CN110066163A - A kind of preparation method and the big plate of ceramics of the big plate of stone multi-panel ceramics - Google Patents
A kind of preparation method and the big plate of ceramics of the big plate of stone multi-panel ceramics Download PDFInfo
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- CN110066163A CN110066163A CN201910440748.6A CN201910440748A CN110066163A CN 110066163 A CN110066163 A CN 110066163A CN 201910440748 A CN201910440748 A CN 201910440748A CN 110066163 A CN110066163 A CN 110066163A
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Abstract
, the green body of the big plate of preparation ceramics the invention discloses the preparation methods of the one big plate of stone multi-panel ceramics of one kind, comprising the following steps: (1);(2), it is decorated in the form of inkjet printing on green body: the big figure of one width being divided into the small figure of muti-piece in the input terminal of ink-jet printer, input ink-jet printer prints on green body after the pattern edge of small figure is extended, and every piece small figure corresponds to one piece of green body;(3), kiln-firing obtains the big plate of ceramics that there is pattern texture to decorate;(4), the big plate of the ceramics being fired into is subjected to edging processing, for making the pattern of the big plate of adjacent two pieces of ceramics match.The invention also discloses the big plates of ceramics obtained by above-mentioned preparation method accordingly.After split, pattern can coincide ceramic big plate, and after the big plate of muti-piece ceramics is laid with, pattern texture can be in one or more surfaces extension, so that pattern texture is arbitrarily natural, three-dimensional sense is strong.
Description
Technical field
The present invention relates to ceramic technology field, more particularly to the preparation method and ceramics of the one big plate of stone multi-panel ceramics of one kind are big
Plate.
Background technique
Waste residue waste material can be generated during Production of Ceramics, these waste residue waste materials are usually as garbage loading embeading or conduct at present
Lower quality feedstocks turn for wall brick, road or are used for concrete material, have the defects that widely apply, finished product added value
Not high and performance is poor.The high-quality ceramic tile of ceramic industry generally uses good raw mineral materials, and ceramic waste residue is difficult to apply high-quality
In ceramic product.
Ceramic big plate have the succinct atmosphere of decorative effect, stay stitch less, avoid sheltering evil people and countenance evil practices, paving of constructing is high-efficient etc.
Advantage, occupation rate in high-end family product market by continuous increase.In the prior art, the big plate of ceramics is with inkjet printing
Or decorative pattern texture is arranged in the mode of screen printing, by the big plate split paving of muti-piece ceramics, makes pattern split.Since adobe is burnt
There is certain shrinking percentage at rear, this results in the pattern dislocation of ceramic big plate split after paving, it is difficult to coincide, this is resulted in
The decorative effect of ceramic big plate is bad.
Summary of the invention
It is an object of the invention to propose the preparation method and the big plate of ceramics of the one big plate of stone multi-panel ceramics of one kind, there is pattern
Splice the good feature of property of coincideing.
To achieve this purpose, the present invention adopts the following technical scheme:
A kind of preparation method of the big plate of stone multi-panel ceramics, comprising the following steps:
(1), the green body of the big plate of preparation ceramics;
(2), it is decorated in the form of inkjet printing on green body: being divided into the big figure of a width in the input terminal of ink-jet printer
The small figure of muti-piece, input ink-jet printer prints on green body after the pattern edge of small figure is extended, and every piece small figure is corresponding
One piece of green body;
(3), kiln-firing obtains the big plate of ceramics that there is pattern texture to decorate;
(4), the big plate of the ceramics being fired into is subjected to edging processing, for making the pattern kissing of the big plate of adjacent two pieces of ceramics
It closes.
Further, in step (2), the size of inkjet printing pattern and in the same size, the pattern expansion of small figure of green body
Side edge forms pattern by inkjet printing on the edge of green body and extends side;
In step (4), when edging is handled, the pattern extension side on ceramic big plate is ground off, keeps the big figure of a width corresponding
In split, the texture joining place of the big plate of adjacent two pieces of ceramics matches the big plate of muti-piece ceramics.
Further, the pattern extension edge of small figure is directed towards what the pattern that the small figure connects was extended.
Further, in step (2) and (4), the default stock removal of one side length of ceramic wafer is ⊿ L, the pattern on green body
Extension hem width degree is L1, and the shrinking percentage after green body firing is A, A=2 × ⊿ L/L1.
Further, in step (2), by the big figure of a width by inkjet printing on one group of green body, through polishing after firing
This big plate capable assembling of group ceramics be big figure pattern;The big plate of multiple groups ceramics, which is laid with, is presented duplicate pattern texture.
Further, in step (1), include edging slag 6- by weight percentage in the body recipe of the big plate of ceramics
10% and polishing slag 1-3%.
Further, the raw material of the body recipe of the big plate of ceramics by weight percentage further include: weathering aloxite 33-
39%, potassium sodium sand 25-35%, magnesium soil 3-7%, black mud 8-12% and bentonite 7-10%.
