CN109401413A - A kind of moisture-proof anti-crack mastic powder containing Chinese alpine rush component - Google Patents
A kind of moisture-proof anti-crack mastic powder containing Chinese alpine rush component Download PDFInfo
- Publication number
- CN109401413A CN109401413A CN201811364748.4A CN201811364748A CN109401413A CN 109401413 A CN109401413 A CN 109401413A CN 201811364748 A CN201811364748 A CN 201811364748A CN 109401413 A CN109401413 A CN 109401413A
- Authority
- CN
- China
- Prior art keywords
- powder
- weight
- alpine rush
- chinese alpine
- epoxy resin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/34—Filling pastes
Abstract
A kind of moisture-proof anti-crack mastic powder containing Chinese alpine rush component, belong to the field of building materials, by grey calcium, coarse whiting, cement, anti-crack fiber and reinforcing agent is combined to be made, anti-crack fiber is mixed by polystyrene fiber, polypropene staple, lignocellulosic and modified starch.Anti-crack fiber in formula of the invention containing special composition and combine reinforcing agent, to significantly improve the bond strength in powder of lacquer putty for use between each component, the moisture-proof crack resistance of powder of lacquer putty for use on has not only been greatly enhanced, and the water resistance and hardness of powder of lacquer putty for use on can also be improved, the modified starch contained in anti-crack fiber can be more uniform Dispersed precipitate in the surface of polystyrene fiber, polypropene staple, and then in conjunction with lignocellulosic, bond strength and waterproof performance between each component have been greatly enhanced in powder of lacquer putty for use on, to improve cracking resistance and humidity resistance.
Description
Present patent application is the divisional application application No. is 2017102604029, and the applying date of original application is 2017
On April 13, in, application No. is: 2017102604029, a kind of invention and created name are as follows: moisture-proof anti-crack mastic powder.
Technical field
The present invention relates to the powder of lacquer putty for use on used in the field of building materials, specifically a kind of moisture-proof anti-crack mastic powder.
Background technique
Powder of lacquer putty for use on is one kind of building decoration materials, is a kind of substrate levelling for wall-surface patching, to decorate in next step
(brush paint wallpaper) lays a good foundation.Putty is divided into interior wall and two kinds of exterior wall, and exterior wall putty will resist exposing to the weather institute
It is big with colloidality, intensity is high, environmentally friendly index is slightly lower.Inner wall putty composite index is preferable, health environment-friendly, so interior wall not external application, outside
Wall is not interior to be used.Usual putty is gypsum or cement base, and it is secured that such rough surface is easier bonding.But in construction
When still to brush a bed boundary Ji Lai sealing base in base while improve the adhesive force of metope, make putty more preferable
Be bonded on basal plane.Base's crack resistance is a kind of evaluation index of powder of lacquer putty for use on, it is required that material itself has certain elasticity
Or plasticity, when micro-crack occurs for base, flexible type plastic deformation has occurred under external force and occurs surface not for material
Crackle, existing powder of lacquer putty for use on main component coarse whiting (or talcum powder), grey calcium etc., but since it is formulated built-in problem,
Cause its cracking resistance to be not very ideal, in the prior art in order to enhance the crack resistance of powder of lacquer putty for use on, is generally used increasing water
The dosage of the bonding agents such as mud or rubber powder, but the effect is unsatisfactory.
Summary of the invention
The object of the present invention is to provide a kind of moisture-proof anti-crack mastic powders, by anti-crack fiber wherein and combine reinforcing agent,
To significantly improve the bond strength in powder of lacquer putty for use between each component, the moisture-proof crack resistance of powder of lacquer putty for use on has not only been greatly enhanced, and
And the water resistance and hardness of powder of lacquer putty for use on can also be improved；Meanwhile it wherein being played good also without containing volatility Toxics such as formaldehyde
Good environment protecting；And powder of lacquer putty for use on is being constructed to after in wall matrix, fine mineral therein can directly penetrate into basal plane with
A kind of chain type crystallization reaction of molecular level occurs for substrate, and crystallization reaction rear substrate passes through with the Nanoparticle in powder of lacquer putty for use on
Strand becomes a secured and stable entirety, thus formed one layer ventilative, fire prevention, moisture-proof anticorrosive putty layer.
The present invention to realize the above-mentioned technical purpose used by technical solution are as follows: a kind of moisture-proof anti-crack mastic powder, according to weight
Ratio is measured, by 46-50 parts of grey calcium, 28-36 parts of coarse whiting, 12-16 parts of cement, 7-9 parts of anti-crack fiber and 8-12 parts of knot
It closes reinforcing agent to be made, the anti-crack fiber is by polystyrene fiber, polypropene staple, lignocellulosic and modified starch with 3-
The ratio of 5:8-10:3-4:5-7 mixes, and the preparation method of the modified starch is that starch is added to as its weight 3-5
Times water in be uniformly mixed, the tin coupling agent of starch weight 8%-10% is then added thereto and with sulphur acid for adjusting pH value to 4-
5, then the eucommia ulmoides extracts of starch weight 1-3% are added thereto, 60-65 DEG C is adjusted the temperature to after mixing and keeps the temperature 2-3h,
Finally thereto be added starch weight 4-5% stearic acid, drying to constant weight under the conditions of 100-110 DEG C after mixing evenly to get
To modified starch；The eucommia ulmoides extracts are to filter out the resulting filter of solid residue after Eucommia ulmoides Oliv. leaves boil 20-30min in water
Liquid is evaporated the powder finally obtained.
The combination reinforcing agent is by sepiolite cashmere powder, zeolite powder, modified manometer silicon dioxide, polyethylene glycol, composite epoxy
Resin, putty rubber powder and water by 5-6:8-10:5-7:16-18:3-4:8-10:55-60 weight ratio mixing after at 100-120 DEG C
Under the conditions of be evaporated liquid and obtain；Wherein, modified manometer silicon dioxide is the surface of commercially available nano silica and its weight 3-4%
Inorganic agent is mixed to get, which is mixed by benzoic acid, acetone and KH560 according to the ratio of weight ratio 2-3:1-2:35
It forms；The composite epoxy resin is by 4 parts of bisphenol A type epoxy resin, 0.5 part of butylene epoxy resin, 0.5 part of glycerol ring
Oxygen resin, 2 parts of diisocyanate and 2 parts of modified silicasol are made, and modified silicasol is successively added in commercially available silica solution
Enter the KH560 of the silicon powder of silica solution weight 2-3%, the sodium acetate of silica solution weight 0.8-1% and silica solution weight 3-4%, then
The mixture that 1-2h is obtained is stirred under the conditions of 70-80 DEG C.
The sepiolite cashmere powder and zeolite powder are first carrying out modification using preceding so that sepiolite cashmere powder, zeolite powder and
Modified manometer silicon dioxide more preferably combines；It is described processing is modified to sepiolite cashmere powder and zeolite powder to refer to: to take commercially available Hai Pao
Aminanthine powder and zeolite powder and both the methyl methacrylate of total weight 3%, both total weight 5% KH560 after mixing, make
The ultrasonication 2-3min for being 200-240KHz with frequency is obtained.
Wastewaters with modified calcium sulfate whiskers in the combination reinforcing agent also containing sepiolite cashmere powder weight 4-5%, the modified sulfuric acid
Calcium pyroborate is to be mixed to get the surface treating agent of commercially available calcium sulfate crystal whiskers and its weight 3-4%, and the surface treating agent is by benzene first
Acid, acetone and KH560 are mixed according to the ratio of weight ratio 2-3:1-2:35.
The preparation method of the composite epoxy resin the following steps are included:
1) modified silicasol is prepared, it is spare；
The modified silicasol is the silicon powder that silica solution weight 2-3% is sequentially added in commercially available silica solution, silica solution weight
The sodium acetate of 0.8-1% and the KH560 of silica solution weight 3-4% then stir the mixing that 1-2h is obtained under the conditions of 70-80 DEG C
Object；
2) each component is weighed according to the ratio, after then melting bisphenol A type epoxy resin, is successively added and weighs thereto
Good butylene epoxy resin, glycerol epoxy resin and diisocyanate stirs after melting completely, be cooled to 60-70 DEG C again to
Modified silicasol made from step 1) is wherein added, obtains composite epoxy resin after mixing evenly.
