CN109745262A - A kind of composition for Whitening, spot face cream - Google Patents
A kind of composition for Whitening, spot face cream Download PDFInfo
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- CN109745262A CN109745262A CN201910216868.8A CN201910216868A CN109745262A CN 109745262 A CN109745262 A CN 109745262A CN 201910216868 A CN201910216868 A CN 201910216868A CN 109745262 A CN109745262 A CN 109745262A
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Abstract
The present invention relates to the technical fields of cosmetics, more particularly it relates to a kind of composition and preparation method thereof for Whitening, spot face cream.The first aspect of the invention provides a kind of composition for Whitening, spot face cream, including A phase, B phase, C phase, D phase component and water；Wherein, A phase component includes thickener, function additive, jojoba seed oil, tocopherol acetate, hard ester alcohol glycyrrhetin acid esters and sodium bacillus subtilis lipopeptide；B phase component includes alcohols material, allantoin, tranexamic acid, niacinamide, ascorbyl palmitate phosphate trisodium and potassium citrate；C phase component includes polyacrylate -13, polyisobutene and polysorbate -20；D phase component includes panthenol and xylitol substances.
Description
Technical field
The present invention relates to the technical field of cosmetics, more particularly it relates to a kind of for Whitening, spot face cream
Composition and preparation method thereof.
Background technique
With the improvement of living standards, the effect of beauty and skin care is increasingly taken seriously, and people are to skin care item and safety
It is required that also higher and higher, the facial colour spot due to caused by heredity, ultraviolet light irradiation or other reasons, coarse also become of face perplex
The problem of each age level crowd.
Skin care item are also deep always therewith to be doted on by numerous women, shows various skin care item types in the market,
Such as facial cleanser (frost/cream), lotion, toner, face cream, face cream, mascara.For product of single type, producer is also developed not
The product of congenerous type, such as whitening, nti-freckle, moisturizing and oil-control.
Facial colour spot is a kind of chromatodermatosis for betiding face, belongs to " chloasma hepaticum ", " dusty complexion " of traditional Chinese medicine
Equal scopes, facial colour spot are more common with chloasma and freckle.Chinese medicine think facial colour spot mostly because of stagnation of QI due to depression of the liver, blood-head stasis,
Or spleen deficiency precise and tiny, the deficiency of qi and blood that is unable to metaplasia, failure of skin and muscle to be nourished and kidney water cannot make fire, contain in abnormal heat, caused by strongly fragrant resistance skin.Doctor trained in Western medicine
Think mainly due to melanin deposition, and tyrosinase is the Major Enzymes to form melanin.Facial colour spot clinical manifestation is Huang
It exhausts color, light exhaust color and crineous spot or diffusivity patch.It is in irregular shape, obscure boundary Chu, be apt to occur in cheek, forehead, nose,
Face or ear front and back, lip, some expands to entire face, or even involves neck.
The various heavy compound such as mercury compound added in skin-lightening cosmetic in the prior art is complexed due to being formed
Object is very competent, and the formation of epidermis enzyme can be destroyed from mechanism, to inhibit the formation of melanin, plays the role of whitening,
Such product, long-time service are easy carcinogenic；Part lead-containing compounds play vision whitening function by covering；Portioned product is also
Skin surface is bleached using strong oxidizer, the modes such as excessive exfoliating carry out whitening, be chronic to skin if things go on like this
It disfeatures, so a safely and effectively Whitening, spot product of research and development, is one of the emphasis of cosmetics research and development.Therefore a kind of choosing is prepared
It is highly important for selecting safe and efficient multi-functional Whitening, spot face cream.
Summary of the invention
To solve the above problems, the first aspect of the invention provides a kind of composition for Whitening, spot face cream,
Including A phase, B phase, C phase, D phase component and water；Wherein, A phase component includes thickener, function additive, jojoba seed oil, fertility
Phenol acetic acid esters, hard ester alcohol glycyrrhetin acid esters and sodium bacillus subtilis lipopeptide；B phase component include alcohols material, allantoin, tranexamic acid,
Niacinamide, ascorbyl palmitate phosphate trisodium and potassium citrate；C phase component includes polyacrylate -13, poly- isobutyl
Alkene and polysorbate -20；D phase component includes panthenol and xylitol substances.
As a preferred technical solution of the present invention, wherein weight in percentage terms, including 0.13~40%A phase group
Point, 0.8~43%B phase component, 0.1-7.0%C phase component, 0.1~8.0%D phase component and excess water.
As a preferred technical solution of the present invention, wherein thickener includes the first component, the second component, third group
Point and the 4th component；Wherein, the first component includes arachidic alcohol, docosyl alcohol and arachidic alcohol glucoside, and the second component includes that oil is hard
Lipidol, docosyl alcohol, palmitinic acid, stearic acid, lecithin, laruyl alcohol, cardanol and cetanol, third component include the hard ester of glycerol
Acid esters and PEG-100 stearate, the 4th component includes the hard ester alcohol of spermaceti and cetanol ethylhexoate.
As a preferred technical solution of the present invention, wherein the first component, the second component, third component and the 4th
The weight ratio of component is (0.5~3.0): (0.2~5.0): (0.1~3.0): (0.2~17.0).
As a preferred technical solution of the present invention, wherein xylitol substances include Xylitol-based glucoside, dehydration
Xylitol and xylitol.
As a preferred technical solution of the present invention, wherein function additive includes pepper seed extract, para hydroxybenzene second
Ketone, Parleam and 12 carbonic acyl radical phenylalanines.
As a preferred technical solution of the present invention, wherein thickener, function additive, Jojoba seed in A phase component
Oil, tocopherol acetate, hard ester alcohol glycyrrhetin acid esters and sodium bacillus subtilis lipopeptide weight ratio be (1.0~28): (0.2~
13): (0.1~6.0): (0.01~1.0): (0.01~0.6): (0.01~1.0).
As a preferred technical solution of the present invention, wherein alcohols material, allantoin, tranexamic acid in B phase component,
The weight ratio of niacinamide, ascorbyl palmitate phosphate trisodium and potassium citrate is (0.3~30): (0.1~1.0):
(0.1~4.0): (0.1~10): (0.1~6.0): (0.1~7.0).
The second aspect of the invention provides the preparation method of the composition of the Whitening, spot face cream, including walks as follows
It is rapid:
(1) substance in component A is added in oily phase pot, and stirred evenly；
(2) substance in B component is added in water phase pot, and stirred evenly；
(3) uniformly mixed A phase component is poured into the B phase component in step 2, is uniformly mixed；
(4) cool down, C phase component is added, stirs evenly；
(5) cool down, D phase component is added, stirs evenly to get face cream composition.
