-11-09 2014-03-12 イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー フルオロポリエーテル酸または塩および炭化水素系界面活性剤を含む重合剤を用いるフッ素化モノマーの水性重合
US8338517B2 (en) 2007-05-23 2012-12-25 3M Innovative Properties Company Aqueous compositions of fluorinated surfactants and methods of using the same
WO2008154345A1 (en) 2007-06-06 2008-12-18 3M Innovative Properties Company Fluorinated ether compositions and methods of using the same
CN101274969B (zh) * 2007-11-20 2010-12-29 山东东岳神舟新材料有限公司 一种含氟聚合物的微乳液聚合方法
US20090281261A1 (en) * 2008-05-09 2009-11-12 E. I. Du Pont De Nemours And Company Abatement of Fluoroether Carboxylic Acids or Salts Employed in Fluoropolymer Resin Manufacture
EP2133370A1 (en) * 2008-06-02 2009-12-16 Solvay Solexis S.p.A. Vinylidene fluoride and trifluoroethylene containing polymers
WO2010009191A2 (en) 2008-07-18 2010-01-21 3M Innovative Properties Company Fluorinated ether compounds and methods of using the same
US8629089B2 (en) 2008-12-18 2014-01-14 3M Innovative Properties Company Method of contacting hydrocarbon-bearing formations with fluorinated ether compositions
CN102333825B (zh) 2008-12-31 2014-02-26 埃西勒国际通用光学公司 增强导电性聚合物基涂料的抗静电性能的添加剂
EP2248865A1 (en) 2009-05-07 2010-11-10 Essilor International (Compagnie Générale D'Optique) Antistatic sol/gel compositions and optical articles coated therewith
US8329813B2 (en) 2009-05-08 2012-12-11 E I Du Pont De Nemours And Company Thermal reduction of fluoroether carboxylic acids or salts from fluoropolymer dispersions
CN102822213B (zh) * 2009-12-18 2016-06-15 索尔维特殊聚合物意大利有限公司 制造偏二氟乙烯聚合物分散体的方法
US9803036B2 (en) 2009-12-18 2017-10-31 Solvay Specialty Polymers Italy S.P.A. Method for manufacturing fluoropolymers
EP2450193B1 (en) 2010-11-09 2015-05-06 ESSILOR INTERNATIONAL (Compagnie Générale d'Optique) A process for tinting articles, and tintable compositions for use in said process
CN103270060B (zh) 2010-12-22 2016-02-24 索尔维特殊聚合物意大利有限公司 偏二氟乙烯以及三氟乙烯聚合物
WO2012084578A1 (en) 2010-12-22 2012-06-28 Solvay Specialty Polymers Italy S.P.A. Vinylidene fluoride copolymers
CN102225980B (zh) * 2011-04-29 2012-11-21 内蒙古三爱富万豪氟化工有限公司 一种含氟醚端基结构的聚偏氟乙烯树脂及其制备方法
WO2013010936A1 (en) 2011-07-15 2013-01-24 Solvay Specialty Polymers Italy S.P.A. Aqueous vinylidene fluoride polymer latex
CN103987738B (zh) 2011-12-16 2016-06-01 索尔维特殊聚合物意大利有限公司 氟烯丙基磺酰叠氮化物单体以及由此的聚合物
US10414844B2 (en) 2011-12-16 2019-09-17 Solvay Specialty Polymers Italy S.P.A. Crosslinkable vinylidene fluoride and trifluoroethylene polymers
US10081691B2 (en) 2011-12-16 2018-09-25 Solvay Specialty Polymers Italy S.P.A. Crosslinkable compositions based on vinylidene fluoride-trifluoroethylene polymers
DK3004223T3 (da) 2013-06-04 2021-06-07 Solvay Specialty Polymers It Fremgangsmåde til fremstilling af fluorpolymerkompositter
WO2015128337A1 (en) 2014-02-28 2015-09-03 Solvay Specialty Polymers Italy S.P.A. Crosslinkable fluoropolymers
WO2015169836A1 (en) 2014-05-09 2015-11-12 Solvay Specialty Polymers Italy S.P.A. Fluoropolymer compositions
CN103936906B (zh) * 2014-05-09 2016-08-31 成都晨光博达橡塑有限公司 一种不含全氟辛酸或全氟辛磺酸的含氟聚合物
CN103936905B (zh) * 2014-05-09 2016-09-14 成都晨光博达橡塑有限公司 一种含氟聚合物及其制备方法
JP6722593B2 (ja) 2014-05-19 2020-07-15 アーケマ・インコーポレイテッド 高いメルトフロー性のフルオロポリマー組成物
CN104448078A (zh) * 2014-12-08 2015-03-25 浙江孚诺林化工新材料有限公司 一种采用氟醚磺酸盐制备聚偏氟乙烯的方法
FR3043084B1 (fr) 2015-10-29 2017-10-27 Arkema France Copolymeres fluores fonctionnalises
EP3436524B1 (en) 2016-04-01 2022-06-15 Arkema Inc. 3-d printed fluoropolymer structures
US11629249B2 (en) 2016-10-05 2023-04-18 Solvay Specialty Polymers Italy S.P.A. Vinylidene fluoride and trifluoroethylene containing polymers latexes
EP3645587B1 (en) 2017-06-30 2023-06-14 Solvay Specialty Polymers Italy S.p.A. Method for manufacturing partially fluorinated polymers
FR3069544B1 (fr) 2017-07-28 2020-05-15 Arkema France Procede de preparation d'un film de polymere fluore reticule
WO2019057682A1 (en) * 2017-09-20 2019-03-28 Solvay Specialty Polymers Italy S.P.A. POROUS MEMBRANE AND METHOD FOR MANUFACTURING THE SAME
CN109810212B (zh) * 2017-11-20 2020-05-01 中昊晨光化工研究院有限公司 一种高介电常数聚偏氟乙烯及其制备方法和应用
KR20230007367A (ko) 2020-04-21 2023-01-12 솔베이 스페셜티 폴리머스 이태리 에스.피.에이. 비닐리덴 플루오라이드 및 트리플루오로에틸렌 함유 중합체의 수성 분산물

