CN109400101A - Metope repair materials and preparation method thereof - Google Patents
Metope repair materials and preparation method thereof Download PDFInfo
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- CN109400101A CN109400101A CN201811532270.1A CN201811532270A CN109400101A CN 109400101 A CN109400101 A CN 109400101A CN 201811532270 A CN201811532270 A CN 201811532270A CN 109400101 A CN109400101 A CN 109400101A
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- metope
- loess
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/14—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing calcium sulfate cements
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
- C04B2111/2038—Resistance against physical degradation
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/72—Repairing or restoring existing buildings or building materials
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
Abstract
The present invention relates to the field of building materials, and in particular to a kind of metope repair materials and preparation method thereof.Its available Analysis of Loess Cave Dwellings reparation of metope repair materials, in parts by weight comprising 360-540 parts of sticky rice syrups, 100-150 parts of silicon ashes, 100-200 parts of quick limes, 200-300 parts of semi-hydrated gypsums, 500-600 parts of cave dwellings original sample soil, 1-4 parts of fibrous materials and 10-18 parts of water-reducing agents to be repaired.Its bridging structure filled or formed to loess intergranular space is attached loess particle, it is cementing inside enhancing, the problem of improving the gap structure of the inside of natural loess and easily corroding, then it solves the strong water suction of loess and meets the characteristic that water is fallen, and promote the ability of cave dwelling freeze thawing resistance, weathering resistance, anti-drying and watering cycle.
Description
Technical field
The present invention relates to the field of building materials, and in particular to a kind of metope repair materials and preparation method thereof.
Background technique
With North Shaanxi afforestation, the implementation for the policy conceded the land to forestry, apparent variation, year occur for the environment of northern Shensi
Average rainfall increases, and mostly occurs heavy rainfall in the flood season of 7-Septembers.The change of amblent air temperature make some loess building by
It destroys, Analysis of Loess Cave Dwellings is made around cave dwelling in loess body as the typical case that loess building is destroyed due to the increase of average annual rainfall
The increase of moisture content, meanwhile, the process of inside soil body moisture loss causes wall internal moisture constantly into Analysis of Loess Cave Dwellings
Metope migration, this by the corrosion of the binding material between causing loess metope soil particle, so as to cause metope shortcakeization, fall off, rouse
The generation of phenomena such as packet, crackle.Metope on the outside of cave dwelling, then suffer from continuous weathering, wind erosion and Frozen-thawed cycled repeatedly and
Bring is destroyed under the collective effects such as drying and watering cycle, ultimately causes the dusting of wall face, phenomena such as wall skin falls off.
The principle for repairing Analysis of Loess Cave Dwellings metope is to ensure that the concordance for repairing metope and ambient enviroment and without cement etc.
On the basis of modern architecture material, making full use of loess is that main material carries out reparation to cave dwelling metope, with reach repair it is old such as
Old purpose.And mixing and stirring by using powder of lacquer putty for use on and loess at present, the reparation to Analysis of Loess Cave Dwellings is carried out, the bonding group in putty
Point primarily serve it is cementing between bonding wall and soil particle, it is therein viscous but in the water suction and dehydration process of metope repeatedly
Knot component constantly expand, shrink, finally lose the characteristic of bonding, resist moisture erosiveness and weatherability compared with
Difference does not ensure that the durability for repairing metope.The reparation of loess Architecture site metope lacks a kind of reparation material of ecological, environmental protective
Material, can guarantee repair area and ambient enviroment harmony, and have good gas permeability on the basis of possess stronger water resistant
It corrodes, ageing resistance.
Research at present about Analysis of Loess Cave Dwellings metope reparation is less, lacks practicable repair materials to protect loess kiln
Hole ruins.
Summary of the invention
The purpose of the present invention is to provide a kind of metope repair materials, can not only fill in loess intergranular space
And connection, and improve the gap structure and density problem of the inside of natural loess, to solve loess strong water suction and chance
The characteristic that water is fallen.In addition, improving the ability of freeze thawing resistance, weathering resistance, anti-drying and watering cycle.
Another object of the present invention is to provide a kind of preparation method of metope repair materials, method is easy to operate, anti-
Mild condition is answered, metope repair materials can quickly be prepared.
