CN110051601B

CN110051601B - Face-activating and repairing composition containing mineral spring water

Info

Publication number: CN110051601B
Application number: CN201910382525.9A
Authority: CN
Inventors: 王烯睿
Original assignee: Yili Miyuequan Bio Tech Co ltd
Current assignee: Yili Miyuequan Bio Tech Co ltd
Priority date: 2019-05-09
Filing date: 2019-05-09
Publication date: 2021-12-10
Anticipated expiration: 2039-05-09
Also published as: CN110051601A

Abstract

The invention relates to the field of preparation of cosmetics, and provides a face-activating and repairing composition containing mineral spring water, which at least comprises a humectant, a skin conditioner and a solvent, wherein the weight ratio of the humectant to the skin conditioner to the solvent is 1: (0.5-1.5): (1-5); the skin conditioner comprises one or more of rice chaff extract, panthenol, plant composite anti-allergy agent, rice fermentation liquor, rose hydrosol, butanediol, water, kava pepper extract, hydrogenated lecithin and 1, 2-hexanediol; also provided is a daily chemical product containing the face-activating and repairing composition and a preparation method thereof.

Description

Face-activating and repairing composition containing mineral spring water

Technical Field

The invention relates to the field of preparation of cosmetics, in particular to a face-activating repair composition containing mineral spring water, a daily chemical product containing the face-activating repair composition and a preparation method of the daily chemical product.

Background

With the continuous improvement of living standard of people, the pursuit of beauty is higher and higher, especially the pursuit of cosmetics such as a mild and safe mask is higher and higher, but factors such as air pollution, ultraviolet ray damage, environmental allergen invasion, unsafe mask and cosmetics use and the like increase the damage to the skin of a human body, and the phenomena of face drying discomfort, allergy and the like can be caused after a long time. However, in the existing essence liquid products on the market, partial components have stimulation to skin and have safety risk: such as solubilizing agents (PEG-60 hydrogenated castor oil, polysorbate-20), preservatives (methyl hydroxybenzoate, propyl hydroxybenzoate, methylisothiazolinone, phenoxyethanol), allergen components (perfumes), and irregular animal and plant extracts, and the like, can bring unsafe potential risks to the facial skin after long-term use. Moreover, most products in the market are sticky, thick and not fresh, are not beneficial to skin absorption, and influence skin breathing and metabolism. At present, most mask products have general effects, particularly, anti-allergy masks are few and few, the anti-allergy masks cannot well meet the requirements of the current market, and the pursuit of consumers for safe and mild cosmetics cannot be better met.

Therefore, how to achieve zero irritation of the product, quickly permeate the skin and absorb the skin, and the effect of the functional components on the allergy relieving and repairing effect of the facial skin is extremely good, and the problem to be solved is urgently needed in the research of products in the field of skin care products at present.

Disclosure of Invention

In order to solve the technical problems, the invention provides a mineral spring water-containing face-refreshing and repairing composition, which at least comprises a humectant, a skin conditioner and a solvent, wherein the weight ratio of the humectant to the skin conditioner to the solvent is 1: (0.5-1.5): (1-5); the skin conditioner comprises one or more of rice chaff extract, panthenol, plant composite anti-allergy agent, rice fermentation liquor, rose hydrosol, butanediol, water, kava pepper extract, hydrogenated lecithin and 1, 2-hexanediol.

In a preferred embodiment, the skin conditioner of the present invention further comprises at least one of a moisturizing agent and hydrolyzed collagen.

As a preferable technical scheme, the weight ratio of the moisturizing humectant, the hydrolyzed collagen and the rose hydrosol in the invention is (1-5): 1: (1-5).

In a preferred embodiment, the skin conditioner of the present invention further comprises at least one of a moisturizing composition and glycosaminoglycans.

As a preferable technical scheme, the weight ratio of the rose hydrosol, the rice fermentation liquor, the glucosaminoglycan and the moisturizing composition in the invention is (10-20): (5-15): (1-10): 1.

as a preferred technical scheme, the solvent is spring water; the spring water contains 0.02-0.08mg/L of molybdenum and 0.03-0.1mg/L of strontium.

In a second aspect of the present invention, there is provided a daily chemical comprising the face-beautifying and repairing composition, wherein the raw materials comprise, by weight, at least, 10-50% of the face-beautifying and repairing composition according to any one of claims 1-5, 0.01-0.1% of a chelating agent, 0.1-1% of a thickener, 0.1-0.5% of a preservative, 0.01-0.1% of a pH regulator, and the balance of a solvent.

As a preferable technical scheme, the raw material of the daily chemical product in the invention also comprises 0.05-1 wt% of glycosphingolipids.

As a preferred technical solution, the thickener in the present invention is selected from one or more of xanthan gum, carbomer 20, carbomer 940, high molecular cellulose, xanthan gum, arabic gum, and sodium acrylate/sodium acryloyldimethyl taurate copolymer.

The third aspect of the invention provides a preparation method of the daily chemical product, which comprises the steps of adding a thickening agent into a preparation pot containing a chelating agent and a solvent, stirring, adding a pH regulator into the preparation pot, and continuously stirring uniformly; adding the face-activating repairing composition into a preparation pot, stirring uniformly, filtering and discharging to obtain the face-activating repairing composition.

Has the advantages that:

the product of the invention has better moisture retention, increases the moisture content of the horny layer, further repairs the skin barrier, and makes the skin more smooth, mild, safe, smooth and elastic; has better circulation stability and obviously improved lactic acid stabbing pain result.

The technical features, content and advantages of the invention described in the preceding section are more readily understood by reference to the following details.

Detailed Description

Unless otherwise indicated, implied from the context, or customary in the art, all parts and percentages herein are by weight and the testing and characterization methods used are synchronized with the filing date of the present application. To the extent that a definition of a particular term disclosed in the prior art is inconsistent with any definitions provided herein, the definition of the term provided herein controls.

The technical features of the technical solutions provided by the present invention are further clearly and completely described below with reference to the specific embodiments, and the scope of protection is not limited thereto.

