CN110312784A - 洗涤剂组合物 - Google Patents
洗涤剂组合物 Download PDFInfo
- Publication number
- CN110312784A CN110312784A CN201780080202.3A CN201780080202A CN110312784A CN 110312784 A CN110312784 A CN 110312784A CN 201780080202 A CN201780080202 A CN 201780080202A CN 110312784 A CN110312784 A CN 110312784A
- Authority
- CN
- China
- Prior art keywords
- sodium
- glutamate
- cocoyl
- potassium
- oil
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 39
- 239000003599 detergent Substances 0.000 title claims description 20
- 239000004094 surface-active agent Substances 0.000 claims abstract description 13
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 11
- 229930195729 fatty acid Natural products 0.000 claims abstract description 11
- 239000000194 fatty acid Substances 0.000 claims abstract description 11
- 150000004665 fatty acids Chemical class 0.000 claims abstract description 10
- 150000001413 amino acids Chemical class 0.000 claims abstract description 8
- 239000002904 solvent Substances 0.000 claims abstract description 5
- 239000011734 sodium Substances 0.000 claims description 15
- 229910052708 sodium Inorganic materials 0.000 claims description 15
- 150000003626 triacylglycerols Chemical class 0.000 claims description 14
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical group C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 13
- 102000004190 Enzymes Human genes 0.000 claims description 12
- 108090000790 Enzymes Proteins 0.000 claims description 12
- -1 stearyl disodium glutamate Chemical compound 0.000 claims description 12
- 235000004279 alanine Nutrition 0.000 claims description 10
- 229910052700 potassium Inorganic materials 0.000 claims description 10
- 239000011591 potassium Substances 0.000 claims description 10
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 9
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 8
- 239000007788 liquid Substances 0.000 claims description 8
- QNAYBMKLOCPYGJ-REOHCLBHSA-N L-alanine Chemical compound C[C@H](N)C(O)=O QNAYBMKLOCPYGJ-REOHCLBHSA-N 0.000 claims description 7
- 125000002252 acyl group Chemical group 0.000 claims description 7
- 239000004359 castor oil Substances 0.000 claims description 7
- 235000019438 castor oil Nutrition 0.000 claims description 7
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims description 7
- FSYKKLYZXJSNPZ-UHFFFAOYSA-N sarcosine Chemical compound C[NH2+]CC([O-])=O FSYKKLYZXJSNPZ-UHFFFAOYSA-N 0.000 claims description 7
- WHUUTDBJXJRKMK-UHFFFAOYSA-N Glutamic acid Natural products OC(=O)C(N)CCC(O)=O WHUUTDBJXJRKMK-UHFFFAOYSA-N 0.000 claims description 6
- 229940024606 amino acid Drugs 0.000 claims description 6
- 235000001014 amino acid Nutrition 0.000 claims description 6
- 235000013922 glutamic acid Nutrition 0.000 claims description 6
- 239000004220 glutamic acid Substances 0.000 claims description 6
- 235000013905 glycine and its sodium salt Nutrition 0.000 claims description 6