The eucommia ulmoides extracts in the preparation, first carry out the following processing Eucommia ulmoides Oliv. leaves:
1) it is dipped into 2h in the sodium chloride solution that mass concentration is 30% after washing with water Eucommia ulmoides Oliv. leaves completely, then pulls out simultaneously
It is dipped into 20min in the sodium hydroxide solution that mass concentration is 35%, then pulls out and is rinsed well with clear water；
Wherein, after Eucommia ulmoides Oliv. leaves impregnate 10min in sodium hydroxide solution, apply the microwave treatment that power is 400W into solution
2min；
2) it in the clear water that the Eucommia ulmoides Oliv. leaves that clear water in step 1) is rinsed well are impregnated to 3-5 times of its weight, is then added thereto
The cellulase of Eucommia ulmoides Oliv. leaves weight 1%, and stand 3-4h, then cleaned up and completed pair with clear water after Eucommia ulmoides Oliv. leaves are pulled out
The processing of Eucommia ulmoides Oliv. leaves.
Hydroxyethyl cellulose and coarse whiting weight 6-8% in the moisture-proof anti-crack mastic powder also containing coarse whiting weight 4-6%
Silicon powder.
The Chinese alpine rush slurry of grey calcium weight 3-4% and the Chinese alpine rush of grey calcium weight 0.6% are additionally added in the moisture-proof anti-crack mastic powder
Powder；The Chinese alpine rush slurry is with Chinese alpine rush powder the preparation method comprises the following steps: taking the leaf of tender Chinese alpine rush and stem to clean up and obtaining Chinese alpine rush cake after squeezing
And juice, the powder that juice is evaporated are Chinese alpine rush powder, it is molten that Chinese alpine rush cake is dipped into the sodium hydroxide that mass concentration is 30%
24-28h in liquid, again by its water with 3-4 times of weight of Chinese alpine rush cake, the calcium oxide of Chinese alpine rush cake weight 60%, Chinese alpine rush cake weight after pulling out
Defibrination obtains Chinese alpine rush slurry after 30% hydroxypropyl methyl cellulose mixing.
The preparation method of above-mentioned moisture-proof anti-crack mastic powder prepares anti-crack fiber respectively first and combines reinforcing agent, then presses
Each component material is weighed according to aforementioned proportion, is then mixed grey calcium, anti-crack fiber and combination reinforcing agent, and three is added thereto
8-10 times of gross weight of water, then heating evaporates the water until moisture content is 60%, then remaining component is added thereto, and mix is uniform
Obtain product.
In the present invention, the preparation method in conjunction with reinforcing agent is first to mix polyethylene glycol simultaneously with sepiolite cashmere powder, zeolite powder
It is heated to 80-90 DEG C, remaining ingredient is added thereto again after polyethylene glycol is completely melt and is uniformly mixed.
Putty rubber powder used in the present invention is hydroxypropyl methyl cellulose type putty rubber powder.
Also contain the pig manure extract of grey calcium weight 10%, the preparation of the pig manure extract in the present invention, in the powder of lacquer putty for use on
Method are as follows: be milled after drying pig manure, and the diethyl hydroxyl of pig manure weight 3-4% is added after mixing with 8-10 times of its weight of water
Amine then boils 5-10min in the absence of air conditions, and cooling later is obtained by filtration filtrate, then concentrates the filtrate to substance
Long-pending 10% obtains pig manure extract；
Pig manure extract is mixed and added into after diethyl hydroxylamine with water and boils in the case where completely cutting off air conditions using pig manure as raw material
Boiling, diethyl hydroxylamine can effectively eliminate the stink in pig manure while consuming the dissolved oxygen in water, and can make after filtering
The organic oil content contained in pig manure retains, and then is concentrated, and after it is added in powder of lacquer putty for use on, can mix with modified starch, thus
The organic adhesive system that organic oil content coexists with modified starch is formd, guarantees the bond strength of each constituent, to improve
The intensity and waterproof performance of powder of lacquer putty for use on；
Anti-crack fiber of the invention is mixed by polystyrene fiber, polypropene staple, lignocellulosic and modified starch,
And modified starch therein is that eucommia ulmoides extracts, Du contained in eucommia ulmoides extracts are added thereto when starch is modified
Secondary glycosides has multiple polar functional groups, and property is active, produces under the action of tin coupling agent and starch similar with glutaraldehyde
Dialdehyde structure, so that the Dispersed precipitate for keeping the modified starch generated more uniform is in polystyrene fiber, the short fibre of polypropylene
The surface of dimension, and then in conjunction with lignocellulosic, bond strength and waterproofness between each component have been greatly enhanced in powder of lacquer putty for use on
Can, to improve cracking resistance and humidity resistance.
The composite epoxy resin that present invention combination reinforcing agent contains is molten by three kinds of epoxy resin, diisocyanate and modified silicon
Glue is made, and not only has both the characteristic of three kinds of epoxy resin, and diisocyanate during the preparation process thereon-NCO group with
The epoxy group reaction of epoxy resin generates the five-ring heterocycles structure oxazolidone of carbon, oxygen, nitrogen composition, enhances strand
Rigidity, reduce the quantity of weak bond and hydroxyl quantity on main chain, so as to improve the toughness of epoxy resin, thermal stability, resistance to
It is aqueous, it is added in powder of lacquer putty for use on, can be combined with the ingredient in powder of lacquer putty for use on as strong bonding agent in composite epoxy resin in this way,
To enhance the binding force between powder of lacquer putty for use on each component, crack resistance and moisture-proof water resistance are improved；Meanwhile it being added and changing in system
Property silica solution particle, the two combination can substantially improve the mechanical property and thermal property of epoxy resin, and modified silicasol
The addition of particle is equal to the raising of the tensile property of component mixing, product in preparation process and the final interpenetrating form of product
Favorably.