The words "preferred", "preferably", "more preferred", and the like, in the present invention, refer to embodiments of the invention that may provide certain benefits, under certain circumstances. However, other embodiments may be preferred, under the same or other circumstances. Furthermore, the recitation of one or more preferred embodiments does not imply that other embodiments are not useful, nor is it intended to exclude other embodiments from the scope of the invention. The sources of components not mentioned in the present invention are all commercially available.

Face-care composition containing mineral spring water

The invention provides a face-activating and repairing composition containing mineral spring water, which at least comprises a humectant, a skin conditioner and a solvent, wherein the weight ratio of the humectant to the skin conditioner to the solvent is 1: (0.5-1.5): (1-5); the skin conditioner comprises one or more of rice chaff extract, panthenol, plant composite anti-allergy agent, rice fermentation liquor, rose hydrosol, butanediol, water, kava pepper extract, hydrogenated lecithin and 1, 2-hexanediol.

Preferably, the face-beautifying and repairing composition containing mineral spring water comprises the components of a humectant, a skin conditioner and a solvent, wherein the weight ratio of the humectant to the skin conditioner to the solvent is 1: (0.8-1.2): (2-4); more preferably, the mineral spring water-containing face-beautifying and repairing composition comprises the components of a humectant, a skin conditioner and a solvent, wherein the weight ratio of the humectant to the skin conditioner to the solvent is 1: 1: 2.5.

skin conditioning agent

In some embodiments, the skin conditioner comprises a combination of one or more of rice chaff extract, panthenol, botanical composite anti-sensitivity agents, rice broth, rose hydrosol, butylene glycol, water, kava pepper extract, hydrogenated lecithin, 1, 2-hexanediol; preferably, the skin conditioner comprises one or more of rice chaff extract, panthenol, plant composite anti-allergy agent, rice fermentation liquor and rose hydrosol; more preferably, the skin conditioner comprises one or more of rice fermentation liquor and rose hydrosol; most preferably, the skin conditioner comprises rice fermentation liquor and rose hydrosol.

In some embodiments, the skin conditioning agent further comprises at least one of a moisturizing agent, hydrolyzed collagen; preferably, the skin conditioner further comprises a moisturizing agent and hydrolyzed collagen.

In some embodiments, the moisturizing agent, the hydrolyzed collagen, and the rose hydrosol are present in a weight ratio of (1-5): 1: (1-5); preferably, the weight ratio of the moisturizing humectant to the hydrolyzed collagen to the rose hydrosol is (2-4): 1: (2-4); more preferably, the weight ratio of the moisturizing humectant to the hydrolyzed collagen to the rose hydrosol is 2: 1: 3.

the inventor of the application finds that the spring water adopted by the application is greatly different from the common water quality, the water contains a plurality of trace elements such as Mo, Sr and the like, and the rose hydrosol contains certain trace elements, so the moisturizing agent and the hydrolyzed collagen liquid are adopted to be matched with the rose hydrosol and the spring water, the skin can be further lubricated, mild and safe, the inventor speculates that the possible reason is that firstly, EDTA disodium, PHL and the like chelate a large amount of alkali metals in the water quality to make the alkali metals hardly generate normal valence reaction, secondly, the moisturizing agent, the hydrolyzed collagen liquid and the trace elements are adopted to form a stable chemical structure through coordination and complexation, thereby avoiding the valence transformation of the hydrolyzed collagen liquid and other components after being placed for a long time, leading to the skin allergy, and protecting the physicochemical properties of the trace elements, the skin can fully absorb and utilize trace elements, so that the skin activity is further improved, the skin is kept healthy, moist, smooth and elastic, the influence of the components on the circulation stability is avoided, and the repairing cream has better experience.

In some embodiments, the skin conditioning agent further comprises at least one of a moisturizing composition, a glycosaminoglycans; preferably, the skin conditioner further comprises a moisturizing composition, glucosaminoglycans.

In some embodiments, the weight ratio of the rose hydrosol, rice broth, glycosaminoglycans, and moisturizing composition is (10-20): (5-15): (1-10): 1; preferably, the weight ratio of the rose hydrosol, the rice fermentation liquor, the glucosaminoglycan and the moisturizing composition is (12-18): (8-12): (3-8): 1; more preferably, the weight ratio of the rose hydrosol, the rice fermentation liquor, the glucosaminoglycan and the moisturizing composition is 15: 10: 5: 1.

in some embodiments, the moisturizing composition is selected from the group consisting of tropolone, caprylhydroxamic acid, ethylhexylglycerin, butylene glycol, glycerin, 1, 2-pentanediol, 1, 2-hexanediol, sodium hyaluronate, an amino acid humectant, trehalose; preferably, the moisturizing composition is a combination of tropolone, caprylhydroxamic acid, ethylhexyl glycerin and butanediol; more preferably, the moisturizing composition is CP05, available from shanghai fine chemicals, ltd, under the designation CP 05.

In some embodiments, the moisturizing composition is selected from the group consisting of tropolone, butylene glycol, glycerin, 1, 2-pentanediol, 1, 2-hexanediol, sodium hyaluronate, an amino acid moisturizer, trehalose; preferably, the moisturizing composition is a combination of tropolone, butanediol and glycerol; further preferably, the weight ratio of the tropolone to the butanediol to the glycerol is 1: (0.5-1.5): (0.5-2); further preferably, the weight ratio of the tropolone to the butanediol to the glycerol is 1: 1: 1.5.

in some embodiments, the moisturizing composition is a combination of one or more of tropolone, sodium hyaluronate, an amino acid humectant, trehalose; preferably, the moisturizing composition is a combination of tropolone, sodium hyaluronate, an amino acid humectant and trehalose; further preferably, the weight ratio of the tropolone to the sodium hyaluronate to the amino acid humectant to the trehalose is 1: (0.1-0.5): (0.5-1.5): (0.1-1); preferably, the weight ratio of the tropolone to the sodium hyaluronate to the amino acid humectant to the trehalose is 1: 0.3: 1: 0.5.

the inventor finds that the rose hydrosol, the rice fermentation liquor and the moisturizing composition have better moisturizing performance, so that the moisture content of the horny layer is increased, and the skin barrier is further repaired. The inventor conjectures that the possible reasons are that by adopting the components, on one hand, the tropolone in the moisturizing composition can permeate into the skin to play a moisturizing role, and due to the special structure, the tropolone can act in the horny layer of the skin together with the rose hydrosol and the natural moisturizing factor NMF rich in the rice fermentation liquor, and then a water locking film is formed on the surface of the skin through glucosaminoglycan to form a sandwich structure in a matrix, so that the moisturizing role is played, the skin is in a balanced state, and the skin barrier is repaired; in addition, the existence of the moisturizing composition also enables the rose hydrosol to have better antibacterial property, avoids the deterioration and the putrefaction of the rose hydrosol in the product, and improves the stability of the product.