The present invention solves its technical problem and adopts the following technical solutions to realize:
The present invention proposes a kind of metope repair materials, Analysis of Loess Cave Dwellings reparation can be used, in parts by weight comprising 360-
540 parts of sticky rice syrups, 100-150 parts of silicon ashes, 100-200 parts of quick limes, 200-300 parts of semi-hydrated gypsums, 500-600 parts it is to be repaired
Cave dwelling original sample soil, 1-4 parts of fibrous materials and 10-18 parts of water-reducing agents.
The present invention proposes a kind of preparation method of metope repair materials, comprising the following steps: by sticky rice syrup, silicon ash, raw stone
Soil and water-reducing agent are mixed to form metope repair materials as former state for ash, semi-hydrated gypsum, fibrous material, cave dwelling to be repaired.
The beneficial effects of the present invention are: metope repair materials of the invention pass through 360-540 parts of sticky rice syrups, 100-150 parts
Silicon ash, 100-200 part quick lime, 200-300 parts of semi-hydrated gypsums, 500-600 parts of cave dwellings original sample soil to be repaired, 1-4 parts of fibers
Material and 10-18 parts of water-reducing agents mutually act synergistically, and loess can be bonded on matrix well, while metope repair materials
Carburizing reagent occurs and generates calcium carbonate crystal to the filling of loess intergranular space or the bridging structure formed to the progress of loess particle
The problem of connection enhances the cementing of inside, improves the gap structure of the inside of natural loess and easily corrodes, it is strong then to solve loess
Water suction and meet the characteristic fallen of water, and promote the ability of cave dwelling freeze thawing resistance, weathering resistance, anti-drying and watering cycle.
Detailed description of the invention
It in order to more clearly explain the embodiment of the invention or the technical proposal in the existing technology, below will be to institute in embodiment
Attached drawing to be used is needed to be briefly described.
Fig. 1 be embodiment 1 reparation before Analysis of Loess Cave Dwellings structure chart;
Fig. 2 be embodiment 1 reparation after Analysis of Loess Cave Dwellings structure chart.
Specific embodiment
It in order to make the object, technical scheme and advantages of the embodiment of the invention clearer, below will be in the embodiment of the present invention
Technical solution be clearly and completely described.The person that is not specified actual conditions in embodiment, according to normal conditions or manufacturer builds
The condition of view carries out.Reagents or instruments used without specified manufacturer is the conventional production that can be obtained by commercially available purchase
Product.
In the description of the present invention, it should be noted that term " first ", " second " etc. are only used for distinguishing description, without
It can be interpreted as indication or suggestion relative importance.
Below to the metope repair materials of the embodiment of the present invention, preparation method and the work for repairing the impaired metope of Analysis of Loess Cave Dwellings
Skill is specifically described.
The embodiment of the present invention provides a kind of metope repair materials, can be used for Analysis of Loess Cave Dwellings reparation, and generally current existing
Match, can then guarantee its repairing effect.Specifically, in parts by weight comprising 360-540 parts of sticky rice syrups, 100-150 parts of silicon
Ash, 100-200 parts of quick limes, 200-300 parts of semi-hydrated gypsums, 500-600 parts of cave dwellings original sample soil to be repaired, 1-4 parts of undulation degrees
Material and 10-18 parts of water-reducing agents.Or in parts by weight comprising 400-450 parts of sticky rice syrups, 120-130 parts of silicon ashes, 120-150
Part quick lime, 250-280 parts of semi-hydrated gypsums, 550-570 parts of cave dwellings original sample soil to be repaired, 2-3 parts of fibrous materials and 13-15 parts
Water-reducing agent.
It can guarantee that metope repair materials have good intensity and glue by the synergistic effect between above-mentioned each substance
Knot effect, and the calcium carbonate crystal for guaranteeing that the carbonization of metope repair materials itself generates can be filled in loess intergranular space,
Or the bridging structure formed is attached loess particle, enhances the cementing of inside, then improves the sky of the inside of natural loess
Gap structure and easy erosion problem to solve the strong water suction of loess and meet the characteristic that water is fallen, and can be improved further
Freeze thawing resistance, salt resistance invade, the ability of anti-drying and watering cycle.
Further, the base-material used for cave dwelling to be repaired soil, such as loess etc. as former state, can guarantee restoring area with
Difference between non-restoring area is small, guarantees repairing effect.
Further, cave dwelling original sample soil's water content to be repaired is 8-12%, controls cave dwelling original sample soil to be repaired
Water content is conducive to improve mobility and intensity of metope repair materials etc., then guarantees repairing effect.
