ES2181206T3 - Polimerizacion catalizada por acido mejorada. - Google Patents
Polimerizacion catalizada por acido mejorada.Info
- Publication number
- ES2181206T3 ES2181206T3 ES98918759T ES98918759T ES2181206T3 ES 2181206 T3 ES2181206 T3 ES 2181206T3 ES 98918759 T ES98918759 T ES 98918759T ES 98918759 T ES98918759 T ES 98918759T ES 2181206 T3 ES2181206 T3 ES 2181206T3
- Authority
- ES
- Spain
- Prior art keywords
- acid catalyst
- polymerization
- acid
- acrylic
- salts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F12/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
- C08F12/02—Monomers containing only one unsaturated aliphatic radical
- C08F12/04—Monomers containing only one unsaturated aliphatic radical containing one ring
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polymerisation Methods In General (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
La presente invención se refiere a un perfeccionamiento del procedimiento de polimerización en masa de radicales libres para la preparación de un polímero de masa molecular elevada a partir de un monómero aromático del vinilo. Este procedimiento se caracteriza porque la polimerización se efectúa en presencia de un catalizador ácido que presenta a 25ºC un pKa inferior a 2 o en presencia de una de sus sales. El perfeccionamiento consiste en dispersar el catalizador ácido o sus sales, en un ácido acrílico o metacrílico, o en uno de sus ésteres, antes del contacto con el monómero acromático de vinilo. Este ácido acrílico o metacrílico o los ésteres correspondientes permiten la dispersión del catalizador ácido en el interior del monómero ácido de vinilo sin provocar la polimerización catiónica. El catalizador ácido o la sal correspondiente cataliza la reacción de polimerización de los radicales libres para producir en plazos de reacción razonables polímeros de masa molecular elevada.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US5082997P | 1997-06-26 | 1997-06-26 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2181206T3 true ES2181206T3 (es) | 2003-02-16 |
Family
ID=21967705
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES98918759T Expired - Lifetime ES2181206T3 (es) | 1997-06-26 | 1998-04-24 | Polimerizacion catalizada por acido mejorada. |
Country Status (14)
| Country | Link |
|---|---|
| US (1) | US5948874A (es) |
| EP (1) | EP0990004B1 (es) |
| JP (1) | JP2002506478A (es) |
| CN (1) | CN1261378A (es) |
| AU (1) | AU730639B2 (es) |
| BR (1) | BR9810454A (es) |
| CA (1) | CA2288857A1 (es) |
| CO (1) | CO5040129A1 (es) |
| DE (1) | DE69807079T2 (es) |
| ES (1) | ES2181206T3 (es) |
| HU (1) | HUP0004087A3 (es) |
| ID (1) | ID22688A (es) |
| PL (1) | PL337689A1 (es) |
| WO (1) | WO1999000432A1 (es) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6084044A (en) * | 1994-12-14 | 2000-07-04 | The Dow Chemical Company | Catalyzed process for producing high molecular weight monovinylidene aromatic polymers |
| US6214945B1 (en) * | 1999-05-07 | 2001-04-10 | The Dow Chemical Company | Process for producing high molecular weight monovinylidene aromatic polymers and polymodal compositions |
| EP1226019B1 (en) * | 1999-11-05 | 2004-03-03 | Z Corporation | Methods of three-dimensional printing |
| JP4032033B2 (ja) * | 2003-06-30 | 2008-01-16 | ローム アンド ハース カンパニー | 高純度メタクリル酸の製造法 |
