CN1098113A - 含二氮杂萘结构的聚醚砜及制备法 - Google Patents
含二氮杂萘结构的聚醚砜及制备法 Download PDFInfo
- Publication number
- CN1098113A CN1098113A CN 93109180 CN93109180A CN1098113A CN 1098113 A CN1098113 A CN 1098113A CN 93109180 CN93109180 CN 93109180 CN 93109180 A CN93109180 A CN 93109180A CN 1098113 A CN1098113 A CN 1098113A
- Authority
- CN
- China
- Prior art keywords
- polyethersulfone
- preparation
- naphthyridine
- reaction
- naphthyridine structure
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000004695 Polyether sulfone Substances 0.000 title claims description 21
- 229920006393 polyether sulfone Polymers 0.000 title claims description 21
- FLBAYUMRQUHISI-UHFFFAOYSA-N 1,8-naphthyridine Chemical group N1=CC=CC2=CC=CN=C21 FLBAYUMRQUHISI-UHFFFAOYSA-N 0.000 title claims description 15
- 238000002360 preparation method Methods 0.000 title claims description 8
- 239000000178 monomer Substances 0.000 claims abstract description 13
- 229920000642 polymer Polymers 0.000 claims abstract description 9
- 229910052736 halogen Inorganic materials 0.000 claims abstract description 8
- 150000002367 halogens Chemical class 0.000 claims abstract description 8
- 238000000034 method Methods 0.000 claims abstract description 5
- 239000002798 polar solvent Substances 0.000 claims abstract description 4
- 239000002994 raw material Substances 0.000 claims abstract description 4
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims abstract description 3
- 150000001342 alkaline earth metals Chemical class 0.000 claims abstract description 3
- 229910052728 basic metal Inorganic materials 0.000 claims abstract description 3
- 150000003818 basic metals Chemical class 0.000 claims abstract description 3
- 150000003839 salts Chemical class 0.000 claims abstract description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 18
- 238000006243 chemical reaction Methods 0.000 claims description 15
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 12
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 12
- 239000000126 substance Substances 0.000 claims description 9
- 238000001556 precipitation Methods 0.000 claims description 6
- 239000003795 chemical substances by application Substances 0.000 claims description 5
- 238000003756 stirring Methods 0.000 claims description 5
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 4
- 230000018044 dehydration Effects 0.000 claims description 4
- 238000006297 dehydration reaction Methods 0.000 claims description 4
- 238000001914 filtration Methods 0.000 claims description 4
- 238000000926 separation method Methods 0.000 claims description 4
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 3
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 3
- 238000000710 polymer precipitation Methods 0.000 claims description 3
- 239000012965 benzophenone Substances 0.000 claims description 2
- 230000035484 reaction time Effects 0.000 claims description 2
- 239000003054 catalyst Substances 0.000 claims 1
- 239000007810 chemical reaction solvent Substances 0.000 claims 1
- 239000012046 mixed solvent Substances 0.000 claims 1
- 229920005989 resin Polymers 0.000 abstract description 13
- 239000011347 resin Substances 0.000 abstract description 13
- 238000006116 polymerization reaction Methods 0.000 abstract description 8
- 125000001174 sulfone group Chemical group 0.000 abstract description 8
- 229920000090 poly(aryl ether) Polymers 0.000 abstract description 4
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 abstract description 2
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 abstract description 2
- 229910052801 chlorine Inorganic materials 0.000 abstract description 2
- 239000000460 chlorine Substances 0.000 abstract description 2
- 230000009970 fire resistant effect Effects 0.000 abstract description 2
- 229910052731 fluorine Inorganic materials 0.000 abstract description 2
- 239000011737 fluorine Substances 0.000 abstract description 2
- 239000011521 glass Substances 0.000 abstract 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 6
- 239000000463 material Substances 0.000 description 5
- 238000010992 reflux Methods 0.000 description 5
- 230000007704 transition Effects 0.000 description 5
- 239000004721 Polyphenylene oxide Substances 0.000 description 4
- 229920002492 poly(sulfone) Polymers 0.000 description 4
- 229920000570 polyether Polymers 0.000 description 4
- FXHOOIRPVKKKFG-UHFFFAOYSA-N N,N-Dimethylacetamide Chemical compound CN(C)C(C)=O FXHOOIRPVKKKFG-UHFFFAOYSA-N 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 238000001226 reprecipitation Methods 0.000 description 3