Compared with existing powder of lacquer putty for use on, the invention has the following advantages:
1) present invention by anti-crack fiber wherein and combines reinforcing agent, to significantly improve the combination in powder of lacquer putty for use between each component
Intensity, has not only been greatly enhanced the moisture-proof crack resistance of powder of lacquer putty for use on, but also can also improve the water resistance and hardness of powder of lacquer putty for use on, and
Anti-crack fiber is mixed by polystyrene fiber, polypropene staple, lignocellulosic and modified starch, modified shallow lake therein
Powder is that eucommia ulmoides extracts are added thereto when starch is modified, and the Cortex Eucommiae glycosides contained in eucommia ulmoides extracts has multiple poles
Property functional group, property is active, dialdehyde structure similar with glutaraldehyde is produced under the action of tin coupling agent and starch, to make
The modified starch of generation can be more uniform Dispersed precipitate in the surface of polystyrene fiber, polypropene staple, Jin Eryu
Lignocellulosic combines, and bond strength and waterproof performance between each component has been greatly enhanced in powder of lacquer putty for use on, to improve anti-
Fragility energy and humidity resistance；
2) the sepiolite cashmere powder and zeolite powder contained in combination reinforcing agent of the invention is all the material with microcellular structure, is being made
During standby, it is able to enter a part of modified manometer silicon dioxide and fills the micropore of a part, to form increasing
Strong particle, and these enhancing particles, in powder of lacquer putty for use on, as time goes by, a part of modified manometer silicon dioxide can be from
It is slowly detached from microcellular structure, and is combined with components such as grey calcium in powder of lacquer putty for use on, so that the powder of lacquer putty for use on that slowly gathers flows at any time
Die reduced intensity；And in the preparation process of powder of lacquer putty for use on, grey calcium is mixed with sustained release agent first and water is added to be evaporated, had been evaporated
Cheng Zhong, a part ash calcium can be also filled into microcellular structure, made that reinforcing agent is combined to combine closely with grey calcium, not only increased putty
The cracking resistance and hardness of powder, and be also improved to some extent to its waterproof performance；
Meanwhile in conjunction with composite epoxy resin and putty rubber powder is contained in reinforcing agent, composite epoxy resin therein is by three kinds of epoxies
Resin, diisocyanate and modified silicasol are made, and not only have both the characteristic of three kinds of epoxy resin, but also diisocyanate is being made
During standby thereon-NCO group react with the epoxy group of epoxy resin and generates the five-ring heterocycles that carbon, oxygen, nitrogen form
Structure oxazolidone enhances molecule chain rigidity, reduces the quantity of weak bond and hydroxyl quantity on main chain, so as to improve ring
Toughness, thermal stability, the water resistance of oxygen resin, are added in powder of lacquer putty for use in composite epoxy resin in this way, can be as strong bonding
Agent is combined with the ingredient in powder of lacquer putty for use on, to enhance the binding force between powder of lacquer putty for use on each component, improves crack resistance and moisture-proof
Water resistance；
3) sepiolite cashmere powder of the invention and zeolite powder are first carrying out modification using preceding, so that sepiolite cashmere powder, zeolite powder
It is more preferably combined with modified manometer silicon dioxide, the ultrasonication that when modification uses can destroy a part of sepiolite cashmere powder
With microcellular structure possessed by zeolite powder, so that its surfaces externally and internally be made to contact with methyl methacrylate and KH560, and then make
The surfaces externally and internally of sepiolite cashmere powder and zeolite powder is grafted a large amount of silicone hydroxyl, these groups are by chemically reacting both objects
Matter is connected with modified manometer silicon dioxide, is all had between guarantee three and between the ingredients such as three and grey calcium, coarse whiting
Good interface binding power further enhances the anti-of powder of lacquer putty for use on to improve the binding performance of each constituent in powder of lacquer putty for use on
Fragility energy and waterproof performance；
4) wastewaters with modified calcium sulfate whiskers can also be contained in combination reinforcing agent of the invention, since its wastewaters with modified calcium sulfate whiskers have passed through
Surface modification treatment when in this way in being added in powder of lacquer putty for use on, can not only be uniformly distributed in material, and can be by remaining
Component is preferably incorporated in its surface, to further enhance the cracking resistance of powder of lacquer putty for use on, hardness and waterproof performance；
5) present invention is using surface treating agent made of benzoic acid, acetone and KH560 to nano silica and calcium sulfate crystal whiskers
It is surface-treated, to make effect of the surface of the two by hydroxyl, in conjunction with a certain number of oxygen-containing functional groups, is increased
Surface compatability, in this way when it is sufficiently mixed with remaining raw material, because these particle very littles, and large specific surface area, it is subtle
The structure of change increases rest materials and its contact area, thus keep two kinds of substances evenly dispersed in material, and
And the combination of remaining substance generation physical surface；
6) hydroxyethyl cellulose and silicon powder can also be contained in powder of lacquer putty for use on of the present invention, hydroxyethyl cellulose therein is dissolved in water
Afterwards, since its surface-active action guarantees that it can form evenly dispersed gelling system in water, and then in silicon powder, oxidation
The surface of aluminium micro mist and modified manometer silicon dioxide forms one layer of protecting colloid, is the equal of being formed on the surface of these three powders
One layer " lubricating film ", enables bonding agent to be uniformly distributed in powder of lacquer putty for use on, and then each component of powder of lacquer putty for use on is combined closely,
To further enhance cracking resistance, hardness and the waterproof performance of powder of lacquer putty for use on；And in the silicon powder and powder of lacquer putty for use on wherein contained
Cement, calcium oxide mix and generate alkali-activator calcium hydroxide after water, and then generate hydrated calcium silicate isogel, improve putty
The intensity of powder, and these bonding components can promote gain in strength (the especially increasing of tensile strength after powder of lacquer putty for use on construction
It is long)；
7) for the present invention when extracting eucommia ulmoides extracts from Eucommia ulmoides Oliv. leaves, Eucommia ulmoides Oliv. leaves successively pass through sodium chloride solution and hydroxide
The immersion of sodium solution can cause a degree of destruction to the cell wall on surface layer, thus make its it is internal intracellular it is effective at
Divide easier can be precipitated through cell membrane and cell wall, and its cellulosic structure is enable to become loose, thus
It is subsequent to be digested by cellulase, and then the effective component that it can be enable internal is effectively precipitated；Likewise, in hydroxide
With microwave-assisted at when impregnating in sodium solution, the lignin and pentosan contained in Eucommia ulmoides Oliv. leaves cell wall can be effectively removed,
To cause greatly to destroy to cell wall, it can be precipitated by cell wall convenient for intracellular effective component, finally be mentioned
The high extraction pick-up rate of Cortex Eucommiae glycosides；
8) Chinese alpine rush slurry and Chinese alpine rush powder, the Chinese alpine rush cake and hydrogen-oxygen that Chinese alpine rush obtains after squeezing can also be added in powder of lacquer putty for use on of the invention
Change sodium processing, original cellulose can not only be made to become soft fluffy state from dense state, it can not only be with water and remaining component
It preferably combines, and a part of cellulose forms a large amount of alkali process cellulose through naoh treatment, these alkali process are fine
Chinese alpine rush slurry is collectively formed with calcium oxide (calcium hydroxide), hydroxypropyl methyl cellulose in dimension element, can not only be by sepiolite cashmere powder, boiling
Mountain flour and grey calcium etc. are combined closely, to further enhance the crack resistance energy and waterproof performance of powder of lacquer putty for use on, and Chinese alpine rush is starched
It can be improved the bonding capacity of powder of lacquer putty for use on, and the addition of Chinese alpine rush powder, it can also play the role of certain minor glue；
9) health environment-friendly
Various raw materials of the invention are directly derived from nature, will not generate pollution to environment in production and use process, product exists
Be when use using water as decentralized medium, it is nontoxic, free from extraneous odour, nonirritant, adverse effect will not be generated to environment and residents ' health；
10) construction technology is simple, adhesive force is strong
Powder of lacquer putty for use on of the invention in alkalinity, more suitable for being used in the bases such as cement and sand-lime, can with it is inorganic in these substrates
Object occurs chemically and physically reaction and generates crystal and colloidal sol, to enhance the adhesive force with base；
11) the putty layer surface hardness formed after constructing is high, water-proof breathable properties are good
For the present invention after constructing onto metope, certain little particle components therein can penetrate into metope, and then expand crystallization
Reaction, the crystal that reaction generates volume expansion are filled into substrate microcrack and sand holes, its surface hardness of the putty layer of formation is high,
Wear-resistant and washing ability is strong, non-scale, can be blistered and is fallen off with through a long time flushing；And the putty layer not only performance formed
Stablize, the service life of architectural surface can be extended, and there is good permeability, it is not only waterproof as the skin of people but also can arrange
Sweat while waterproof is penetrated into, and can make the intracorporal moisture evaporation of base and be discharged；
12) widely used
A series of physical and chemical reaction can occur for powder of lacquer putty for use on of the invention, anti-when metope with construction after water mix
The combination that molecule chain type should be formed afterwards can be widely applied to the dress of the substrate surfaces such as concrete, wall body brick, ceramic tile even glass
Decoration is repaired, is filled suitable for the interior in the places such as house, public place of entertainment, hotel, market, hospital, school, kindergarten and outdoor wall surface
Decoration is repaired, especially its putty layer formed has waterproof and breathable function, biggishly more suitable for underground garage, coastal moisture
The inner-outer wall in area is fitted up.
Specific embodiment
The present invention is further elaborated combined with specific embodiments below.
Embodiment 1
A kind of moisture-proof anti-crack mastic powder, according to weight ratio, by 46 parts of grey calcium, 28 parts of coarse whiting, 12 parts of cement, 7 parts anti-
The combination reinforcing agent for splitting fiber and 8 parts is made, and the anti-crack fiber is by polystyrene fiber, polypropene staple, wood fibre
Element and modified starch are mixed with the ratio of 3:8:3:5, and the preparation method of the modified starch is that starch is added to as it
It is uniformly mixed in the water that 3 times of weight, the tin coupling agent of starch weight 8% is then added thereto and with sulphur acid for adjusting pH value to 4,
The eucommia ulmoides extracts of starch weight 1% are added thereto again, adjusts the temperature to 60 DEG C after mixing and keeps the temperature 2h, finally to it
The middle stearic acid that starch weight 4% is added, drying to constant weight under the conditions of 100 DEG C after mixing evenly to get modified starch is arrived；Institute
Stating eucommia ulmoides extracts is that Eucommia ulmoides Oliv. leaves are boiled to filter out the resulting filtrate of solid residue after 20min and be evaporated in water and finally obtained
Powder.
