CN109333762A - A kind of manufacturing method of reduced stone color, clear patterns natural marble stone ceramic tile - Google Patents

A kind of manufacturing method of reduced stone color, clear patterns natural marble stone ceramic tile Download PDF

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Publication number
CN109333762A
CN109333762A CN201811181631.2A CN201811181631A CN109333762A CN 109333762 A CN109333762 A CN 109333762A CN 201811181631 A CN201811181631 A CN 201811181631A CN 109333762 A CN109333762 A CN 109333762A
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China
Prior art keywords
stone
ceramic tile
manufacturing
ink
natural marble
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Pending
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CN201811181631.2A
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Chinese (zh)
Inventor
梁胜远
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GUANGDONG GRIFINE CERAMIC CO Ltd
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GUANGDONG GRIFINE CERAMIC CO Ltd
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Priority to CN201811181631.2A priority Critical patent/CN109333762A/en
Publication of CN109333762A publication Critical patent/CN109333762A/en
Pending legal-status Critical Current

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B28WORKING CEMENT, CLAY, OR STONE
    • B28BSHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28B3/00Producing shaped articles from the material by using presses; Presses specially adapted therefor
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B28WORKING CEMENT, CLAY, OR STONE
    • B28BSHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28B11/00Apparatus or processes for treating or working the shaped or preshaped articles
    • B28B11/04Apparatus or processes for treating or working the shaped or preshaped articles for coating or applying engobing layers
    • B28B11/048Apparatus or processes for treating or working the shaped or preshaped articles for coating or applying engobing layers by spraying or projecting
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B28WORKING CEMENT, CLAY, OR STONE
    • B28BSHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28B11/00Apparatus or processes for treating or working the shaped or preshaped articles
    • B28B11/24Apparatus or processes for treating or working the shaped or preshaped articles for curing, setting or hardening
    • B28B11/243Setting, e.g. drying, dehydrating or firing ceramic articles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00Duplicating or marking methods; Sheet materials for use therein
    • B41M5/0041Digital printing on surfaces other than ordinary paper
    • B41M5/007Digital printing on surfaces other than ordinary paper on glass, ceramic, tiles, concrete, stones, etc.
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B44DECORATIVE ARTS
    • B44FSPECIAL DESIGNS OR PICTURES
    • B44F9/00Designs imitating natural patterns
    • B44F9/04Designs imitating natural patterns of stone surfaces, e.g. marble
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/01Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
    • C04B35/14Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on silica
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Ceramic Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Structural Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Finishing Walls (AREA)

Abstract

A kind of manufacturing method of reduced stone color, clear patterns natural marble stone ceramic tile, sorting → ingredient → ball milling → mixes colours → and powder → cloth compacting → drying → leaching glaze → ink-jet processed adds screen printing → firing → polishing → pick → to pack → put in storage;Micro- (receiving) the rice nonpolluting coating technique of spraying is added between cloth pressing process and drying process;Cloth pressing process: powder is broken → and the straight material of full-automatic computer control panel → lines micro mist cloth falls within mold → base-material (12 pipeline) cloth → compression moulding;Stamp ink-jetting process: the too small drying → scraping of at least 13 stamps crosses brick prime cement → firing at least after 3 stamps → ink-jet style, one stone multi-panel (9 faces) → ink-jet before ink-jet;Primary raw material weight percent: soft-paste mountain flour 10~15%;Medium temperature porcelain sand 10~20%;Pate dure sand 9~18%;Wash black mud 10~15%;Sodium mountain flour 10~15%;Alumina porcelain sand 5~10%;Sodium porcelain sand 10~20%;Ball clay 5~18%;Degumming agent 0.5~1%;Colorant 0.5~1.5%.Layer depth is permeated in the present invention, 720DP high definition is differentiated, and texture is true to nature, natural.