The third aspect of the invention provides a kind of Whitening, spot face cream, the combination containing the Whitening, spot face cream
Object.
Beneficial effects of the present invention: Whitening, spot provided by the invention can effectively improve the whitening effect of skin, eliminate
The light spot of face, additionally it is possible to promote wound healing, treatment inflammation；In addition, preferable appearance is presented in the composition, have suitable viscous
Degree, is easily sprawled, and exquisiteness is good, and the lotion state of flowing will not be presented, and is tended to smear out and the absorption of skin of face, and will not be led
Phenomena such as causing allergy, expands the use scope of product；On the other hand, composition provided by the invention has good stability
Can, it is easily stored.
Specific embodiment
In order to solve the above technical problems, first aspect of the present invention provides a kind of combination for Whitening, spot face cream
Object comprising A phase, B phase, C phase, D phase component and water；Wherein, A phase component includes thickener, function additive, Jojoba seed
Oil, tocopherol acetate, hard ester alcohol glycyrrhetin acid esters and sodium bacillus subtilis lipopeptide；B phase component include alcohols material, allantoin,
Tranexamic acid, niacinamide, ascorbyl palmitate phosphate trisodium and potassium citrate；C phase component includes polyacrylate-
13, polyisobutene and polysorbate -20；D phase component includes panthenol and xylitol substances.
In one embodiment, in percentage terms, the composition for Whitening, spot face cream includes 0.13 to weight
~40%A phase component, 0.8~43%B phase component, 0.1-7.0%C phase component, 0.1~8.0%D phase component and excess water；
Preferably, the composition for Whitening, spot face cream includes 15~35%A phase component, 20~40%B phase component, 2.0-
5.0%C phase component, 2.0~6.0%D phase component and excess water；It is highly preferred that the combination for Whitening, spot face cream
Object includes 30%A phase component, 35%B phase component, 3.5%C phase component, 4.5%D phase component and excess water.
In one embodiment, thickener includes the first component, the second component, third component and the 4th component；Its
In, the first component includes arachidic alcohol, docosyl alcohol and arachidic alcohol glucoside, and the second component includes oleostearin alcohol, docosyl alcohol, palm
Acid, stearic acid, lecithin, laruyl alcohol, cardanol and cetanol, third component include glycerol stearic acid ester and PEG-100 hard
Resin acid ester, the 4th component include the hard ester alcohol of spermaceti and cetanol ethylhexoate.
In one embodiment, the weight ratio of the first component, the second component, third component and the 4th component is (0.5
~3.0): (0.2~5.0): (0.1~3.0): (0.2~17.0)；Preferably, the first component, the second component, third component with
And the 4th component weight ratio be (1.0~2.0): (1.0~4.0): (1.0~2.5): (5~10)；It is highly preferred that first group
Point, the weight ratio of the second component, third component and the 4th component be 1.5:2.5:2.0:13.
In one embodiment, the weight ratio of the arachidic alcohol in the first component, docosyl alcohol and arachidic alcohol glucoside is 1:
(0.5~3): (1~3)；Preferably, the weight ratio of the arachidic alcohol, docosyl alcohol and arachidic alcohol glucoside is 1:2.2:1.8.
In one embodiment, the oleostearin alcohol in the second component, docosyl alcohol, palmitinic acid, stearic acid, lecithin, the moon
The weight ratio of cinnamic alcohol, cardanol and cetanol is 1:(0.5~2): (0.5~2): (0.5~2): (1~3): (1~3): (1
~3): (0.8~2.5)；Preferably, the oleostearin alcohol, docosyl alcohol, palmitinic acid, stearic acid, lecithin, laruyl alcohol, cardanol
And the weight ratio of cetanol is 1:1.3:1.5:1.5:2.0:2.0:2.1:1.6.
In one embodiment, the glycerol stearic acid ester in third component and the weight ratio of PEG-100 stearate are
1:(0.8~2.5)；Preferably, the weight ratio of the glycerol stearic acid ester and PEG-100 stearate is 1:1.25.
In one embodiment, the hard ester alcohol of spermaceti in the 4th component and the weight ratio of cetanol ethylhexoate are
(0.1-7.0): (0.1-10.0)；Preferably, the hard ester alcohol of the spermaceti and the weight ratio of cetanol ethylhexoate are 1:5.
Ascorbyl palmitate phosphate trisodium:
Ascorbyl palmitate phosphate trisodium can promote the synthesis of skin epineural amide, increase skin emolliency degree,
Moisten degree；Meanwhile ascorbyl palmitate phosphate trisodium is a kind of water-soluble vitamin c derivative, can penetrate skin simultaneously
By the role transformation of enzyme in skin at free vitamin C, it is also beneficial to promote collage synthesis, inhibits decomposition of collagen, improve
Skin ageing phenomenon.
Miglyol 812N:
Miglyol 812N is the high-purity grease as made of caprylic/capric and glycerine esterification.It is a kind of outstanding
Moist grease, make skin have smooth but not greasy feeling, be easy to be absorbed by the skin；The uniform and smooth of cosmetics is played very well
Effect, keep skin lubrication glossy；Caprylic/capric triglyceride can be used as the base-material of moisturizing factor, the stabilizer of cosmetics,
Antifreezing agent, homogeneous agent.
Caprylic/capric triglyceride clearly to faint yellow, be it is high clearly spend tasteless grease, belong to palm oil or coconut oil
Derivative；It is extracted using hot fractional method；Since it and human skin have compatible feature, so being also suitble to Oily
It uses, and pore will not be blocked；It has non-greasy texture, its extensibility can be improved by being added in creams or lotion, there is lubrication
With make the effect of skin softness, and had the function of filtering ultraviolet.
Caprylic/capric triglyceride keeping quality be it is stable, can be stored 6 months or more behind Kaifeng, also need to depend on certainly
Whether there is a condition of storage appropriate, such as low-temperature storage and avoids direct contact with sunlight etc..
Jojoba seed oil:
Jojoba seed oil is a kind of ingredient common in skin care item, is a kind of object by drawing after cold pressing oil expression processing
Matter is easy to be absorbed by the body because the sebum of molecule and human body that it is included is very close, skin can be helped to solve dry
Dry water shortage, the coarse skin flaw problem such as obscure.