The above are the basic embodiments of the present embodiment, further can be improved, optimized and limited on the basis of above:
Such as, the combination reinforcing agent is by sepiolite cashmere powder, zeolite powder, modified manometer silicon dioxide, polyethylene glycol, composite epoxy
Resin, putty rubber powder and water are evaporated what liquid obtained under the conditions of 100 DEG C by after the weight ratio mixing of 5:8:5:16:3:8:55；
Wherein, modified manometer silicon dioxide is that the surface treating agent of commercially available nano silica and its weight 3% is mixed to get, the surface
Inorganic agent is mixed by benzoic acid, acetone and KH560 according to the ratio of weight ratio 2:1:35；The composite epoxy resin is by 4
Part bisphenol A type epoxy resin, 0.5 part of butylene epoxy resin, 0.5 part of glycerol epoxy resin, 2 parts of diisocyanate and
2 parts of modified silicasol is made, and modified silicasol is the silicon powder that silica solution weight 2% is sequentially added in commercially available silica solution, silicon
The sodium acetate of sol weight 0.8% and the KH560 of silica solution weight 3% then stir the mixture that 1h is obtained under the conditions of 70 DEG C；
Further, the sepiolite cashmere powder and zeolite powder need to be modified processing in advance before use, so that sepiolite cashmere
Powder, zeolite powder and modified manometer silicon dioxide more preferably combine；It is described processing is modified to sepiolite cashmere powder and zeolite powder to refer to:
Take methyl methacrylate, the KH560 of the two total weight 5% of commercially available sepiolite cashmere powder and zeolite powder and the two total weight 3% mixed
After closing uniformly, frequency of use is that the ultrasonication 2min of 200KHz is obtained.
Further, the wastewaters with modified calcium sulfate whiskers in the combination reinforcing agent also containing sepiolite cashmere powder weight 4%, institute
Stating wastewaters with modified calcium sulfate whiskers is to be mixed to get commercially available calcium sulfate crystal whiskers and the surface treating agent of its weight 3%, the surface treatment
Agent is mixed by benzoic acid, acetone and KH560 according to the ratio of weight ratio 2:1:35；
Further, the composite epoxy resin preparation method the following steps are included:
1) modified silicasol is prepared, it is spare；
The modified silicasol is the silicon powder that silica solution weight 2% is sequentially added in commercially available silica solution, silica solution weight 0.8%
Sodium acetate and silica solution weight 3% KH560,1h obtained mixture is then stirred under the conditions of 70 DEG C；
2) each component is weighed according to the ratio, after then melting bisphenol A type epoxy resin, is successively added and weighs thereto
Good butylene epoxy resin, glycerol epoxy resin and diisocyanate stirs after melting completely, is cooled to 60 DEG C again thereto
Modified silicasol made from step 1) is added, obtains composite epoxy resin after mixing evenly.
Further again, the eucommia ulmoides extracts in the preparation, first carry out the following processing Eucommia ulmoides Oliv. leaves:
1) it is dipped into 2h in the sodium chloride solution that mass concentration is 30% after washing with water Eucommia ulmoides Oliv. leaves completely, then pulls out simultaneously
It is dipped into 20min in the sodium hydroxide solution that mass concentration is 35%, then pulls out and is rinsed well with clear water；
Wherein, after Eucommia ulmoides Oliv. leaves impregnate 10min in sodium hydroxide solution, apply the microwave treatment that power is 400W into solution
2min；
2) in the clear water that the Eucommia ulmoides Oliv. leaves that clear water in step 1) is rinsed well are impregnated to 3 times of its weight, Du is then added thereto
The cellulase of secondary leaf weight 1%, and 3h is stood, then cleaned up after Eucommia ulmoides Oliv. leaves are pulled out with clear water and completed to Cortex Eucommiae
The processing of blade；
For another example, the hydroxyethyl cellulose and coarse whiting weight 6% of coarse whiting weight 4% can also be added in the moisture-proof anti-crack mastic powder
Silicon powder；
For another example, the Chinese alpine rush slurry of grey calcium weight 3% and the alpine rush or palm-bark rain cape of grey calcium weight 0.6% can also be added in the moisture-proof anti-crack mastic powder
Grass meal；The Chinese alpine rush slurry is with Chinese alpine rush powder the preparation method comprises the following steps: taking the leaf of tender Chinese alpine rush and stem to clean up and obtaining Chinese alpine rush after squeezing
Cake and juice, the powder that juice is evaporated are Chinese alpine rush powder, and Chinese alpine rush cake is dipped into the sodium hydroxide that mass concentration is 30%
In solution for 24 hours, again by its water with 3 times of Chinese alpine rush cake weight, the calcium oxide of Chinese alpine rush cake weight 60%, Chinese alpine rush cake weight 30% after pulling out
Hydroxypropyl methyl cellulose mixing after defibrination i.e. obtain Chinese alpine rush slurry.
Embodiment 2
A kind of moisture-proof anti-crack mastic powder, according to weight ratio, by 50 parts of grey calcium, 36 parts of coarse whiting, 16 parts of cement, 9 parts anti-
The combination reinforcing agent for splitting fiber and 12 parts is made, and the anti-crack fiber is by polystyrene fiber, polypropene staple, wood fibre
Element and modified starch are mixed with the ratio of 5:10:4:7, and the preparation method of the modified starch is, by starch be added to for
It is uniformly mixed in the water of 5 times of its weight, the tin coupling agent of starch weight 10% is then added thereto and with sulphur acid for adjusting pH value
To 5, then the eucommia ulmoides extracts of addition starch weight 3% thereto, 65 DEG C are adjusted the temperature to after mixing and keeps the temperature 3h, finally
The stearic acid of starch weight 5% is added thereto, drying to constant weight under the conditions of 110 DEG C after mixing evenly forms sediment to get to modified
Powder；The eucommia ulmoides extracts are that Eucommia ulmoides Oliv. leaves boil in water and filter out the resulting filtrate of solid residue after 30min and be evaporated finally
Obtained powder.
The above are the basic embodiments of the present embodiment, further can be improved, optimized and limited on the basis of above:
Such as, the combination reinforcing agent is by sepiolite cashmere powder, zeolite powder, modified manometer silicon dioxide, polyethylene glycol, composite epoxy
Resin, putty rubber powder and water are evaporated liquid under the conditions of 120 DEG C after mixing by the weight ratio of 6:10:7:18:4:10:60 and obtain
's；Wherein, modified manometer silicon dioxide is that the surface treating agent of commercially available nano silica and its weight 4% is mixed to get, the table
Surface treatment agent is mixed by benzoic acid, acetone and KH560 according to the ratio of weight ratio 3:2:35；The composite epoxy resin by
4 parts of bisphenol A type epoxy resin, 0.5 part of butylene epoxy resin, 0.5 part of glycerol epoxy resin, 2 parts of diisocyanate
Modified silicasol with 2 parts is made, modified silicasol be the silicon powder that silica solution weight 3% is sequentially added in commercially available silica solution,
The sodium acetate of silica solution weight 1% and the KH560 of silica solution weight 4% then stir the mixture that 2h is obtained under the conditions of 80 DEG C；
Further, the sepiolite cashmere powder and zeolite powder need to be modified processing in advance before use, so that sepiolite cashmere
Powder, zeolite powder and modified manometer silicon dioxide more preferably combine；It is described processing is modified to sepiolite cashmere powder and zeolite powder to refer to:
Take methyl methacrylate, the KH560 of the two total weight 5% of commercially available sepiolite cashmere powder and zeolite powder and the two total weight 3% mixed
After closing uniformly, frequency of use is that the ultrasonication 3min of 240KHz is obtained.
