MX168234B - Acidos policarboxilicos con pequeña cantidad de monomero residual - Google Patents
Acidos policarboxilicos con pequeña cantidad de monomero residualInfo
- Publication number
- MX168234B MX168234B MX007015A MX701587A MX168234B MX 168234 B MX168234 B MX 168234B MX 007015 A MX007015 A MX 007015A MX 701587 A MX701587 A MX 701587A MX 168234 B MX168234 B MX 168234B
- Authority
- MX
- Mexico
- Prior art keywords
- small amount
- polycarboxylic acids
- residual monomer
- acid monomer
- percent
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
- C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
- C08F20/04—Acids, Metal salts or ammonium salts thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/04—Acids; Metal salts or ammonium salts thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
La presente invencón se refiere a procedimiento para preparar pólimeros apartir de mónomeros carboxílicos que contienen menos de 0.2 por ciento de mónomero sin reaccionar y que tienen mas de 1 por ciento de grupos carboxílicos en el monómero de ácido neutralizado, que comprende polimerizar una carga monómerica que contiene cuando menos una cantidad preponderante de un monómero de ácido carboxílico olefínicamente insaturado y su sal, que contiene de 3 a 5 átomos de carbono a tmperatura de 40 a 80 grados centigrados en la presencia de un solvente, un indicador de radicales libres y un entrelazador.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US07/017,966 US4758641A (en) | 1987-02-24 | 1987-02-24 | Polycarboxylic acids with small amount of residual monomer |
Publications (1)
Publication Number | Publication Date |
---|---|
MX168234B true MX168234B (es) | 1993-05-13 |
Family
ID=21785532
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MX007015A MX168234B (es) | 1987-02-24 | 1987-06-19 | Acidos policarboxilicos con pequeña cantidad de monomero residual |
Country Status (13)
Country | Link |
---|---|
US (1) | US4758641A (es) |
EP (1) | EP0279892B1 (es) |
JP (1) | JP2690308B2 (es) |
KR (1) | KR940010338B1 (es) |
AU (1) | AU7424887A (es) |
BR (1) | BR8703136A (es) |
CA (1) | CA1283246C (es) |
DE (1) | DE3750220T2 (es) |
ES (1) | ES2059325T3 (es) |
IN (1) | IN170759B (es) |
MX (1) | MX168234B (es) |
PT (1) | PT85207B (es) |
ZA (1) | ZA874436B (es) |
Families Citing this family (52)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6330505A (ja) * | 1986-07-24 | 1988-02-09 | Mitsubishi Petrochem Co Ltd | 吸水性複合材料の製造法 |
US4923940A (en) * | 1988-02-19 | 1990-05-08 | The B.F. Goodrich Company | Polycarboxylic acids with higher thickening capacity and better clarity |
CA2003808C (en) * | 1988-11-28 | 1999-11-09 | Eugene Joseph Sehm | Crosslinked polyacrylic acid |
US5221722A (en) * | 1988-11-28 | 1993-06-22 | The B. F. Goodrich Company | Crosslinked polyacrylic acid |
EP0448717B1 (en) * | 1989-07-25 | 1995-11-29 | Nippon Shokubai Co., Ltd. | Cement admixture, production thereof, and cement composition |
EP0529910B1 (en) * | 1991-08-23 | 1996-03-13 | Nippon Shokubai Co., Ltd. | Biodegradable hydrophilic crosslinked polymer, process for producing it, and uses thereof |
US5849838A (en) * | 1992-10-28 | 1998-12-15 | S. C. Johnson & Son, Inc. | Aqueous scratch cover compositions for finished wooden articles |
US5393608A (en) * | 1993-05-25 | 1995-02-28 | Moore Business Forms | Non-silicone release polymer |
US5942484A (en) * | 1995-03-30 | 1999-08-24 | The Procter & Gamble Company | Phase-stable liquid fabric refreshment composition |
US5547476A (en) * | 1995-03-30 | 1996-08-20 | The Procter & Gamble Company | Dry cleaning process |