- 239000004247 glycine and its sodium salt Substances 0.000 claims description 6
- 239000003921 oil Substances 0.000 claims description 6
- 235000019198 oils Nutrition 0.000 claims description 6
- 229940029258 sodium glycinate Drugs 0.000 claims description 6
- 108010077895 Sarcosine Proteins 0.000 claims description 5
- 125000001419 myristoyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 5
- 108700004121 sarkosyl Proteins 0.000 claims description 5
- XOAAWQZATWQOTB-UHFFFAOYSA-N taurine Chemical compound NCCS(O)(=O)=O XOAAWQZATWQOTB-UHFFFAOYSA-N 0.000 claims description 5
- FXALIOUHXMVTMJ-UHFFFAOYSA-N CCCCCCCCCCCC([Na])=O Chemical compound CCCCCCCCCCCC([Na])=O FXALIOUHXMVTMJ-UHFFFAOYSA-N 0.000 claims description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 4
- 235000014121 butter Nutrition 0.000 claims description 4
- PXEDJBXQKAGXNJ-QTNFYWBSSA-L disodium L-glutamate Chemical compound [Na+].[Na+].[O-]C(=O)[C@@H](N)CCC([O-])=O PXEDJBXQKAGXNJ-QTNFYWBSSA-L 0.000 claims description 4
- 235000013919 monopotassium glutamate Nutrition 0.000 claims description 4
- 239000004006 olive oil Substances 0.000 claims description 4
- 235000008390 olive oil Nutrition 0.000 claims description 4
- KSAVQLQVUXSOCR-UHFFFAOYSA-M sodium lauroyl sarcosinate Chemical compound [Na+].CCCCCCCCCCCC(=O)N(C)CC([O-])=O KSAVQLQVUXSOCR-UHFFFAOYSA-M 0.000 claims description 4
- JWGGSJFIGIGFSQ-UHFFFAOYSA-N N-dodecanoylglycine Chemical compound CCCCCCCCCCCC(=O)NCC(O)=O JWGGSJFIGIGFSQ-UHFFFAOYSA-N 0.000 claims description 3
- 125000002811 oleoyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])/C([H])=C([H])\C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 3
- JAJWGJBVLPIOOH-IZYKLYLVSA-M sodium taurocholate Chemical compound [Na+].C([C@H]1C[C@H]2O)[C@H](O)CC[C@]1(C)[C@@H]1[C@@H]2[C@@H]2CC[C@H]([C@@H](CCC(=O)NCCS([O-])(=O)=O)C)[C@@]2(C)[C@@H](O)C1 JAJWGJBVLPIOOH-IZYKLYLVSA-M 0.000 claims description 3
- 229960003080 taurine Drugs 0.000 claims description 3
- UYTOHYBIBPDOKX-ZDUSSCGKSA-N (2s)-2-(dodecanoylamino)propanoic acid Chemical compound CCCCCCCCCCCC(=O)N[C@@H](C)C(O)=O UYTOHYBIBPDOKX-ZDUSSCGKSA-N 0.000 claims description 2
- LFJJOPDNPVFCNZ-UHFFFAOYSA-N 2-[hexadecanoyl(methyl)amino]acetic acid Chemical compound CCCCCCCCCCCCCCCC(=O)N(C)CC(O)=O LFJJOPDNPVFCNZ-UHFFFAOYSA-N 0.000 claims description 2
- DXDTUQXKMVJYAM-UHFFFAOYSA-N 2-aminoacetic acid;potassium Chemical compound [K].NCC(O)=O DXDTUQXKMVJYAM-UHFFFAOYSA-N 0.000 claims description 2
- UJGIYHXRNBCGRE-UHFFFAOYSA-N C(CCCCCCCCCCCCCCC)[Na] Chemical compound C(CCCCCCCCCCCCCCC)[Na] UJGIYHXRNBCGRE-UHFFFAOYSA-N 0.000 claims description 2
- FPXFWAJWBGDRTP-UHFFFAOYSA-N C(CCCCCCCCCCCCCCCCC)C[Na] Chemical compound C(CCCCCCCCCCCCCCCCC)C[Na] FPXFWAJWBGDRTP-UHFFFAOYSA-N 0.000 claims description 2
- XHDJZIZDKIUZGM-UHFFFAOYSA-N CCCCCCCCCCCCC(=O)[Na] Chemical compound CCCCCCCCCCCCC(=O)[Na] XHDJZIZDKIUZGM-UHFFFAOYSA-N 0.000 claims description 2
- 244000060011 Cocos nucifera Species 0.000 claims description 2