Further, the wastewaters with modified calcium sulfate whiskers in the combination reinforcing agent also containing sepiolite cashmere powder weight 5%, institute
Stating wastewaters with modified calcium sulfate whiskers is to be mixed to get commercially available calcium sulfate crystal whiskers and the surface treating agent of its weight 4%, the surface treatment
Agent is mixed by benzoic acid, acetone and KH560 according to the ratio of weight ratio 3:2:35；
Further, the composite epoxy resin preparation method the following steps are included:
1) modified silicasol is prepared, it is spare；
The modified silicasol is the silicon powder that silica solution weight 3% is sequentially added in commercially available silica solution, silica solution weight 1%
The KH560 of sodium acetate and silica solution weight 4% then stirs the mixture that 2h is obtained under the conditions of 80 DEG C；
2) each component is weighed according to the ratio, after then melting bisphenol A type epoxy resin, is successively added and weighs thereto
Good butylene epoxy resin, glycerol epoxy resin and diisocyanate stirs after melting completely, is cooled to 70 DEG C again thereto
Modified silicasol made from step 1) is added, obtains composite epoxy resin after mixing evenly.
Further again, the eucommia ulmoides extracts in the preparation, first carry out the following processing Eucommia ulmoides Oliv. leaves:
1) it is dipped into 2h in the sodium chloride solution that mass concentration is 30% after washing with water Eucommia ulmoides Oliv. leaves completely, then pulls out simultaneously
It is dipped into 20min in the sodium hydroxide solution that mass concentration is 35%, then pulls out and is rinsed well with clear water；
Wherein, after Eucommia ulmoides Oliv. leaves impregnate 10min in sodium hydroxide solution, apply the microwave treatment that power is 400W into solution
2min；
2) in the clear water that the Eucommia ulmoides Oliv. leaves that clear water in step 1) is rinsed well are impregnated to 5 times of its weight, Du is then added thereto
The cellulase of secondary leaf weight 1%, and 4h is stood, then cleaned up after Eucommia ulmoides Oliv. leaves are pulled out with clear water and completed to Cortex Eucommiae
The processing of blade；
For another example, the hydroxyethyl cellulose and coarse whiting weight 8% of coarse whiting weight 6% can also be added in the moisture-proof anti-crack mastic powder
Silicon powder；
For another example, the Chinese alpine rush slurry of grey calcium weight 4% and the alpine rush or palm-bark rain cape of grey calcium weight 0.6% can also be added in the moisture-proof anti-crack mastic powder
Grass meal；The Chinese alpine rush slurry is with Chinese alpine rush powder the preparation method comprises the following steps: taking the leaf of tender Chinese alpine rush and stem to clean up and obtaining Chinese alpine rush after squeezing
Cake and juice, the powder that juice is evaporated are Chinese alpine rush powder, and Chinese alpine rush cake is dipped into the sodium hydroxide that mass concentration is 30%
28h in solution, again by its water with 4 times of Chinese alpine rush cake weight, the calcium oxide of Chinese alpine rush cake weight 60%, Chinese alpine rush cake weight 30% after pulling out
Hydroxypropyl methyl cellulose mixing after defibrination i.e. obtain Chinese alpine rush slurry.
Embodiment 3
A kind of moisture-proof anti-crack mastic powder, according to weight ratio, by 48 parts of grey calcium, 32 parts of coarse whiting, 14 parts of cement, 8 parts anti-
The combination reinforcing agent for splitting fiber and 10 parts is made, and the anti-crack fiber is by polystyrene fiber, polypropene staple, wood fibre
Element and modified starch are mixed with the ratio of 4:9:3.5:6, and the preparation method of the modified starch is, by starch be added to for
In the water of 4 times of its weight be uniformly mixed, then thereto be added starch weight 9% tin coupling agent and with sulphur acid for adjusting pH value extremely
4.5, then the eucommia ulmoides extracts of starch weight 2% are added thereto, 63 DEG C are adjusted the temperature to after mixing and keeps the temperature 2.5h, most
The stearic acid of starch weight 4.5% is added thereto afterwards, drying to constant weight under the conditions of 105 DEG C after mixing evenly to get modification is arrived
Starch；The eucommia ulmoides extracts are that Eucommia ulmoides Oliv. leaves boil in water and filter out the resulting filtrate of solid residue after 25min and be evaporated most
The powder obtained afterwards.
The above are the basic embodiments of the present embodiment, further can be improved, optimized and limited on the basis of above:
Such as, the combination reinforcing agent is by sepiolite cashmere powder, zeolite powder, modified manometer silicon dioxide, polyethylene glycol, composite epoxy
Resin, putty rubber powder and water are evaporated liquid under the conditions of 110 DEG C after mixing by the weight ratio of 5.5:9:6:17:3.5:9:58 and obtain
's；Wherein, modified manometer silicon dioxide is that the surface treating agent of commercially available nano silica and its weight 3.5% is mixed to get, should
Surface treating agent is mixed by benzoic acid, acetone and KH560 according to the ratio of weight ratio 2.5:1.5:35；The composite epoxy
Resin is by 4 parts of bisphenol A type epoxy resin, 0.5 part of butylene epoxy resin, 0.5 part of glycerol epoxy resin, the two of 2 parts different
Cyanate and 2 parts of modified silicasol are made, and modified silicasol is that silica solution weight 2.5% is sequentially added in commercially available silica solution
Silicon powder, the sodium acetate of silica solution weight 0.9% and the KH560 of silica solution weight 3.5%, then stirred under the conditions of 75 DEG C
The mixture that 1.5h is obtained；
Further, the sepiolite cashmere powder and zeolite powder need to be modified processing in advance before use, so that sepiolite cashmere
Powder, zeolite powder and modified manometer silicon dioxide more preferably combine；It is described processing is modified to sepiolite cashmere powder and zeolite powder to refer to:
Take methyl methacrylate, the KH560 of the two total weight 5% of commercially available sepiolite cashmere powder and zeolite powder and the two total weight 3% mixed
After closing uniformly, frequency of use is that the ultrasonication 2-3min of 220KHz is obtained.
Further, the wastewaters with modified calcium sulfate whiskers in the combination reinforcing agent also containing sepiolite cashmere powder weight 4.5%,
The wastewaters with modified calcium sulfate whiskers is to be mixed to get commercially available calcium sulfate crystal whiskers and the surface treating agent of its weight 3.5%, the surface
Inorganic agent is mixed by benzoic acid, acetone and KH560 according to the ratio of weight ratio 2.5:1.5:35；
Further, the composite epoxy resin preparation method the following steps are included:
1) modified silicasol is prepared, it is spare；
The modified silicasol is the silicon powder that silica solution weight 2.5% is sequentially added in commercially available silica solution, silica solution weight
0.9% sodium acetate and the KH560 of silica solution weight 3.5% then stir the mixture that 1.5h is obtained under the conditions of 75 DEG C；
2) each component is weighed according to the ratio, after then melting bisphenol A type epoxy resin, is successively added and weighs thereto
Good butylene epoxy resin, glycerol epoxy resin and diisocyanate stirs after melting completely, is cooled to 65 DEG C again thereto
Modified silicasol made from step 1) is added, obtains composite epoxy resin after mixing evenly.