Further, the raw material of the body recipe of the big plate of ceramics by weight percentage are as follows: weathering aloxite 36%, potassium sodium sand
30%, magnesium soil 5%, black mud 10%, bentonite 9%, edging slag 8% and polishing slag 2%.
Further, in step (1), green body has used toner material to carry out cloth with multitube distributing mode, makes to be pressed into
Green body texture match with inkjet printing pattern texture;The charity ground coat enamel on green body;
In step (2), the charity transparent protective layer on the green body with inkjet printing pattern.
A kind of big plate of ceramics, the big plate of ceramics are obtained using above-mentioned preparation method.
The invention has the benefit that
In decoration step of the invention, inkjet printing will be carried out after the group's border extended for the small figure being divided into, make to be printed upon
Pattern texture on green body is also extended, this allows for that there is the edge presence on the green body of adjacent patterns texture to be repeated
The pattern texture of printing also has the duplicate official documents and correspondence texture on the big edges of boards edge of ceramics after firing.In step (4), ceramic wafer
It needs to carry out edging processing after forming by a firing, to repeat answer for having on ceramic big plate to ceramic wafer correction of the flank shape and round edge
Part grind away, this is it is ensured that pattern can fit like a glove after ceramic wafer split.
By the way that the inkjet printing pattern on ceramic wafer is carried out border extended, the edge of extension is passed through into polishing after firing
Removal, can exclude the influence of green body percent of firing shrinkage, make ceramic wafer after split, and pattern can coincide, when muti-piece ceramic wafer is laid with
Afterwards, pattern texture can be in one or more surfaces extension, so that pattern texture is arbitrarily natural, three-dimensional sense is strong.It is received after ceramic wafer firing
Contracting, what pattern texture thereon was also difficult to avoid that shrinks, and deformation occurs or shrinks at the edge of pattern texture, when ceramic wafer is spelled
When conjunction, there are gap and dislocation between the pattern texture of adjacent two plate, using above-mentioned inkjet printing mode and edging operation come
Overcome the problems, such as split gap and dislocation.
Detailed description of the invention
Fig. 1 is the pattern of the small figure of inkjet printing of the preparation method of a big plate of stone multi-panel ceramics of one embodiment of the invention
Border extended schematic diagram.
Specific embodiment
With reference to the accompanying drawing and specific embodiment further illustrates technical solution of the present invention.
A kind of preparation method of the big plate of stone multi-panel ceramics, comprising the following steps:
(1), the green body of the big plate of preparation ceramics;
(2), it is decorated in the form of inkjet printing on green body: being divided into the big figure of a width in the input terminal of ink-jet printer
The small figure of muti-piece, input ink-jet printer prints on green body after the pattern edge of small figure is extended, and every piece small figure is corresponding
One piece of green body;
(3), kiln-firing obtains the big plate of ceramics that there is pattern texture to decorate;
(4), the big plate of the ceramics being fired into is subjected to edging processing, for making the pattern kissing of the big plate of adjacent two pieces of ceramics
It closes.
In decoration step of the invention, inkjet printing will be carried out after the group's border extended for the small figure being divided into, make to be printed upon
Pattern texture on green body is also extended, this allows for that there is the edge presence on the green body of adjacent patterns texture to be repeated
The pattern texture of printing also has the duplicate official documents and correspondence texture on the big edges of boards edge of ceramics after firing.In step (4), ceramic wafer
It needs to carry out edging processing after forming by a firing, to repeat answer for having on ceramic big plate to ceramic wafer correction of the flank shape and round edge
Part grind away, this is it is ensured that pattern can fit like a glove after ceramic wafer split.
By the way that the inkjet printing pattern on ceramic wafer is carried out border extended, the edge of extension is passed through into polishing after firing
Removal, can exclude the influence of green body percent of firing shrinkage, make ceramic wafer after split, and pattern can coincide, when muti-piece ceramic wafer is laid with
Afterwards, pattern texture can be in one or more surfaces extension, so that pattern texture is arbitrarily natural, three-dimensional sense is strong.It is received after ceramic wafer firing
Contracting, what pattern texture thereon was also difficult to avoid that shrinks, and deformation occurs or shrinks at the edge of pattern texture, when ceramic wafer is spelled
When conjunction, there are gap and dislocation between the pattern texture of adjacent two plate, using above-mentioned inkjet printing mode and edging operation come
Overcome the problems, such as split gap and dislocation.
Further, in step (2), the size of inkjet printing pattern and in the same size, the pattern expansion of small figure of green body
Side edge forms pattern by inkjet printing on the edge of green body and extends side;
In step (4), when edging is handled, the pattern extension side on ceramic big plate is ground off, keeps the big figure of a width corresponding
In split, the texture joining place of the big plate of adjacent two pieces of ceramics matches the big plate of muti-piece ceramics.
In step (2), enable the pattern of inkjet printing that green body is completely covered, pattern texture extends to the edge of green body,
This just makes ceramic big plate that can reduce stock removal in edging operation, reduces technology difficulty.