In one embodiment, function additive include pepper seed extract, parahydroxyacet-ophenone, Parleam with
And 12 carbonic acyl radical phenylalanine；Preferably, the pepper seed extract, parahydroxyacet-ophenone, Parleam and ten
The weight ratio of two carbonic acyl radical phenylalanines is (0.01-0.5): (0.1-0.8): (0.1-10.0): (0.01-1.0)；More preferably
Ground, the pepper seed extract, parahydroxyacet-ophenone, Parleam and 12 carbonic acyl radical phenylalanines weight ratio be
0.25:0.45:5.5:0.45.
Parahydroxyacet-ophenone:
Parahydroxyacet-ophenone (English name p-Hydroxyacetophenone) also known as 4-hydroxyacetophenone (4-
Hydroxyacetophenone), 4- acetyl phenol (4-Acetylphenol), to acetyl phenol (p-
Acetylphenol), 4- hydroxyphenylmethyl ketone (4-hydroxyphenyl methyl ketone), is commonly called as piceol
It (piceol), is white, needle-shaped crystals under room temperature, it is flammable, it is soluble in hot water, methanol, ethyl alcohol, ether, acetone, benzene are insoluble in stone
Oily ether.It is naturally present in stem, the leaf of compositae plant artemisia scoparia, in the roots of plants such as Artemisia capillaris, Asclepiadaceae plant kerr tylophora root, this
Product are for manufacturing cholagogic and the raw material of other organic syntheses；Animal experiments show that this product can increase the secretion of rat bile, together
When also can increase the discharge rate of solids in bile, cholic acid, bilirubin, also have same work to hepatic injury caused by carbon tetrachloride
With；This product is clinically used for treatment hepatitis, has certain curative effect to removing jaundice, therefore this product nocuousness of eating, and contacts to eyes, respiratory system
With the irritating effect of skin.
Tocopherol acetate:
Tocopherol acetate is a kind of chemical substance, is soluble in chloroform, ether, acetone and vegetable oil, is dissolved in alcohol, does not dissolve in
Water.Heat resistance is preferable, and meeting light can be oxidized, and color deepens.
In one embodiment, the thickener in A phase component, function additive, jojoba seed oil, tocopherol acetate,
The weight ratio of hard ester alcohol glycyrrhetin acid esters and sodium bacillus subtilis lipopeptide is (1.0~28): (0.2~13): (0.1~6.0):
(0.01~1.0): (0.01~0.6): (0.01~1.0)；Preferably, the thickener in A phase component, function additive, Jojoba
Seed oil, tocopherol acetate, hard ester alcohol glycyrrhetin acid esters and sodium bacillus subtilis lipopeptide weight ratio be (5~20): (3~10):
(2.0~4.0): (0.1~0.8): (0.2~0.4): (0.1~0.8)；It is highly preferred that the thickener, function in A phase component help
Agent, jojoba seed oil, tocopherol acetate, hard ester alcohol glycyrrhetin acid esters and sodium bacillus subtilis lipopeptide weight ratio be 12.5:
6.5:3.0:0.3:3.0:0.45.
In one embodiment, A phase component further includes dimethicone and caprylic/capric triglyceride.
In one embodiment, the weight ratio of dimethicone, caprylic/capric triglyceride and jojoba seed oil is
(0.1~5.0): (0.1~8.0): (0.1~6.0)；Preferably, the dimethicone, caprylic/capric triglyceride with suddenly
The weight ratio of bar seed oil is (1.0~4.0): (1.0~6.0): (1.0~5.0) suddenly；It is highly preferred that the dimethicone, pungent
The weight ratio of acid/Triglyceride DDD and jojoba seed oil is 2.5:3.5:3.0.
The thickener of above-mentioned specific components is added in face cream composition of the invention, can promote to be formed in face paste
Frost, while being conducive to improve the sprawling of face cream, moisturizing, light spot, anti-acne, the performance of whitening may be due to according to above-mentioned grouping
The addition thickener of situation, the compatibility between each component is maximum, and the reduction surface tension of maximum possible will not generate microfacies
Layering, coagulation phenomenon, and promotion oil that macroscopically can be optimal mutually dissolves each other with water phase, makes to reach balance between it, will not
Viscosity is not easy greatly very much to sprawl, and also avoids being in flowable state, not easy to apply and skin of face absorption, and stable under various circumstances
Property is preferable.
In one embodiment, the alcohols material in B phase component, allantoin, tranexamic acid, niacinamide, ascorbic acid palm fibre
Glycerin monostearate phosphate trisodium and the weight ratio of potassium citrate are (0.3~30): (0.1~1.0): (0.1~4.0): (0.1~
10): (0.1~6.0): (0.1~7.0)；Preferably, the alcohols material, allantoin, tranexamic acid, niacinamide, ascorbic acid palm fibre
Glycerin monostearate phosphate trisodium and the weight ratio of potassium citrate are (5~20): (0.3~0.8): (1.0~3.0): (2~8):
(1.0~5.0): (1.0~6.0)；It is highly preferred that the alcohols material, allantoin, tranexamic acid, niacinamide, ascorbic acid palm
Acid esters phosphate trisodium and the weight ratio of potassium citrate are 12.5:0.5:2.0:5.0:3.0:3.5.
In one embodiment, the alcohols material in B phase component includes glycerol, 1,3-BDO and 1,2- oneself two
Alcohol；Preferably, the weight ratio of the glycerol, 1,3-BDO and 1,2- hexylene glycol is (0.1~10): (0.1~8.0):
(0.1~10)；It is highly preferred that the glycerol, 1,3-BDO and 1, the weight ratio of 2- hexylene glycol is 5.5:3.5:5.0.
Niacinamide:
Niacinamide most important effect in terms of skin anti-aging is to mitigate and prevent skin to produce in early stage aging course
The raw colour of skin is dull, turns to be yellow, famished look.Certainly, niacinamide can also repair impaired cutin to the contribution this and more of skin
Layer lipid barrier, improves skin resistance.There are also some the effect of may being ignored by people, are exactly the deep layer water lock function of niacinamide
Effect, so, the skin care item containing niacinamide are to having extremely strong water lock, moisture-keeping efficacy；External application niacinamide can be reduced in sebum
The generation of fatty acid and triglycerides, to receive fine, soft fur hole and reduce severity when acne occurs.
But niacinamide under normal circumstances, is crossed in the solution that pH value is 6, optimal stability；In pH value higher or lower than 6
In solution, it can be hydrolyzed, and niacin be formed, so as to cause skin allergy.So the formula general control pH of niacinamide-containing is 5~7
Between, to reduce the formation of niacin.