The CAS number of the rice chaff extract is 90106-37-9;

the ubiquinol INCI is named as ubiquinol and is available under the designation VB5, and is purchased from the Shanghai autumn-hydrogness business Co.

The plant composite antiallergic agent INCI is selected from butanediol, water, herba Centellae (CENTELLA ASIATICA) extract, rhizoma Polygoni Cuspidati (Polygonum CUSPIDATUM) root extract, Scutellariae radix (Scutellaria BAICALENSIS) root extract, folium Camelliae sinensis (CAMELLIA SINENSIS) leaf extract, Glycyrrhiza GLABRA (Glycyrrhiza GLABRA) root extract, flos Matricariae Chamomillae (Chamomilla RECUTITA) flower extract, and herba Rosmarini OFFICINALIS (Rosmarinus OFFICINALIS) leaf extract; the trademark Calmyang was purchased from chemical Co., Ltd.

The rice fermentation liquor INCI is named as yeast/rice fermentation product filtrate, 1, 2-hexanediol and butanediol; the brand is rice fermentation liquor and is purchased from Shanghai Auxue chemical Co.

The INCI name of the rose hydrosol is rose hydrosol, which is purchased from a huatianbao Chinese herbal medicine biological product factory in Jiean, Damascus rose hydrosol.

The kava extract has CAS number of 84696-40-2.

The CAS number of the hydrogenated lecithin is 92128-87-5, and the hydrogenated lecithin is purchased from Shanghai Haoyun chemical company.

The moisturizing agent INCI is water, glycerin, butylene glycol, Acidobacterium/soybean fermentation product extract, Viscum ALBUM leaf extract, and lalang grass rhizome (IMPERATA CYLINDRICA MAJOR) extract, and is available from CHEMICAL CO.

The CAS number of the hydrolyzed collagen is 92113-31-0; the brand is purchased from Shanghai Yaolan chemical Co Ltd.

The CAS number of the glycosaminoglycans is 94945-04-7.

Moisture-retaining agent

In some embodiments, the humectant is selected from the group consisting of methyl propylene glycol, glycerin, sodium hyaluronate, betaine, PHL, PEG/PPG-14/7 dimethyl ether in combination with one or more; preferably, the humectant is selected from one or more of methyl propylene glycol, glycerin and sodium hyaluronate; more preferably, the humectant is selected from the group consisting of methyl propylene glycol, glycerin, sodium hyaluronate.

In some embodiments, the weight ratio of methyl propylene glycol, glycerin, sodium hyaluronate is 1: (0.1-1.5): (0.01-0.1); preferably, the weight ratio of the methyl propylene glycol, the glycerol and the sodium hyaluronate is 1: (0.5-1): (0.02-0.05); more preferably, the weight ratio of the methyl propylene glycol, the glycerol and the sodium hyaluronate is 1: 0.75: 0.025.

the methyl propylene glycol is purchased from Shanghai force refiner, Inc. and is under the MPG trademark.

The sodium hyaluronate is purchased from Shandong Dongxin chemical Co., Ltd, and the brand is HA.

The PEG/PPG-14/7 dimethyl ether was purchased from Shanghai Ringhong chemical Co., Ltd., trade name 147.

Solvent(s)

In some embodiments, the solvent is spring water; the spring water contains 0.02-0.08mg/L of molybdenum and 0.03-0.1mg/L of strontium; preferably, the spring water contains 0.04-0.07mg/L of molybdenum and 0.04-0.08mg/L of strontium; more preferably, the spring water contains 0.042mg/L of molybdenum and 0.051mg/L of strontium; purchased from illinois foundation biotechnology limited.

According to the invention, the spring water with different molybdenum contents and contents can be obtained by selecting other types of spring water to be compounded according to the required concentration.

The invention provides a preparation method of the face-activating and repairing composition, which at least comprises the following steps:

firstly, adding the components in the humectant into a preparation pot filled with a solvent for mixing, raising the temperature to 70-90 ℃, reducing the temperature to 30-50 ℃, and then sequentially adding the skin conditioner for continuous mixing.

Preferably, the method for preparing the face-repairing composition at least comprises the following steps:

firstly, the components in the humectant are added into a preparation pot filled with a solvent for mixing, the temperature is increased to 80 ℃, the temperature is reduced to 40 ℃, and then the skin conditioner is sequentially added for continuous mixing.

According to the second aspect of the invention, the daily chemical product of the face-activating and repairing composition is provided, and the raw materials at least comprise, by weight, 10-50% of the face-activating and repairing composition, 0.01-0.1% of a chelating agent, 0.1-1% of a thickening agent, 0.1-0.5% of a preservative, 0.01-0.1% of a pH regulator and the balance of a solvent; preferably, the raw materials at least comprise, by weight, 20-40% of the face-repairing composition, 0.02-0.08% of a chelating agent, 0.2-0.5% of a thickening agent, 0.15-0.3% of a preservative, 0.02-0.05% of a pH regulator and the balance of a solvent; more preferably, the raw materials at least comprise, by weight, 30% of the face-repairing composition, 0.05% of a chelating agent, 0.35% of a thickening agent, 0.15% of a preservative, 0.03% of a pH regulator and the balance of a solvent.