Further again, the eucommia ulmoides extracts in the preparation, first carry out the following processing Eucommia ulmoides Oliv. leaves:
1) it is dipped into 2h in the sodium chloride solution that mass concentration is 30% after washing with water Eucommia ulmoides Oliv. leaves completely, then pulls out simultaneously
It is dipped into 20min in the sodium hydroxide solution that mass concentration is 35%, then pulls out and is rinsed well with clear water；
Wherein, after Eucommia ulmoides Oliv. leaves impregnate 10min in sodium hydroxide solution, apply the microwave treatment that power is 400W into solution
2min；
2) in the clear water that the Eucommia ulmoides Oliv. leaves that clear water in step 1) is rinsed well are impregnated to 4 times of its weight, Du is then added thereto
The cellulase of secondary leaf weight 1%, and 3.5h is stood, then cleaned up after Eucommia ulmoides Oliv. leaves are pulled out with clear water and completed to Du
The processing of secondary blade；
For another example, the hydroxyethyl cellulose and coarse whiting weight 7% of coarse whiting weight 5% can also be added in the moisture-proof anti-crack mastic powder
Silicon powder；
For another example, the Chinese alpine rush slurry and ash calcium weight 0.6% of grey calcium weight 3.5% can also be added in the moisture-proof anti-crack mastic powder
Chinese alpine rush powder；The Chinese alpine rush slurry is with Chinese alpine rush powder the preparation method comprises the following steps: taking the leaf of tender Chinese alpine rush and stem to clean up and obtaining alpine rush or palm-bark rain cape after squeezing
Glutinous rice balls and juice, the powder that juice is evaporated are Chinese alpine rush powder, and Chinese alpine rush cake is dipped into the hydroxide that mass concentration is 30%
26h in sodium solution, again by itself and 3.5 times of Chinese alpine rush cake weight of water, calcium oxide, the Chinese alpine rush cake weight of Chinese alpine rush cake weight 60% after pulling out
Defibrination obtains Chinese alpine rush slurry after the hydroxypropyl methyl cellulose mixing of amount 30%.
Powder of lacquer putty for use on of the invention can directly construct during decoration construction in such as cleaning, the newly-built wall without greasy dirt
The existing surface of wall of body or old-wall renewing, removes surface and oil contaminant or dirt carries out the surface treatment of matrix, does not need centre
The interfacial agents of medium can directly be applied to surface of wall.
Dynamic cracking resistance test
The dynamic cracking resistance test recorded with the Appendix B of People's Republic of China (PRC) building industry professional standard JG/T157-2009
Method is tested:
Prepare following sample respectively first, and the size of sample meets People's Republic of China (PRC) building industry professional standard JG/
The demand for the dynamic cracking resistance tester that the Appendix B of T157-2009 is recorded, the formula of the sample are as follows:
Sample 1: according to weight ratio, powder of lacquer putty for use on is by 50 parts of grey calcium, 28 parts of coarse whiting, 14 parts of cement, 8 parts of commercially available poly- third second
Alkene anti-crack fiber, 10 parts of commercially available putty rubber powder are made；
Sample 2: according to weight ratio, powder of lacquer putty for use on is by 50 parts of grey calcium, 28 parts of coarse whiting, 14 parts of cement, 8 parts by polystyrene fibre
Anti-crack fiber made of dimension, the ratio of polypropene staple, lignocellulosic and modified starch with 4:8:4:5,10 parts commercially available
Putty rubber powder is made；
Sample 3: on the basis of sample 2 is formulated, 10 parts of commercially available putty rubber powder is replaced with 10 parts by sepiolite cashmere powder, zeolite
Powder, modified manometer silicon dioxide, polyethylene glycol, composite epoxy resin, putty rubber powder and water press the weight of 5:10:5:16:3:8:55
Measure the combination reinforcing agent obtained than being evaporated liquid after mixing under the conditions of 120 DEG C；
Sample 4: on the basis of sample 3 is formulated, sepiolite cashmere powder therein and zeolite powder are first being modified place using preceding
Reason；
Sample 5: on the basis of sample 2 is formulated, sepiolite cashmere powder weight 4% will additionally be added in combination reinforcing agent therein
Wastewaters with modified calcium sulfate whiskers；
Sample 6: on the basis of sample 2 is formulated, the hydroxyethyl cellulose and coarse whiting weight of coarse whiting weight 5% are additionally added thereto
The silicon powder of amount 8%；
Sample 7: on the basis of sample 2 is formulated, the Chinese alpine rush powder of additional the Chinese alpine rush slurry that grey calcium weight 4% is added and grey calcium weight 0.6%；
The Chinese alpine rush slurry is with Chinese alpine rush powder the preparation method comprises the following steps: taking the leaf of tender Chinese alpine rush and stem to clean up and obtaining Chinese alpine rush cake and juice after squeezing
Liquid, the powder that juice is evaporated are Chinese alpine rush powder, Chinese alpine rush cake are dipped into the sodium hydroxide solution that mass concentration is 30%
For 24 hours, after pulling out again by it with 4 times of Chinese alpine rush cake weight of water, the hydroxypropyl of the calcium oxide of Chinese alpine rush cake weight 60%, Chinese alpine rush cake weight 30%
Defibrination obtains Chinese alpine rush slurry after the mixing of ylmethyl cellulose；
Then the above sample is remembered according to the Appendix B of People's Republic of China (PRC) building industry professional standard JG/T157-2009 respectively
The dynamic cracking resistance test method of load is tested, and upper machine is tested after the completion of maintenance in 7 days, and 6 points are first marked before test
And the initial crack width before test is read, in experimentation, stop test when naked eyes visible crack occurs in putty layer, again
The crack width of respective point is read, the difference of the two chooses wherein maximum four points of numerical value as experimental result, takes it average
It is worth the final testing result as the sample；
Final experimental result: sample 1 is 0.07mm, and sample 2 is 0.05mm, and sample 3 is 0.04mm, and sample 4 is 0.05mm, sample
5 be 0.05mm, and sample 6 is 0.04mm, and it is p-type powder of lacquer putty for use on that sample 7, which is 0.03mm,；
In order to verify the crack resistance and waterproofness of each sample, the present invention takes following easy means to test, and sample is still taken
Sample in dynamic cracking resistance test, experiment condition are as follows: it is as follows that the sample after conserving seven days is in progress in the following conditions
Circular treatment until it macroscopic crackle occurs, and records undergo cycle-index, as assess the sample crack resistance with
The index of waterproofness:
Experiment condition: drenching sample in specimen surface spray water with watering can, then utilizes hot wind by specimen surface using hair dryer
Drying often soaks primary and drying and is once denoted as one cycle；
Experimental result: sample 1 is 25 times, and sample 2 is 34 times, and sample 3 is 42 times, and sample 4 is 35 times, and sample 5 is 37 times, sample
6 be 44 times, and sample 7 is 51 times；
From the above experimental results, we know that the crack resistance of powder of lacquer putty for use on can be obviously improved after the anti-crack fiber that special composition is added
With waterproofness the cycle-index of sample 1 (sample 2 be greater than), and the combination reinforcing agent of special composition and the cracking resistance of special composition are used
After fiber cooperation, capable of further enhancing its crack resistance and waterproofness, (cycle-index of sample 3,4 and 5 is greater than sample 1 and sample 2
Cycle-index), and hydroxyethyl cellulose and silicon powder are additionally added in powder of lacquer putty for use on, also can be improved crack resistance and waterproofness
(cycle-index that the cycle-index of sample 6 is greater than sample 1 and sample 2), finally, Chinese alpine rush slurry and Chinese alpine rush are added in powder of lacquer putty for use on
Powder, (cycle-index of sample 7 is greater than the circulation time of sample 1 and sample 2 to the crack resistance and waterproofness that also can be improved powder of lacquer putty for use on
Number).