Further, sticky rice syrup is the sticky rice syrup that mass percentage concentration is 2-3%.Using the glutinous rice of the mass percentage concentration
Slurry can guarantee that sticky rice syrup can mutually act synergistically with substances such as quick lime, semi-hydrated gypsums well, then regulate and control well
Calcium carbonate crystal growth.If sticky rice syrup concentration is too low, causes the metope repair materials of preparation excessively dilute, then lead to its adhesive property
And strength reduction, silicon ash etc. cannot be acted on fully with sticky rice syrup, then lead to solidified earth reduced performance.If excessive concentration,
Cause moisture content too low, be then unfavorable for reacting with quick lime, be unfavorable for each material and be uniformly mixed, then influences metope and repair
The repairing effect of multiple material.
Further, the moisture in quick lime and sticky rice syrup reacts, and generates white lime, and issues a large amount of heat, makes
Sticky rice syrup be further gelatinized so that sticky rice syrup strand be fully extended, the hydroxyl carried on starch branch is sufficiently sudden and violent
Dew then promotes the performance of the arrangement of hydroxyl regulation calcium carbonate crystal, growth in starch branch in metope repair materials.
And carburizing reagent occurs under the action of moisture and air for the white lime generated, the calcium carbonate for generating hexagonal structure is brilliant
Body, production quantity is related with the degree that carburizing reagent carries out, and under normal circumstances, the height of carbonizing degree depends on hydrogen-oxygen in system
Change the saturation ion concentration of calcium and enters the carbon dioxide content in system.Carburizing reagent is a slow process, longer
It could be completed in time, therefore calcium carbonate crystal is mainly to provide the later strength of solidified earth.In carbonation reaction, early period
Hydroxyl in starch branch provides binding site for the growth of calcium carbonate, plays the role of biological template, regulates and controls the anti-of carbonization
Process is answered, arrangement, the direction, crystal form of calcium carbonate crystal are controlled.The calcium carbonate crystal of generation can bond loess particle
And the gap between filler particles, the density in loess metope is promoted, improves its internal gap structure, it is strong to solve loess
Water suction and meet the characteristic fallen of water, and be able to ascend its water resistant and corrode and the ability of freeze thawing resistance.
Water loss is big when further, due to quick lime and reaction of moisture, and temperature is excessively high, and therefore, it is necessary to control it to add
Dosage, if quick lime additive amount is excessive, the metope repair materials poor fluidity being prepared, and each material is easy mixing not
Uniformly, then lead to its adhesive property and solidified earth strength reduction.
Further, semi-hydrated gypsum and sticky rice syrup interaction, to provide early strength, and it is anti-for the carbonization of white lime
Stable environment should be provided, the intensity and durability for solidifying the soil body are increased.Specifically, semi-hydrated gypsum can be reacted with water
The dihydrate gypsum of monoclinic system is generated, and is hardened in a relatively short period of time, it is strong mainly to provide early period for the solidification soil body
Degree, stable environment is provided for carbonisation, and can further promote the weathering resistance of loess wall and the ability of dry and wet.
The semi-hydrated gypsum used is 2CaSO4·H2O, also referred to as bassanite, crystal is in micro-needle shape, like gypsum illusion,
It is colourless or white in bulk, streak white, like glassy lustre.
And silicon ash can then fill hole in solidified earth body, further promote the intensity for solidifying the soil body.Specifically, sticky rice syrup
Solidify in the soil body that there are certain holes with the formation such as semi-hydrated gypsum, quick lime and white lime, be unfavorable for the stabilization of solidified earth,
And silicon ash is then able to enter hole, substantially reduces the pore-size of solidified earth, improves compactness, and then improves and solidify the soil body
Intensity.Meanwhile silicon ash can also be filled the gap between loess, further promote the density of loess metope.
And water-reducing agent is able to ascend the mobility of metope repair materials, controls the shrinkage etc. of metope repair materials.Pass through
Above-mentioned substance and aforementioned proportion can guarantee that the sticky rice syrup being prepared is capable of forming that intensity height, resistance to erosion, barrier properties are good to be consolidated
Change the soil body, then impaired metope is repaired well.The embodiment of the present invention uses water-reducing agent for routine in the prior art
Water-reducing agent.
Further, fibrous material can prevent metope from cracking after repair, can reduce loess metope and fall off, so that repairing
Complex has tensile strength well, and can further improve the hole between loess particle and closely knit problem.