Description

A kind of manufacturing method of reduced stone color, clear patterns natural marble stone ceramic tile
Technical field
The present invention relates to a kind of manufacturing method of ceramic polished brick, in particular to a kind of reduced stone color, clear patterns The manufacturing method of natural marble stone ceramic tile.
Background technique
Occur a kind of parian entire body Ceramic Tiles in the prior art comprising entire body adobe layer and charity are in all-body tile Cover coat on base layer, the entire body adobe layer include according to the weight percentage of raw materials 22~40% potassium sand, 15~30% Potassium albite, 10~20% potassium feldspar, 10~22% black mud, 2~10% kaolin, 2~6% bentonite, 1~ 4% life talcum, 2~10% colorant;Closely the potassium sodium including 30~60% is long according to the weight percentage of raw materials for the cover coat Stone, 15~30% kaolin, 5~10% wollastonite, 5~10% aluminium oxide, 2~8% talcum, 2~10% oxygen Change the calcium carbonate of zinc, 10~20%.The ceramic tile solves the problems, such as that entire body Ceramic Tiles are dysoxidizable on firing process, can prepare Thickness is greater than 1cm entire body Ceramic Tiles out, and the entire body Ceramic Tiles oxidation susceptibility is good, and middle layer is less prone to pin hole, black line, bubble etc. Phenomenon, while by adjusting overglaze component and proportion, it solves entire body Ceramic Tiles overglaze texture and is unable to reach natural marble The problem of surface tactile sensation, so that the entire body ceramic brick surface texture is closer to natural marble.
The prior art has also appeared a kind of manufacturing method of three-dimensional entire body texture ceramic tile, comprising steps of A: according to selection Natural marble stone obtains multiple ceramic tile design drawings;B: according to the ceramic tile design drawing of selection, preparation is used for green body layer cloth The location grid of material and silk screen group for glaze paint stamp;C: cloth, compacting are carried out by the location grid, obtain porcelain The green body layer of brick, the green body layer include green body background area and green body pattern zone;D: by the silk screen group, in the institute suppressed The upper surface for stating green body layer carries out glaze surface treatment, obtains glazed layer;The pattern of the glazed layer and selected ceramic tile design drawing Pattern it is identical.Using the raw Dali stone ceramic tile of the manufacturing method, the texture of the decorative pattern on green body layer inside and surface, face Color, lines and level correspond, and beautiful careful, visual effect is true to nature such as stone material.
Occur a kind of high emulation entire body in the prior art and throws glaze Dali stone ceramic tile and its production method, production method packet entirely It includes step: A, reaching 45 degree or more of basic components using whiteness, above-mentioned basic components are successively carried out to ball milling, toning and do It is dry to obtain basic powder;B, feed powder material in opposite is crushed, and then carries out cloth using truck, then suppressed to obtain with press Then green body is dried;C, green body is carried out throwing base processing, then successively applies overglaze, stamp and apply throwing glaze, is re-fed into Dry kiln is dry, is then fed into calcining kiln firing;D, the semi-finished product glazed tile after kiln discharge carries out after edging and polishing treatment Sorting and storage.This method uses high whiteness raw material, improves the brightness of the hair color effect of green body glaze paint, improves pattern effect It is true to nature.This method uses distributing technique, so that blank pattern effect and glaze paint pattern effect are close, is slotted, after chamfering It is with uniformity between green body and glaze paint, extend the full application range for throwing glaze Dali stone ceramic tile.
The preparation method for having also appeared a kind of entire body Dali stone ceramic tile in the prior art belongs to artificial marble ceramic tiles preparation Technical field of improvement.This method is to combine and prepare green body dry method colour mixture technique and three-dimensional distributing technique, is applied in billet surface Then overglaze successively sprays on overglaze surface layer and peels off ink and stripping glaze, is finally fired to obtain entire body Dali stone ceramic tile.The party Method is simple, energy conservation and environmental protection, breaches the bottleneck of traditional handicraft, is widely used, the ceramic tile of preparation really reduces natural stone material Sense, overall beautiful, spatial decoration effect is more life-like, more there is texture.
A kind of entire body marble ceramic tile making method, equipment and entire body Dali stone ceramic tile, warp are also disclosed in the prior art No matter the entire body Dali stone ceramic tile for crossing this method production carries out trimming, kerve or chamfered to it, any section all embodies day Right marble grain is not in white crops for rotation and influences beauty.This method is handed over the spraying material of several colors by pre-defined rule It is laid in glass case for inclination, texture layer is made, interspersed means processing by glaze paints such as silk screen, ink-jets on texture layer and generate Decorative layer.
The production method of above-mentioned entire body Dali stone ceramic tile, process flow tradition, the entire body Dali stone ceramic tile lines produced Not clear enough, permeable formation is not deep enough, and resolution is undesirable, and glossiness is undesirable, and there are lines of demarcation with texture layer for green body layer.
Summary of the invention
