CN109651535A - 烃的聚合 - Google Patents
烃的聚合 Download PDFInfo
- Publication number
- CN109651535A CN109651535A CN201811130106.8A CN201811130106A CN109651535A CN 109651535 A CN109651535 A CN 109651535A CN 201811130106 A CN201811130106 A CN 201811130106A CN 109651535 A CN109651535 A CN 109651535A
- Authority
- CN
- China
- Prior art keywords
- reaction vessel
- hydrocarbon
- light
- photoinitiator
- passed
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000004215 Carbon black (E152) Substances 0.000 title claims abstract description 50
- 229930195733 hydrocarbon Natural products 0.000 title claims abstract description 50
- 150000002430 hydrocarbons Chemical class 0.000 title claims abstract description 50
- 238000006116 polymerization reaction Methods 0.000 title claims abstract description 33
- 238000006243 chemical reaction Methods 0.000 claims abstract description 72
- 238000000034 method Methods 0.000 claims abstract description 23
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000001301 oxygen Substances 0.000 claims abstract description 13
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 13
- 238000003756 stirring Methods 0.000 claims abstract description 10
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 8
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 claims description 8
- 239000000463 material Substances 0.000 claims description 6
- 239000000178 monomer Substances 0.000 claims description 5
- KFSLWBXXFJQRDL-UHFFFAOYSA-N Peracetic acid Chemical compound CC(=O)OO KFSLWBXXFJQRDL-UHFFFAOYSA-N 0.000 claims description 4
- 239000007787 solid Substances 0.000 claims description 4
- 238000005401 electroluminescence Methods 0.000 claims description 3
- 239000002002 slurry Substances 0.000 claims description 3
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 2
- 239000004342 Benzoyl peroxide Substances 0.000 claims description 2
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 claims description 2
- 235000019400 benzoyl peroxide Nutrition 0.000 claims description 2
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims description 2
- 150000002118 epoxides Chemical class 0.000 claims description 2
- 150000002978 peroxides Chemical class 0.000 claims description 2
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims 2
- CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 claims 2
- 239000005711 Benzoic acid Substances 0.000 claims 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims 1
- 239000005977 Ethylene Substances 0.000 claims 1
- 235000010233 benzoic acid Nutrition 0.000 claims 1
- 150000003951 lactams Chemical class 0.000 claims 1
- 230000005855 radiation Effects 0.000 abstract description 3
- 239000000203 mixture Substances 0.000 description 10
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 238000010526 radical polymerization reaction Methods 0.000 description 4
- 230000008901 benefit Effects 0.000 description 3
- 238000010926 purge Methods 0.000 description 3
- 238000005481 NMR spectroscopy Methods 0.000 description 2
- -1 acyl Amine Chemical class 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 238000005227 gel permeation chromatography Methods 0.000 description 2
- 239000011261 inert gas Substances 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 239000011368 organic material Substances 0.000 description 2
- 229920001195 polyisoprene Polymers 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 229930195735 unsaturated hydrocarbon Natural products 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 230000003466 anti-cipated effect Effects 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- CHIHQLCVLOXUJW-UHFFFAOYSA-N benzoic anhydride Chemical compound C=1C=CC=CC=1C(=O)OC(=O)C1=CC=CC=C1 CHIHQLCVLOXUJW-UHFFFAOYSA-N 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 238000010538 cationic polymerization reaction Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 238000004134 energy conservation Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 231100000206 health hazard Toxicity 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- YVJRCWCFDJYONJ-UHFFFAOYSA-N hydroperoxymethylbenzene Chemical compound OOCC1=CC=CC=C1 YVJRCWCFDJYONJ-UHFFFAOYSA-N 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 238000003780 insertion Methods 0.000 description 1
- 230000037431 insertion Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 230000002285 radioactive effect Effects 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F136/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F136/02—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F136/04—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
- C08F136/08—Isoprene
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
- B01J19/12—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electromagnetic waves
- B01J19/122—Incoherent waves
- B01J19/127—Sunlight; Visible light
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F120/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
- C08F120/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F120/04—Acids; Metal salts or ammonium salts thereof
- C08F120/06—Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/46—Polymerisation initiated by wave energy or particle radiation
- C08F2/48—Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