Further, fibrous material is plant fiber, it is preferable that for any one in hemp cut, shredded coconut meat and wheat straw.Using upper
The effect that plant fiber can be further ensured that fiber is stated, linkage function well is played, prevents wall crazing.
Further, the length of fibrous material is 1-2 centimetres.The length of control fibrous material can be further ensured that fiber
The mixed effect of material and each substance, and guarantee that fibrous material can give full play to its effect, if fiber is too short or too long equal
It will lead to repairing effect reduction.
The present invention also provides a kind of preparation methods of metope repair materials, comprising the following steps:
By sticky rice syrup, silicon ash, quick lime, semi-hydrated gypsum, fibrous material, cave dwelling to be repaired, soil and water-reducing agent are mixed as former state
To form metope repair materials.
Specifically: firstly, preparing sticky rice syrup: glutinous rice flour and water being carried out pre-gelatinized, the time of pre-gelatinized is 60-90 points
Clock, the temperature of pre-gelatinized are 80-90 DEG C.It can guarantee that glutinous rice and water are sufficiently gelatinized using the temperature and time of above-mentioned pre-gelatinized
To sticky rice syrup, avoiding glutinous rice from being gelatinized insufficient or gelatinization excessively leads to the destructurized of sticky rice syrup.And in pre-gelatinized
Need to be continuously agitated in the process and guaranteed water level it is constant, the reunion of glutinous rice flour is avoided, conducive to the abundant gelatinization of glutinous rice starch.
Sticky rice syrup is then cooled to 20-30 DEG C, then guarantee sticky rice syrup can well with lime, gypsum, to be repaired
The substances such as cave dwelling original sample soil be sufficiently mixed, reduce the moisture loss in whipping process.
After being then stirred the above-mentioned sticky rice syrup being prepared and silicon ash and the cave dwelling original sample soil to be repaired
The first mixture arrived forms viscous paste, and the time of stirring is 1-2 minutes, mixing speed 500-600rad/min, first will
Above-mentioned substance is mixed, and prevents subsequent sticky rice syrup from reacting with quick lime, consumes excessive moisture, is then easy to cause each material
Mixing is uneven, therefore, guarantees the mixed uniformity to mixing is carried out, then guarantees the performance of metope repair materials.
Then successively mixed again with the quick lime, the semi-hydrated gypsum and the water-reducing agent in the first mixture.Using
Above-mentioned order by merging can guarantee the interaction of the substances such as sticky rice syrup and quick lime and semi-hydrated gypsum, then guarantee metope reparation
The repairing performance of material.It will lead to metope repair materials poor fluidity, the consolidating strength of preparation if having changed order by merging
It is low, cohesive force poor the problems such as poor to gap filling effect.
Specifically, the first mixture and the quick lime are with the mixing speed hybrid reaction 1-2 of 500-600rad/min points
Zhong Houzai was with identical mixing speed and semi-hydrated gypsum hybrid reaction 1-2 minutes, and finally and water-reducing agent is with 500-600rad/min
Mixing speed hybrid reaction 2-4 minutes.
Thick slurry material and the fibrous material are finally mixed to form the repair materials i.e. metope repair materials, finally added again
Add fibrous material, can guarantee that fibrous material plays its effect, guarantees that wall is not easy to crack.
Feature and performance of the invention are described in further detail with reference to embodiments.
Embodiment 1
The present embodiment provides a kind of metope repair materials comprising 360 parts of sticky rice syrup, 205 parts of semi-hydrated gypsum, 133
Quick lime, 150 parts of wollastonite in powder, 13 parts of water-reducing agent, cave dwelling original sample native 555 parts and 4 parts of fibrous materials to be repaired of part.Its
In, the cave dwelling to be repaired loess that native moisture content is 10% as former state, fibrous material is hemp cut fiber, and length is 2 centimetres, sticky rice syrup
Mass percentage concentration be 2.5%.
The present embodiment provides a kind of preparation methods of metope repair materials:
Pre-gelatinized is carried out firstly, glutinous rice flour and water are mixed according to the ratio that mass ratio is 39:1, the time of pre-gelatinized is
20 minutes, the temperature of pre-gelatinized was 90 DEG C.Then obtained slurries are cooled down, so that the temperature of sticky rice syrup is 20 DEG C.