Panthenol:
Panthenol is also known as general phthalyl alcohol, is the liquid of transparent, slightly red moisture absorption, slightly special odor；It is soluble easily in water, it is imitative to be dissolved in hydrogen
And ether；Panthenol can be transformed into pantothenic acid in skin and hair has moisturizing, anti-inflammatory, stimulation carefully to skin and hair by very little panthenol
The effects of born of the same parents divide.
Allantoin:
Allantoin alias Allantoin, Allantoin, Allantion, Allantoin are a kind of second
Interior ureide derivative；About 50,000 tons of annual production capacity of allantoin in the world at present, market be mainly medicine, cosmetics and
Agriculture three big fields, the content that natural allantoin is extracted from natural animal-plant due to traditional handicraft is very low, complex process, cost
It is too high, it can not use on a large scale.
Allantoin sterling is a kind of nontoxic, tasteless and nonirritant, without hypersensitive white crystal, and crystallization is single rib in water
Cylinder or colorless crystalline powder；Hot water, the pure and mild diluted sodium hydroxide solution of heat can be dissolved in；It is slightly soluble in the water and alcohol of room temperature, indissoluble
In the organic solvents such as ether and chloroform；Its saturated aqueous solution (concentration 0.6%) is in subacidity；PH is 5.5；It is 4-9 in pH value
Aqueous solution in stablize, it is also stable in nonaqueous solvents and dry air；It can under boiling and be exposed to sunlight in strong alkali solution
It decomposes.
In terms of medicine: allantoin, which has, promotes cell growth, accelerates wound healing, the physiology function such as cutin-softening albumen
Can, it is the good consolidant and antiulcer agents of skin trauma；It can be used as alleviating and treating xerodermia, scaling skin disease
Trouble, skin ulcer, digestive tract ulcer and inflammation have good therapeutic effect to osteomyelitis, diabetes, cirrhosis, acne.
In terms of cosmetics: since allantoin is a kind of amphoteric compound, double salt can be formed in conjunction with many kinds of substance, have and keep away
Light, sterilization and anticorrosion, analgesic, antioxidation can make skin keep moisture content, moisten and soft, are the cosmetics such as cosmetology
Additive is widely used in freckle cream, anti-acne toner, shampoo, perfumed soap, toothpaste, shaving lotion, conditioner, astringent, anti-sweat remove
The additive of smelly lotion etc.；The cosmetics of addition allantoin have protective tissue, it is hydrophilic, absorb water and prevent moisture from distributing etc. and make
With；Hair-cream, hair cream, the shampoo for adding allantoin, have protective effect to hair, can make hair not bifurcated, constantly hair；Addition urine
Lipstick, the face cream of Bursin can make skin, lip soft and high resilience, and have beautiful gloss；Allantoin promotes tissue growth,
Cell metabolism, cutin-softening layer albumen.
Agriculturally: allantoin is excellent plant growth regulator, can stimulate plant growth, to wheat, citrus, water
Rice, vegetables, soybean etc. have significant effect of increasing production, and have solid fruit, precocity effect.
It is found through experiments that, when niacinamide being added in composition system, can effectively improve the ageing resistance of face cream, protects
It is moist, reduce the phenomenon that closed pore, bored acne, light spot, but skin is it some times happens that allergic phenomena, this may be since niacinamide exists
Niacin is hydrolyzed to form in vivo, Nicotinic Acid Content is higher, promotes blood vessel dilatation, and the flowing of moisture can generate erythema；And when in composition
Can have when allantoin is added and weaken the phenomenon, the niacin of formation may can be fixed due to allantoin, reduces it in skin
Flowing and effect, while improving the performance of keeping humidity of system, reduce the diffusion of moisture, promote absorption of the skin to ingredient, thus
Reduce the generation of erythema.
Potassium citrate:
Potassium citrate (Potassium citrate) also known as potassium citrate, citric acid tri potassium；Potassium citrate is a kind of lemon
Lemon hydrochlorate, molecular formula C6H5K3O7, molecular weight 306.39500, it is a kind of white, slightly hygroscopic crystalline powder, nothing
It is smelly, there is the taste of physiological saline, it is soluble easily in water, it is slow to be dissolved in glycerol, alcohol is not dissolved in, taste is salty and cool, makees stabilizer and pH buffer
Deng.China's regulation can be used for varieties of food items, need appropriate use by production；Medically, it can be used to control to come from or kidney knot
Stone uric acid or cystine, for preventing and treating hypopotassaemia and alkalized urine.
In one embodiment, the polyacrylate -13 in C phase component, polyisobutene and polysorbate -20
Weight ratio is 1:(0.8~2.0): (0.5~1.5)；Preferably, the polyacrylate -13, polyisobutene and polysorbate
The weight ratio of ester -20 is 1:1.5:1.
In one embodiment, the weight ratio of the panthenol in D phase component and xylitol substances is (0.1~3.0):
(0.01~4.0)；Preferably, the weight ratio of the panthenol and xylitol substances is (1.0~2.0): (1.0~4.0)；More
Preferably, the weight ratio of the panthenol and xylitol substances is 1.5:2.5.
In one embodiment, the xylitol substances in D phase component include Xylitol-based glucoside, anhydro xylitol
And xylitol；Preferably, the weight ratio of the Xylitol-based glucoside, anhydro xylitol and xylitol is 1:(1~3):
(1~3)；It is highly preferred that the weight ratio of the Xylitol-based glucoside, anhydro xylitol and xylitol is 1:2:2.
A certain amount of tranexamic acid, niacinamide, potassium citrate, Vitamin C are added in composition system firstly, having been surprisingly found that
Sour palmitate phosphate trisodium can effectively improve the ageing resistance and whitening of face cream system, may be due to maintaining
While system pH stability, niacinamide is it is possible to prevente effectively from ascorbyl palmitate phosphate trisodium hydrolyzes to form Vitamin C
Problem of oxidation after acid extends action time and the functioning efficiency of face cream；Also avoiding niacinamide hydrolyzes to form hydrochloric acid simultaneously,
The problem of causing skin allergy；
The pH of the adjustable system of potassium citrate, and the pH of maintenance system is 7.5~7.8, the alkalescent system of formation,
Surface-active is strong, and good penetrability, dissolving power is strong, so being easy to participate in a series of biochemical activities of cell, alkalescent water can be
The acid product for having neutralized cell metabolism to a certain extent improves the whitening effect of face cream；But it is also easy to keep skin dry, can make
It has dry skin tight, or even itches；But applicant has been surprisingly found that, composition system provided by the invention is not in such asks
Topic, may be due to forming fine and close network in skin surface under above-mentioned substance thickener, C phase, the synergistic effect of D phase component
Structure has good moisture retention, while also forming hydrophobic layer in skin surface, reduces the expanding of moisture.