Glycosphingolipids

In some embodiments, the commodity material further comprises 0.05-1% by weight of glycosphingolipids; preferably, the daily chemical raw material also comprises glycosphingolipids with the weight percentage of 0.1-0.5%; more preferably, the daily chemical raw material also comprises 0.2 weight percent of glycosphingolipids.

The inventor of the application finds that through the action of the glycosphingolipid and the carbomer U20, the xanthan gum and the like, hydrophilic sugar chains of the glycosphingolipid are similar to the xanthan gum, the emulsifying performance of the glycosphingolipid is improved due to the action of intermolecular force, and then the longer fat chain segments on the other side of the glycosyl end are interlaced and wound in a system and are matched with the carbomer U20, so that the original HLB value range is enlarged, the emulsifying capacity is further improved, the phenomena of flocculation and the like of various active ingredients in the plant composite anti-allergy agent are prevented from occurring after long-term standing, and the essence of the invention is more stable. In addition, the glycosphingolipid, the hydrolyzed collagen liquid, the glucosaminoglycan and the like are easily adsorbed on the cell surface, so that the adhesion between keratinocytes can be enhanced, the water content of the stratum corneum is increased, and the skin barrier is stably maintained, thereby remarkably improving the lactic acid sting result.

The glycosphingolipids are purchased from Beijing lingbao technologies, Inc., brand HMH.

Chelating agents

In some embodiments, the chelating agent is EDTA sodium salt; preferably, the sodium salt of EDTA is disodium EDTA.

The EDTA disodium is also called ethylene diamine tetraacetic acid disodium; the disodium EDTA and the glycerol are purchased from Shanghai Yuan biological technology Co., Ltd; CAS number 139-33-3.

Thickening agent

In some embodiments, the thickener is selected from the group consisting of xanthan gum, carbomer 20, carbomer 940, polymeric cellulose, xanthan gum, gum arabic, sodium acrylate/sodium acryloyldimethyl taurate copolymer in combination with one or more; preferably, the thickening agent is selected from one or more of xanthan gum, carbomer 20 and carbomer 940; preferably, the thickening agent is selected from one or more of xanthan gum and carbomer 20; preferably, the thickener is a combination of xanthan gum, carbomer 20.

In some embodiments, the xanthan gum and carbomer 20 are present in a weight ratio of 1: (1-5); preferably, the weight ratio of the xanthan gum to the carbome 20 is 1: (2-4); more preferably, the weight ratio of the xanthan gum to the carbomer 20 is 1: 2.5.

preservative

In some embodiments, the preservative in the present invention is selected from the group consisting of chlorphenesin, ethylhexylglycerin, phenoxyethanol, caprylyl hydroxamic acid in combination with one or more thereof; preferably, the preservative is selected from one or more of chlorphenesin and ethylhexyl glycerol; preferably, the preservative is chlorophenyl glucoside ether.

The CAS number of the chlorophenyl glycoside ether is 104-29-0, purchased from Shanghai Qianjin chemical company, Inc., and named as CPH; the CAS number of the ethylhexyl glycerol is 70445-33-9, and the CAS number of the phenoxyethanol is 122-99-6; the CAS number of the caprylyl hydroximic acid is 7377-03-9.

pH regulator

In some embodiments, the pH adjusting agent of the present invention is an alkali metal agent.

In some embodiments, the alkali metal agent is selected from the group consisting of sodium hydroxide, potassium carbonate, sodium carbonate, in combination of one or more thereof; preferably, the alkali metal reagent is selected from one or more of sodium hydroxide and potassium hydroxide; more preferably, the alkali metal reagent is sodium hydroxide.

In some embodiments, the alkali metal reagent is a 5 to 15 wt% aqueous solution; preferably, the alkali metal reagent is a 10 wt% aqueous solution.

Solvent(s)

In some embodiments, the solvent in the consumer chemical product of the present invention is the same solvent as the solvent used in the color rejuvenating composition.

The third aspect of the invention provides a preparation method of the daily chemical product, which at least comprises the steps of adding the thickening agent into a preparation pot containing the chelating agent and the solvent for stirring, adding the pH regulator into the preparation pot, and continuously stirring uniformly; adding the face-activating repairing composition into a preparation pot, stirring uniformly, filtering and discharging to obtain the face-activating repairing composition.

In some preferred embodiments, the method for preparing a daily chemical article at least comprises the steps of,

(1) adding the thickening agent into a preparation pot containing the chelating agent and the solvent, stirring and heating to 70-100 ℃;

(2) cooling to 50-70 deg.C, adding pH regulator into the preparation pot, and stirring;

(3) cooling to 30-50 deg.C, adding the composition and the rest raw materials into a preparation pot, stirring, filtering with 50-300 mesh filter cloth, and discharging.

In some more preferred embodiments, the method for preparing a daily chemical article comprises at least the steps of,

(1) adding the thickening agent into a preparation pot containing the chelating agent and the solvent, stirring and heating to 75-90 ℃;

(2) cooling to 55-65 deg.C, adding pH regulator into the preparation pot, and stirring;

(3) cooling to 35-45 ℃, adding the face-activating repair composition and the rest raw materials into a preparation pot, stirring uniformly, filtering with 100-mesh filter cloth of 200 meshes, and discharging to obtain the face-activating repair composition.

In a further preferred embodiment, the method for preparing the daily chemical product at least comprises the steps of,

(1) adding the thickening agent into a preparation pot containing the chelating agent and the solvent, stirring and heating to 80 ℃;

(2) cooling to 60 ℃, adding the pH regulator into the preparation pot, and continuously stirring uniformly;

(3) cooling to 40 ℃, adding the face-activating and repairing composition and the rest raw materials into a preparation pot, stirring uniformly, filtering by a 100-mesh filter cloth, and discharging to obtain the face-activating and repairing composition.

The present invention is described in detail below with reference to examples, which are provided for the purpose of further illustration only and are not to be construed as limiting the scope of the present invention, and the insubstantial modifications and adaptations thereof by those skilled in the art based on the teachings of the present invention will still fall within the scope of the present invention.

Example 1

A face-activating and repairing composition containing mineral spring water comprises a humectant, a skin conditioner and a solvent, wherein the weight ratio of the humectant to the solvent is 1: 1: 2.5; the skin conditioner comprises rice fermentation liquor, rose hydrosol, a moisturizing composition, glucosaminoglycan, a moisturizing humectant and hydrolyzed collagen, wherein the weight ratio of the moisturizing humectant to the hydrolyzed collagen to the rose hydrosol is 2: 1: 3; the weight ratio of the rose hydrosol to the rice fermentation liquor to the glucosaminoglycan to the moisturizing composition is 15: 10: 5: 1, the moisturizing composition is CP 05; the humectant is selected from the combination of methyl propylene glycol, glycerin and sodium hyaluronate, and the weight ratio is 1: 0.75: 0.025; the solvent is spring water containing 0.042mg/L molybdenum and 0.051mg/L strontium, and is purchased from Yili Mieyuan Biotech Co.

The preparation method of the face-repairing composition at least comprises the following steps: firstly, adding the components in the humectant into a preparation pot filled with a solvent for mixing, raising the temperature to 80 ℃, reducing the temperature to 40 ℃, sequentially adding the skin conditioner and continuously mixing;

a daily chemical product containing the face-activating and repairing composition, which comprises the raw materials of, by weight percentage, at least 30% of the face-activating and repairing composition, 0.05% of chelating agent, 0.35% of thickening agent, 0.15% of preservative, 0.03% of pH regulator, 0.2% of glycosphingolipids and the balance of solvent;

the chelating agent is EDTA disodium; the thickening agent is a combination of xanthan gum and carbomer 20, and the weight ratio is 1: 2.5; the preservative is chlorophenyl glucoside ether; the pH regulator is 10 wt% sodium hydroxide aqueous solution;

the preparation method of the daily chemical product at least comprises the following steps,

Example 2

A face-activating and repairing composition containing mineral spring water comprises a humectant, a skin conditioner and a solvent, wherein the weight ratio of the humectant to the solvent is 1: 0.5: 1; the skin conditioner comprises rice fermentation liquor, rose hydrosol, a moisturizing composition, glucosaminoglycan, a moisturizing humectant and hydrolyzed collagen, wherein the weight ratio of the moisturizing humectant to the hydrolyzed collagen to the rose hydrosol is 1: 1: 1; the weight ratio of the rose hydrosol to the rice fermentation liquor to the glucosaminoglycan to the moisturizing composition is 10: 5: 1: 1, the moisturizing composition is tropolone, butanediol and glycerol, and the weight ratio is 1: 1: 1.5; the humectant is selected from the combination of methyl propylene glycol, glycerin and sodium hyaluronate, and the weight ratio is 1: 0.1: 0.01; the solvent is spring water containing 0.02mg/L molybdenum and 0.03mg/L strontium, and is purchased from Yili Miyaoquan Biotech Co.

a daily chemical product containing the face-activating and repairing composition, which comprises the raw materials of, by weight percentage, at least 10% of the face-activating and repairing composition, 0.01% of chelating agent, 0.1% of thickening agent, 0.1% of preservative, 0.01% of pH regulator, 0.05% of glycosphingolipids and the balance of solvent;

the chelating agent is EDTA disodium; the thickening agent is a combination of xanthan gum and carbomer 20, and the weight ratio is 1: 1; the preservative is chlorophenyl glucoside ether; the pH regulator is 5 wt% sodium hydroxide aqueous solution;

(1) adding the thickening agent into a preparation pot containing the chelating agent and the solvent, stirring and heating to 70 ℃;

(2) cooling to 50 ℃, adding the pH regulator into the preparation pot, and continuously stirring uniformly;

(3) cooling to 30 ℃, adding the face-activating and repairing composition and the rest raw materials into a preparation pot, stirring uniformly, filtering by a 100-mesh filter cloth, and discharging to obtain the face-activating and repairing composition.

Example 3

A face-activating and repairing composition containing mineral spring water comprises a humectant, a skin conditioner and a solvent, wherein the weight ratio of the humectant to the solvent is 1: 1.5: 5; the skin conditioner comprises rice fermentation liquor, rose hydrosol, a moisturizing composition, glucosaminoglycan, a moisturizing humectant and hydrolyzed collagen, wherein the weight ratio of the moisturizing humectant to the hydrolyzed collagen to the rose hydrosol is 5: 1: 5; the weight ratio of the rose hydrosol to the rice fermentation liquor to the glucosaminoglycan to the moisturizing composition is 20: 15: 10: 1, the moisturizing composition is a combination of tropolone, sodium hyaluronate, an amino acid humectant and trehalose, and the weight ratio is 1: 0.3: 1: 0.5; the humectant is selected from the combination of methyl propylene glycol, glycerin and sodium hyaluronate, and the weight ratio is 1: 1.5: 0.1; the solvent is spring water containing 0.08mg/L molybdenum and 0.1mg/L strontium, and is purchased from Yili Miyaoquan Biotech Co.

a daily chemical product containing the face-activating and repairing composition, which comprises the raw materials of, by weight percentage, at least 50% of the face-activating and repairing composition, 0.1% of chelating agent, 1% of thickening agent, 0.5% of preservative, 0.1% of pH regulator, 1% of glycosphingolipids and the balance of solvent;

the chelating agent is EDTA disodium; the thickening agent is a combination of xanthan gum and carbomer 20, and the weight ratio is 1: 5; the preservative is chlorophenyl glucoside ether; the pH regulator is 15 wt% sodium hydroxide aqueous solution;

(1) adding the thickening agent into a preparation pot containing the chelating agent and the solvent, stirring and heating to 100 ℃;

(2) cooling to 70 ℃, adding the pH regulator into the preparation pot, and continuously stirring uniformly;

(3) cooling to 50 deg.C, adding the composition and the rest raw materials into a preparation pot, stirring, filtering with 100 mesh filter cloth, and discharging.