First obtained after then the loess of the sticky rice syrup being prepared and silicon ash and moisture content 10% is stirred mixes
Close object, time of stirring be 1 minute, mixing speed 500rad/min, then the first mixture and the quick lime with
Again with identical mixing speed and semi-hydrated gypsum hybrid reaction 1 minute behind mixing speed hybrid reaction 1 minute of 500rad/min,
Then with water-reducing agent with mixing speed hybrid reaction 1 minute of 500rad/min, finally with hemp cut fiber with 500rad/min's
Mixing speed hybrid reaction 2 minutes, finally obtain above-mentioned metope repair materials.
The Analysis of Loess Cave Dwellings of North Shaanxi is repaired using the metope repair materials of embodiment 1, preprosthetic structure ginseng
See Fig. 1, then by the metope repair materials of embodiment 1 pour with area to be repaired, repaired, repair result referring to fig. 2.
Embodiment 2-6
The metope repair materials that embodiment 2-6 is provided and the metope repair materials ingredient that embodiment 1 provides are almost the same, area
It is not that the proportion of each raw material is different, what the preparation method and embodiment 1 for the metope repair materials that embodiment 2-6 is provided provided
The preparation method of metope repair materials is almost the same, and difference is that specific operating condition changes.
Embodiment 2
Metope repair materials include 360 parts of sticky rice syrups, 100 parts of silicon ashes, 100 parts of quick limes, 200 parts of semi-hydrated gypsums, 500 parts
Cave dwelling original sample soil, 1 part of fibrous material and 10 parts of water-reducing agents to be repaired.Wherein, cave dwelling to be repaired is native as former state is for moisture content
8% loess, the mass percentage concentration of sticky rice syrup are 2%, and fibrous material is shredded coconut meat, and length is 1 centimetre.
Temperature is 80 DEG C when preparing sticky rice syrup, and the pre-gelatinized time is 40 minutes, and the temperature of sticky rice syrup is 30 DEG C after cooling.
Prepare the first mixture be mixing time be 2 minutes, revolving speed 600rad/min, with quick lime stirring time and
Revolving speed is followed successively by 2 minutes, 600rad/min;It is 2 minutes with the time of semi-hydrated gypsum stirring and revolving speed, 600rad/min;With subtract
The time of aqua stirring and revolving speed are 2 minutes, 600rad/min;It is 1 minute with the time of shredded coconut meat stirring and revolving speed, 600rad/
min。
Embodiment 3
Metope repair materials include 540 parts of sticky rice syrups, 150 parts of silicon ashes, 200 parts of quick limes, 300 parts of semi-hydrated gypsums, 600 parts
Cave dwelling original sample soil, 4 parts of fibrous materials and 18 parts of water-reducing agents to be repaired.Wherein, cave dwelling to be repaired is native as former state is for moisture content
12% loess, the mass percentage concentration of sticky rice syrup are 3%, and fibrous material is wheat straw, and length is 1.5 centimetres.
Temperature is 85 DEG C when preparing sticky rice syrup, and the pre-gelatinized time is 35 minutes, and the temperature of sticky rice syrup is 25 DEG C after cooling.
Prepare the first mixture be mixing time be 1.5 minutes, revolving speed 550rad/min, with quick lime stirring time
It is followed successively by 1 minute with revolving speed, 550rad/min;It is 2 minutes with the time of semi-hydrated gypsum stirring and revolving speed, 550rad/min;With
The time of water-reducing agent stirring and revolving speed are 1 minute, 550rad/min;It is 2 minutes with the time of wheat straw stirring and revolving speed,
550rad/min。
Embodiment 4
Metope repair materials include 400 parts of sticky rice syrups, 130 parts of silicon ashes, 150 parts of quick limes, 280 parts of semi-hydrated gypsums, 550 parts
Cave dwelling original sample soil, 2 parts of fibrous materials and 13 parts of water-reducing agents to be repaired.Wherein, cave dwelling to be repaired is native as former state is for moisture content
11% loess, the mass percentage concentration of sticky rice syrup are 2.7%, and fibrous material is shredded coconut meat, and length is 1.2 centimetres.
Temperature is 87 DEG C when preparing sticky rice syrup, and the pre-gelatinized time is 25 minutes, and the temperature of sticky rice syrup is 22 DEG C after cooling.