The second aspect of the invention provides the preparation method of the composition of the Whitening, spot face cream, including walks as follows
It is rapid:
(1) substance in component A is added in oily phase pot, and stirred evenly；
(2) substance in B component is added in water phase pot, and stirred evenly；
(3) uniformly mixed A phase component is poured into the B phase component in step 2, is uniformly mixed；
(4) cool down, C phase component is added, stirs evenly；
(5) cool down, D phase component is added, stirs evenly to get face cream composition.
Preferably, the preparation method of the composition of the Whitening, spot face cream, includes the following steps:
(1) substance in component A is added 80~85 DEG C, in the oily phase pot of -0.5~1MPa, stirred evenly；
(2) substance in B component is added 80~85 DEG C, in the water phase pot of -0.5~1MPa, stirred evenly；
(3) uniformly mixed A phase component is poured into the B phase component in step 2 at 80~85 DEG C, the item of -0.5~1MPa
Under part, it is uniformly mixed；
(4) 70~75 DEG C are cooled to, C phase component is added, is stirred evenly under conditions of -0.5~1MPa；
(5) 40~45 DEG C are cooled to, D phase component is added, is stirred evenly under conditions of -0.5~1MPa to get face cream combination
Object.
It is highly preferred that the preparation method of the composition of the Whitening, spot face cream, includes the following steps:
(1) substance in component A is added 80~85 DEG C, in the oily phase pot of -0.65MPa, stirred evenly；
(2) substance in B component is added 80~85 DEG C, in the water phase pot of -0.65MPa, stirred evenly；
(3) uniformly mixed A phase component is poured into the B phase component in step 2 at 80~85 DEG C, the condition of -0.65MPa
Under, it is uniformly mixed；
(4) 70~75 DEG C are cooled to, C phase component is added, is stirred evenly under conditions of -0.65MPa；
(5) 40~45 DEG C are cooled to, D phase component is added, is stirred evenly under conditions of -0.65MPa to get face cream combination
Object.
The third aspect of the invention provides a kind of Whitening, spot face cream, the combination containing the Whitening, spot face cream
Object.
Embodiment 1
The embodiment of the present invention 1 provides a kind of composition of Whitening, spot face cream, weight in percentage terms, the combination
Object includes 30%A phase component, 35%B phase component, 3.5%C phase component, 4.5%D phase component and excess water；
A phase component include thickener, function additive, jojoba seed oil, tocopherol acetate, hard ester alcohol glycyrrhetin acid esters,
Sodium bacillus subtilis lipopeptide, dimethicone and caprylic/capric triglyceride；
Thickener, function additive, jojoba seed oil, tocopherol acetate, hard ester alcohol glycyrrhetin acid esters in A phase component with
And the weight ratio of sodium bacillus subtilis lipopeptide is 12.5:6.5:3.0:0.3:3.0:0.45；Dimethicone, caprylic/capric glycerol three
The weight ratio of ester and jojoba seed oil is 2.5:3.5:3.0；
Thickener includes the first component, the second component, third component and the 4th component；Wherein, the first component includes flower
Raw alcohol, docosyl alcohol and arachidic alcohol glucoside, the second component include oleostearin alcohol, docosyl alcohol, palmitinic acid, stearic acid, lecithin, the moon
Cinnamic alcohol, cardanol and cetanol, third component include glycerol stearic acid ester and PEG-100 stearate, and the 4th component includes
The hard ester alcohol of spermaceti and cetanol ethylhexoate；
First component, the second component, the weight ratio of third component and the 4th component are 1.5:2.5:2.0:13；
The weight ratio of arachidic alcohol, docosyl alcohol and arachidic alcohol glucoside in first component is 1:2.2:1.8；
Oleostearin alcohol, docosyl alcohol, palmitinic acid, stearic acid, lecithin, laruyl alcohol, cardanol and whale in second component
The weight ratio of ceryl alcohol is 1:1.3:1.5:1.5:2.0:2.0:2.1:1.6；
The weight ratio of glycerol stearic acid ester and PEG-100 stearate in third component is 1:1.25；
The weight ratio of the hard ester alcohol of spermaceti and cetanol ethylhexoate in 4th component is 1:5；
Function additive includes pepper seed extract, parahydroxyacet-ophenone, Parleam and 12 carbonic acyl radical phenylpropyl alcohols
Propylhomoserin, the weight ratio of the pepper seed extract, parahydroxyacet-ophenone, Parleam and 12 carbonic acyl radical phenylalanines
For 0.25:0.45:5.5:0.45；
B phase component include alcohols material, allantoin, tranexamic acid, niacinamide, ascorbyl palmitate phosphate trisodium with
And potassium citrate, the alcohols material, allantoin, tranexamic acid, niacinamide, ascorbyl palmitate phosphate trisodium and lemon
The weight ratio of lemon acid potassium is 12.5:0.5:2.0:5.0:3.0:3.5；
Alcohols material in B phase component includes glycerol, 1,3-BDO and 1,2- hexylene glycol, the glycerol, 1,3- fourth
The weight ratio of glycol and 1,2- hexylene glycol is 5.5:3.5:5.0；
C phase component includes polyacrylate -13, polyisobutene and polysorbate -20, the polyacrylate -13,
The weight ratio of polyisobutene and polysorbate -20 is 1:1.5:1；
D phase component includes panthenol and xylitol substances, and the weight ratio of the panthenol and xylitol substances is
1.5:2.5；
Xylitol substances in D phase component include Xylitol-based glucoside, anhydro xylitol and xylitol, the wood
The weight ratio of sugar alcohol base glucoside, anhydro xylitol and xylitol is 1:2:2；
The preparation method of the composition of the Whitening, spot face cream, includes the following steps:
(1) substance in component A is added 80~85 DEG C, in the oily phase pot of -0.65MPa, stirred evenly；
(2) substance in B component is added 80~85 DEG C, in the water phase pot of -0.65MPa, stirred evenly；
(3) uniformly mixed A phase component is poured into the B phase component in step 2 at 80~85 DEG C, the condition of -0.65MPa
Under, it is uniformly mixed；
(4) 70~75 DEG C are cooled to, C phase component is added, is stirred evenly under conditions of -0.65MPa；
(5) 40~45 DEG C are cooled to, D phase component is added, is stirred evenly under conditions of -0.65MPa to get face cream combination
Object.