- 235000013162 Cocos nucifera Nutrition 0.000 claims description 2
- 244000068988 Glycine max Species 0.000 claims description 2
- 235000010469 Glycine max Nutrition 0.000 claims description 2
- 244000147568 Laurus nobilis Species 0.000 claims description 2
- 235000017858 Laurus nobilis Nutrition 0.000 claims description 2
- WJLBKEUGXBEMGJ-RJXKWAGSSA-N N[C@@H](CCC(=O)O)C(=O)O.C(CCCCCCC)(=O)[K] Chemical compound N[C@@H](CCC(=O)O)C(=O)O.C(CCCCCCC)(=O)[K] WJLBKEUGXBEMGJ-RJXKWAGSSA-N 0.000 claims description 2
- JQBREOFGAISFRW-RJXKWAGSSA-N N[C@@H](CCC(=O)O)C(=O)O.C(CCCCCCC)(=O)[Na] Chemical compound N[C@@H](CCC(=O)O)C(=O)O.C(CCCCCCC)(=O)[Na] JQBREOFGAISFRW-RJXKWAGSSA-N 0.000 claims description 2
- VWQBCYCSVGZJAV-RJXKWAGSSA-N N[C@@H](CCC(=O)O)C(=O)O.C(CCCCCCCCC=C)(=O)[Na] Chemical compound N[C@@H](CCC(=O)O)C(=O)O.C(CCCCCCCCC=C)(=O)[Na] VWQBCYCSVGZJAV-RJXKWAGSSA-N 0.000 claims description 2
- WOTRANRFHZOPBS-RJXKWAGSSA-N N[C@@H](CCC(=O)O)C(=O)O.C(CCCCCCCCCCCCCCC)[Na] Chemical compound N[C@@H](CCC(=O)O)C(=O)O.C(CCCCCCCCCCCCCCC)[Na] WOTRANRFHZOPBS-RJXKWAGSSA-N 0.000 claims description 2
- IVGMSMNEJSUKOZ-RJXKWAGSSA-N N[C@@H](CCC(=O)O)C(=O)O.C(CCCCCCCCCCCCCCCCC)[K] Chemical compound N[C@@H](CCC(=O)O)C(=O)O.C(CCCCCCCCCCCCCCCCC)[K] IVGMSMNEJSUKOZ-RJXKWAGSSA-N 0.000 claims description 2
- 235000019482 Palm oil Nutrition 0.000 claims description 2
- 235000019483 Peanut oil Nutrition 0.000 claims description 2
- 235000019484 Rapeseed oil Nutrition 0.000 claims description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 2
- 239000005864 Sulphur Substances 0.000 claims description 2
- 235000005212 Terminalia tomentosa Nutrition 0.000 claims description 2
- OXPALDDHUVJIPQ-GXKRWWSZSA-N [K].[K].C(CCCCCCCCC=C)(=O)N[C@@H](CCC(=O)O)C(=O)O Chemical compound [K].[K].C(CCCCCCCCC=C)(=O)N[C@@H](CCC(=O)O)C(=O)O OXPALDDHUVJIPQ-GXKRWWSZSA-N 0.000 claims description 2
- COTJVGBAHUVVHH-UHFFFAOYSA-N [Na].C(CCCCC)(=O)N(CCS(=O)(=O)O)C Chemical compound [Na].C(CCCCC)(=O)N(CCS(=O)(=O)O)C COTJVGBAHUVVHH-UHFFFAOYSA-N 0.000 claims description 2
- 239000003240 coconut oil Substances 0.000 claims description 2
- 235000019864 coconut oil Nutrition 0.000 claims description 2
- 235000012343 cottonseed oil Nutrition 0.000 claims description 2
- 239000002385 cottonseed oil Substances 0.000 claims description 2
- WDRWZVWLVBXVOI-QTNFYWBSSA-L dipotassium;(2s)-2-aminopentanedioate Chemical compound [K+].[K+].[O-]C(=O)[C@@H](N)CCC([O-])=O WDRWZVWLVBXVOI-QTNFYWBSSA-L 0.000 claims description 2
- 235000021323 fish oil Nutrition 0.000 claims description 2
- 239000008169 grapeseed oil Substances 0.000 claims description 2
- 239000000944 linseed oil Substances 0.000 claims description 2
- 235000021388 linseed oil Nutrition 0.000 claims description 2
- 239000002540 palm oil Substances 0.000 claims description 2
- 108700009886 palmitoyl sarcosine Proteins 0.000 claims description 2
- 239000000312 peanut oil Substances 0.000 claims description 2