Claims (3)
1. a kind of moisture-proof anti-crack mastic powder containing Chinese alpine rush component, according to weight ratio, by 46-50 parts of grey calcium, 28-36 parts of weight
Calcium, 12-16 parts of cement, 7-9 parts of anti-crack fiber and 8-12 parts of combination reinforcing agent is made, it is characterised in that: the cracking resistance
Fiber is by polystyrene fiber, polypropene staple, lignocellulosic and modified starch with the weight of 3-5:8-10:3-4:5-7
Than mixing, the preparation method of the modified starch is that starch is added in the water for 3-5 times of its weight and is uniformly mixed,
Then thereto be added starch weight 8%-10% tin coupling agent and use sulphur acid for adjusting pH value to 4-5, then thereto be added shallow lake
The eucommia ulmoides extracts of powder weight 1-3% adjust the temperature to 60-65 DEG C after mixing and keep the temperature 2-3h, are finally added and form sediment thereto
The stearic acid of powder weight 4-5%, drying to constant weight under the conditions of 100-110 DEG C after mixing evenly to get modified starch is arrived；It is described
Eucommia ulmoides extracts are that Eucommia ulmoides Oliv. leaves are boiled to filter out the resulting filtrate of solid residue after 20-30min and be evaporated in water and finally obtained
Powder；
The combination reinforcing agent by sepiolite cashmere powder, zeolite powder, modified manometer silicon dioxide, polyethylene glycol, composite epoxy resin,
Putty rubber powder and water by after the weight ratio mixing of 5-6:8-10:5-7:16-18:3-4:8-10:55-60 in 100-120 DEG C of condition
Under be evaporated liquid and obtain；Wherein, modified manometer silicon dioxide is the surface treatment of commercially available nano silica and its weight 3-4%
Agent is mixed to get, the surface treating agent by benzoic acid, acetone and KH560 according to weight ratio 2-3:1-2:35 ratio mixing and
At；According to weight ratio, the composite epoxy resin is by 4 parts of bisphenol A type epoxy resin, 0.5 part of butylene epoxy resin, 0.5
The glycerol epoxy resin, 2 parts of diisocyanate and 2 parts of modified silicasol of part are made, and modified silicasol is molten in commercially available silicon
The silicon powder of silica solution weight 2-3%, the sodium acetate of silica solution weight 0.8-1% and silica solution weight 3-4% are sequentially added in glue
KH560 then stirs the mixture that 1-2h is obtained under the conditions of 70-80 DEG C；
It is additionally added Chinese alpine rush component in the moisture-proof anti-crack mastic powder, which is starched by the Chinese alpine rush of grey calcium weight 3-4% and grey calcium
The Chinese alpine rush powder of weight 0.6% forms；The Chinese alpine rush slurry is with Chinese alpine rush powder the preparation method comprises the following steps: the leaf of tender Chinese alpine rush and stem is taken to clean up
And Chinese alpine rush cake and juice are obtained after squeezing, the powder that juice is evaporated is Chinese alpine rush powder, and it is dense that Chinese alpine rush cake is dipped into quality
Degree is 24-28h in 30% sodium hydroxide solution, again by its water with 3-4 times of weight of Chinese alpine rush cake, Chinese alpine rush cake weight 60% after pulling out
Calcium oxide, Chinese alpine rush cake weight 30% hydroxypropyl methyl cellulose mixing after defibrination i.e. obtain Chinese alpine rush slurry.
2. a kind of moisture-proof anti-crack mastic powder containing Chinese alpine rush component according to claim 1, it is characterised in that: described compound
The preparation method of epoxy resin the following steps are included:
1) modified silicasol is prepared, it is spare；
The modified silicasol is the silicon powder that silica solution weight 2-3% is sequentially added in commercially available silica solution, silica solution weight
The sodium acetate of 0.8-1% and the KH560 of silica solution weight 3-4% then stir the mixing that 1-2h is obtained under the conditions of 70-80 DEG C
Object；
2) ratio described in accordance with the claim 1 weighs each component, after then melting bisphenol A type epoxy resin, successively to it
It is middle that load weighted butylene epoxy resin, glycerol epoxy resin and diisocyanate is added, it stirs after melting completely, is cooled to
60-70 DEG C is added modified silicasol made from step 1) thereto again, obtains composite epoxy resin after mixing evenly.
3. a kind of moisture-proof anti-crack mastic powder containing Chinese alpine rush component according to claim 1, it is characterised in that: the Cortex Eucommiae
Extract in the preparation, first carries out the following processing Eucommia ulmoides Oliv. leaves:
1) it is dipped into 2h in the sodium chloride solution that mass concentration is 30% after washing with water Eucommia ulmoides Oliv. leaves completely, then pulls out simultaneously
It is dipped into 20min in the sodium hydroxide solution that mass concentration is 35%, then pulls out and is rinsed well with clear water；
Wherein, after Eucommia ulmoides Oliv. leaves impregnate 10min in sodium hydroxide solution, apply the microwave treatment that power is 400W into solution
2min；
2) it in the clear water that the Eucommia ulmoides Oliv. leaves that clear water in step 1) is rinsed well are impregnated to 3-5 times of its weight, is then added thereto
The cellulase of Eucommia ulmoides Oliv. leaves weight 1%, and stand 3-4h, then cleaned up and completed pair with clear water after Eucommia ulmoides Oliv. leaves are pulled out
The processing of Eucommia ulmoides Oliv. leaves.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811364748.4A CN109401413B (en) | 2017-04-13 | 2017-04-13 | Moisture-proof anti-cracking putty powder containing sedum orientalis components |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811364748.4A CN109401413B (en) | 2017-04-13 | 2017-04-13 | Moisture-proof anti-cracking putty powder containing sedum orientalis components |
| CN201710260402.9A CN107011714B (en) | 2017-04-13 | 2017-04-13 | A kind of moisture-proof anti-crack mastic powder |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710260402.9A Division CN107011714B (en) | 2017-04-13 | 2017-04-13 | A kind of moisture-proof anti-crack mastic powder |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN109401413A true CN109401413A (en) | 2019-03-01 |
| CN109401413B CN109401413B (en) | 2020-09-04 |
Family
ID=59446809
Family Applications (3)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811364740.8A Active CN109517419B (en) | 2017-04-13 | 2017-04-13 | Moisture-proof anti-cracking putty powder containing modified calcium sulfate whiskers |
| CN201811364748.4A Active CN109401413B (en) | 2017-04-13 | 2017-04-13 | Moisture-proof anti-cracking putty powder containing sedum orientalis components |
| CN201710260402.9A Expired - Fee Related CN107011714B (en) | 2017-04-13 | 2017-04-13 | A kind of moisture-proof anti-crack mastic powder |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811364740.8A Active CN109517419B (en) | 2017-04-13 | 2017-04-13 | Moisture-proof anti-cracking putty powder containing modified calcium sulfate whiskers |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710260402.9A Expired - Fee Related CN107011714B (en) | 2017-04-13 | 2017-04-13 | A kind of moisture-proof anti-crack mastic powder |
Country Status (1)
| Country | Link |
|---|---|
| CN (3) | CN109517419B (en) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107418286A (en) * | 2017-09-23 | 2017-12-01 | 江苏昶浩建材有限公司 | A kind of moistureproof powder of lacquer putty for use on |
| CN108504163B (en) * | 2018-04-09 | 2020-02-11 | 漳州市龙文区康保建材有限公司 | Bioengineering interior wall putty powder and preparation method thereof |
| CN109266108A (en) * | 2018-07-20 | 2019-01-25 | 山东天汇防水股份有限公司 | A kind of inner wall of building water-proof heat-insulating paint and its manufacturing method applied to indoor environment |
| CN113337151A (en) * | 2021-07-12 | 2021-09-03 | 广东粤冠建材有限公司 | Waterproof putty with modified attapulgite for inner wall surface |
| CN116041908B (en) * | 2023-02-02 | 2023-09-05 | 南雄市星隆化工有限公司 | Modified epoxy resin with antifouling effect and preparation method thereof |