It is an object of the invention to overcome the deficiencies of existing technologies, one kind is provided, natural stone texture, color is allowed to be able to Whole existing, pure color, texture be true to nature, naturally, high temperature and pressure efficiently solves 85%SiO2The free difficult point of quartz in content formula, Pioneering original stone chromophoric mechanism in green body, double promotion nanometer color development ion permeate green body colour generation, and reduced stone color, pattern are clear The manufacturing method of clear natural marble stone ceramic tile.
What the purpose of the present invention was achieved through the following technical solutions:
The manufacturing method of a kind of reduced stone color, clear patterns natural marble stone ceramic tile, the manufacturing approach craft stream Journey: sorting → ingredient → ball milling → mixes colours → powder → cloth compacting → drying → leaching glaze → ink-jet processed add screen printing → firing → Polishing → pick → is packed → is put in storage;
Spraying nano antifouling coating process is added between the cloth pressing process and drying process;
The cloth pressing process include: powder it is broken → the straight material of full-automatic computer control panel → lines micro mist cloth falls within Mold → base-material cloth → compression moulding;
The base-material distributing technique uses 12 pipeline clothes;
The stamp ink-jetting process includes: at least 3 stamps → ink-jet style, one stone multi-panel (9 faces) → ink-jet before ink-jet Too small drying → the scraping of at least 13 stamps crosses brick prime cement afterwards;
A kind of reduced stone color, clear patterns natural marble stone ceramic tile manufacturing method in ceramic tile primary raw material weight Percentage are as follows: soft-paste mountain flour 10~15%;Medium temperature porcelain sand 10~20%;Pate dure sand 9~18%;Washing black mud 10~ 15%;Sodium mountain flour 10~15%;Alumina porcelain sand 5~10%;Sodium porcelain sand 10~20%;Ball clay 5~18%;Degumming agent 0.5~ 1%;Colorant 0.5~1.5%.
The present invention by adopting the above technical scheme after can obtain following effect:
1, creative.Reduced stone color, clear patterns natural marble stone ceramic tile have the infiltration of 0.5~5mm in the present invention Layer, 720DP high definition are differentiated, and nanoparticle ink color development is more bright-coloured, 3 times of strong coloring force, especially red, meet CMYK four primary Management.There are enough conditions that more natural stone textures, color is allowed to emerge from pure color, texture true to nature, natural.High temperature and pressure Efficiently solve 85%SiO2The free difficult point of quartz in content formula, initiates original stone chromophoric mechanism in green body, double promotion nanometer Color development ion permeates green body colour generation.Wear-resisting endoplasm, the polished bricks Snow Flower White of complete vitreous are promoted using 7 grades of hardness of vitreous silica Base bottom whiteness is up to 60 degree.Surface is thought and acted in one and the same way with base bottom, and centre does not have line of demarcation, and endoplasm close structure is careful, Mohs' hardness It up to 7 grades, being handled using the soft polishing technology of Seiko porcelain, inlet module, water ripples are unobvious, and 3 grades of wear resistance.
2, good texture.Reduced stone color, clear patterns natural marble stone ceramic tile restore natural stone texture in the present invention, Surface is exquisite fine and smooth, and the transition of skin texture lines is naturally, tool lithotome sense, and pattern is fine and smooth, clear, in bright and gay colors, good texture.
3, good in economic efficiency.Product texture produced by the present invention is high-grade, adapts to now since its own has the advantage that The high demand of society, it is contemplated that profit increases by 85% than common ceramic tile, market economy remarkable benefit.
Specific embodiment
Below in conjunction with specific embodiment invention is further described in detail table 1
The manufacturing method of a kind of reduced stone color, clear patterns natural marble stone ceramic tile, the manufacturing approach craft stream Journey: sorting → ingredient → ball milling → mixes colours → powder → cloth compacting → drying → leaching glaze → ink-jet processed add screen printing → firing → Polishing → pick → is packed → is put in storage;
Spraying nano antifouling coating process is added between the cloth pressing process and drying process;
The cloth pressing process include: powder it is broken → the straight material of full-automatic computer control panel → lines micro mist cloth falls within Mold → base-material cloth → compression moulding;
The base-material distributing technique uses 12 pipeline clothes;
The stamp ink-jetting process process: at least 3 stamps → ink-jet style, one stone multi-panel (9 faces) → ink-jet before ink-jet Too small drying → the scraping of at least 13 stamps crosses brick prime cement afterwards;
A kind of reduced stone color, clear patterns natural marble stone ceramic tile manufacturing method in ceramic tile primary raw material weight Percentage are as follows: soft-paste mountain flour 10~15%;Medium temperature porcelain sand 10~20%;Pate dure sand 9~18%;Washing black mud 10~ 15%;Sodium mountain flour 10~15%;Alumina porcelain sand 5~10%;Sodium porcelain sand 10~20%;Ball clay 5~18%;Degumming agent 0.5~ 1%;Colorant 0.5~1.5%.
It can by the performance of a kind of reduced stone color, clear patterns natural marble stone ceramic tile made of above-mentioned process flow It reaches: product water absorption rate average value≤0.03%, monolithic value≤0.05%, glossiness >=90,3 grades of wear resistance, External Exposure Index 0.39, Outreach services 0.69, performance parameter ratio is better than common ceramic tile.
The prior art can be used in other Processes and apparatus of the invention.
Highly preferred embodiment of the present invention has illustrated, and those skilled in the art make further according to the present invention Expansion is each fallen among protection scope of the present invention.