Prepare the first mixture be mixing time be 2 minutes, revolving speed 520rad/min, with quick lime stirring time and
Revolving speed is followed successively by 2 minutes, 520rad/min;It is 2 minutes with the time of semi-hydrated gypsum stirring and revolving speed, 520rad/min;With subtract
The time of aqua stirring and revolving speed are 1 minute, 520rad/min;It is 2 minutes with the time of shredded coconut meat stirring and revolving speed, 520rad/
min。
Embodiment 5
Metope repair materials include 450 parts of sticky rice syrups, 150 parts of silicon ashes, 120 parts of quick limes, 250 parts of semi-hydrated gypsums, 570 parts
Cave dwelling original sample soil, 3 parts of fibrous materials and 15 parts of water-reducing agents to be repaired.Wherein, cave dwelling to be repaired is native as former state is for moisture content
9% loess, the mass percentage concentration of sticky rice syrup are 2.3%, and fibrous material is wheat straw, and length is 1.7 centimetres.
Temperature is 84 DEG C when preparing sticky rice syrup, and the pre-gelatinized time is 32 minutes, and the temperature of sticky rice syrup is 26 DEG C after cooling.
Prepare the first mixture be mixing time be 1.5 minutes, revolving speed 570rad/min, with quick lime stirring time
1.5 minutes are followed successively by with revolving speed, 570rad/min;With the time and revolving speed 1.5 minutes of semi-hydrated gypsum stirring, 570rad/min;
It is 1.5 minutes with the time of water-reducing agent stirring and revolving speed, 570rad/min;It is 1.5 minutes with the time of wheat straw stirring and revolving speed,
570rad/min。
Embodiment 6
Metope repair materials include 500 parts of sticky rice syrups, 140 parts of silicon ashes, 170 parts of quick limes, 220 parts of semi-hydrated gypsums, 525 parts
Cave dwelling original sample soil, 2.5 parts of fibrous materials and 14 parts of water-reducing agents to be repaired.Wherein, soil is moisture content to cave dwelling to be repaired as former state
For 8.5% loess, the mass percentage concentration of sticky rice syrup is 2.3%, and fibrous material is hemp cut, and length is 1.7 centimetres.
Temperature is 82 DEG C when preparing sticky rice syrup, and the pre-gelatinized time is 28 minutes, and the temperature of sticky rice syrup is 27 DEG C after cooling.
Prepare the first mixture be mixing time be 1 minute, revolving speed 530rad/min, with quick lime stirring time and
Revolving speed is followed successively by 1 minute, 530rad/min;With the time and revolving speed 1 minute of semi-hydrated gypsum stirring, 530rad/min;With diminishing
The time of agent stirring and revolving speed are 1 minute, 530rad/min;It is 1 minute with the time of hemp cut stirring and revolving speed, 530rad/
min。
Comparative example 1: metope repair materials are prepared according to the preparation method that embodiment 1 provides, difference is to replace quick lime
It is changed to the white lime of equivalent.
Comparative example 2: metope repair materials are prepared according to the preparation method that embodiment 1 provides, difference is to be formulated are as follows: 360
Part sticky rice syrup, 205 parts of semi-hydrated gypsum, 283 parts of quick lime, 13 parts of water-reducing agent, cave dwelling to be repaired as former state 555 parts of soil and
4 parts of fibrous materials.
Comparative example 3: metope repair materials are prepared according to the preparation method that embodiment 1 provides, difference is to be formulated are as follows: 360
Part sticky rice syrup, 308 parts of quick lime, 150 parts of wollastonite in powder, 13 parts of water-reducing agent, cave dwelling to be repaired as former state 555 parts of soil and
4 parts of fibrous materials.
Comparative example 4: metope repair materials are prepared according to the preparation method that embodiment 1 provides, difference is to be formulated are as follows: 360
The sticky rice syrup, 205 parts of semi-hydrated gypsum, 283 parts of wollastonite in powder, 13 parts of water-reducing agent, cave dwelling to be repaired of part are 555 parts native as former state
With 4 parts of fibrous materials.
Comparative example 5: metope repair materials are prepared according to the preparation method that embodiment 1 provides, difference is to be formulated are as follows: 360
Part sticky rice syrup, 205 parts of semi-hydrated gypsum, 133 parts of quick lime, 154 parts of wollastonite in powder, 13 parts of water-reducing agent, to be repaired
Cave dwelling is 555 parts native as former state.
Comparative example 6 prepares metope repair materials according to the preparation method that embodiment 1 provides, and difference is glutinous rice directly
Soil, quick lime, white lime, semi-hydrated gypsum and water-reducing agent disposably directly mix as former state for slurry, silicon ash, cave dwelling to be repaired.