Citations (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1138444A (en) * | 1996-05-09 | 1996-12-25 | 王佐存 | Method for prodn. of imitation ancient health carved chair |
| US20020009622A1 (en) * | 1999-08-03 | 2002-01-24 | Goodson David M. | Sprayable phosphate cementitious coatings and a method and apparatus for the production thereof |
| CN101054486A (en) * | 2007-05-30 | 2007-10-17 | 翟翠明 | Water resistance putty powder with adsorption function and preparation method thereof |
| WO2010027756A2 (en) * | 2008-09-02 | 2010-03-11 | Ppg Industries Ohio, Inc. | Multi-cure compositions comprising polythiol |
| CN101787234A (en) * | 2010-04-01 | 2010-07-28 | 北京今鼎新翰文化艺术有限公司 | Antique tusche and new preparation method thereof |
| KR20110086888A (en) * | 2010-01-25 | 2011-08-02 | 임기태 | Multifunctional sound absorption putty composition and manufacturing method thereof |
| CN102391725A (en) * | 2011-08-29 | 2012-03-28 | 山西新今鼎文化产业发展有限公司 | Antique water-solubility black ink based on corn starch for screen printing and preparation method thereof |
| CN103265235A (en) * | 2013-04-18 | 2013-08-28 | 张家港市一达新型建材有限公司 | Anti-crack and anti-seepage putty powder for exterior walls |
| WO2014107199A2 (en) * | 2012-10-01 | 2014-07-10 | Rutgers, The State University Of New Jersey | Precursors and transport methods for hydrothermal liquid phase sintering (hlps) |
| WO2016032893A1 (en) * | 2014-08-25 | 2016-03-03 | Ticona Gmbh | Treated polyoxymethylene fibers for use in structural matrices |
| CN106084972A (en) * | 2016-08-26 | 2016-11-09 | 樊之雄 | A kind of interior wall mildew-proof water-resistant powder of lacquer putty for use on |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH02263878A (en) * | 1989-04-04 | 1990-10-26 | Dai Ichi Kogyo Seiyaku Co Ltd | Metal-coating composition |
| US20050058689A1 (en) * | 2003-07-03 | 2005-03-17 | Reactive Surfaces, Ltd. | Antifungal paints and coatings |
| EP1405881A1 (en) * | 2002-10-04 | 2004-04-07 | Eftec Europe Holding AG | Coating composition |
| US8277881B2 (en) * | 2004-05-21 | 2012-10-02 | Building Materials Investment Corporation | White reflective coating for modified bitumen membrane |
| CN101434773A (en) * | 2007-11-15 | 2009-05-20 | 马海涛 | Anti-corrosive construction coating |
| CN103613972A (en) * | 2013-11-19 | 2014-03-05 | 江苏蓝圈新材料有限公司 | Interior and exterior wall putty powder |
| CN104559405A (en) * | 2014-12-12 | 2015-04-29 | 青岛无为保温材料有限公司 | Damp-proof anti-cracking putty powder |
| CN104559407A (en) * | 2014-12-25 | 2015-04-29 | 青岛文创科技有限公司 | Cold-resistant waterproof putty powder |
| CN104945997B (en) * | 2015-06-17 | 2016-10-19 | 杭州正博新型建筑材料有限公司 | A kind of outer wall flexible waterproof putty powder |
| CN105348896A (en) * | 2015-12-17 | 2016-02-24 | 常熟市万象涂料有限公司 | Putty paint |
| CN106118203A (en) * | 2016-08-17 | 2016-11-16 | 安庆市美孚建材有限公司 | A kind of putty powder for exterior wall and preparation method thereof |
-
2017
- 2017-04-13 CN CN201811364740.8A patent/CN109517419B/en active Active
- 2017-04-13 CN CN201811364748.4A patent/CN109401413B/en active Active
- 2017-04-13 CN CN201710260402.9A patent/CN107011714B/en not_active Expired - Fee Related
Patent Citations (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1138444A (en) * | 1996-05-09 | 1996-12-25 | 王佐存 | Method for prodn. of imitation ancient health carved chair |
| US20020009622A1 (en) * | 1999-08-03 | 2002-01-24 | Goodson David M. | Sprayable phosphate cementitious coatings and a method and apparatus for the production thereof |
| CN101054486A (en) * | 2007-05-30 | 2007-10-17 | 翟翠明 | Water resistance putty powder with adsorption function and preparation method thereof |
| WO2010027756A2 (en) * | 2008-09-02 | 2010-03-11 | Ppg Industries Ohio, Inc. | Multi-cure compositions comprising polythiol |
| KR20110086888A (en) * | 2010-01-25 | 2011-08-02 | 임기태 | Multifunctional sound absorption putty composition and manufacturing method thereof |
| CN101787234A (en) * | 2010-04-01 | 2010-07-28 | 北京今鼎新翰文化艺术有限公司 | Antique tusche and new preparation method thereof |
| CN102391725A (en) * | 2011-08-29 | 2012-03-28 | 山西新今鼎文化产业发展有限公司 | Antique water-solubility black ink based on corn starch for screen printing and preparation method thereof |
| WO2014107199A2 (en) * | 2012-10-01 | 2014-07-10 | Rutgers, The State University Of New Jersey | Precursors and transport methods for hydrothermal liquid phase sintering (hlps) |
| CN103265235A (en) * | 2013-04-18 | 2013-08-28 | 张家港市一达新型建材有限公司 | Anti-crack and anti-seepage putty powder for exterior walls |
| WO2016032893A1 (en) * | 2014-08-25 | 2016-03-03 | Ticona Gmbh | Treated polyoxymethylene fibers for use in structural matrices |
| CN106084972A (en) * | 2016-08-26 | 2016-11-09 | 樊之雄 | A kind of interior wall mildew-proof water-resistant powder of lacquer putty for use on |
Non-Patent Citations (2)
| Title |
|---|
| SANJAY M. ATHAVALE，ETAL: "Silly putty of the tympanic cavity: The migrating "Earplug"", 《INTERNATIONAL JOURNAL OF PEDIATRIC OTORHINOLARYNGOLOGY EXTRA》 * |
| 徐峰等: "新型粉状内墙腻子的研制", 《装饰装修材料》 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN109517419B (en) | 2021-02-05 |
| CN109517419A (en) | 2019-03-26 |
| CN107011714A (en) | 2017-08-04 |
| CN109401413B (en) | 2020-09-04 |
| CN107011714B (en) | 2019-05-28 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN107011714B (en) | A kind of moisture-proof anti-crack mastic powder | |
| CN109161245B (en) | Waterproof putty containing waterproof additive for interior wall surface | |
| CN106590133B (en) | A kind of building inside and outside wall powder of lacquer putty for use on and preparation method thereof | |
| CN101942234A (en) | Environment friendly dry powder emulsion paint and preparation method thereof | |
| CN107474619B (en) | A kind of artificial marble sawdust outer wall flexible putty | |
| CN101974261A (en) | Neutral water-resistance putty paste and preparation method thereof | |
| CN111875328A (en) | Lightweight gypsum mortar and preparation method thereof | |
| CN108383478A (en) | A kind of high cracking resistance construction material and preparation method thereof | |
| CN106590132B (en) | A kind of freedom from cracking powder of lacquer putty for use on and preparation method thereof | |
| CN109400101A (en) | Metope repair materials and preparation method thereof | |
| CN102070319A (en) | Interior wall coating | |
| CN105731982A (en) | Non-toxic anti-crack putty and method for preparing same | |
| CN108751901A (en) | A kind of plastering gupsum mortar and preparation method thereof | |
| KR101139474B1 (en) | Color clay using nature inorganic pigment and nature binder and method for fabricating the same | |
| CN104909706A (en) | Fracture-resistant glass magnesium board containing modifying agents such as EVA emulsion, and preparation method thereof | |
| CN109251564A (en) | A kind of compound diatom ooze of no rubber powder and preparation method thereof | |
| CN107418332A (en) | A kind of exterior coating for building and preparation method thereof | |
| CN108751830B (en) | Application of rose essential oil tail waste material, home decoration plate and preparation method | |
| CN104829191A (en) | High hardness thermal insulation plant fiber cement composite strip plate and producing method thereof | |
| CN105397897A (en) | Production method for antiflaming wood manmade carbonized wood | |
| CN109970395A (en) | A kind of wearable environment protection composite light lacquer and its manufacturing method | |
| KR20200063791A (en) | Process for preparing eco-friendly paint composition comprising Polygoum tinctoria and trass | |
| CN108384457A (en) | A kind of two-component indoor wall renovation agent and its preparation, application method | |
| CN104803639A (en) | Heat preservation and sound insulation type batten compounded with plant fiber and cement and preparation method of batten | |
| CN1417271A (en) | Oil Putty for outer wall |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20200810 Address after: Xixi section of national highway 206, Xixi village, Xichang Town, Jiedong District, Jieyang City, Guangdong Province Applicant after: Guangdong Hanhe New Material Co., Ltd Address before: 471000 Family Home No. 4 of Ludian Township Education Group, Yichuan County, Luoyang City, Henan Province Applicant before: Liu Yihui |
|
| TA01 | Transfer of patent application right | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |