EP3559182B1 - Composition detergente - Google Patents
Composition detergente Download PDFInfo
- Publication number
- EP3559182B1 EP3559182B1 EP17832279.8A EP17832279A EP3559182B1 EP 3559182 B1 EP3559182 B1 EP 3559182B1 EP 17832279 A EP17832279 A EP 17832279A EP 3559182 B1 EP3559182 B1 EP 3559182B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- sodium
- glutamate
- cocoyl
- potassium
- methyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000000203 mixture Substances 0.000 title claims description 39
- 239000003599 detergent Substances 0.000 title claims description 17
- 229910052708 sodium Inorganic materials 0.000 claims description 17
- 239000011734 sodium Substances 0.000 claims description 17
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 15
- 108090000790 Enzymes Proteins 0.000 claims description 10
- 102000004190 Enzymes Human genes 0.000 claims description 10
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 10
- 229910052700 potassium Inorganic materials 0.000 claims description 10
- 239000011591 potassium Substances 0.000 claims description 10
- 239000004094 surface-active agent Substances 0.000 claims description 10
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 claims description 8
- 108010077895 Sarcosine Proteins 0.000 claims description 8
- 150000003626 triacylglycerols Chemical class 0.000 claims description 7
- 239000004359 castor oil Substances 0.000 claims description 6
- 235000019438 castor oil Nutrition 0.000 claims description 6
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 6
- 229930195729 fatty acid Natural products 0.000 claims description 6
- 239000000194 fatty acid Substances 0.000 claims description 6
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims description 6
- KSAVQLQVUXSOCR-UHFFFAOYSA-M sodium lauroyl sarcosinate Chemical compound [Na+].CCCCCCCCCCCC(=O)N(C)CC([O-])=O KSAVQLQVUXSOCR-UHFFFAOYSA-M 0.000 claims description 6
- 235000001014 amino acid Nutrition 0.000 claims description 5
- 150000001413 amino acids Chemical class 0.000 claims description 5
- 150000004665 fatty acids Chemical class 0.000 claims description 5
- 239000007788 liquid Substances 0.000 claims description 5
- 239000004471 Glycine Substances 0.000 claims description 4
- QNAYBMKLOCPYGJ-REOHCLBHSA-N L-alanine Chemical compound C[C@H](N)C(O)=O QNAYBMKLOCPYGJ-REOHCLBHSA-N 0.000 claims description 4
- JWGGSJFIGIGFSQ-UHFFFAOYSA-N N-dodecanoylglycine Chemical compound CCCCCCCCCCCC(=O)NCC(O)=O JWGGSJFIGIGFSQ-UHFFFAOYSA-N 0.000 claims description 4
- 235000004279 alanine Nutrition 0.000 claims description 4
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 4
- 229940045885 sodium lauroyl sarcosinate Drugs 0.000 claims description 4
- 239000002904 solvent Substances 0.000 claims description 4
- 229940104261 taurate Drugs 0.000 claims description 4
- XOAAWQZATWQOTB-UHFFFAOYSA-N taurine Chemical compound NCCS(O)(=O)=O XOAAWQZATWQOTB-UHFFFAOYSA-N 0.000 claims description 4
- WHUUTDBJXJRKMK-VKHMYHEASA-N L-glutamic acid Chemical compound OC(=O)[C@@H](N)CCC(O)=O WHUUTDBJXJRKMK-VKHMYHEASA-N 0.000 claims description 3
- 229930195712 glutamate Natural products 0.000 claims description 3
- -1 lauroyl methyl Chemical group 0.000 claims description 3
- 229940048109 sodium methyl cocoyl taurate Drugs 0.000 claims description 3
- KVTFEOAKFFQCCX-UHFFFAOYSA-N N-hexadecanoylglycine Chemical compound CCCCCCCCCCCCCCCC(=O)NCC(O)=O KVTFEOAKFFQCCX-UHFFFAOYSA-N 0.000 claims description 2
- DYUGTPXLDJQBRB-UHFFFAOYSA-N N-myristoylglycine Chemical compound CCCCCCCCCCCCCC(=O)NCC(O)=O DYUGTPXLDJQBRB-UHFFFAOYSA-N 0.000 claims description 2
- GNMAJAFGCGXYGH-ZOWNYOTGSA-M N[C@@H](CCC(=O)[O-])C(=O)OC(CCCCCCCCC=C)=O.[Na+] Chemical compound N[C@@H](CCC(=O)[O-])C(=O)OC(CCCCCCCCC=C)=O.[Na+] GNMAJAFGCGXYGH-ZOWNYOTGSA-M 0.000 claims description 2
- ACAXXPXMEBRGLB-IZHYLRJQSA-L N[C@@H](CCC(=O)[O-])C(=O)OC(CCCCCCCCC=C)=O.[Na+].[Na+].C(CCCCCCCCC=C)(=O)OC([C@@H](N)CCC(=O)[O-])=O Chemical compound N[C@@H](CCC(=O)[O-])C(=O)OC(CCCCCCCCC=C)=O.[Na+].[Na+].C(CCCCCCCCC=C)(=O)OC([C@@H](N)CCC(=O)[O-])=O ACAXXPXMEBRGLB-IZHYLRJQSA-L 0.000 claims description 2