US5591236A (en) * | 1995-03-30 | 1997-01-07 | The Procter & Gamble Company | Polyacrylate emulsified water/solvent fabric cleaning compositions and methods of using same |
EP0817877A1 (en) * | 1995-03-30 | 1998-01-14 | The Procter & Gamble Company | Dry cleaning article |
US5630847A (en) * | 1995-03-30 | 1997-05-20 | The Procter & Gamble Company | Perfumable dry cleaning and spot removal process |
US5632780A (en) * | 1995-03-30 | 1997-05-27 | The Procter & Gamble Company | Dry cleaning and spot removal proces |
WO1996030416A1 (fr) * | 1995-03-31 | 1996-10-03 | Sekisui Kagaku Kogyo Kabushiki Kaisha | Procede de preparation d'adhesifs acryliques du genre solvant, sensibles a la pression, et adhesif medical sensible a la pression |
US5585104A (en) * | 1995-04-12 | 1996-12-17 | The Procter & Gamble Company | Cleansing emulsions |
US5630848A (en) * | 1995-05-25 | 1997-05-20 | The Procter & Gamble Company | Dry cleaning process with hydroentangled carrier substrate |
AU5859796A (en) * | 1995-05-26 | 1996-12-11 | Igen, Inc. | Molecularly imprinted beaded polymers and stabilized suspens ion polymerization of the same in perfluorocarbon liquids |
US5687591A (en) * | 1995-06-20 | 1997-11-18 | The Procter & Gamble Company | Spherical or polyhedral dry cleaning articles |
US5912408A (en) * | 1995-06-20 | 1999-06-15 | The Procter & Gamble Company | Dry cleaning with enzymes |
US5681355A (en) * | 1995-08-11 | 1997-10-28 | The Procter & Gamble Company | Heat resistant dry cleaning bag |
US5789368A (en) * | 1996-01-26 | 1998-08-04 | The Procter & Gamble Company | Fabric care bag |
US6233771B1 (en) | 1996-01-26 | 2001-05-22 | The Procter & Gamble Company | Stain removal device |
US5840675A (en) * | 1996-02-28 | 1998-11-24 | The Procter And Gamble Company | Controlled released fabric care article |
US5663253A (en) * | 1996-06-20 | 1997-09-02 | 3V Inc. | Policarboxylic acids |
US5891197A (en) * | 1996-08-02 | 1999-04-06 | The Proctor & Gamble Company | Stain receiver for dry cleaning process |
US5872090A (en) * | 1996-10-25 | 1999-02-16 | The Procter & Gamble Company | Stain removal with bleach |
US5849039A (en) * | 1997-01-17 | 1998-12-15 | The Procter & Gamble Company | Spot removal process |
US5762648A (en) * | 1997-01-17 | 1998-06-09 | The Procter & Gamble Company | Fabric treatment in venting bag |
US6538088B1 (en) * | 1997-02-04 | 2003-03-25 | National Starch And Chemical Investment Holding Corporation | Methods for making polymers from N-vinyl acetamide monomer |
DE19741184A1 (de) | 1997-09-18 | 1999-03-25 | Basf Ag | Verfahren zur Verminderung von Restmonomeren in Flüssigsystemen unter Zugabe eines Redoxinitiatorsystems |
US6326344B1 (en) * | 2000-01-27 | 2001-12-04 | Ecolab Inc. | Carpet spot removal composition |
US6803041B2 (en) * | 2001-03-20 | 2004-10-12 | Boehringer Ingelheim Vetmedica, Inc. | Equine herpesvirus vaccine |
DE102004041127A1 (de) * | 2004-08-24 | 2006-03-02 | Basf Ag | Verfahren zur Herstellung von carboxylatreichen Copolymeren aus monoethylenisch ungesättigten Mono- und Dicarbonsäuren sowie carboxylatreiche Copolymere mit niedrigem Neutralisationsgrad |
EP2027162A1 (de) * | 2006-01-23 | 2009-02-25 | Basf Se | Verfahren zur herstellung von polymeren in wässrigen lösungsmitteln |
KR20090005347A (ko) * | 2006-03-31 | 2009-01-13 | 바스프 에스이 | 아크릴레이트 공중합체의 제조 방법 |
KR20090014188A (ko) * | 2006-05-04 | 2009-02-06 | 바스프 에스이 | 중화된 산기-함유 중합체 및 그의 용도 |
KR20110073492A (ko) * | 2008-09-04 | 2011-06-29 | 바스프 에스이 | 글리세린 모노스테아레이트의 존재 하의 침전 중합 |
US8673275B2 (en) | 2010-03-02 | 2014-03-18 | Basf Se | Block copolymers and their use |
JP2013521363A (ja) | 2010-03-02 | 2013-06-10 | ビーエイエスエフ・ソシエタス・エウロパエア | ブロックコポリマーおよびその使用 |
US20110218295A1 (en) * | 2010-03-02 | 2011-09-08 | Basf Se | Anionic associative rheology modifiers |
ES2554952T3 (es) | 2011-09-13 | 2015-12-28 | Lubrizol Advanced Materials, Inc. | Microgeles sensibles a tensioactivos |
US10265263B2 (en) | 2011-09-13 | 2019-04-23 | Lubrizol Advanced Materials, Inc. | Surfactant responsive emulsion polymerized micro-gels |
JP6165735B2 (ja) | 2011-09-13 | 2017-07-19 | ルブリゾル アドバンスド マテリアルズ, インコーポレイテッド | 界面活性剤応答性分散重合ミクロゲル |
WO2015059084A1 (de) | 2013-10-21 | 2015-04-30 | Basf Se | Fällungspolymerisation in gegenwart eines tertiären amins und eines anhydrids |
US20160304646A1 (en) | 2013-12-17 | 2016-10-20 | Lubrizol Advanced Materials, Inc. | Surfactant Responsive Emulsion Polymerization Micro-Gels |
EP2907828A1 (de) | 2014-02-14 | 2015-08-19 | Basf Se | Verfahren zur Herstellung von kationogen-ampholytischen VP/VI-Copolymeren |
EP2942063A1 (en) | 2014-05-06 | 2015-11-11 | S.I.I.T. S.r.L. - Unipersonale | Composition for fluidizing mucus comprising chitosan and copolymers |
US20170369614A1 (en) | 2014-12-17 | 2017-12-28 | Lubrizol Advanced Materials, Inc. | Surfactant responsive emulsion polymerized micro-gels |
WO2018118679A1 (en) | 2016-12-19 | 2018-06-28 | Lubrizol Advanced Materials, Inc. | Surfactant responsive emulsion polymerized micro-gels |
EP3635017B1 (en) | 2017-05-04 | 2021-07-07 | Lubrizol Advanced Materials, Inc. | Dual activated microgel |
WO2023074720A1 (ja) * | 2021-10-27 | 2023-05-04 | 住友精化株式会社 | α,β-不飽和カルボン酸化合物の架橋重合体及びその用途 |
Family Cites Families (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2798053A (en) * | 1952-09-03 | 1957-07-02 | Goodrich Co B F | Carboxylic polymers |
US4027082A (en) * | 1972-06-26 | 1977-05-31 | Ceskoslovenska Akademie Ved | Powdery hydrophilic fillers |
SU474540A1 (ru) * | 1972-07-21 | 1979-01-30 | Филиал Института Химической Физики Ан Ссср | Способ получени сополимеров ацетона |
AU7930075A (en) * | 1974-04-03 | 1976-09-23 | Ici Australia Limited, And Commonwealth Scientific And Industrial Research Organization | Process |
US3943103A (en) * | 1974-04-09 | 1976-03-09 | Union Carbide Corporation | Radiation curable compositions of vinyl acetate polymers |
US3940351A (en) * | 1974-07-02 | 1976-02-24 | The B. F. Goodrich Company | Polymerization of carboxylic acid monomers and alkyl acrylate esters in chlorofluoroethane |
US3915921A (en) * | 1974-07-02 | 1975-10-28 | Goodrich Co B F | Unsaturated carboxylic acid-long chain alkyl ester copolymers and tri-polymers water thickening agents and emulsifiers |
US4062817A (en) * | 1977-04-04 | 1977-12-13 | The B.F. Goodrich Company | Water absorbent polymers comprising unsaturated carboxylic acid, acrylic ester containing alkyl group 10-30 carbon atoms, and another acrylic ester containing alkyl group 2-8 carbon atoms |
US4066583A (en) * | 1977-05-16 | 1978-01-03 | The B. F. Goodrich Company | Flexible water absorbent polymer compositions comprising (a) unsaturated carboxylic acid, acrylic ester containing alkyl group 10-30 carbon atoms, additional monomer plus (b) aliphatic diol |
US4151143A (en) * | 1977-08-19 | 1979-04-24 | American Cyanamid Company | Surfactant-free polymer emulsion coating composition and method for preparing same |
US4267103A (en) * | 1978-12-07 | 1981-05-12 | The B. F. Goodrich Company | Solvent polymerization of carboxyl containing monomers |
US4375533A (en) * | 1981-07-08 | 1983-03-01 | The Bf Goodrich Company | Polymerization process for carboxyl containing polymers |
US4509949A (en) * | 1983-06-13 | 1985-04-09 | The B. F. Goodrich Company | Water thickening agents consisting of copolymers of crosslinked acrylic acids and esters |
-
1987
- 1987-02-24 US US07/017,966 patent/US4758641A/en not_active Expired - Lifetime
- 1987-06-15 CA CA000539729A patent/CA1283246C/en not_active Expired - Lifetime
- 1987-06-15 AU AU74248/87A patent/AU7424887A/en not_active Abandoned
- 1987-06-17 IN IN518/DEL/87A patent/IN170759B/en unknown
- 1987-06-17 ES ES87108729T patent/ES2059325T3/es not_active Expired - Lifetime
- 1987-06-17 EP EP87108729A patent/EP0279892B1/en not_active Expired - Lifetime
- 1987-06-17 DE DE3750220T patent/DE3750220T2/de not_active Expired - Lifetime
- 1987-06-19 ZA ZA874436A patent/ZA874436B/xx unknown
- 1987-06-19 MX MX007015A patent/MX168234B/es unknown
- 1987-06-22 BR BR8703136A patent/BR8703136A/pt unknown
- 1987-06-29 KR KR1019870006628A patent/KR940010338B1/ko not_active IP Right Cessation
- 1987-06-29 PT PT85207A patent/PT85207B/pt not_active IP Right Cessation
- 1987-08-17 JP JP62203225A patent/JP2690308B2/ja not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
EP0279892B1 (en) | 1994-07-13 |
DE3750220D1 (de) | 1994-08-18 |
KR880010002A (ko) | 1988-10-06 |
DE3750220T2 (de) | 1994-11-17 |
EP0279892A3 (en) | 1989-10-18 |
JP2690308B2 (ja) | 1997-12-10 |
KR940010338B1 (ko) | 1994-10-22 |
CA1283246C (en) | 1991-04-16 |
US4758641A (en) | 1988-07-19 |
ES2059325T3 (es) | 1994-11-16 |
AU7424887A (en) | 1988-08-25 |
PT85207A (en) | 1987-07-01 |
IN170759B (es) | 1992-05-16 |
EP0279892A2 (en) | 1988-08-31 |
JPS63295609A (ja) | 1988-12-02 |
ZA874436B (en) | 1988-04-12 |
BR8703136A (pt) | 1988-08-23 |
PT85207B (pt) | 1990-11-20 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
MX168234B (es) | Acidos policarboxilicos con pequeña cantidad de monomero residual | |
MX171770B (es) | Acidos policarboxilicos con mayor capacidad de espesamiento y mejor claridad | |
GB1550874A (en) | Process for producing fluorinated copolymer having ion-exchange groups | |
MX168679B (es) | Composiciones adhesivas que contiene aditivos de polimero de bajo peso molecular | |
GB1096912A (en) | Synthetic polymers | |
SE8405324D0 (sv) | In-mold coating composition | |
US3647736A (en) | Hydrophilic contact lens material | |
GB1552060A (en) | Process for producing fluorinated copolymer having ion-exchange groups | |
SE8000821L (sv) | Joniska kolvetepolymerer med forbettrad vidheftning till nylon | |
JPS5676408A (en) | Block copolymer | |
GB1102746A (en) | Process for the production of copolymers of vinyl esters and ethylene | |
GB1519355A (en) | Thermoplastic nylon moulding materials of toughness | |
PT71935B (de) | Verfahren zur herstellung von oh-gruppen enthaltenden copotlymerisaten | |
MX170383B (es) | Polimezclas de terpolimeros de estireno anhidrido maleico-metacrilato de metilo, polimeros de acrilonitrilo-butadieno-estireno y policarbonatos | |
MX166251B (es) | Procedimiento para la preparacion de polieterpolioles de oxetano | |
KR900016277A (ko) | 일산화 탄소와 불포화 화합물과의 중합체 제조방법 | |
GR34006B (el) | Υδροφιλα πολυμερη, ειδη και μεθοδοι παρασκευης αυτων. | |
IT1099019B (it) | Procedimento per la preparazione di un copolimero di acrilato di basso peso molecolare,e di una composizione di rivestimento liquida avente un contenuto elevato in prodotti solidi a base del copolimero di acrilato cosi' ottenuto | |
GB1048060A (en) | Addition copolymers and water dilutable salts thereof | |
MX162628A (es) | Mejoras a proceso para preparar una pelicula acrilica | |
EP0018558A3 (de) | Verfahren zur lösungsmittelfreien Herstellung von hydrophilen Füllstoffpulvern | |
FR2037979A5 (en) | Mixtures of polyamides with ethylene copol - ymers have improved flexibility and impact | |
SU935080A1 (ru) | Способ полимеризации флагеллина | |
GB2137637B (en) | Polymers containing anhydride groups | |
ES464456A1 (es) | Mejoras en un procedimiento de preparacion de un polimero deun haluro de vinilo. |