- RWDOCBHBDDFEQV-UQKRIMTDSA-M potassium;(4s)-4-amino-5-dodecanoyloxy-5-oxopentanoate Chemical compound [K+].CCCCCCCCCCCC(=O)OC(=O)[C@@H](N)CCC([O-])=O RWDOCBHBDDFEQV-UQKRIMTDSA-M 0.000 claims description 2
- 229940043230 sarcosine Drugs 0.000 claims description 2
- 229940045944 sodium lauroyl glutamate Drugs 0.000 claims description 2
- IWIUXJGIDSGWDN-UQKRIMTDSA-M sodium;(2s)-2-(dodecanoylamino)pentanedioate;hydron Chemical compound [Na+].CCCCCCCCCCCC(=O)N[C@H](C([O-])=O)CCC(O)=O IWIUXJGIDSGWDN-UQKRIMTDSA-M 0.000 claims description 2
- ZEZSZCSSTDPVDM-DKWTVANSSA-M sodium;(2s)-2-aminopropanoate Chemical compound [Na+].C[C@H](N)C([O-])=O ZEZSZCSSTDPVDM-DKWTVANSSA-M 0.000 claims description 2
- WUWHFEHKUQVYLF-UHFFFAOYSA-M sodium;2-aminoacetate Chemical compound [Na+].NCC([O-])=O WUWHFEHKUQVYLF-UHFFFAOYSA-M 0.000 claims description 2
- 229940104261 taurate Drugs 0.000 claims description 2
- 235000013923 monosodium glutamate Nutrition 0.000 claims 2
- 229940073490 sodium glutamate Drugs 0.000 claims 2
- OTTPFCJTQXRWHO-UHFFFAOYSA-N 3-(2,3-dichloroanilino)cyclohex-2-en-1-one Chemical compound ClC1=CC=CC(NC=2CCCC(=O)C=2)=C1Cl OTTPFCJTQXRWHO-UHFFFAOYSA-N 0.000 claims 1
- YNDCACVZPKJRGE-UHFFFAOYSA-N CCCCCCCCCCCCCCC(=O)[Na] Chemical compound CCCCCCCCCCCCCCC(=O)[Na] YNDCACVZPKJRGE-UHFFFAOYSA-N 0.000 claims 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 1
- MQDWHVKPPBIIBX-RJXKWAGSSA-N N[C@@H](CCC(=O)O)C(=O)O.C(CCCCCCCCC=C)(=O)[K] Chemical compound N[C@@H](CCC(=O)O)C(=O)O.C(CCCCCCCCC=C)(=O)[K] MQDWHVKPPBIIBX-RJXKWAGSSA-N 0.000 claims 1
- 235000019082 Osmanthus Nutrition 0.000 claims 1
- 241000333181 Osmanthus Species 0.000 claims 1
- ZPAJGVUFOJABIW-XRIOVQLTSA-N [K].[K].C(CCCCCCC)(=O)N[C@@H](CCC(=O)O)C(=O)O Chemical compound [K].[K].C(CCCCCCC)(=O)N[C@@H](CCC(=O)O)C(=O)O ZPAJGVUFOJABIW-XRIOVQLTSA-N 0.000 claims 1
- SNGZVXPRGLTKNU-RGMNGODLSA-N [Na].C(CC)N[C@@H](CCO)C(=O)O Chemical compound [Na].C(CC)N[C@@H](CCO)C(=O)O SNGZVXPRGLTKNU-RGMNGODLSA-N 0.000 claims 1
- 229910052799 carbon Inorganic materials 0.000 claims 1
- KMSXHXLZXWCJIO-DTUYJQALSA-L disodium (4S)-4-amino-5-dodecanoyloxy-5-oxopentanoate Chemical compound N[C@@H](CCC(=O)[O-])C(=O)OC(CCCCCCCCCCC)=O.[Na+].[Na+].C(CCCCCCCCCCC)(=O)OC([C@@H](N)CCC(=O)[O-])=O KMSXHXLZXWCJIO-DTUYJQALSA-L 0.000 claims 1
- 125000001924 fatty-acyl group Chemical group 0.000 claims 1
- 125000003342 alkenyl group Chemical group 0.000 abstract description 2
- 125000005466 alkylenyl group Chemical group 0.000 abstract description 2
- 150000001768 cations Chemical class 0.000 abstract description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 abstract description 2
- WHUUTDBJXJRKMK-VKHMYHEASA-N L-glutamic acid Chemical compound OC(=O)[C@@H](N)CCC(O)=O WHUUTDBJXJRKMK-VKHMYHEASA-N 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- 241001465754 Metazoa Species 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 235000018102 proteins Nutrition 0.000 description 3
- 102000004169 proteins and genes Human genes 0.000 description 3
- 108090000623 proteins and genes Proteins 0.000 description 3
- 229940048098 sodium sarcosinate Drugs 0.000 description 3
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 description 2
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical group CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 230000003213 activating effect Effects 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- MRUAUOIMASANKQ-UHFFFAOYSA-N cocamidopropyl betaine Chemical group CCCCCCCCCCCC(=O)NCCC[N+](C)(C)CC([O-])=O MRUAUOIMASANKQ-UHFFFAOYSA-N 0.000 description 2
- 239000003344 environmental pollutant Substances 0.000 description 2
- 238000007046 ethoxylation reaction Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 231100000719 pollutant Toxicity 0.000 description 2
- ZUFONQSOSYEWCN-UHFFFAOYSA-M sodium;2-(methylamino)acetate Chemical compound [Na+].CNCC([O-])=O ZUFONQSOSYEWCN-UHFFFAOYSA-M 0.000 description 2
- MTJZWYHTZFVEGI-INIZCTEOSA-N (2s)-2-(tetradecanoylamino)pentanedioic acid Chemical compound CCCCCCCCCCCCCC(=O)N[C@H](C(O)=O)CCC(O)=O MTJZWYHTZFVEGI-INIZCTEOSA-N 0.000 description 1
- QXNVGIXVLWOKEQ-UHFFFAOYSA-N Disodium Chemical compound [Na][Na] QXNVGIXVLWOKEQ-UHFFFAOYSA-N 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 239000004471 Glycine Substances 0.000 description 1
- CKLJMWTZIZZHCS-REOHCLBHSA-N L-aspartic acid Chemical compound OC(=O)[C@@H](N)CC(O)=O CKLJMWTZIZZHCS-REOHCLBHSA-N 0.000 description 1
- BACYUWVYYTXETD-UHFFFAOYSA-N N-Lauroylsarcosine Chemical compound CCCCCCCCCCCC(=O)N(C)CC(O)=O BACYUWVYYTXETD-UHFFFAOYSA-N 0.000 description 1
- DYUGTPXLDJQBRB-UHFFFAOYSA-N N-myristoylglycine Chemical compound CCCCCCCCCCCCCC(=O)NCC(O)=O DYUGTPXLDJQBRB-UHFFFAOYSA-N 0.000 description 1
- FPPWIAWPRDIRHZ-RJXKWAGSSA-N N[C@@H](CCC(O)=O)C(O)=O.CCCCCCCCCCCCCCCCCC[Na] Chemical compound N[C@@H](CCC(O)=O)C(O)=O.CCCCCCCCCCCCCCCCCC[Na] FPPWIAWPRDIRHZ-RJXKWAGSSA-N 0.000 description 1
- 150000001294 alanine derivatives Chemical class 0.000 description 1
- 229940009098 aspartate Drugs 0.000 description 1
- 235000009508 confectionery Nutrition 0.000 description 1
- 230000001236 detergent effect Effects 0.000 description 1
- KCIDZIIHRGYJAE-YGFYJFDDSA-L dipotassium;[(2r,3r,4s,5r,6r)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl] phosphate Chemical compound [K+].[K+].OC[C@H]1O[C@H](OP([O-])([O-])=O)[C@H](O)[C@@H](O)[C@H]1O KCIDZIIHRGYJAE-YGFYJFDDSA-L 0.000 description 1
- JRHWWJSWHFFZRY-XRIOVQLTSA-L disodium;(2s)-2-(octanoylamino)pentanedioate Chemical compound [Na+].[Na+].CCCCCCCC(=O)N[C@H](C([O-])=O)CCC([O-])=O JRHWWJSWHFFZRY-XRIOVQLTSA-L 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 229940049906 glutamate Drugs 0.000 description 1
- 229930195712 glutamate Natural products 0.000 description 1
- 229960002449 glycine Drugs 0.000 description 1
- 150000002632 lipids Chemical class 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- LPUQAYUQRXPFSQ-DFWYDOINSA-M monosodium L-glutamate Chemical compound [Na+].[O-]C(=O)[C@@H](N)CCC(O)=O LPUQAYUQRXPFSQ-DFWYDOINSA-M 0.000 description 1
- 238000007781 pre-processing Methods 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 210000002345 respiratory system Anatomy 0.000 description 1
- 229940071089 sarcosinate Drugs 0.000 description 1
- 230000001235 sensitizing effect Effects 0.000 description 1
- 229940079781 sodium cocoyl glutamate Drugs 0.000 description 1
- 235000011121 sodium hydroxide Nutrition 0.000 description 1
- 229940048109 sodium methyl cocoyl taurate Drugs 0.000 description 1
- PWWJJDVDTKXWOF-UHFFFAOYSA-M sodium;2-[hexadecanoyl(methyl)amino]ethanesulfonate Chemical compound [Na+].CCCCCCCCCCCCCCCC(=O)N(C)CCS([O-])(=O)=O PWWJJDVDTKXWOF-UHFFFAOYSA-M 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001755 vocal effect Effects 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2065—Polyhydric alcohols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/04—Carboxylic acids or salts thereof
- C11D1/10—Amino carboxylic acids; Imino carboxylic acids; Fatty acid condensates thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/28—Sulfonation products derived from fatty acids or their derivatives, e.g. esters, amides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/37—Mixtures of compounds all of which are anionic
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
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Abstract
本发明具体地涉及一种组合物，其包含：(i)一种或多种衍生自脂肪酸和氨基酸的表面活性剂和(ii)溶剂，并具有3.0至11.0的pH。在本发明的上下文中，术语“衍生自脂肪酸和氨基酸的表面活性剂”应理解为表示式(I)的分子，其中R1是C8至C24烷基或链烯基；R2是‑H、C1至C4烷基、苯基或‑CH2COOM；R3是‑C‑R4 2；n是1到4；R4是H、C1至C6烷基或C1至C6烷基酯；并且M是H或阳离子，或其混合物。
Description
技术领域
本发明涉及洗涤剂产品领域。更具体地，本发明涉及工业洗涤剂领域，特别是涉及饲料和畜牧业领域。本发明具体地涉及即用型或浓缩型组合物，其在高温和相对非极端的pH下具有高度稳定性。
背景技术
工业中使用的洗涤剂组合物有时需要在其对用户和环境的有效性和毒性方面的矛盾目标作出响应。
为了获得关于污染的良好结果，可以长时间使用具有极端pH的高腐蚀性产品(特别是基于苛性钠)。然而，所述产品与与流出物有关的环境标准越来越不兼容，并且对于暴露于其使用的那些人是危险的。
为了替代现有技术的组合物，已经提出了能够分解基于蛋白质的污染物的酶溶液。所述组合物是本领域技术人员熟知的，并且目前用于家用产品领域，诸如洗衣洗涤剂。
然而，与所有蛋白质一样，酶具有与工业洗涤剂的使用条件不太相容的稳定性水平。它们尤其对高温非常敏感，诸如在地球的某些部分中发现的高温，这显著降低了它们的稳定性并因此降低了它们的使用持续时间。此外，这些酶具有呼吸道致敏特性，这使用户面临不可忽视的风险。
因此，需要不一定含有某些酶的洗涤剂产品，这些洗涤剂产品具有轻微的腐蚀性，但仍能在专业工业部门、畜牧业、社区和家庭用途中处理基于蛋白质的污染。
此外，所述洗涤剂产品必须尊重环境并且必须在没有预先处理的情况下可与废水一起任意处理。
因此，本发明提出一种即用型或浓缩型洗涤剂组合物，其具有与目前可用的洗涤剂组合物相当的洗涤剂效果、非极端pH和增加的稳定性。
发明内容
因此，本发明具体地涉及一种组合物，其包含：(i)一种或多种衍生自脂肪酸和氨基酸的表面活性剂和(ii)溶剂，并具有3.0至11.0的pH。
在本发明的上下文中，术语“衍生自脂肪酸和氨基酸的表面活性剂”应理解为表示式(I)的分子，
其中R1是C8至C24烷基或链烯基；R2是-H、C1至C4烷基、苯基或-CH2COOM；R3是-C-R4 2；n是1到4；R4是H、C1至C6烷基或C1至C6烷基酯；并且M是H或阳离子，或其混合物。
在本发明的上下文中，术语“即用型”意指所述组合物可以在该状态下用于清洁。
在本发明的优选实施例中，衍生自脂肪酸和氨基酸的表面活性剂选自包含基于牛磺酸盐、谷氨酸盐、丙氨酸、丙氨酸盐、肌氨酸盐、天冬氨酸盐和甘氨酸的表面活性剂的组。
根据本发明的更优选实施例，所述衍生自脂肪酸和氨基酸的表面活性剂不是油酰基肌氨酸钠。
根据本发明的优选实施例，所述衍生自脂肪酸和氨基酸的表面活性剂选自包含以下的组：椰油酰基牛磺酸钾、甲基椰油酰基牛磺酸钾、己酰基甲基牛磺酸钠、椰油酰基牛磺酸钠、月桂酰基牛磺酸钠、甲基椰油酰基牛磺酸钠、甲基月桂酰基牛磺酸钠、甲基肉豆蔻酰基牛磺酸钠、甲基油酰基牛磺酸钠、甲基棕榈酰基牛磺酸钠、甲基硬脂酰基牛磺酸钠、辛酰基谷氨酸二钾、十一碳烯酰基谷氨酸二钾、辛酰基谷氨酸二钠、椰油酰基谷氨酸二钠、月桂酰基谷氨酸二钠、硬脂酰基谷氨酸二钠、十一碳烯酰基谷氨酸二钠、辛酰基谷氨酸钾、椰油酰基谷氨酸钾、月桂酰基谷氨酸钾、肉豆蔻酰基谷氨酸钾、硬脂酰基谷氨酸钾、十一碳烯酰基谷氨酸钾、辛酰基谷氨酸钠、椰油酰基谷氨酸钠、月桂酰基谷氨酸钠、肉豆蔻酰基谷氨酸钠、橄榄油酰基谷氨酸钠、棕榈酰基谷氨酸钠、硬脂酰基谷氨酸钠、十一碳烯酰基谷氨酸钠、椰油酰基甲基B1丙氨酸、月桂酰基l-丙氨酸、月桂酰基甲基B-丙氨酸、肉豆蔻酰基B-丙氨酸、月桂酰基甲基G丙氨酸钾、椰油酰基丙氨酸钠、椰油酰基甲基B-丙氨酸钠、肉豆蔻酰基甲基B丙氨酸棕榈酰基甘氨酸钠、月桂酰基甘氨酸钠、椰油酰基甘氨酸钠、肉豆蔻酰基甘氨酸钠、月桂酰基甘氨酸钾、椰油酰基甘氨酸钾、月桂酰基肌氨酸钾、椰油酰基肌氨酸钾、椰油酰基肌氨酸钠、月桂酰基肌氨酸钠、肉豆蔻酰基肌氨酸钠、棕榈酰基肌氨酸钠及其混合物。