Example 4

A face-activating and repairing composition containing mineral spring water comprises a humectant, a skin conditioner and a solvent, wherein the weight ratio of the humectant to the solvent is 1: 0.8: 2; the skin conditioner comprises rice fermentation liquor, rose hydrosol, a moisturizing composition, glucosaminoglycan, a moisturizing humectant and hydrolyzed collagen, wherein the weight ratio of the moisturizing humectant to the hydrolyzed collagen to the rose hydrosol is 2: 1: 2; the weight ratio of the rose hydrosol to the rice fermentation liquor to the glucosaminoglycan to the moisturizing composition is 12: 8: 3: 1, the moisturizing composition is a combination of tropolone, sodium hyaluronate, an amino acid humectant and trehalose, and the weight ratio is 1: 0.1: 0.5: 0.1; the humectant is selected from the combination of methyl propylene glycol, glycerin and sodium hyaluronate, and the weight ratio is 1: 0.5: 0.02; the solvent is spring water containing 0.04mg/L molybdenum and 0.04mg/L strontium, and is purchased from Yili Miyaoquan Biotech Co.

a daily chemical product containing the face-activating and repairing composition, which comprises the raw materials of, by weight percentage, 20% of the face-activating and repairing composition, 0.02% of chelating agent, 0.2% of thickening agent, 0.15% of preservative, 0.02% of pH regulator, 0.1% of glycosphingolipids and the balance of solvent;

the chelating agent is EDTA disodium; the thickening agent is a combination of xanthan gum and carbomer 20, and the weight ratio is 1: 2; the preservative is chlorophenyl glucoside ether; the pH regulator is 10 wt% sodium hydroxide aqueous solution;

(1) adding the thickening agent into a preparation pot containing the chelating agent and the solvent, stirring and heating to 75 ℃;

(2) cooling to 55 ℃, adding a pH regulator into the preparation pot, and continuously stirring uniformly;

(3) cooling to 35 deg.C, adding the composition and the rest raw materials into a preparation pot, stirring to uniform, filtering with 100 mesh filter cloth, and discharging.

Example 5

A face-activating and repairing composition containing mineral spring water comprises a humectant, a skin conditioner and a solvent, wherein the weight ratio of the humectant to the solvent is 1: 1.2: 4; the skin conditioner comprises rice fermentation liquor, rose hydrosol, a moisturizing composition, glucosaminoglycan, a moisturizing humectant and hydrolyzed collagen, wherein the weight ratio of the moisturizing humectant to the hydrolyzed collagen to the rose hydrosol is 4: 1: 4; the weight ratio of the rose hydrosol to the rice fermentation liquor to the glucosaminoglycan to the moisturizing composition is 18: 12: 8: 1, the moisturizing composition is a combination of tropolone, butanediol and glycerol, and the weight ratio is 1: 0.5: 0.5; the humectant is selected from the combination of methyl propylene glycol, glycerin and sodium hyaluronate, and the weight ratio is 1: 1: 0.05; the solvent is spring water containing 0.07mg/L molybdenum and 0.08mg/L strontium, and is purchased from Yili Miyaoquan Biotech Co.

a daily chemical product containing the face-activating and repairing composition, which comprises the raw materials of, by weight percentage, at least 40% of the face-activating and repairing composition, 0.08% of chelating agent, 0.5% of thickening agent, 0.3% of preservative, 0.05% of pH regulator, 0.5% of glycosphingolipids and the balance of solvent;

the chelating agent is EDTA disodium; the thickening agent is a combination of xanthan gum and carbomer 20, and the weight ratio is 1: 4; the preservative is chlorophenyl glucoside ether; the pH regulator is 10 wt% sodium hydroxide aqueous solution;

Example 6

A face-activating and repairing composition containing mineral spring water comprises a humectant, a skin conditioner and a solvent, wherein the weight ratio of the humectant to the solvent is 1: 1: 2.5; the skin conditioner comprises rice fermentation liquor, rose hydrosol, a moisturizing composition, glucosaminoglycan and hydrolyzed collagen, wherein the weight ratio of the hydrolyzed collagen to the rose hydrosol is 1: 3; the weight ratio of the rose hydrosol to the rice fermentation liquor to the glucosaminoglycan to the moisturizing composition is 15: 10: 5: 1, the moisturizing composition is CP 05; the humectant is selected from the combination of methyl propylene glycol, glycerin and sodium hyaluronate, and the weight ratio is 1: 0.75: 0.025; the solvent is spring water containing 0.042mg/L molybdenum and 0.051mg/L strontium, and is purchased from Yili Mieyuan Biotech Co.

Example 7

A face-activating and repairing composition containing mineral spring water comprises a humectant, a skin conditioner and a solvent, wherein the weight ratio of the humectant to the solvent is 1: 1: 2.5; the skin conditioner comprises rice fermentation liquor, rose hydrosol, a moisturizing composition, glucosaminoglycan and a moisturizing agent, wherein the moisturizing agent and the rose hydrosol are mixed in a weight ratio of 2: 3; the weight ratio of the rose hydrosol to the rice fermentation liquor to the glucosaminoglycan to the moisturizing composition is 15: 10: 5: 1, the moisturizing composition is CP 05; the humectant is selected from the combination of methyl propylene glycol, glycerin and sodium hyaluronate, and the weight ratio is 1: 0.75: 0.025; the solvent is spring water containing 0.042mg/L molybdenum and 0.051mg/L strontium, and is purchased from Yili Mieyuan Biotech Co.

Example 8

A face-activating and repairing composition containing mineral spring water comprises a humectant, a skin conditioner and a solvent, wherein the weight ratio of the humectant to the solvent is 1: 1: 2.5; the skin conditioner comprises rice fermentation liquor, rose hydrosol, a moisturizing composition, glucosaminoglycan, a moisturizing humectant and hydrolyzed collagen, wherein the weight ratio of the moisturizing humectant to the hydrolyzed collagen to the rose hydrosol is 0.1: 1: 3; the weight ratio of the rose hydrosol to the rice fermentation liquor to the glucosaminoglycan to the moisturizing composition is 15: 10: 5: 1, the moisturizing composition is CP 05; the humectant is selected from the combination of methyl propylene glycol, glycerin and sodium hyaluronate, and the weight ratio is 1: 0.75: 0.025; the solvent is spring water containing 0.042mg/L molybdenum and 0.051mg/L strontium, and is purchased from Yili Mieyuan Biotech Co.

Example 9

A face-activating and repairing composition containing mineral spring water comprises a humectant, a skin conditioner and a solvent, wherein the weight ratio of the humectant to the solvent is 1: 1: 2.5; the skin conditioner comprises rose hydrosol, a moisturizing composition, glucosaminoglycan, a moisturizing humectant and hydrolyzed collagen, wherein the weight ratio of the moisturizing humectant to the hydrolyzed collagen to the rose hydrosol is 2: 1: 3; the weight ratio of the rose hydrosol to the glucosaminoglycan to the moisturizing composition is 15: 5: 1, the moisturizing composition is CP 05; the humectant is selected from the combination of methyl propylene glycol, glycerin and sodium hyaluronate, and the weight ratio is 1: 0.75: 0.025; the solvent is spring water containing 0.042mg/L molybdenum and 0.051mg/L strontium, and is purchased from Yili Mieyuan Biotech Co.

Example 10

A face-activating and repairing composition containing mineral spring water comprises a humectant, a skin conditioner and a solvent, wherein the weight ratio of the humectant to the solvent is 1: 1: 2.5; the skin conditioner comprises rice fermentation liquor, rose hydrosol, glucosaminoglucan, a moisturizing humectant and hydrolyzed collagen, wherein the weight ratio of the moisturizing humectant to the hydrolyzed collagen to the rose hydrosol is 2: 1: 3; the weight ratio of the rose hydrosol to the rice fermentation liquor to the glucosaminoglycan is 3: 2: 1; the humectant is selected from the combination of methyl propylene glycol, glycerin and sodium hyaluronate, and the weight ratio is 1: 0.75: 0.025; the solvent is spring water containing 0.042mg/L molybdenum and 0.051mg/L strontium, and is purchased from Yili Mieyuan Biotech Co.

Example 11

A face-activating and repairing composition containing mineral spring water comprises a humectant, a skin conditioner and a solvent, wherein the weight ratio of the humectant to the solvent is 1: 1: 2.5; the skin conditioner comprises rice fermentation liquor, rose hydrosol, a moisturizing composition, glucosaminoglycan, a moisturizing humectant and hydrolyzed collagen, wherein the weight ratio of the moisturizing humectant to the hydrolyzed collagen to the rose hydrosol is 2: 1: 3; the weight ratio of the rose hydrosol to the rice fermentation liquor to the glucosaminoglycan to the moisturizing composition is 5: 1: 1: 1, the moisturizing composition is CP 05; the humectant is selected from the combination of methyl propylene glycol, glycerin and sodium hyaluronate, and the weight ratio is 1: 0.75: 0.025; the solvent is spring water containing 0.042mg/L molybdenum and 0.051mg/L strontium, and is purchased from Yili Mieyuan Biotech Co.

Example 12

A face-activating and repairing composition containing mineral spring water comprises a humectant, a skin conditioner and a solvent, wherein the weight ratio of the humectant to the solvent is 1: 1: 2.5; the skin conditioner comprises rice fermentation liquor, rose hydrosol, a moisturizing composition, a moisturizing humectant and hydrolyzed collagen, wherein the weight ratio of the moisturizing humectant to the hydrolyzed collagen to the rose hydrosol is 2: 1: 3; the weight ratio of the rose hydrosol to the rice fermentation liquor to the moisturizing composition is 15: 10: 1, the moisturizing composition is CP 05; the humectant is selected from the combination of methyl propylene glycol, glycerin and sodium hyaluronate, and the weight ratio is 1: 0.75: 0.025; the solvent is spring water containing 0.042mg/L molybdenum and 0.051mg/L strontium, and is purchased from Yili Mieyuan Biotech Co.

Example 13

a daily chemical product containing the face-activating and repairing composition, which at least comprises, by weight, 30% of the face-activating and repairing composition, 0.05% of a chelating agent, 0.35% of a thickening agent, 0.15% of a preservative, 0.03% of a pH regulator and the balance of a solvent;

Example 14

a daily chemical product containing the face-activating and repairing composition, which comprises the raw materials of, by weight percentage, at least 30% of the face-activating and repairing composition, 0.05% of chelating agent, 0.35% of thickening agent, 0.15% of preservative, 0.03% of pH regulator, 2% of glycosphingolipids and the balance of solvent;

Example 15

a daily chemical product containing the face-activating and repairing composition, which comprises the raw materials of, by weight percentage, at least 30% of the face-activating and repairing composition, 0.05% of chelating agent, 0.35% of thickening agent, 0.15% of preservative, 0.03% of pH regulator, 0.01% of glycosphingolipids and the balance of solvent;

Example 16

A face-activating and repairing composition containing mineral spring water comprises a humectant, a skin conditioner and a solvent, wherein the weight ratio of the humectant to the solvent is 1: 1: 2.5; the skin conditioner comprises rice fermentation liquor, rose hydrosol, a moisturizing composition, glucosaminoglycan, a moisturizing humectant and hydrolyzed collagen, wherein the weight ratio of the moisturizing humectant to the hydrolyzed collagen to the rose hydrosol is 2: 1: 3; the weight ratio of the rose hydrosol to the rice fermentation liquor to the glucosaminoglycan to the moisturizing composition is 15: 10: 5: 1, the moisturizing composition is CP 05; the humectant is selected from the combination of methyl propylene glycol, glycerin and sodium hyaluronate, and the weight ratio is 1: 0.75: 0.025; the solvent is mineral water purchased from the market;

Performance testing

1. Moisture content of skin stratum corneum:

selecting sensitive skin to satisfy TEWL>15g/h/m²270 subjects with stratum corneum water content were randomly divided into 9 groups of 30 persons each, and the age ranged from 25 to 55 years. The daily chemical products prepared in the examples were used asThe test subjects were used once a day, morning and evening, and the skin lotion was replaced with face cleanser for whole face use; the moisture content of the skin cuticle of a subject is respectively measured before the face uses the test product, after the face uses the test product for 2 weeks and after the face uses the test product for 4 weeks, and the moisture content of the skin cuticle of the face before the face uses the test product is a basic value; the difference from the base value after 2 weeks and 4 weeks was calculated as the increase in the water content of the stratum corneum, and the results are shown in Table 2; detection of the site: the detection indexes on the left side of the cheek are shown in table 1;

the test environment of the test has the temperature of 20.0-21.5 ℃ and the relative humidity of 48.0-56.0 percent, and meets the requirement of scheme design. The statistical method comprises the following steps: wilcoxon signed rank analysis was used with test level α of 0.05. Significance labeling method: "n.s." means no statistical difference, p > 0.05; "x", p < 0.05.