It takes the metope repair materials of same amount of embodiment 1-6 and comparative example 1-6 to be detected, detects metope repair materials
Water imbibition and immersion under the conditions of mass loss rate and freeze thawing resistance circulation, the detection of specific water imbibition referring to test method one,
The detection that the detection of mass loss under the conditions of immersion is recycled referring to test method two, freeze thawing resistance is referring to test method three, specifically
Testing result is referring to table 1.
Test method one: water imbibition test, the sample of 28d curing age are put into electric drying oven with forced convection, are dried to perseverance
Weight (drying temperature is 80 DEG C), the sample of drying, which is placed in drier, is cooled to room temperature, tests the sample unit matter of different moments
Measure water absorption rate.The unit mass water absorption rate of sample is calculated as follows
Wherein WrFor water absorption rate, %;moFor the quality of sample drying to constant weight, g;mtMatter at the time of for sample after water suction
Amount, g.
Test method two: specimen size is φ 61.8mm × 20mm, and maintenance is soaked to specified age under the conditions of standard curing
In soaked, 90d impregnate after dry, measure sample with the mass loss situation under soaking conditions.Collapsing for sample is calculated as follows
Solve mass loss rate
Wherein Δ w is mass change amount, g;w0For the initial mass after each sample drying, g;D is mass loss
Rate, %.
Test method three: the influence for simulation freeze thawing to solidified earth as coating material detects the freeze thawing resistance energy of solidified earth
Power pours into the slurries being stirred in φ 120mm × 5mm die trial, conserve for 24 hours under the dry condition after, with wax to sample with
Annular gap between die trial blocks, and then moves under the conditions of standard curing and is conserved, is carried out to the sample of maintenance 28d age
Freezing-thawing test.First by sample drying before freeze thawing, each Frozen-thawed cycled by freeze under conditions of full water 18h, -20 ± 2 DEG C 3h, 50 DEG C ±
3h composition is dried in 2 DEG C of baking oven.Different ratio is recorded, specimen surface generates the freezing-thawing cycles of large area stripping damage.
1 testing result of table
According to table 1, by quality water absorption rate characterize metope repair materials water imbibition, sticky rice syrup dosage, quick lime,
Gypsum, fibers content and length can influence the water imbibition of metope repair materials, and wherein quick lime influences water absorption rate maximum,
The incorporation of fiber improves the water absorption rate of metope repair materials.
According to table 1, by characterizing the water stability of metope repair materials to the mass loss rate under the conditions of immersion, wherein
Lime is maximum to the mass loss rate of material, and adding of fiber can effectively improve the structural stability of metope repair materials, subtract
Mass loss under the conditions of few immersion.
According to table 1, by the test to freezing-thawing cycles, it is resistance to seasonal temperature variation that metope repair materials are characterized
Long property, wherein quick lime, gypsum all larger impacts metope repair materials freeze thawing resistance circulation, the addition of plant fiber can be effective
Destruction of the reduction Frozen-thawed cycled to metope repair materials.
According to table 1, silicon ash, which adds, largely affects the water absorption rates of metope repair materials, the incorporation of silicon ash compared with
No silicon ash admixture reduces metope repair materials interior porosity, thereby reduces water absorption rate.Though the admixture sequence of material component
It is so smaller for the mass loss rate under the conditions of the water absorption rate of metope repair materials, immersion, the influence of freeze thawing resistance cycle-index, still
Spike sequence will affect the mobility of metope repair materials.
In conclusion metope repair materials of the invention pass through 360-540 parts of sticky rice syrups, 100-150 parts of silicon ashes, 100-
200 parts of quick limes, 200-300 parts of semi-hydrated gypsums, 500-600 parts of cave dwellings original sample soil, 1-4 parts of fibrous materials and 10- to be repaired
18 parts of water-reducing agents mutually act synergistically, can well by by loess bonding with matrix on, while metope repair materials occur carbon
Change the bridging structure that reaction generation calcium carbonate crystal is filled loess intergranular space or formed to be attached loess particle, increase
The problem of inside is cementing by force, improves the gap structure of the inside of natural loess and easily corrodes, the then strong water suction of solution loess
The characteristic fallen with chance water, and promote the ability of cave dwelling freeze thawing resistance, weathering resistance, anti-drying and watering cycle.
Embodiments described above is a part of the embodiment of the present invention, instead of all the embodiments.Reality of the invention
The detailed description for applying example is not intended to limit the range of claimed invention, but is merely representative of selected implementation of the invention
Example.Based on the embodiments of the present invention, obtained by those of ordinary skill in the art without making creative efforts
Every other embodiment, shall fall within the protection scope of the present invention.