- GPAPPPVRLPGFEQ-UHFFFAOYSA-N 4,4'-dichlorodiphenyl sulfone Chemical compound C1=CC(Cl)=CC=C1S(=O)(=O)C1=CC=C(Cl)C=C1 GPAPPPVRLPGFEQ-UHFFFAOYSA-N 0.000 description 2
- YYZIUYKVJGFWIZ-UHFFFAOYSA-N 4-(1-hydroxy-2H-1,8-naphthyridin-4-yl)phenol Chemical compound ON1CC=C(C2=CC=CN=C12)C1=CC=C(C=C1)O YYZIUYKVJGFWIZ-UHFFFAOYSA-N 0.000 description 2
- 238000005266 casting Methods 0.000 description 2
- 150000002576 ketones Chemical class 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 238000010189 synthetic method Methods 0.000 description 2
- 238000001291 vacuum drying Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- PZDAAZQDQJGXSW-UHFFFAOYSA-N 1-fluoro-4-(4-fluorophenyl)benzene Chemical group C1=CC(F)=CC=C1C1=CC=C(F)C=C1 PZDAAZQDQJGXSW-UHFFFAOYSA-N 0.000 description 1
- MNAHQWDCXOHBHK-UHFFFAOYSA-N 1-phenylpropane-1,1-diol Chemical compound CCC(O)(O)C1=CC=CC=C1 MNAHQWDCXOHBHK-UHFFFAOYSA-N 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 229920006026 co-polymeric resin Polymers 0.000 description 1
- 239000007891 compressed tablet Substances 0.000 description 1
- 238000000748 compression moulding Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000007336 electrophilic substitution reaction Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000009775 high-speed stirring Methods 0.000 description 1
- 238000002329 infrared spectrum Methods 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 238000010534 nucleophilic substitution reaction Methods 0.000 description 1
- 229920000620 organic polymer Polymers 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 230000001376 precipitating effect Effects 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 229920005992 thermoplastic resin Polymers 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
Landscapes
- Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
Abstract
Description
Claims (5)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN 93109180 CN1032758C (zh) | 1993-07-26 | 1993-07-26 | 含二氮杂萘结构的聚醚砜及制备法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN 93109180 CN1032758C (zh) | 1993-07-26 | 1993-07-26 | 含二氮杂萘结构的聚醚砜及制备法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1098113A true CN1098113A (zh) | 1995-02-01 |
CN1032758C CN1032758C (zh) | 1996-09-11 |
Family
ID=4987514
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN 93109180 Expired - Lifetime CN1032758C (zh) | 1993-07-26 | 1993-07-26 | 含二氮杂萘结构的聚醚砜及制备法 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN1032758C (zh) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2004096418A1 (fr) * | 2003-05-01 | 2004-11-11 | Tsinghua University | Membrane d'ultrafiltration a fibres creuses a base de poly(phtalazinone ether-fulfone), du poly(phtalazinone-ether-cetone) ou du poly(phtalazinone ether-sulfone-cetone) et preparation de celle-ci |
CN100443543C (zh) * | 2005-09-09 | 2008-12-17 | 大连理工大学 | 连续纤维增强含二氮杂环新型聚芳醚树脂基复合材料的界面改性方法 |
CN102558557A (zh) * | 2010-12-02 | 2012-07-11 | 现代自动车株式会社 | 具有阳离子交换基团的聚(亚芳基醚)共聚物、其制造方法及其用途 |
CN102831964A (zh) * | 2012-07-27 | 2012-12-19 | 河南华泰特种电缆有限公司 | 杂环联苯聚醚砜绝缘特种电缆 |
CN114479062A (zh) * | 2020-10-26 | 2022-05-13 | 中国石油化工股份有限公司 | 一种含萘结构的聚芳醚酮及其制备方法 |
-
1993
- 1993-07-26 CN CN 93109180 patent/CN1032758C/zh not_active Expired - Lifetime
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2004096418A1 (fr) * | 2003-05-01 | 2004-11-11 | Tsinghua University | Membrane d'ultrafiltration a fibres creuses a base de poly(phtalazinone ether-fulfone), du poly(phtalazinone-ether-cetone) ou du poly(phtalazinone ether-sulfone-cetone) et preparation de celle-ci |
CN100443543C (zh) * | 2005-09-09 | 2008-12-17 | 大连理工大学 | 连续纤维增强含二氮杂环新型聚芳醚树脂基复合材料的界面改性方法 |
CN102558557A (zh) * | 2010-12-02 | 2012-07-11 | 现代自动车株式会社 | 具有阳离子交换基团的聚(亚芳基醚)共聚物、其制造方法及其用途 |
CN102558557B (zh) * | 2010-12-02 | 2015-09-09 | 现代自动车株式会社 | 具有阳离子交换基团的聚(亚芳基醚)共聚物、其制造方法及其用途 |
CN102831964A (zh) * | 2012-07-27 | 2012-12-19 | 河南华泰特种电缆有限公司 | 杂环联苯聚醚砜绝缘特种电缆 |
CN114479062A (zh) * | 2020-10-26 | 2022-05-13 | 中国石油化工股份有限公司 | 一种含萘结构的聚芳醚酮及其制备方法 |
Also Published As
Publication number | Publication date |
---|---|
CN1032758C (zh) | 1996-09-11 |
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Effective date of registration: 20090619 Address after: No. 488, Northeast Main Street, Dalian economic and Technological Development Zone, Liaoning Patentee after: Dalian Chemphy Fine Chemical Co., Ltd. Address before: Box 158, box 137, Zhongshan Road, Liaoning, Dalian Patentee before: Dalian Polymer New Material Co., Ltd. |
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Expiration termination date: 20130726 Granted publication date: 19960911 |