| EP2089215B1 (en) | 2006-12-08 | 2015-02-18 | 3D Systems Incorporated | Three dimensional printing material system |
| JP5129267B2 (ja) | 2007-01-10 | 2013-01-30 | スリーディー システムズ インコーポレーテッド | 改良された色、物品性能及び使用の容易さ、を持つ３次元印刷材料システム |
| US7968626B2 (en) | 2007-02-22 | 2011-06-28 | Z Corporation | Three dimensional printing material system and method using plasticizer-assisted sintering |
| WO2014111292A1 (en) | 2013-01-18 | 2014-07-24 | Basf Se | Acrylic dispersion-based coating compositions |
| CN104017124A (zh) * | 2014-03-13 | 2014-09-03 | 南京工业大学 | 一种含有2-丙烯酰胺-2-甲基丙磺酸(amps)的高分子皂洗剂的制备 |
| TWI664199B (zh) * | 2014-12-26 | 2019-07-01 | 日商日鐵化學材料股份有限公司 | 末端改質可溶性多官能乙烯基芳香族共聚合物、其製造方法、硬化性組成物、硬化物、膜、硬化性複合材料、積層體、帶有樹脂的金屬箔、電路基板材料用清漆、硬化性樹脂組成物、光導波管形成用樹脂膜及光導波管 |
| CN110257041B (zh) * | 2019-06-26 | 2021-05-14 | 滨州学院 | 压裂液用瓜尔胶-纳米纤维素纤维交联增稠剂及制备方法 |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5254650A (en) * | 1988-07-22 | 1993-10-19 | Kayaku Akzo Corporation | Process for the preparation of styrene or styrene derivative-containing copolymers |
| US5115055A (en) * | 1991-05-23 | 1992-05-19 | The Dow Chemical Company | Hydroperoxide catalyzed free radical polymerization of vinyl aromatic monomers |
| US5145924A (en) * | 1991-02-06 | 1992-09-08 | The Dow Chemical Company | Free radical polymerization of styrene monomer |
| WO1992013904A1 (en) * | 1991-02-06 | 1992-08-20 | The Dow Chemical Company | Free radical polymerization of vinyl aromatic monomers |
| JPH10510858A (ja) * | 1994-12-14 | 1998-10-20 | ザ ダウ ケミカル カンパニー | ビニル酸触媒のフリーラジカル重合による高分子量ポリスチレンの製造 |
| US5608023A (en) * | 1995-03-30 | 1997-03-04 | Xerox Corporation | Rate enhanced polymerization processes |
-
1998
- 1998-04-24 ID IDW991343A patent/ID22688A/id unknown
- 1998-04-24 BR BR9810454-3A patent/BR9810454A/pt not_active Application Discontinuation
- 1998-04-24 PL PL98337689A patent/PL337689A1/xx unknown
- 1998-04-24 AU AU71623/98A patent/AU730639B2/en not_active Ceased
- 1998-04-24 HU HU0004087A patent/HUP0004087A3/hu unknown
- 1998-04-24 JP JP50552099A patent/JP2002506478A/ja active Pending
- 1998-04-24 CA CA002288857A patent/CA2288857A1/en not_active Abandoned
- 1998-04-24 ES ES98918759T patent/ES2181206T3/es not_active Expired - Lifetime
- 1998-04-24 US US09/065,974 patent/US5948874A/en not_active Expired - Fee Related
- 1998-04-24 EP EP98918759A patent/EP0990004B1/en not_active Expired - Lifetime
- 1998-04-24 WO PCT/US1998/008392 patent/WO1999000432A1/en active IP Right Grant
- 1998-04-24 CN CN98806460A patent/CN1261378A/zh active Pending
- 1998-04-24 DE DE69807079T patent/DE69807079T2/de not_active Expired - Fee Related
- 1998-06-25 CO CO98036383A patent/CO5040129A1/es unknown
Also Published As
| Publication number | Publication date |
|---|---|
| CN1261378A (zh) | 2000-07-26 |
| EP0990004B1 (en) | 2002-08-07 |
| PL337689A1 (en) | 2000-08-28 |
| HUP0004087A3 (en) | 2001-04-28 |
| CA2288857A1 (en) | 1999-01-07 |
| DE69807079T2 (de) | 2002-12-05 |
| EP0990004A1 (en) | 2000-04-05 |
| JP2002506478A (ja) | 2002-02-26 |
| BR9810454A (pt) | 2000-09-05 |
| ID22688A (id) | 1999-12-09 |
| AU730639B2 (en) | 2001-03-08 |
| US5948874A (en) | 1999-09-07 |
| AU7162398A (en) | 1999-01-19 |
| CO5040129A1 (es) | 2001-05-29 |
| HUP0004087A2 (en) | 2001-03-28 |
| DE69807079D1 (de) | 2002-09-12 |
| WO1999000432A1 (en) | 1999-01-07 |
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