Embodiment 2
The embodiment of the present invention 2 provides a kind of composition of Whitening, spot face cream, weight in percentage terms, the combination
Object includes 15%A phase component, 20%B phase component, 2.0%C phase component, 2.0%D phase component and excess water；
A phase component include thickener, function additive, jojoba seed oil, tocopherol acetate, hard ester alcohol glycyrrhetin acid esters,
Sodium bacillus subtilis lipopeptide, dimethicone and caprylic/capric triglyceride；
Thickener, function additive, jojoba seed oil, tocopherol acetate, hard ester alcohol glycyrrhetin acid esters in A phase component with
And the weight ratio of sodium bacillus subtilis lipopeptide is 1.0:0.2:0.1:0.01:0.01:0.01；Dimethicone, caprylic/capric glycerol three
The weight ratio of ester and jojoba seed oil is 1:1:1；
Thickener includes the first component, the second component, third component and the 4th component；Wherein, the first component includes flower
Raw alcohol, docosyl alcohol and arachidic alcohol glucoside, the second component include oleostearin alcohol, docosyl alcohol, palmitinic acid, stearic acid, lecithin, the moon
Cinnamic alcohol, cardanol and cetanol, third component include glycerol stearic acid ester and PEG-100 stearate, and the 4th component includes
The hard ester alcohol of spermaceti and cetanol ethylhexoate；
First component, the second component, the weight ratio of third component and the 4th component are 0.5:0.2:0.1:0.2；
The weight ratio of arachidic alcohol, docosyl alcohol and arachidic alcohol glucoside in first component is 1:0.5:1；
Oleostearin alcohol, docosyl alcohol, palmitinic acid, stearic acid, lecithin, laruyl alcohol, cardanol and whale in second component
The weight ratio of ceryl alcohol is 1:0.5:0.5:0.5:1:1:1:0.8；
The weight ratio of glycerol stearic acid ester and PEG-100 stearate in third component is 1:0.8；
The weight ratio of the hard ester alcohol of spermaceti and cetanol ethylhexoate in 4th component is 1:1；
Function additive includes pepper seed extract, parahydroxyacet-ophenone, Parleam and 12 carbonic acyl radical phenylpropyl alcohols
Propylhomoserin, the weight ratio of the pepper seed extract, parahydroxyacet-ophenone, Parleam and 12 carbonic acyl radical phenylalanines
For 0.25:0.45:5.5:0.45；
B phase component include alcohols material, allantoin, tranexamic acid, niacinamide, ascorbyl palmitate phosphate trisodium with
And potassium citrate, the alcohols material, allantoin, tranexamic acid, niacinamide, ascorbyl palmitate phosphate trisodium and lemon
The weight ratio of lemon acid potassium is 0.3:0.1:0.1:0.1:0.1:0.1；
Alcohols material in B phase component includes glycerol, 1,3-BDO and 1,2- hexylene glycol, the glycerol, 1,3- fourth
The weight ratio of glycol and 1,2- hexylene glycol is 1:1:1；
C phase component includes polyacrylate -13, polyisobutene and polysorbate -20, the polyacrylate -13,
The weight ratio of polyisobutene and polysorbate -20 is 1:0.8:0.5；
D phase component includes panthenol and xylitol substances, and the weight ratio of the panthenol and xylitol substances is
0.1:0.01；
Xylitol substances in D phase component include Xylitol-based glucoside, anhydro xylitol and xylitol, the wood
The weight ratio of sugar alcohol base glucoside, anhydro xylitol and xylitol is 1:1:1；
The preparation method of the composition of the Whitening, spot face cream, includes the following steps:
(1) substance in component A is added 80~85 DEG C, in the oily phase pot of -0.65MPa, stirred evenly；
(2) substance in B component is added 80~85 DEG C, in the water phase pot of -0.65MPa, stirred evenly；
(3) uniformly mixed A phase component is poured into the B phase component in step 2 at 80~85 DEG C, the condition of -0.65MPa
Under, it is uniformly mixed；
(4) 70~75 DEG C are cooled to, C phase component is added, is stirred evenly under conditions of -0.65MPa；
(5) 40~45 DEG C are cooled to, D phase component is added, is stirred evenly under conditions of -0.65MPa to get face cream combination
Object.
Embodiment 3
The embodiment of the present invention 3 provides a kind of composition of Whitening, spot face cream, weight in percentage terms, the combination
Object includes 40%A phase component, 43%B phase component, 7.0%C phase component, 8.0%D phase component and excess water；
A phase component include thickener, function additive, jojoba seed oil, tocopherol acetate, hard ester alcohol glycyrrhetin acid esters,
Sodium bacillus subtilis lipopeptide, dimethicone and caprylic/capric triglyceride；
Thickener, function additive, jojoba seed oil, tocopherol acetate, hard ester alcohol glycyrrhetin acid esters in A phase component with
And the weight ratio of sodium bacillus subtilis lipopeptide is 28:13:6.0:1.0:0.6:1.0；Dimethicone, caprylic/capric triglyceride with
The weight ratio of jojoba seed oil is 5.0:8.0:6.0；
Thickener includes the first component, the second component, third component and the 4th component；Wherein, the first component includes flower
Raw alcohol, docosyl alcohol and arachidic alcohol glucoside, the second component include oleostearin alcohol, docosyl alcohol, palmitinic acid, stearic acid, lecithin, the moon
Cinnamic alcohol, cardanol and cetanol, third component include glycerol stearic acid ester and PEG-100 stearate, and the 4th component includes
The hard ester alcohol of spermaceti and cetanol ethylhexoate；
First component, the second component, the weight ratio of third component and the 4th component are 3.0:5.0:3.0:17；
The weight ratio of arachidic alcohol, docosyl alcohol and arachidic alcohol glucoside in first component is 1:3:3；
Oleostearin alcohol, docosyl alcohol, palmitinic acid, stearic acid, lecithin, laruyl alcohol, cardanol and whale in second component
The weight ratio of ceryl alcohol is 1:2:2:2:3:3:3:2.5；
The weight ratio of glycerol stearic acid ester and PEG-100 stearate in third component is 1:2.5；
The weight ratio of the hard ester alcohol of spermaceti and cetanol ethylhexoate in 4th component is 1:10；
Function additive includes pepper seed extract, parahydroxyacet-ophenone, Parleam and 12 carbonic acyl radical phenylpropyl alcohols
Propylhomoserin, the weight ratio of the pepper seed extract, parahydroxyacet-ophenone, Parleam and 12 carbonic acyl radical phenylalanines
For 0.25:0.45:5.5:0.45；
B phase component include alcohols material, allantoin, tranexamic acid, niacinamide, ascorbyl palmitate phosphate trisodium with
And potassium citrate, the alcohols material, allantoin, tranexamic acid, niacinamide, ascorbyl palmitate phosphate trisodium and lemon
The weight ratio of lemon acid potassium is 30:1.0:4.0:10:6.0:7.0；
Alcohols material in B phase component includes glycerol, 1,3-BDO and 1,2- hexylene glycol, the glycerol, 1,3- fourth
The weight ratio of glycol and 1,2- hexylene glycol is 10:8:10；
C phase component includes polyacrylate -13, polyisobutene and polysorbate -20, the polyacrylate -13,
The weight ratio of polyisobutene and polysorbate -20 is 1:2.0:1.5；
D phase component includes panthenol and xylitol substances, and the weight ratio of the panthenol and xylitol substances is
3.0:4.0；
Xylitol substances in D phase component include Xylitol-based glucoside, anhydro xylitol and xylitol, the wood
The weight ratio of sugar alcohol base glucoside, anhydro xylitol and xylitol is 1:3:3；
The preparation method of the composition of the Whitening, spot face cream, includes the following steps:
(1) substance in component A is added 80~85 DEG C, in the oily phase pot of -0.65MPa, stirred evenly；
(2) substance in B component is added 80~85 DEG C, in the water phase pot of -0.65MPa, stirred evenly；
(3) uniformly mixed A phase component is poured into the B phase component in step 2 at 80~85 DEG C, the condition of -0.65MPa
Under, it is uniformly mixed；
(4) 70~75 DEG C are cooled to, C phase component is added, is stirred evenly under conditions of -0.65MPa；
(5) 40~45 DEG C are cooled to, D phase component is added, is stirred evenly under conditions of -0.65MPa to get face cream combination
Object.
Embodiment 4
The embodiment of the present invention 4 provides a kind of composition of Whitening, spot face cream, the same embodiment of specific embodiment
1, the difference is that, the content of dimethicone and caprylic/capric triglyceride in A phase component is 0.
Embodiment 5
The embodiment of the present invention 5 provides a kind of composition of Whitening, spot face cream, the same embodiment of specific embodiment
1, the difference is that, the content of niacinamide is 0 in B phase component.
Embodiment 6
The embodiment of the present invention 6 provides a kind of composition of Whitening, spot face cream, the same embodiment of specific embodiment
1, the difference is that, the content of allantoin is 0 in B phase component.
Embodiment 7
The embodiment of the present invention 7 provides a kind of composition of Whitening, spot face cream, the same embodiment of specific embodiment
1, the difference is that, the content of allantoin and niacinamide is 0 in B phase component.
Embodiment 8
The embodiment of the present invention 8 provides a kind of composition of Whitening, spot face cream, the same embodiment of specific embodiment
1, the difference is that, the content of tranexamic acid is 0 in B phase component.
Embodiment 9
The embodiment of the present invention 9 provides a kind of composition of Whitening, spot face cream, the same embodiment of specific embodiment
1, the difference is that, the content of potassium citrate is 0 in B phase component.
Embodiment 10
The embodiment of the present invention 10 provides a kind of composition of Whitening, spot face cream, the same embodiment of specific embodiment
1, the difference is that, the content of the first component of the thickener in A phase component is 0.
Embodiment 11
The embodiment of the present invention 11 provides a kind of composition of Whitening, spot face cream, the same embodiment of specific embodiment
1, the difference is that, the content of the second component of the thickener in A phase component is 0.
Embodiment 12
The embodiment of the present invention 12 provides a kind of composition of Whitening, spot face cream, the same embodiment of specific embodiment
1, the difference is that, the content of the third component of the thickener in A phase component is 0.
Embodiment 13
The embodiment of the present invention 13 provides a kind of composition of Whitening, spot face cream, the same embodiment of specific embodiment
1, the difference is that, the content of the 4th component of the thickener in A phase component is 0.
Embodiment 14
The embodiment of the present invention 14 provides a kind of composition of Whitening, spot face cream, the same embodiment of specific embodiment
1, the difference is that, the first component of the thickener in A phase component and the content of the second component are 0.
Embodiment 15
The embodiment of the present invention 15 provides a kind of composition of Whitening, spot face cream, the same embodiment of specific embodiment
1, the difference is that, the content of the first component of the thickener in A phase component, the second component and third component is 0.
Embodiment 16
The embodiment of the present invention 16 provides a kind of composition of Whitening, spot face cream, the same embodiment of specific embodiment
1, the difference is that, the content of the second component of the thickener in A phase component, third component and the 4th component is 0.
Embodiment 17
The embodiment of the present invention 17 provides a kind of composition of Whitening, spot face cream, the same embodiment of specific embodiment
1, the difference is that, the thickener in A phase component includes the first component, the second component, third component and the 4th component；
First component includes arachidic alcohol, docosyl alcohol and laruyl alcohol, the second component include oleostearin alcohol, docosyl alcohol, stearic acid,
Cetanol ethylhexoate, arachidic alcohol glucoside, cardanol and cetanol, third component include glycerol stearic acid ester and PEG-
100 stearates, the 4th component include the hard ester alcohol of spermaceti, palmitinic acid and lecithin.
Embodiment 18
The embodiment of the present invention 18 provides a kind of composition of Whitening, spot face cream, the same embodiment of specific embodiment
1, the difference is that, the weight of the first component of the thickener in A phase component, the second component, third component and the 4th component
Amount is than being 5:5:3:19.
Embodiment 19
The embodiment of the present invention 19 provides a kind of composition of Whitening, spot face cream, the same embodiment of specific embodiment
1, the difference is that, C phase component content is 0.
Embodiment 20
The embodiment of the present invention 20 provides a kind of composition of Whitening, spot face cream, the same embodiment of specific embodiment
1, the difference is that, D phase component content is 0.
Performance Evaluation:
1. the appearance character of face cream composition: face cream composition prepared by Examples 1 to 20 being placed at room temperature, is then seen
Its appearance character is examined, reference standard part table 1, experimental result is shown in Table 2；
2. heat resistance: being carried out referring to People's Republic of China's light industry standard cream kind cosmetics quality examination criteria resistance to
Hot, cold-resistant detection test, detection method is respectively that heat resistant test is that face cream composition prepared by Examples 1 to 20 is placed on 45
DEG C insulating box in keep for 24 hours, observing its appearance character and water-oil separating phenomenon, reference standard is shown in Table 1, and experimental result is shown in Table 2；
3. skin effects are tested: in order to relatively accurately react its using effect, this test invites 20 groups, and every group 50 are not
Same age bracket (20,30,40,50 and 60 years old each 10) face has the professional testing crew of light spot to carry out sense organ overall characteristic to it
It is evaluated, including spreadability, exquisiteness and whitening effect, taking its average value is last each item rating；Specific scoring mark
Quasi- such as table 1；In addition, also having seen whether erythema appearance, the accounting for erythema occur is calculated, experimental result is shown in Table 2.
1 Performance evaluation criterion of table
2 the performance test results of table
Whitening, spot provided by the invention can effectively improve the whitening effect of skin it can be seen from experimental result, disappear
Except the light spot of face；In addition, preferable appearance is presented in the composition, there is suitable viscosity, easily sprawl, exquisiteness is good, will not
The lotion state that flowing is presented, tends to smear out and the absorption of skin of face, and phenomena such as not will lead to allergy, expands making for product
Use range；On the other hand, composition provided by the invention has good stability, easily stored.
It may be noted that the foregoing is merely the preferable specific embodiments of the present invention, but protection scope of the present invention is not
Be confined to this, anyone skilled in the art in the technical scope disclosed by the present invention, the variation that can readily occur in or
Replacement, should be covered by the protection scope of the present invention.
Claims (10)
1. a kind of composition for Whitening, spot face cream, which is characterized in that including A phase, B phase, C phase, D phase component and water；
Wherein, A phase component include thickener, function additive, jojoba seed oil, tocopherol acetate, hard ester alcohol glycyrrhetin acid esters and
Sodium bacillus subtilis lipopeptide；B phase component includes alcohols material, allantoin, tranexamic acid, niacinamide, ascorbyl palmitate phosphate
Trisodium and potassium citrate；C phase component includes polyacrylate -13, polyisobutene and polysorbate -20；D phase component packet
Include panthenol and xylitol substances.
2. the composition of Whitening, spot face cream according to claim 1, which is characterized in that weight in percentage terms, including
0.13~40%A phase component, 0.8~43%B phase component, 0.1-7.0%C phase component, 0.1~8.0%D phase component and surplus
Water.
3. the composition of Whitening, spot face cream according to claim 1, which is characterized in that thickener includes the first component, the
Two components, third component and the 4th component；Wherein, the first component includes arachidic alcohol, docosyl alcohol and arachidic alcohol glucoside, and
Two components include oleostearin alcohol, docosyl alcohol, palmitinic acid, stearic acid, lecithin, laruyl alcohol, cardanol and cetanol, third group
Dividing includes glycerol stearic acid ester and PEG-100 stearate, and the 4th component includes the hard ester alcohol of spermaceti and cetanol thylhexoic acid
Ester.
4. the composition of Whitening, spot face cream according to claim 3, which is characterized in that the first component, the second component, third
The weight ratio of component and the 4th component is (0.5~3.0): (0.2~5.0): (0.1~3.0): (0.2~17.0).
5. the composition of Whitening, spot face cream according to claim 1, which is characterized in that xylitol substances include xylitol
Base glucoside, anhydro xylitol and xylitol.
6. the composition of Whitening, spot face cream according to claim 1, which is characterized in that function additive includes that pepper seed extracts
Object, parahydroxyacet-ophenone, Parleam and 12 carbonic acyl radical phenylalanines.
7. the composition of Whitening, spot face cream according to claim 1, which is characterized in that thickener, function in A phase component
Auxiliary agent, jojoba seed oil, tocopherol acetate, hard ester alcohol glycyrrhetin acid esters and sodium bacillus subtilis lipopeptide weight ratio be (1.0~
28): (0.2~13): (0.1~6.0): (0.01~1.0): (0.01~0.6): (0.01~1.0).
8. the composition of Whitening, spot face cream according to claim 1, which is characterized in that alcohols material, urine in B phase component
Bursin, tranexamic acid, niacinamide, ascorbyl palmitate phosphate trisodium and potassium citrate weight ratio be (0.3~30):
(0.1~1.0): (0.1~4.0): (0.1~10): (0.1~6.0): (0.1~7.0).
9. a kind of preparation method of the composition of any one of claim 1~8 Whitening, spot face cream, which is characterized in that packet
Include following steps:
(1) substance in component A is added in oily phase pot, and stirred evenly；
(2) substance in B component is added in water phase pot, and stirred evenly；
(3) uniformly mixed A phase component is poured into the B phase component in step 2, is uniformly mixed；
(4) cool down, C phase component is added, stirs evenly；
(5) cool down, D phase component is added, stirs evenly to get face cream composition.
10. a kind of Whitening, spot face cream, which is characterized in that containing the Whitening, spot face cream as described in any one of claim 1~8
Composition.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112386517A (en) * | 2019-08-19 | 2021-02-23 | 广东伊涵坊生物科技有限公司 | Whitening and spot-fading face cream |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101590003A (en) * | 2009-06-23 | 2009-12-02 | 广州保税区雅兰国际化妆品有限公司 | A kind of whitening spot-relieving cream cosmetic and preparation method thereof |
| CN105616312A (en) * | 2014-10-31 | 2016-06-01 | 沈阳市坤美惜美容用品有限公司 | Spot-removal cosmetic and preparation method thereof |
| KR20170009107A (en) * | 2015-07-15 | 2017-01-25 | 미 정 박 | cosmetic method of manufacture method |
| JP2017101018A (en) * | 2015-11-06 | 2017-06-08 | ジョンソン・アンド・ジョンソン・コンシューマー・インコーポレイテッド | Topical gel cream composition |
-
2019
- 2019-03-20 CN CN201910216868.8A patent/CN109745262B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101590003A (en) * | 2009-06-23 | 2009-12-02 | 广州保税区雅兰国际化妆品有限公司 | A kind of whitening spot-relieving cream cosmetic and preparation method thereof |
| CN105616312A (en) * | 2014-10-31 | 2016-06-01 | 沈阳市坤美惜美容用品有限公司 | Spot-removal cosmetic and preparation method thereof |
| KR20170009107A (en) * | 2015-07-15 | 2017-01-25 | 미 정 박 | cosmetic method of manufacture method |
| JP2017101018A (en) * | 2015-11-06 | 2017-06-08 | ジョンソン・アンド・ジョンソン・コンシューマー・インコーポレイテッド | Topical gel cream composition |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112386517A (en) * | 2019-08-19 | 2021-02-23 | 广东伊涵坊生物科技有限公司 | Whitening and spot-fading face cream |
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