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN87103869A (zh) * 1986-06-26 1988-01-06 奥西蒙特公司 在水分散液中氟化单体的聚合方法
US4990283A (en) * 1986-06-26 1991-02-05 Ausimont S.P.A. Microemulsions containing perfluoropolyethers
US5473030A (en) * 1993-11-25 1995-12-05 Ausimont S.P.A. Process for preparing vinylidenefluoride polymers

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IT1265067B1 (it) * 1993-05-18 1996-10-30 Ausimont Spa Processo di (co)polimerizzazione in emulsione acquosa di monomeri olefinici fluorurati
IT1265033B1 (it) * 1993-05-28 1996-10-28 Ausimont Spa Polivinilidenfluoruro ad elevate prestazioni meccaniche ed elevata stabilita' termochimica, e relativo processo di preparazione
IT1271422B (it) * 1993-10-15 1997-05-28 Ausimont Spa Procedimento per la preparazione di copolimeri del tetrafluoroetilene con altri monomeri perfluorurati

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN87103869A (zh) * 1986-06-26 1988-01-06 奥西蒙特公司 在水分散液中氟化单体的聚合方法
US4990283A (en) * 1986-06-26 1991-02-05 Ausimont S.P.A. Microemulsions containing perfluoropolyethers
US5473030A (en) * 1993-11-25 1995-12-05 Ausimont S.P.A. Process for preparing vinylidenefluoride polymers

Also Published As

Publication number Publication date
DE69704040D1 (de) 2001-03-15
RU2184744C2 (ru) 2002-07-10
IT1295535B1 (it) 1999-05-12
MX9704991A (es) 1998-06-28
CA2209324C (en) 2008-09-16
KR100476078B1 (ko) 2005-06-16
KR980009299A (ko) 1998-04-30
CN1172122A (zh) 1998-02-04
EP0816397B1 (en) 2001-02-07
ITMI961342A0 (enExample) 1996-07-01
US7122608B1 (en) 2006-10-17
DE69704040T2 (de) 2001-09-20
ITMI961342A1 (it) 1998-01-01
JPH1060054A (ja) 1998-03-03
CA2209324A1 (en) 1998-01-01
EP0816397A1 (en) 1998-01-07

Similar Documents

Publication Publication Date Title
CN1103785C (zh) 偏氟乙烯聚合方法
US8119750B2 (en) Explosion taming surfactants for the production of perfluoropolymers
US7671112B2 (en) Method of making fluoropolymer dispersion
EP1963247B1 (en) Fluorinated surfactants for making fluoropolymers
US7776946B2 (en) Aqueous emulsion polymerization of fluorinated monomers using a fluorinated surfactant
EP1888655B1 (en) Aqueous emulsion polymerization of fluorinated monomers in the presence of a partially fluorinated oligomer as an emulsifier
RU2158273C2 (ru) Фторированные термопластичные эластомеры и способ их получения
US9676929B2 (en) Employing polyalkylene oxides for nucleation in aqueous polymerization of fluoromonomer
WO2007062059A1 (en) Fluorinated surfactants for use in making a fluoropolymer
JP2011520021A (ja) フルオロポリエーテル酸またはその塩の混合物を使用するフッ素化モノマーの水性重合
CN87103158A (zh) 氟化单体在水分散液中的聚合方法
CN1328579A (zh) 氟单体的聚合反应
US8329813B2 (en) Thermal reduction of fluoroether carboxylic acids or salts from fluoropolymer dispersions
EP3375798A1 (en) Method for making fluoropolymers
CN102762611B (zh) 生产氟聚合物的方法
JP3924242B2 (ja) 含フッ素共重合体

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
CX01 Expiry of patent term
CX01 Expiry of patent term

Granted publication date: 20030326