- B01J2219/0869—Feeding or evacuating the reactor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
- B01J2219/12—Processes employing electromagnetic waves
- B01J2219/1203—Incoherent waves
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Physics & Mathematics (AREA)
- Electromagnetism (AREA)
- General Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Polymerisation Methods In General (AREA)
- Polymerization Catalysts (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IN3272/MUM/2013 | 2013-10-18 | ||
| IN3272MU2013 IN2013MU03272A (enExample) | 2013-10-18 | 2014-10-16 | |
| CN201480057162.7A CN105658680A (zh) | 2013-10-18 | 2014-10-16 | 烃的聚合 |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201480057162.7A Division CN105658680A (zh) | 2013-10-18 | 2014-10-16 | 烃的聚合 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109651535A true CN109651535A (zh) | 2019-04-19 |
Family
ID=53180343
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811130106.8A Pending CN109651535A (zh) | 2013-10-18 | 2014-10-16 | 烃的聚合 |
| CN201480057162.7A Pending CN105658680A (zh) | 2013-10-18 | 2014-10-16 | 烃的聚合 |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201480057162.7A Pending CN105658680A (zh) | 2013-10-18 | 2014-10-16 | 烃的聚合 |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US9969825B2 (enExample) |
| EP (1) | EP3058000A4 (enExample) |
| JP (1) | JP6598770B2 (enExample) |
| CN (2) | CN109651535A (enExample) |
| IN (1) | IN2013MU03272A (enExample) |
| WO (1) | WO2015075733A2 (enExample) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TW201528379A (zh) * | 2013-12-20 | 2015-07-16 | Applied Materials Inc | 雙波長退火方法與設備 |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4517063A (en) * | 1984-02-13 | 1985-05-14 | The Standard Oil Company | Photochemical reactor and method for carrying out photochemical reactions therein |
| CN1729108A (zh) * | 2002-12-20 | 2006-02-01 | 塞里考尔有限公司 | 固化 |
| CN101605525A (zh) * | 2006-07-06 | 2009-12-16 | 百齿可股份有限公司 | 发黄程度减轻的发光二极管可固化丙烯酸酯 |
| CN102181001A (zh) * | 2011-03-11 | 2011-09-14 | 北京化工大学 | 一种可控/活性自由基聚合方法 |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2857322A (en) * | 1954-04-28 | 1958-10-21 | Chemstrand Corp | Photopolymerization of acrylonitrile |
| US3859189A (en) * | 1968-01-14 | 1975-01-07 | Central De Chimie Fizica | Polymerization of acrylonitrile using radiation in the presence of dimethylsulphoxide and a protein |
| NL162087C (nl) * | 1970-04-21 | 1980-04-15 | Ceskoslovenska Akademie Ved | Werkwijze voor het polymeriseren van monoalkenische monomeren op zichzelf of voor het copolymeriseren met andere onverzadigde verbindingen. |
| FR2200283B1 (enExample) * | 1972-09-22 | 1979-01-26 | Toyo Soda Mfg Co Ltd | |
| US4325794A (en) * | 1980-06-02 | 1982-04-20 | Calgon Corporation | Combined visible light and thermally activated continuous polymerization process |
| JP2692194B2 (ja) * | 1988-11-14 | 1997-12-17 | 日本合成ゴム株式会社 | 水素化ブロック共重合体及びその組成物 |
| US5187236A (en) * | 1990-01-16 | 1993-02-16 | Mobil Oil Corporation | Solid block and random elastomeric copolymers |
| US5149895A (en) | 1990-01-16 | 1992-09-22 | Mobil Oil Corporation | Vulcanizable liquid compositions |
| USH1786H (en) * | 1993-07-12 | 1999-02-02 | Shell Oil Company | Process for radiation cured conjugated diene-vinyl aromatic hydrocarbon block copolymers |
| DE19736471A1 (de) * | 1997-08-21 | 1999-02-25 | Espe Dental Ag | Lichtinduziert kationisch härtende Zusammensetzungen und deren Verwendung |
| CA2434919A1 (en) * | 2001-01-15 | 2002-07-18 | Kaneka Corporation | Process for preparing chlorinated vinyl chloride resin and apparatus for the same |
| KR20130118291A (ko) * | 2010-06-23 | 2013-10-29 | 나가세케무텍쿠스가부시키가이샤 | 내충격성 폴리아미드 조성물 및 그 제조 방법 |
| AU2012336949B2 (en) * | 2011-11-07 | 2015-01-15 | Kaneka Corporation | Method for producing chlorinated vinyl chloride resin |
-
2014
- 2014-10-16 IN IN3272MU2013 patent/IN2013MU03272A/en unknown
- 2014-10-16 WO PCT/IN2014/000655 patent/WO2015075733A2/en not_active Ceased
- 2014-10-16 CN CN201811130106.8A patent/CN109651535A/zh active Pending
- 2014-10-16 EP EP14863811.7A patent/EP3058000A4/en not_active Withdrawn
- 2014-10-16 US US15/029,957 patent/US9969825B2/en active Active
- 2014-10-16 CN CN201480057162.7A patent/CN105658680A/zh active Pending
- 2014-10-16 JP JP2016524464A patent/JP6598770B2/ja active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4517063A (en) * | 1984-02-13 | 1985-05-14 | The Standard Oil Company | Photochemical reactor and method for carrying out photochemical reactions therein |
| CN1729108A (zh) * | 2002-12-20 | 2006-02-01 | 塞里考尔有限公司 | 固化 |
| CN101605525A (zh) * | 2006-07-06 | 2009-12-16 | 百齿可股份有限公司 | 发黄程度减轻的发光二极管可固化丙烯酸酯 |
| CN102181001A (zh) * | 2011-03-11 | 2011-09-14 | 北京化工大学 | 一种可控/活性自由基聚合方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| EP3058000A4 (en) | 2017-04-05 |
| WO2015075733A3 (en) | 2015-12-17 |
| EP3058000A2 (en) | 2016-08-24 |
| WO2015075733A2 (en) | 2015-05-28 |
| CN105658680A (zh) | 2016-06-08 |
| JP6598770B2 (ja) | 2019-10-30 |
| IN2013MU03272A (enExample) | 2015-07-17 |
| US20160244541A1 (en) | 2016-08-25 |
| JP2016533419A (ja) | 2016-10-27 |
| US9969825B2 (en) | 2018-05-15 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20190419 |
|
| RJ01 | Rejection of invention patent application after publication |