根据本发明的优选实施例，所述衍生自脂肪酸和氨基酸的表面活性剂是月桂酰基肌氨酸钠。
在本发明的优选实施例的上下文中，所述溶剂(ii)选自包含甘油、单丙二醇和水的组。根据优选实施例，所述溶剂(ii)是水。根据本发明的优选实施例，所述组合物还包含(iii)乙氧基化甘油三酯。
该最后一个实施例提出了一种组合物，其对饲料的两种类型的污染物有效：蛋白质和脂质。
在本发明的上下文中，术语“乙氧基化甘油三酯”是指甘油三酯，其中的至少一个，优选两个，更优选三个它们的脂肪酸碳链已经进行乙氧基化反应。根据本发明的优选实施例，所述乙氧基化甘油三酯衍生自甘油三酯，所述甘油三酯选自包含动物或植物来源的甘油三酯的组，甚至更优选选自包含以下的组：猪油、牛油、花生油、黄油、棉籽油、亚麻籽油、橄榄油、棕榈油、葡萄籽油、鱼油、豆油、蓖麻油、菜籽油、椰子干油和椰子油。在本发明的上下文中，术语衍生意指所述乙氧基化甘油三酯通过所述甘油三酯的乙氧基化反应获得。
根据本发明的更优选实施例，所述乙氧基化甘油三酯衍生自蓖麻油，诸如乙氧基化蓖麻油。
根据本发明的优选实施例，所述乙氧基化甘油三酯包含脂肪酸的C8至C30碳链。
根据本发明的优选实施例，所述组合物不包含酶。
在本发明的上下文中，术语“不包含酶”具体地意指根据本发明的即用型组合物包含少于0.1％的酶，优选少于0.04％的酶，并且更优选少于0.01％的酶。本发明不排除包含痕量的污染形式的酶的组合物，所述酶没有显示出显著的活性。
在本发明的优选实施例中，所述即用型组合物还包含一种或多种表面活性剂、一种或多种稳定剂、一种或多种流变剂和一种或多种防腐剂。
在本发明的甚至更优选实施例中，所述表面活性剂是椰油酰胺丙基甜菜碱(CAPB)。
根据本发明的优选实施例，相对于所述即用型组合物的总质量，这些其他组分的量在0.02质量％和30质量％之间。
在本发明的优选实施例中，术语“包含”意指根据本发明的组合物包含所引用的组分以排除任何其他组分。
根据本发明的优选实施例，相对于所述即用型组合物的总质量，(i)的含量为在0.005质量％和5质量％之间的量。
根据本发明的优选实施例，相对于所述即用型组合物的总质量，(ii)的含量为在70质量％和99.97质量％之间的量。
根据本发明的优选实施例，相对于所述即用型组合物的总质量，(iii)的含量为在0.005质量％和10质量％之间的量。
根据本发明的优选实施例，相对于所述即用型组合物的总质量，组分(i)和(iii)的量在0.01质量％和15质量％之间。
根据本发明的优选实施例，相对于所述即用型组合物的总质量，组分(i)、(ii)和(iii)的量在70质量％和99.98质量％之间。
根据优选实施例，根据本发明的组合物是专业用途的液体洗涤剂。
本发明还涉及浓缩型组合物，其包含一定浓度的(i)和(iii)，所述浓度大于上述根据本发明的即用型组合物中的浓度。根据优选实施例，所述浓缩型组合物包含的(i)和(iii)的浓度是根据本发明的即用型组合物的浓度的2倍，更优选10倍，并且甚至更优选20倍。
具体实施方式
下面给出的配方代表了优选的实施例，它们不以任何方式限制本发明的洗涤剂组合物。
组合物A(1％稀释的浓缩型组合物)：
月桂酰基肌氨酸钠：2％
乙氧基化蓖麻油：3％
其他表面活性剂：21.5％
其他辅料：2.5％
水：71％
组合物B(即用型组合物)：
月桂酰基肌氨酸钠：0.02％
乙氧基化蓖麻油：0.03％
其他表面活性剂：0.215％
其他辅料：0.025％
水：99.71％
Claims (6)
1.一种专业用途的即用型液体洗涤剂，其包含(i)一种或多种衍生自脂肪酸和氨基酸的表面活性剂，所述表面活性剂选自包含以下的组：椰油酰基牛磺酸钾、甲基椰油酰基牛磺酸钾、己酰基甲基牛磺酸钠、椰油酰基牛磺酸钠、月桂酰基牛磺酸钠、甲基椰油酰基牛磺酸钠、甲基月桂酰基牛磺酸钠、甲基肉豆蔻酰基牛磺酸钠、甲基油酰基牛磺酸钠、甲基棕榈酰基牛磺酸钠、甲基硬脂酰基牛磺酸钠、辛酰基谷氨酸二钾、十一碳烯酰基谷氨酸二钾、辛酰基谷氨酸二钠、椰油酰基谷氨酸二钠、月桂酰基谷氨酸二钠、硬脂酰基谷氨酸二钠、十一碳烯酰基谷氨酸二钠、辛酰基谷氨酸钾、椰油酰基谷氨酸钾、月桂酰基谷氨酸钾、肉豆蔻酰基谷氨酸钾、硬脂酰基谷氨酸钾、十一碳烯酰基谷氨酸钾、辛酰基谷氨酸钠、椰油酰基谷氨酸钠、月桂酰基谷氨酸钠、肉豆蔻酰基谷氨酸钠、橄榄油酰基谷氨酸钠、棕榈酰基谷氨酸钠、硬脂酰基谷氨酸钠、十一碳烯酰基谷氨酸钠、椰油酰基甲基B1丙氨酸、月桂酰基l-丙氨酸、月桂酰基甲基B-丙氨酸、肉豆蔻酰基B-丙氨酸、月桂酰基甲基G丙氨酸钾、椰油酰基丙氨酸钠、椰油酰基甲基B-丙氨酸钠、肉豆蔻酰基甲基B丙氨酸棕榈酰基甘氨酸钠、月桂酰基甘氨酸钠、椰油酰基甘氨酸钠、肉豆蔻酰基甘氨酸钠、月桂酰基甘氨酸钾、椰油酰基甘氨酸钾、月桂酰基肌氨酸钾、椰油酰基肌氨酸钾、椰油酰基肌氨酸钠、月桂酰基肌氨酸钠、肉豆蔻酰基肌氨酸钠、棕榈酰基肌氨酸钠及其混合物，(ii)溶剂，(iii)乙氧基化甘油三酯，并且其pH为3.0-11.0。
2.根据前述权利要求所述的专业用途的即用型液体洗涤剂，其特征在于，所述乙氧基化甘油三酯衍生自选自包含以下的组的甘油三酯：猪油、牛油、花生油、黄油、棉籽油、亚麻籽油、橄榄油、棕榈油、葡萄籽油、鱼油、豆油、蓖麻油、菜籽油、椰子干油和椰子油。
3.根据前述权利要求所述的专业用途的即用型液体洗涤剂，其特征在于，所述乙氧基化甘油三酯衍生自蓖麻油。
4.根据前述权利要求中任一项所述的专业用途的即用型液体洗涤剂，其特征在于，它不包括酶。
5.根据前述权利要求中任一项所述的专业用途的即用型液体洗涤剂，其特征在于，相对于所述组合物的总质量，(i)的含量在0.005质量％和5质量％之间。
6.根据权利要求1至6中任一项所述的专业用途的即用型液体洗涤剂，其特征在于，相对于所述洗涤剂的总质量，(iii)的含量在0.005质量％和10质量％之间。
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| DE10216509A1 (de) * | 2002-04-11 | 2003-10-23 | Beiersdorf Ag | Fließfähige kosmetische und dermatologische Reinigungsgele enthaltend ein oder mehrere vorgelatinisierte, quervernetzte Stärkederivate |
| CN106190627A (zh) * | 2016-08-03 | 2016-12-07 | 安徽三祥羽毛有限公司 | 一种水洗羽毛用洗涤除臭剂及其制备方法 |
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| JPS6087209A (ja) * | 1983-10-18 | 1985-05-16 | Kao Corp | シヤンプ−組成物 |
| JP3216848B2 (ja) * | 1993-06-18 | 2001-10-09 | 株式会社資生堂 | 洗浄剤組成物 |
| JPH08151598A (ja) * | 1994-11-30 | 1996-06-11 | Kawaken Fine Chem Co Ltd | 未変性水溶性コラーゲンの可溶化剤 |
| JP2004035524A (ja) * | 2002-07-08 | 2004-02-05 | Lion Corp | 角質層水分量低減抑制組成物 |
| DE10344527A1 (de) * | 2003-09-25 | 2005-04-21 | Beiersdorf Ag | Schäumende Zubereitungen mit Fließgrenze |
| JP5658277B2 (ja) * | 2009-12-22 | 2015-01-21 | ザ プロクター アンド ギャンブルカンパニー | 液体洗浄及び／又はクレンジング組成物 |
| WO2012068001A1 (en) * | 2010-11-17 | 2012-05-24 | Isp Investments Inc. | N-alkyl lactam ethers, and compositions and uses thereof |
| JP5923409B2 (ja) * | 2012-08-10 | 2016-05-24 | 株式会社マンダム | 皮膚洗浄剤用組成物 |
| JP6336334B2 (ja) * | 2014-06-06 | 2018-06-06 | 花王株式会社 | 液体洗浄剤組成物 |
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2016
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| WO1995033026A1 (en) * | 1994-06-01 | 1995-12-07 | The Procter & Gamble Company | Dye transfer inhibiting compositions containing oleoyl sarcosinate |
| WO1995033811A1 (en) * | 1994-06-02 | 1995-12-14 | The Procter & Gamble Company | Oleoyl sarcosinate with alkanolamides in cleaning products |
| DE10216509A1 (de) * | 2002-04-11 | 2003-10-23 | Beiersdorf Ag | Fließfähige kosmetische und dermatologische Reinigungsgele enthaltend ein oder mehrere vorgelatinisierte, quervernetzte Stärkederivate |
| CN106190627A (zh) * | 2016-08-03 | 2016-12-07 | 安徽三祥羽毛有限公司 | 一种水洗羽毛用洗涤除臭剂及其制备方法 |
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| CN115368971A (zh) * | 2022-08-08 | 2022-11-22 | 南京华狮新材料有限公司 | 一种洗碗机用洗涤剂 |
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| ES2966112T3 (es) | 2024-04-18 |
| RU2019123175A (ru) | 2021-01-25 |
| JP2020504777A (ja) | 2020-02-13 |
| PL3559182T3 (pl) | 2024-02-26 |
| CA3047854A1 (fr) | 2018-06-28 |
| RU2748596C2 (ru) | 2021-05-27 |
| KR20190095449A (ko) | 2019-08-14 |
| EP3559182A1 (fr) | 2019-10-30 |
| FI3559182T3 (fi) | 2023-11-30 |
| PH12019501416A1 (en) | 2020-06-01 |
| CL2019001734A1 (es) | 2019-10-18 |
| BR112019013006A2 (pt) | 2020-05-26 |
| DK3559182T3 (da) | 2023-12-04 |
| UA123377C2 (uk) | 2021-03-24 |
| HUE064245T2 (hu) | 2024-02-28 |
| CO2019007510A2 (es) | 2020-01-17 |
| MX2019007475A (es) | 2020-01-20 |
| RS64826B1 (sr) | 2023-12-29 |
| MA47104A (fr) | 2019-10-30 |
| HRP20231404T1 (hr) | 2024-02-16 |
| AU2017380426A1 (en) | 2019-07-18 |
| MY192891A (en) | 2022-09-14 |
| FR3061201A1 (fr) | 2018-06-29 |
| US20200010779A1 (en) | 2020-01-09 |
| WO2018115777A1 (fr) | 2018-06-28 |
| ZA201904462B (en) | 2020-03-25 |
| FR3061201B1 (fr) | 2020-06-26 |
| RU2019123175A3 (zh) | 2021-01-25 |
| PT3559182T (pt) | 2023-11-14 |
| PE20191538A1 (es) | 2019-10-23 |
| EP3559182B1 (fr) | 2023-10-25 |
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