Claims (10)
1. a kind of metope repair materials, which is characterized in that it can be used for Analysis of Loess Cave Dwellings metope reparation, in parts by weight comprising
360-540 parts of sticky rice syrups, 100-150 parts of silicon ashes, 100-200 parts of quick limes, 200-300 parts of semi-hydrated gypsums, 500-600 parts it is to be repaired
Multiple cave dwelling original sample soil, 1-4 parts of fibrous materials and 10-18 parts of water-reducing agents.
2. metope repair materials according to claim 1, which is characterized in that in parts by weight comprising 400-450 parts of institutes
State sticky rice syrup, the 120-130 parts of silicon ashes, the 120-150 parts of quick limes, 250-280 parts of semi-hydrated gypsums, 550-570
Part cave dwelling original sample soil, the 2-3 parts of fibrous materials and the 13-15 parts of water-reducing agents to be repaired.
3. metope repair materials according to claim 1 or 2, which is characterized in that the sticky rice syrup is mass percentage concentration
For the sticky rice syrup of 2-3%.
4. metope repair materials according to claim 1 or 2, which is characterized in that the length of the fibrous material is 1-2 lis
Rice.
5. metope repair materials according to claim 1 or 2, which is characterized in that the cave dwelling original sample soil to be repaired
Moisture content is 8-12%.
6. metope repair materials according to claim 1 or 2, which is characterized in that the fibrous material is plant fiber, excellent
Choosing, for any one in hemp cut, shredded coconut meat and wheat straw.
7. a kind of preparation method of metope repair materials described in claim 1, which comprises the following steps:
By sticky rice syrup, silicon ash, quick lime, semi-hydrated gypsum, fibrous material, cave dwelling to be repaired, soil and water-reducing agent are mixed with shape as former state
At metope repair materials.
8. preparation method according to claim 7, which is characterized in that the metope repair materials be by the sticky rice syrup,
The silicon ash and the cave dwelling original sample soil to be repaired are mixed to form the first mixture;Then first mixture is successively
Viscous paste is formed after mixing with the quick lime, the semi-hydrated gypsum and the water-reducing agent;Then by the viscous paste with
The fibrous material is mixed to form repair materials.
9. preparation method according to claim 7 or 8, which is characterized in that the sticky rice syrup is by glutinous rice flour and water in 80-
It is stirred 60-90 minutes under conditions of 90 DEG C.
10. preparation method according to claim 8, which is characterized in that first mixture be by the sticky rice syrup with
The silicon ash stirred 1-2 minute according to 500-600 revs/min of condition after again with the cave dwelling to be repaired as former state it is native according to
The mixture that 500-600 revs/min of condition obtains after stirring 1-2 minutes.
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
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CN110510925A (en) * | 2019-09-21 | 2019-11-29 | 安徽宜邦生物质科技有限公司 | A kind of plant fiber and its moulding process of waterproof fireproofing Anti-moth-eating |
CN111398568A (en) * | 2020-04-23 | 2020-07-10 | 六盘水师范学院 | Solid-liquid coupling physical similarity simulation material for coal seam mining and use method thereof |
CN112608755A (en) * | 2020-12-09 | 2021-04-06 | 中建三局集团有限公司 | Composite shrinkage reducing agent suitable for high-flow collapsible loess and application thereof |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN105084848A (en) * | 2015-08-14 | 2015-11-25 | 武汉理工大学 | Repairing material for weathering ganged brick |
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2018
- 2018-12-14 CN CN201811532270.1A patent/CN109400101B/en active Active
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Publication number | Priority date | Publication date | Assignee | Title |
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CN105084848A (en) * | 2015-08-14 | 2015-11-25 | 武汉理工大学 | Repairing material for weathering ganged brick |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110510925A (en) * | 2019-09-21 | 2019-11-29 | 安徽宜邦生物质科技有限公司 | A kind of plant fiber and its moulding process of waterproof fireproofing Anti-moth-eating |
CN111398568A (en) * | 2020-04-23 | 2020-07-10 | 六盘水师范学院 | Solid-liquid coupling physical similarity simulation material for coal seam mining and use method thereof |
CN112608755A (en) * | 2020-12-09 | 2021-04-06 | 中建三局集团有限公司 | Composite shrinkage reducing agent suitable for high-flow collapsible loess and application thereof |
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