- QNAYBMKLOCPYGJ-UHFFFAOYSA-M alaninate Chemical compound CC(N)C([O-])=O QNAYBMKLOCPYGJ-UHFFFAOYSA-M 0.000 claims description 2
- JOLYVEWZEPKDIJ-UTLKBRERSA-L dipotassium;(2s)-2-(dodecanoylamino)pentanedioate Chemical compound [K+].[K+].CCCCCCCCCCCC(=O)N[C@H](C([O-])=O)CCC([O-])=O JOLYVEWZEPKDIJ-UTLKBRERSA-L 0.000 claims description 2
- TWRWROOHGNQOQC-XRIOVQLTSA-L dipotassium;(2s)-2-(octanoylamino)pentanedioate Chemical compound [K+].[K+].CCCCCCCC(=O)N[C@H](C([O-])=O)CCC([O-])=O TWRWROOHGNQOQC-XRIOVQLTSA-L 0.000 claims description 2
- ACNAFCGCINVEDL-GXKRWWSZSA-L dipotassium;(2s)-2-(undec-10-enoylamino)pentanedioate Chemical compound [K+].[K+].[O-]C(=O)CC[C@@H](C([O-])=O)NC(=O)CCCCCCCCC=C ACNAFCGCINVEDL-GXKRWWSZSA-L 0.000 claims description 2
- PXEDJBXQKAGXNJ-QTNFYWBSSA-L disodium L-glutamate Chemical compound [Na+].[Na+].[O-]C(=O)[C@@H](N)CCC([O-])=O PXEDJBXQKAGXNJ-QTNFYWBSSA-L 0.000 claims description 2
- 229940079779 disodium cocoyl glutamate Drugs 0.000 claims description 2
- HWUINYGRRJTXGE-UTLKBRERSA-L disodium;(2s)-2-(dodecanoylamino)pentanedioate Chemical compound [Na+].[Na+].CCCCCCCCCCCC(=O)N[C@H](C([O-])=O)CCC([O-])=O HWUINYGRRJTXGE-UTLKBRERSA-L 0.000 claims description 2
- JRHWWJSWHFFZRY-XRIOVQLTSA-L disodium;(2s)-2-(octanoylamino)pentanedioate Chemical compound [Na+].[Na+].CCCCCCCC(=O)N[C@H](C([O-])=O)CCC([O-])=O JRHWWJSWHFFZRY-XRIOVQLTSA-L 0.000 claims description 2
- 229940049906 glutamate Drugs 0.000 claims description 2
- 125000000400 lauroyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 2
- 229940071088 methyl cocoyl taurate Drugs 0.000 claims description 2
- LPUQAYUQRXPFSQ-DFWYDOINSA-M monosodium L-glutamate Chemical compound [Na+].[O-]C(=O)[C@@H](N)CCC(O)=O LPUQAYUQRXPFSQ-DFWYDOINSA-M 0.000 claims description 2
- 125000001419 myristoyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 2
- 229940075639 palmitoyl glycine Drugs 0.000 claims description 2
- 229940082006 potassium cocoyl glutamate Drugs 0.000 claims description 2
- 229940099874 potassium lauroyl glutamate Drugs 0.000 claims description 2
- RJLXQRRDQRGFJR-ZOWNYOTGSA-M potassium;(2s)-5-hydroxy-5-oxo-2-(undec-10-enoylamino)pentanoate Chemical compound [K+].OC(=O)CC[C@@H](C([O-])=O)NC(=O)CCCCCCCCC=C RJLXQRRDQRGFJR-ZOWNYOTGSA-M 0.000 claims description 2
- KCQOKZAQSWTPIL-BDQAORGHSA-M potassium;(4s)-5-hydroxy-4-(octadecanoylamino)-5-oxopentanoate Chemical compound [H+].[K+].CCCCCCCCCCCCCCCCCC(=O)N[C@H](C([O-])=O)CCC([O-])=O KCQOKZAQSWTPIL-BDQAORGHSA-M 0.000 claims description 2
- WONHSIFWFDNSCE-PPHPATTJSA-M potassium;(4s)-5-hydroxy-4-(octanoylamino)-5-oxopentanoate Chemical compound [H+].[K+].CCCCCCCC(=O)N[C@H](C([O-])=O)CCC([O-])=O WONHSIFWFDNSCE-PPHPATTJSA-M 0.000 claims description 2
- KYLDDUZJZSKJER-NTISSMGPSA-M potassium;(4s)-5-hydroxy-5-oxo-4-(tetradecanoylamino)pentanoate Chemical compound [H+].[K+].CCCCCCCCCCCCCC(=O)N[C@H](C([O-])=O)CCC([O-])=O KYLDDUZJZSKJER-NTISSMGPSA-M 0.000 claims description 2
- JEMLSRUODAIULV-UHFFFAOYSA-M potassium;2-[dodecanoyl(methyl)amino]acetate Chemical compound [K+].CCCCCCCCCCCC(=O)N(C)CC([O-])=O JEMLSRUODAIULV-UHFFFAOYSA-M 0.000 claims description 2
- 229940083542 sodium Drugs 0.000 claims description 2
- 229940079781 sodium cocoyl glutamate Drugs 0.000 claims description 2
- 229940045944 sodium lauroyl glutamate Drugs 0.000 claims description 2
- 229940077092 sodium myristoyl glutamate Drugs 0.000 claims description 2
- 229940060304 sodium myristoyl sarcosinate Drugs 0.000 claims description 2
- 229940077089 sodium palmitoyl glutamate Drugs 0.000 claims description 2
- 229940045898 sodium stearoyl glutamate Drugs 0.000 claims description 2
- IWIUXJGIDSGWDN-UQKRIMTDSA-M sodium;(2s)-2-(dodecanoylamino)pentanedioate;hydron Chemical compound [Na+].CCCCCCCCCCCC(=O)N[C@H](C([O-])=O)CCC(O)=O IWIUXJGIDSGWDN-UQKRIMTDSA-M 0.000 claims description 2
- FCBUGCHAVCFTHW-NTISSMGPSA-N sodium;(2s)-2-(tetradecanoylamino)pentanedioic acid Chemical compound [Na].CCCCCCCCCCCCCC(=O)N[C@H](C(O)=O)CCC(O)=O FCBUGCHAVCFTHW-NTISSMGPSA-N 0.000 claims description 2
- KLIFRVSZGDONER-FERBBOLQSA-M sodium;(4s)-4-(hexadecanoylamino)-5-hydroxy-5-oxopentanoate Chemical compound [H+].[Na+].CCCCCCCCCCCCCCCC(=O)N[C@H](C([O-])=O)CCC([O-])=O KLIFRVSZGDONER-FERBBOLQSA-M 0.000 claims description 2
- KDHFCTLPQJQDQI-BDQAORGHSA-M sodium;(4s)-4-amino-5-octadecanoyloxy-5-oxopentanoate Chemical compound [Na+].CCCCCCCCCCCCCCCCCC(=O)OC(=O)[C@@H](N)CCC([O-])=O KDHFCTLPQJQDQI-BDQAORGHSA-M 0.000 claims description 2
- BCGXTKYOBWQPCN-PPHPATTJSA-M sodium;(4s)-5-hydroxy-4-(octanoylamino)-5-oxopentanoate Chemical compound [H+].[Na+].CCCCCCCC(=O)N[C@H](C([O-])=O)CCC([O-])=O BCGXTKYOBWQPCN-PPHPATTJSA-M 0.000 claims description 2
- BCISDMIQYBCHAT-UHFFFAOYSA-M sodium;2-(dodecanoylamino)ethanesulfonate Chemical compound [Na+].CCCCCCCCCCCC(=O)NCCS([O-])(=O)=O BCISDMIQYBCHAT-UHFFFAOYSA-M 0.000 claims description 2
- ZUFONQSOSYEWCN-UHFFFAOYSA-M sodium;2-(methylamino)acetate Chemical compound [Na+].CNCC([O-])=O ZUFONQSOSYEWCN-UHFFFAOYSA-M 0.000 claims description 2
- UKWMFBTXDPSTCV-UHFFFAOYSA-M sodium;2-[decanoyl(methyl)amino]ethanesulfonate Chemical compound [Na+].CCCCCCCCCC(=O)N(C)CCS([O-])(=O)=O UKWMFBTXDPSTCV-UHFFFAOYSA-M 0.000 claims description 2
- CAVXVRQDZKMZDB-UHFFFAOYSA-M sodium;2-[dodecanoyl(methyl)amino]ethanesulfonate Chemical compound [Na+].CCCCCCCCCCCC(=O)N(C)CCS([O-])(=O)=O CAVXVRQDZKMZDB-UHFFFAOYSA-M 0.000 claims description 2
- AUHKUMFBHOJIMU-UHFFFAOYSA-M sodium;2-[hexadecanoyl(methyl)amino]acetate Chemical compound [Na+].CCCCCCCCCCCCCCCC(=O)N(C)CC([O-])=O AUHKUMFBHOJIMU-UHFFFAOYSA-M 0.000 claims description 2
- PWWJJDVDTKXWOF-UHFFFAOYSA-M sodium;2-[hexadecanoyl(methyl)amino]ethanesulfonate Chemical compound [Na+].CCCCCCCCCCCCCCCC(=O)N(C)CCS([O-])(=O)=O PWWJJDVDTKXWOF-UHFFFAOYSA-M 0.000 claims description 2
- UKSFMDODPANKJI-UHFFFAOYSA-M sodium;2-[methyl(octadecanoyl)amino]ethanesulfonate Chemical compound [Na+].CCCCCCCCCCCCCCCCCC(=O)N(C)CCS([O-])(=O)=O UKSFMDODPANKJI-UHFFFAOYSA-M 0.000 claims description 2
- KHCOJQDJOCNUGV-UHFFFAOYSA-M sodium;2-[methyl(tetradecanoyl)amino]acetate Chemical compound [Na+].CCCCCCCCCCCCCC(=O)N(C)CC([O-])=O KHCOJQDJOCNUGV-UHFFFAOYSA-M 0.000 claims description 2
- HJXBXTZDPSSEST-UHFFFAOYSA-M sodium;2-[methyl(tetradecanoyl)amino]ethanesulfonate Chemical compound [Na+].CCCCCCCCCCCCCC(=O)N(C)CCS([O-])(=O)=O HJXBXTZDPSSEST-UHFFFAOYSA-M 0.000 claims description 2
- IZWPGJFSBABFGL-GMFCBQQYSA-M sodium;2-[methyl-[(z)-octadec-9-enoyl]amino]ethanesulfonate Chemical compound [Na+].CCCCCCCC\C=C/CCCCCCCC(=O)N(C)CCS([O-])(=O)=O IZWPGJFSBABFGL-GMFCBQQYSA-M 0.000 claims description 2
- 229940079784 disodium stearoyl glutamate Drugs 0.000 claims 1
- WODOUQLMOIMKAL-FJSYBICCSA-L disodium;(2s)-2-(octadecanoylamino)pentanedioate Chemical compound [Na+].[Na+].CCCCCCCCCCCCCCCCCC(=O)N[C@H](C([O-])=O)CCC([O-])=O WODOUQLMOIMKAL-FJSYBICCSA-L 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 239000000546 pharmaceutical excipient Substances 0.000 description 4
- 235000018102 proteins Nutrition 0.000 description 4
- 108090000623 proteins and genes Proteins 0.000 description 4
- 102000004169 proteins and genes Human genes 0.000 description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 2
- 108010039491 Ricin Proteins 0.000 description 2
- MRUAUOIMASANKQ-UHFFFAOYSA-N cocamidopropyl betaine Chemical group CCCCCCCCCCCC(=O)NCCC[N+](C)(C)CC([O-])=O MRUAUOIMASANKQ-UHFFFAOYSA-N 0.000 description 2
- 229940073507 cocamidopropyl betaine Drugs 0.000 description 2
- 235000013305 food Nutrition 0.000 description 2
- 244000144972 livestock Species 0.000 description 2
- 108700004121 sarkosyl Proteins 0.000 description 2
- QXNVGIXVLWOKEQ-UHFFFAOYSA-N Disodium Chemical compound [Na][Na] QXNVGIXVLWOKEQ-UHFFFAOYSA-N 0.000 description 1
- BACYUWVYYTXETD-UHFFFAOYSA-N N-Lauroylsarcosine Chemical compound CCCCCCCCCCCC(=O)N(C)CC(O)=O BACYUWVYYTXETD-UHFFFAOYSA-N 0.000 description 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- CHBBKFAHPLPHBY-KHPPLWFESA-N [(z)-octadec-9-enyl] 2-(methylamino)acetate Chemical compound CCCCCCCC\C=C/CCCCCCCCOC(=O)CNC CHBBKFAHPLPHBY-KHPPLWFESA-N 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 230000008094 contradictory effect Effects 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 230000000593 degrading effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000002255 enzymatic effect Effects 0.000 description 1
- 238000007046 ethoxylation reaction Methods 0.000 description 1
- 230000007717 exclusion Effects 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 229940071145 lauroyl sarcosinate Drugs 0.000 description 1
- 150000002632 lipids Chemical class 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000000241 respiratory effect Effects 0.000 description 1
- 229940071089 sarcosinate Drugs 0.000 description 1
- 230000001235 sensitizing effect Effects 0.000 description 1
- CRUUTKINBOXHMH-GMFCBQQYSA-M sodium;2-[methyl-[(z)-octadec-9-enyl]amino]acetate Chemical compound [Na+].CCCCCCCC\C=C/CCCCCCCCN(C)CC([O-])=O CRUUTKINBOXHMH-GMFCBQQYSA-M 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- UFTFJSFQGQCHQW-UHFFFAOYSA-N triformin Chemical compound O=COCC(OC=O)COC=O UFTFJSFQGQCHQW-UHFFFAOYSA-N 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/04—Carboxylic acids or salts thereof
- C11D1/10—Amino carboxylic acids; Imino carboxylic acids; Fatty acid condensates thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2065—Polyhydric alcohols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0008—Detergent materials or soaps characterised by their shape or physical properties aqueous liquid non soap compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/28—Sulfonation products derived from fatty acids or their derivatives, e.g. esters, amides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/37—Mixtures of compounds all of which are anionic
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2093—Esters; Carbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/43—Solvents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/12—Soft surfaces, e.g. textile
Definitions
- the present invention relates to the field of detergent products. More particularly, the present invention relates to the field of industrial detergents, particularly in the field of food and livestock.
- the present invention relates in particular to a composition, ready for use or concentrated, which has good stability at high temperatures and a relatively non-extreme pH.
- the detergent compositions used in industry must meet sometimes contradictory objectives in terms of effectiveness and harmfulness for users and the environment.
- compositions of the prior art In order to replace the compositions of the prior art, enzymatic solutions capable of degrading protein-based stains have in particular been proposed. These compositions are well known to those skilled in the art and commonly used in the field of domestic products such as laundry detergents.
- enzymes like all proteins, have a stability that is not compatible with the conditions of use of an industrial detergent. They are particularly very sensitive to high temperatures such as those encountered in certain regions of the globe, reducing significantly their stability, and therefore their duration of use. Furthermore, enzymes have respiratory sensitizing properties exposing users to a significant risk.
- DE10216509A1 discloses a cosmetic and dermatological composition comprising 1% sodium methylcocoyl taurate, water and an ethoxylated triglyceride.
- ethoxylated tryglyceride is not derived from rcin oil.
- WO95/33811A1 discloses a cleansing composition comprising at least 0.5% of oleoyl sarcosinate and at least 3% of an alkanolamide surfactant.
- WO9533026A1 discloses a composition, for inhibiting color transfer during washing, comprising oleyl sarcosinate
- the present invention therefore provides a detergent composition, ready for use or concentrated, having a detergent effectiveness equivalent to the detergent compositions currently available, a non-extreme pH and increased stability.
- the present invention relates in particular to a composition, ready for use, comprising (i) one or more surfactants derived from a fatty acid and an amino acid, (ii) a solvent, (iii) a Ethoxylated triglyceride derived from castor oil, and having a pH between 3.0 - 11.0.
- ready for use means that said composition can be used as is for cleaning.
- said surfactant derived from a fatty acid and an amino acid is not sodium oleylsarcosinate.
- said surfactant derived from a fatty acid and an amino acid is chosen from the group comprising potassium cocoyl taurate, potassium methyl cocoyl taurate, sodium caproyl methyl taurate, sodium cocoyl taurate, sodium lauroyl taurate, sodium methyl cocoyl taurate, sodium methyl lauroyl taurate, sodium methyl myristoyl taurate, sodium methyl oleoyl taurate, sodium methyl palmitoyl taurate, sodium methyl stearoyl taurate, dipotassium capryloyl glutamate, dipotassium undecylenoyl glutamate, disodium capryloyl glutamate, disodium cocoyl glutamate, disodium lauroyl glutamate, disodium stearoyil glutamate, disodium undecylenoyl glutamate, potassium capryloyl glutamate, potassium cocoyl glutamate, potassium lauroyl glutamate, potassium myristoyl glutamate,
- said surfactant derived from a fatty acid and an amino acid is sodium lauroylsarcosinate.
- said (ii) solvent is chosen from the group comprising glycerol, mono-propylene glycol and water. According to a very preferred embodiment, said (ii) solvent is water. According to the invention, said composition further comprises an (iii) ethoxylated triglyceride.
- This last embodiment offers a composition acting effectively on two food contaminants: proteins and lipids.
- the term derivative means that said ethoxylated triglyceride was obtained by an ethoxylation reaction of the cited triglyceride.
- said ethoxylated triglyceride derives from castor oil such as ethoxylated castor oil.
- said ethoxylated triglyceride comprises C8 to C30 fatty acid carbon chains.
- said composition does not include enzymes.
- the term "does not include an enzyme” is intended more particularly to designate that the ready-to-use composition according to the invention comprises less than 0.1% of enzymes, preferably less than 0.04% of enzymes and most preferably less than 0.01% enzymes.
- the present invention does not intend to exclude compositions comprising traces of enzymes in the form of contamination but not exhibiting significant activities.
- said composition ready for use, further comprises a or more surfactants, one or more stabilizers, one or more rheological agents and one or more preservatives.
- said surfactant is cocamidopropyl betaine (CAPE).
- these other components represent a quantity of between 0.02 and 30 percent by mass relative to the total mass of said composition ready for use.
- the term “includes” means that the composition according to the invention comprises the components mentioned to the exclusion of any other component.
- (i) is contained in an amount between 0.005 and 5 percent by mass relative to the total mass of said composition ready for use.
- (ii) is contained in an amount between 70 and 99.97 percent by mass relative to the total mass of said composition ready for use.
- (iii) is contained in an amount between 0.005 and 10 percent by mass relative to the total mass of said composition ready for use.
- components (i) and (iii) represent a quantity of between 0.01 and 15 percent by mass relative to the total mass of said composition ready for use.
- components (i), (ii) and (iii) represent a quantity of between 70 and 99.98 percent by mass relative to the total mass of said composition ready for use. job.
- the composition according to the invention is a liquid cleaner for professional use.
- the present invention also relates to a concentrated composition which comprises concentrations of (i) and (iii) greater than that of the composition, ready for use, according to the invention described above.
- said concentrated composition comprises concentrations of (i) and (iii) 2 times higher, even more preferably 10 times higher and quite preferably 20 times higher than that of the composition, ready for use. use, according to the invention.
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Detergent Compositions (AREA)
- Cosmetics (AREA)
Description
- La présente invention concerne le domaine des produits détergents. Plus particulièrement, la présente invention concerne le domaine des détergents industriels, notamment dans le domaine de l'alimentation et de l'élevage. La présente invention concerne notamment une composition, prête à l'emploi ou concentrée, qui présente une bonne stabilité aux températures élevées, un pH relativement non extrême.
- Les compositions détergentes utilisées dans l'industrie doivent répondre à des objectifs parfois contradictoires en termes d'efficacité et de nocivité pour les utilisateurs et l'environnement.
- Pour obtenir de bons résultats sur les souillures il a été longtemps possible d'utiliser des produits fortement corrosifs (notamment à base de soude) présentant des pH extrêmes. Toutefois, ces produits sont de moins en moins compatibles avec les normes environnementales en matière de rejets et présentent un danger pour les utilisateurs exposés.
- Afin de remplacer les compositions de l'art antérieur, il a notamment été proposé des solutions enzymatiques aptes à dégrader les souillures à base de protéines. Ces compositions sont bien connues de l'homme du métier et couramment utilisées dans le domaine des produits domestiques tels que les lessives.
- Cependant, les enzymes, comme toutes les protéines, présentent une stabilité peu compatible avec les conditions d'utilisation d'un détergent industriel. Elles sont notamment très sensibles aux fortes températures telles que celles rencontrées dans certaines régions du globe, réduisant significativement leur stabilité, donc leur durée d'utilisation. Par ailleurs, les enzymes présentent des propriétés sensibilisantes respiratoires exposant les utilisateurs à un risque non-négligeable.
-
DE10216509A1 divulgue une composition cosmétique et dermatologique comprenant 1% de methylcocoyl taurate de sodium, de l'eau et un triglycéride éthoxylé. Toutefois, le tryglycéride éthoxylé n'est pas dérivé de l'huile de rcin. -
WO95/33811A1 -
WO9533026A1 - Il existe donc un besoin, pour des produits détergents ne contenant pas nécessairement d'enzymes, peu corrosifs mais capables de traiter les souillures à base de protéines rencontrées dans les domaines professionnel industriel, en élevage, collectivités et en usage domestique.
- Par ailleurs, ces produits détergents doivent être respectueux de l'environnement et doivent pouvoir être rejetés avec les eaux usées sans traitements préalables.
- La présente invention propose donc une composition détergente, prête à l'emploi ou concentrée, présentant une efficacité détergente équivalente aux compositions détergentes actuellement disponibles, un pH non-extrême et une stabilité accrue.
- Ainsi la présente invention selon la revendication 1 concerne notamment une composition, prête à l'emploi, comprenant (i) un ou plusieurs tensioactifs dérivés d'un acide gras et d'un acide aminé, (ii) un solvant, (iii) un triglycéride éthoxylé dérivant de l'huile de ricin, et présentant un pH entre 3,0 - 11,0.
- Dans le cadre de la présente invention, le terme « prête à l'emploi » entend signifier que ladite composition est utilisable en l'état pour le nettoyage.
- Selon un mode de réalisation tout à fait préféré de l'invention, ledit tensioactif dérivé d'un acide gras et d'un acide aminé n'est pas de l'oleylsarcosinate de sodium.
- Selon l'invention, ledit tensioactif dérivé d'un acide gras et d'un acide aminé est choisi dans le groupe comprenant le potassium cocoyl taurate, le potassium methyl cocoyl taurate, le sodium caproyl methyl taurate, le sodium cocoyl taurate, le sodium lauroyl taurate, le sodium methyl cocoyl taurate, le sodium methyl lauroyl taurate, le sodium methyl myristoyl taurate, le sodium methyl oleoyl taurate, le sodium methyl palmitoyl taurate, le sodium methyl stearoyl taurate, le dipotassium capryloyl glutamate, le dipotassium undecylenoyl glutamate, le disodium capryloyl glutamate, le disodium cocoyl glutamate, le disodium lauroyl glutamate, le disodium stearoyil glutamate, le disodium undecylenoyl glutamate, le potassium capryloyl glutamate, le potassium cocoyl glutamate, le potassium lauroyl glutamate, le potassium myristoyl glutamate, le potassium stearoyl glutamate, le potassium undecylenoyl glutamate, le sodium capryloyl glutamate, le sodium cocoyl glutamate, le sodium lauroyl glutamate, le sodium myristoyl glutamate, le sodium olivoyl glutamate, le sodium palmitoyl glutamate, le sodium stearoyl glutamate, le sodium undecylenoyl glutamate, le cocoyl methyl B-l alanine, le lauroyl 1-alanine, le lauroyl methyl B-alanine, le myristoyl B-alanine, le sodium cocoyl alaninate, le sodium cocoyl methyl B-alanine, le sodium myristoyl methyl B alanine palmitoyl glycine, le sodium lauroyl glycine, le sodium cocoyl glycine, le sodium myristoyl glycine, le potassium lauroyl glycine, le potassium cocoyl glycine, le potassium lauroyl sarcosinate, le potassium cocoyl sarcosinate, le sodium cocoyl sarcosinate, le sodium lauroyl sarcosinate, le sodium myristoyl sarcosinate, le sodium palmitoyl sarcosinate et leurs mélanges.
- Selon un mode de réalisation tout à fait préféré de l'invention, ledit tensioactif dérivé d'un acide gras et d'un acide aminé est le lauroylsarcosinate de sodium.
- Dans le cadre d'un mode de réalisation préféré de la présente invention, ledit (ii) solvant est choisi dans le groupe comprenant le glycérol, le mono-propylène glycol et l'eau. Selon un mode de réalisation tout à fait préféré, ledit (ii) solvant est de l'eau. Selon l'invention, ladite composition comprend en outre un (iii) triglycéride éthoxylé.
- Ce dernier mode de réalisation propose une composition agissant efficacement sur deux souillures alimentaires : les protéines et les lipides.
- Dans le cadre de la présente invention, le terme dérive entend signifier que ledit triglycéride éthoxylé a été obtenu par une réaction d'éthoxylation du triglycéride cité.
- Selon l'invention, ledit triglycéride éthoxylé dérive de l'huile de ricin tel que de l'huile de ricin éthoxylé.
- Selon un mode de réalisation préféré de l'invention, ledit triglycéride éthoxylé comprend des chaînes carbonées d'acide gras en C8 à C30.
- Selon un mode de réalisation préféré de l'invention, ladite composition ne comprend pas d'enzymes.
- Dans le cadre de la présente invention, le terme « ne comprend pas d'enzyme » entend plus particulièrement désigner que la composition prête à l'emploi selon l'invention comprend moins de 0.1% d'enzymes, préférentiellement moins de 0.04% d'enzymes et tout à fait préférentiellement moins de 0.01% d'enzymes. La présente invention, n'entend pas exclure les compositions comprenant des traces d'enzymes sous forme de contaminations mais ne présentant pas d'activités notables.
- Dans un mode de réalisation préféré de l'invention, ladite composition, prête à l'emploi, comprend en outre un ou plusieurs tensio-actifs, un ou plusieurs stabilisants, un ou plusieurs agents rhéologiques et un ou plusieurs conservateurs.
- Dans un mode de réalisation encore plus préféré de l'invention ledit tensio-actif est le cocamidopropylbétaine (CAPE).
- Selon un mode de réalisation préféré de l'invention, ces autres composants représentent une quantité comprise entre 0.02 et 30 pourcent en masse par rapport à la masse totale de ladite composition prête à l'emploi.
- Dans un mode de réalisation préféré de l'invention, le terme « comprend » entend signifier que la composition selon l'invention comprend les composants cités à l'exclusion de tout autre composant.
- Selon un mode de réalisation préféré de l'invention, (i) est contenu en une quantité comprise entre 0.005 et 5 pourcent en masse par rapport à la masse totale de ladite composition prête à l'emploi.
- Selon un mode de réalisation préféré de l'invention, (ii) est contenu en une quantité comprise entre 70 et 99,97 pourcent en masse par rapport à la masse totale de ladite composition prête à l'emploi.
- Selon un mode de réalisation préféré de l'invention, (iii) est contenu en une quantité comprise entre 0.005 et 10 pourcent en masse par rapport à la masse totale de ladite composition prête à l'emploi.
- Selon un mode de réalisation préféré de l'invention, les composants (i) et (iii) représentent une quantité comprise entre 0.01 et 15 pourcent en masse par rapport à la masse totale de ladite composition prête à l'emploi.
- Selon un mode de réalisation préféré de l'invention, les composants (i), (ii) et (iii) représentent une quantité comprise entre 70 et 99,98 pourcent en masse par rapport à la masse totale de ladite composition prête à l'emploi.
- Selon un mode de réalisation préféré, la composition selon l'invention est un nettoyant liquide pour usage professionnel.
- La présente invention concerne également une composition concentrée qui comprend des concentrations de (i) et de (iii) supérieures à celle de la composition, prête à l'emploi, selon l'invention décrite ci-dessus. Selon un mode de réalisation préféré, ladite composition concentrée comprend des concentrations de (i) et de (iii) 2 fois supérieures, encore plus préférentiellement 10 fois supérieures et tout à fait préférentiellement 20 fois supérieures à celle de la composition, prête à l'emploi, selon l'invention.
- Les formulations présentées ci-dessous représentent des exemples préférés, mais non limitatifs des compositions détergentes selon l'invention.
- Composition A (composition concentrée à diluer à 1%) :
- Lauroylsarcosinate de sodium : 2 %
- Huile de ricin éthoxylée : 3 %
- Autres tensioactifs : 21.5 %
- Autres excipients : 2.5 %
- eau : 71%
- Composition B (composition prête à l'emploi) :
- Lauroylsarcosinate sodium : 0.02 %
- Huile de ricin éthoxylée : 0.03 %
- Autres tensioactifs : 0.215 %
- Autres excipients : 0.025 %
- eau : 99.71%
Claims (4)
- - Nettoyant liquide pour usage professionnel , comprenant (i) un ou plusieurs tensioactif dérivé d'un acide gras et d'un acide aminé choisi dans le groupe comprenant le potassium cocoyl taurate, le potassium methyl cocoyl taurate, le sodium caproyl methyl taurate, le sodium cocoyl taurate, le sodium lauroyl taurate, le sodium methyl cocoyl taurate, le sodium methyl lauroyl taurate, le sodium methyl myristoyl taurate, le sodium methyl oleoyl taurate, le sodium methyl palmitoyl taurate, le sodium methyl stearoyl taurate, le dipotassium capryloyl glutamate, le dipotassium undecylenoyl glutamate, le disodium capryloyl glutamate, le disodium cocoyl glutamate, le disodium lauroyl glutamate, le disodium stearoyil glutamate, le disodium undecylenoyl glutamate, le potassium capryloyl glutamate, le potassium cocoyl glutamate, le potassium lauroyl glutamate, le potassium myristoyl glutamate, le potassium stearoyl glutamate, le potassium undecylenoyl glutamate, le sodium capryloyl glutamate, le sodium cocoyl glutamate, le sodium lauroyl glutamate, le sodium myristoyl glutamate, le sodium olivoyl glutamate, le sodium palmitoyl glutamate, le sodium stearoyl glutamate, le sodium undecylenoyl glutamate, le cocoyl methyl B-l alanine, le lauroyl l-alanine, le lauroyl methyl B-alanine, le myristoyl B-alanine, le sodium cocoyl alaninate, le sodium cocoyl methyl B-alanine, le sodium myristoyl methyl B alanine palmitoyl glycine, le sodium lauroyl glycine, le sodium cocoyl glycine, le sodium myristoyl glycine, le potassium lauroyl glycine, le potassium cocoyl glycine, le potassium lauroyl sarcosinate, le potassium cocoyl sarcosinate, le sodium cocoyl sarcosinate, le sodium lauroyl sarcosinate, le sodium myristoyl sarcosinate, le sodium palmitoyl sarcosinate et leurs mélanges, (ii) un solvant, (iii) un triglycéride éthoxylé dérivant de l'huile de ricin, et présentant un pH entre 3,0 - 11,0.
- - Nettoyant liquide pour usage professionnel, selon la revendication précédente, caractérisé en ce qu'il ne comprend pas d'enzymes.