Claims (9)

1. the manufacturing method of a kind of reduced stone color, clear patterns natural marble stone ceramic tile, the manufacturing approach craft process: Sorting → ingredient → ball milling → mixes colours → and powder → cloth compacting → drying → leaching glaze → ink-jet processed adds screen printing → firing → throwing Light → pick → is packed → is put in storage;It is characterized by:
Spraying nano antifouling coating process is added between the cloth pressing process and drying process;
The cloth pressing process include: powder it is broken → the straight material of full-automatic computer control panel → lines micro mist cloth falls within mold → base-material cloth → compression moulding;
The base-material distributing technique uses 12 pipeline clothes;
The stamp ink-jetting process includes: before ink-jet at least 13 times at least after 3 stamps → ink-jet style, one stone multi-panel → ink-jet Too small drying → the scraping of stamp crosses brick prime cement;
A stone multi-panel in the one stone multi-panel process of ink-jet style is 9 faces of a stone.
2. the manufacturing method of a kind of reduced stone color according to claim 1, clear patterns natural marble stone ceramic tile, Be characterized in that: a kind of reduced stone color, clear patterns natural marble stone ceramic tile manufacturing method in ceramic tile primary raw material Weight percent are as follows: soft-paste mountain flour 10~15%;Medium temperature porcelain sand 10~20%;Pate dure sand 9~18%;Wash black mud 10~15%;Sodium mountain flour 10~15%;Alumina porcelain sand 5~10%;Sodium porcelain sand 10~20%;Ball clay 5~18%;Degumming agent 0.5 ~1%;Colorant 0.5~1.5%.
3. the manufacturing method of a kind of reduced stone color according to claim 1, clear patterns natural marble stone ceramic tile, It is characterized in that: slurry biodiversity percentage in the ball milling process are as follows: base-material 35~38%, high grade of transparency material 33%~ 36%.
4. the manufacturing method of a kind of reduced stone color according to claim 1, clear patterns natural marble stone ceramic tile, It is characterized in that: powder fineness (250 mesh screen residue) weight percent in the powder miniaturization process are as follows: base-material 0.9~1.8%, High grade of transparency material is 0.1~0.8%.
5. the manufacturing method of a kind of reduced stone color according to claim 1, clear patterns natural marble stone ceramic tile, It is characterized in that: powder biodiversity percentage in the powder miniaturization process are as follows: base-material 7.8~9.5%, high grade of transparency material 5.8~7.6%.
6. the manufacturing method of a kind of reduced stone color according to claim 1, clear patterns natural marble stone ceramic tile, It is characterized in that: the compression moulding pressure: 220~310bar.
7. the manufacturing method of a kind of reduced stone color according to claim 1, clear patterns natural marble stone ceramic tile, It is characterized in that: the drying temperature: 160~260 DEG C, arid cycle: 40~60min.
8. the manufacturing method of a kind of reduced stone color according to claim 1, clear patterns natural marble stone ceramic tile, It is characterized in that: the firing temperature: 1160~1280 DEG C.
9. the manufacturing method of a kind of reduced stone color according to claim 1, clear patterns natural marble stone ceramic tile, It is characterized in that: the firing period: 60~80min.
CN201811181631.2A 2018-10-11 2018-10-11 A kind of manufacturing method of reduced stone color, clear patterns natural marble stone ceramic tile Pending CN109333762A (en)