TABLE 1 test indexes

TABLE 2 skin stratum corneum moisture content results

2. Lactic acid sting test: the daily chemical products prepared in the examples were used as test subjects, and 30 lactic acid stingers (except pregnant or lactating women) aged 18 to 60 years were selected as subjects. Preparing 10 wt% lactic acid solution 50 μ L, dripping on 0.8cm diameter single-layer filter paper, placing on nasolabial sulcus of subject, inquiring about sting feeling of subject and observing skin condition at 3min, 4min and 5min respectively, and grading according to 4-point method (0 is no sting, 1 is mild sting, 2 is moderate sting, 3 is severe sting), and accumulating sting pain more than or equal to 3 is lactic acid sting; the subject uses the skin care lotion once in the morning and at night every day, and the skin care lotion is used for the whole face after face cleaning; the test was carried out after 28 days without any other product during the test period and the same experiment was carried out again after 28 days. The test results are shown in table 3.

Table 3 lactic acid stinging test results

Examples	Before use	After 28 days
			Example 1	3.56	2.10
Example 2	3.21	2.49
			Example 3	3.17	2.51
Example 4	3.70	2.61
			Example 5	3.16	2.55
Example 13	3.25	3.01
			Example 14	3.15	2.98
Example 15	3.42	3.12

3. And (3) safety evaluation: selecting sensitive skin to satisfy TEWL>15g/h/m²270 subjects with stratum corneum water content are randomly divided into 9 groups, each group contains 30 persons, and the age range is 25-55 years old; the safety of the sample on the skin of a human body is observed through a human body trial test, and the test sample is evaluated to have good safety by referring to the skin adverse reaction grading standard of the human body trial test specified in 2015 edition of technical Specification for cosmetic safety. Grading: grade 0 is no reaction; grade 1 is faint erythema; grade 2 is erythema, infiltration, papule; grade 3 erythema, edema, pimple, blister; grade 4, erythema, edema, bulla; the test results are shown in table 4.

TABLE 4 safety evaluation results

The foregoing examples are illustrative only, and serve to explain some of the features of the present disclosure. The appended claims are intended to claim as broad a scope as is contemplated, and the examples presented herein are merely illustrative of selected implementations in accordance with all possible combinations of examples. Accordingly, it is applicants' intention that the appended claims are not to be limited by the choice of examples illustrating features of the invention. And that advances in science and technology will result in possible equivalents or sub-substitutes not currently contemplated for reasons of inaccuracy in language representation, and such changes should also be construed where possible to be covered by the appended claims.

Claims

1. A daily chemical product containing a face-activating and repairing composition is characterized by comprising, by weight, at least 30% of face-activating and repairing composition, 0.05% of chelating agent, 0.35% of thickening agent, 0.15% of preservative, 0.03% of pH regulator, 0.2% of glycosphingolides and the balance of solvent;

the face activating and repairing composition comprises the following components in parts by weight: 1: 2.5; the skin conditioner comprises rice fermentation liquor, rose hydrosol, a moisturizing composition, glucosaminoglycan, a moisturizing humectant and hydrolyzed collagen, wherein the weight ratio of the moisturizing humectant to the hydrolyzed collagen to the rose hydrosol is 2: 1: 3; the weight ratio of the rose hydrosol to the rice fermentation liquor to the glucosaminoglycan to the moisturizing composition is 15: 10: 5: 1, the moisturizing composition is CP 05; the humectant is selected from the combination of methyl propylene glycol, glycerin and sodium hyaluronate, and the weight ratio is 1: 0.75: 0.025; the solvent is spring water which contains 0.042mg/L of molybdenum and 0.051mg/L of strontium.

2. A daily chemical product containing a face-activating and repairing composition is characterized by comprising, by weight, at least 50% of the face-activating and repairing composition, 0.1% of a chelating agent, 1% of a thickening agent, 0.5% of a preservative, 0.1% of a pH regulator, 1% of glycosphingolipids and the balance of a solvent;

the face activating and repairing composition comprises the following components in parts by weight: 1.5: 5; the skin conditioner comprises rice fermentation liquor, rose hydrosol, a moisturizing composition, glucosaminoglycan, a moisturizing humectant and hydrolyzed collagen, wherein the weight ratio of the moisturizing humectant to the hydrolyzed collagen to the rose hydrosol is 5: 1: 5; the weight ratio of the rose hydrosol to the rice fermentation liquor to the glucosaminoglycan to the moisturizing composition is 20: 15: 10: 1, the moisturizing composition is a combination of tropolone, sodium hyaluronate, an amino acid humectant and trehalose, and the weight ratio is 1: 0.3: 1: 0.5; the humectant is selected from the combination of methyl propylene glycol, glycerin and sodium hyaluronate, and the weight ratio is 1: 1.5: 0.1; the solvent is spring water which contains 0.08mg/L of molybdenum and 0.1mg/L of strontium.

3. A method for preparing a daily chemical product according to claim 1 or 2, comprising the steps of adding the thickener to a preparation pot containing the chelating agent and the solvent, stirring, adding the pH adjuster to the preparation pot, and continuing to stir uniformly; the face-rejuvenating composition according to claim 1, wherein the remaining ingredients are added to a compounding pot, stirred until uniform, filtered and discharged.