- - Nettoyant liquide pour usage professionnel, selon l'une des revendications précédentes, caractérisé en ce que (i) est contenu en une quantité comprise entre 0.005 et 5 pourcent en masse par rapport à la masse totale de ladite composition.
- - Nettoyant liquide pour usage professionnel, selon l'une des revendications 1 à 3, caractérisé en ce que (iii) est contenu en une quantité comprise entre 0.005 et 10 pourcent en masse par rapport à la masse totale dudit nettoyant.
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| RS20231068A RS64826B1 (sr) | 2016-12-23 | 2017-12-21 | Sastav deterdženta |
| HRP20231404TT HRP20231404T1 (hr) | 2016-12-23 | 2017-12-21 | Sastav deterdženta |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR1663328A FR3061201B1 (fr) | 2016-12-23 | 2016-12-23 | Composition detergente |
| PCT/FR2017/053797 WO2018115777A1 (fr) | 2016-12-23 | 2017-12-21 | Composition detergente |
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| EP3559182A1 EP3559182A1 (fr) | 2019-10-30 |
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| EP (1) | EP3559182B1 (fr) |
| JP (1) | JP2020504777A (fr) |
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| JPS6087209A (ja) * | 1983-10-18 | 1985-05-16 | Kao Corp | シヤンプ−組成物 |
| JP3216848B2 (ja) * | 1993-06-18 | 2001-10-09 | 株式会社資生堂 | 洗浄剤組成物 |
| WO1995033026A1 (fr) * | 1994-06-01 | 1995-12-07 | The Procter & Gamble Company | Compositions contenant oleoyle sarcosinate empechant le transfert de colorants |
| WO1995033811A1 (fr) * | 1994-06-02 | 1995-12-14 | The Procter & Gamble Company | Produits lessiviels contenant un sarcosinate d'oleyle associe a des alkanolamides |
| JPH08151598A (ja) * | 1994-11-30 | 1996-06-11 | Kawaken Fine Chem Co Ltd | 未変性水溶性コラーゲンの可溶化剤 |
| DE10216509A1 (de) * | 2002-04-11 | 2003-10-23 | Beiersdorf Ag | Fließfähige kosmetische und dermatologische Reinigungsgele enthaltend ein oder mehrere vorgelatinisierte, quervernetzte Stärkederivate |
| JP2004035524A (ja) * | 2002-07-08 | 2004-02-05 | Lion Corp | 角質層水分量低減抑制組成物 |
| DE10344527A1 (de) * | 2003-09-25 | 2005-04-21 | Beiersdorf Ag | Schäumende Zubereitungen mit Fließgrenze |
| CA2785479C (fr) * | 2009-12-22 | 2015-06-16 | The Procter & Gamble Company | Composition de nettoyage et/ou de decontamination liquide |
| WO2012068001A1 (fr) * | 2010-11-17 | 2012-05-24 | Isp Investments Inc. | Éthers de n-alkyl-lactames, compositions les contenant et utilisations |
| JP5923409B2 (ja) * | 2012-08-10 | 2016-05-24 | 株式会社マンダム | 皮膚洗浄剤用組成物 |
| JP6336334B2 (ja) * | 2014-06-06 | 2018-06-06 | 花王株式会社 | 液体洗浄剤組成物 |
| CN106190627A (zh) * | 2016-08-03 | 2016-12-07 | 安徽三祥羽毛有限公司 | 一种水洗羽毛用洗涤除臭剂及其制备方法 |
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- 2017-12-21 US US16/472,391 patent/US20200010779A1/en not_active Abandoned
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| PT3559182T (pt) | 2023-11-14 |
| CA3047854A1 (fr) | 2018-06-28 |
| EP3559182A1 (fr) | 2019-10-30 |
| HRP20231404T1 (hr) | 2024-02-16 |
| BR112019013006A2 (pt) | 2020-05-26 |
| RS64826B1 (sr) | 2023-12-29 |
| FR3061201B1 (fr) | 2020-06-26 |
| ES2966112T3 (es) | 2024-04-18 |
| ZA201904462B (en) | 2020-03-25 |
| RU2019123175A3 (fr) | 2021-01-25 |
| DK3559182T3 (da) | 2023-12-04 |
| WO2018115777A1 (fr) | 2018-06-28 |
| KR20190095449A (ko) | 2019-08-14 |
| JP2020504777A (ja) | 2020-02-13 |
| PH12019501416A1 (en) | 2020-06-01 |
| MY192891A (en) | 2022-09-14 |
| CO2019007510A2 (es) | 2020-01-17 |
| AU2017380426A1 (en) | 2019-07-18 |
| FI3559182T3 (fi) | 2023-11-30 |
| HUE064245T2 (hu) | 2024-02-28 |
| RU2748596C2 (ru) | 2021-05-27 |
| UA123377C2 (uk) | 2021-03-24 |
| PL3559182T3 (pl) | 2024-02-26 |
| US20200010779A1 (en) | 2020-01-09 |
| PE20191538A1 (es) | 2019-10-23 |
| FR3061201A1 (fr) | 2018-06-29 |
| RU2019123175A (ru) | 2021-01-25 |
| MA47104A (fr) | 2019-10-30 |
| MX2019007475A (es) | 2020-01-20 |
| CL2019001734A1 (es) | 2019-10-18 |
| CN110312784A (zh) | 2019-10-08 |
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