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Application Number Priority Date Filing Date Title
CN201811181631.2A CN109333762A (en) 2018-10-11 2018-10-11 A kind of manufacturing method of reduced stone color, clear patterns natural marble stone ceramic tile

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110066163A (en) * 2019-05-24 2019-07-30 佛山市东鹏陶瓷有限公司 A kind of preparation method and the big plate of ceramics of the big plate of stone multi-panel ceramics

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101613198A (en) * 2009-07-27 2009-12-30 广东能强陶瓷有限公司 The manufacture method of a kind of color and luster, sharply marginated natural-like stone ceramic tile
CN103833332A (en) * 2014-01-11 2014-06-04 广东能强陶瓷有限公司 Manufacturing method of ceramic polished tile vividly imitating natural jade texture
CN105254279A (en) * 2015-09-30 2016-01-20 鄂尔多斯市兴辉陶瓷有限公司 Method for manufacturing ceramic tiles by utilizing desert sand and pulverized fuel ash
CN106518170A (en) * 2016-10-18 2017-03-22 蒙娜丽莎集团股份有限公司 A ceramic brick pattern penetrating method
CN107141025A (en) * 2017-07-07 2017-09-08 佛山市章氏兄弟建材有限公司 A kind of marble plating metal modelled after an antique throws the preparation method of glaze Ceramic Tiles
CN107599138A (en) * 2017-10-12 2018-01-19 清远市简陶瓷有限公司 A kind of manufacture method of three-dimensional entire body texture ceramic tile
CN107651839A (en) * 2017-10-11 2018-02-02 佛山市东鹏陶瓷有限公司 A kind of preparation of ceramic tile of stone multiaspect and laying method

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101613198A (en) * 2009-07-27 2009-12-30 广东能强陶瓷有限公司 The manufacture method of a kind of color and luster, sharply marginated natural-like stone ceramic tile
CN103833332A (en) * 2014-01-11 2014-06-04 广东能强陶瓷有限公司 Manufacturing method of ceramic polished tile vividly imitating natural jade texture
CN105254279A (en) * 2015-09-30 2016-01-20 鄂尔多斯市兴辉陶瓷有限公司 Method for manufacturing ceramic tiles by utilizing desert sand and pulverized fuel ash
CN106518170A (en) * 2016-10-18 2017-03-22 蒙娜丽莎集团股份有限公司 A ceramic brick pattern penetrating method
CN107141025A (en) * 2017-07-07 2017-09-08 佛山市章氏兄弟建材有限公司 A kind of marble plating metal modelled after an antique throws the preparation method of glaze Ceramic Tiles
CN107651839A (en) * 2017-10-11 2018-02-02 佛山市东鹏陶瓷有限公司 A kind of preparation of ceramic tile of stone multiaspect and laying method
CN107599138A (en) * 2017-10-12 2018-01-19 清远市简陶瓷有限公司 A kind of manufacture method of three-dimensional entire body texture ceramic tile

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110066163A (en) * 2019-05-24 2019-07-30 佛山市东鹏陶瓷有限公司 A kind of preparation method and the big plate of ceramics of the big plate of stone multi-panel ceramics
CN110066163B (en) * 2019-05-24 2021-08-31 佛山市东鹏陶瓷有限公司 Preparation method of stone multi-face ceramic large plate and ceramic large plate

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