Further, the pattern extension edge of small figure is directed towards what the pattern that the small figure connects was extended, that is, will
The screenshot size of small figure increases, and not fills at the extension edge of small figure with pure color, this allows for the edge mill of ceramic big plate
Pattern texture after cutting thereon can extend to the edge of ceramic big plate, realize that split pattern coincide.
As shown in Figure 1, schematical citing, when 12 blocks of big plates of ceramics piece together repeat patterns, Fig. 1 a is that a width is big
Figure is divided into the partitioning scheme of two pieces of small figures, and Fig. 1 b is the position setting of the big figure in a repeating pattern, and Fig. 1 c is 12 pieces of ceramics
Big plate pieces together the schematic diagram of repeat patterns, and wherein dotted line frame indicates pattern texture range, dotted line frame and reality after a small figure extension
It is extension edge and the extension side for forming ceramic big plate between wire frame.
Further, in step (2) and (4), the default stock removal of one side length of ceramic wafer is ⊿ L, the pattern on green body
Extension hem width degree is L1, and the shrinking percentage after green body firing is A, A=2 × ⊿ L/L1.Come with default stock removal and green body shrinking percentage
The width for calculating pattern extension side, the grinding action after facilitating ceramic wafer to be burnt into.Specifically, the pattern extension side on green body is located at
The surrounding of green body enables pattern texture to extend to the edge of ceramic wafer, makes adjacent two pieces by being ground the extension side of ceramic wafer
The pattern of ceramic wafer can fit like a glove.Default grinding Liang ⊿ L is 25-40mm, i.e., the stock removal of the opposite sides of ceramic wafer it
With for 25-40mm.
Further, in step (2), by the big figure of a width by inkjet printing on one group of green body, through polishing after firing
This big plate capable assembling of group ceramics be big figure pattern;The big plate of multiple groups ceramics, which is laid with, is presented duplicate pattern texture.When pattern line
When reason imitates lithotome, the repeat patterns texture remarkable fluency of formation.In other embodiments, the big figure of a width is passed through into spray
Ink prints on one group of green body, and it is unduplicated list that this big plate capable assembling of group ceramics after firing through polishing, which is the pattern of big figure,
Width pattern texture realizes the presentation of irregular grain, landscape painting, figure map, animal figure etc..
Further, in step (1), include edging slag 6- by weight percentage in the body recipe of the big plate of ceramics
10% and polishing slag 1-3%.Edging slag is the waste residue that ceramic wafer carries out edging operation generation, the ingredient one of the waste residue and Ceramic Tiles
It causes, is added in ceramic board raw material as clinker.When clinker usage amount is excessive in formula, in firing there is no crystal form conversion,
Single structure stabilizing active reduces, and inter-molecular binding force is weaker, to will affect the sintered intensity of adobe.Polishing slag is ceramics
Plate polishes in slag containing ingredients such as resin, silicon carbide, magnesium chlorides in the waste residue for carrying out the generation of surface polishing process, introduces production
Generation carbon monoxide or carbon dioxide gas, gas discharge process can be oxidized when formula, in sintering procedure can make green body gradually
Stomata is formed, ceramic product deformation, compactness and reduced performance are caused, thus is difficult to be recycled, even if being utilized is also
For low-quality road turn or foamed ceramic brick.The present invention controls the dosage of edging slag and polishing slag in 6-10% and 1-3%,
Influence of the waste residue to Ceramic Tiles quality is prevented while using waste residue, waste residue makes the oxygen of body recipe in this amount ranges
Change better performances, the ceramic wafer items atomization after guaranteeing firing is preferable.
Further, the raw material of the body recipe of the big plate of ceramics by weight percentage further include: weathering aloxite 33-
39%, potassium sodium sand 25-35%, magnesium soil 3-7%, black mud 8-12% and bentonite 7-10%.
By adjusting the formula of ceramic wafer green body, it is optimal the oxidation susceptibility of formula, ceramic wafer has preferable product
Matter.Weathering aloxite provides aluminium oxide and silica for formula system, and potassium sodium sand is used to provide biological cycle and silica for formula,
Magnesium soil is used to provide magnesium elements for formula, and black mud and bentonite are used to improve the plasticity of raw material.
The preparation process of green body is as follows:
A, each raw material is crushed respectively;
B, ball mill is added according to formula rate in the powder of each raw material, and addition is the 0.5% of total restatement with formula ratio
Degumming agent, 0.4% waterglass and 0.1%PVA, while adding water to be mixed into ball mill and carrying out ball milling, obtain the satisfactory slurry of fineness
Material;
C, by the powder of slurry spray drying granulation, powder is stored aging;
D, powder is suppressed into green body in the framed middle cloth of press;
E, by body drying.
Further, the raw material of the body recipe of the big plate of ceramics by weight percentage are as follows: weathering aloxite 36%, potassium sodium sand
30%, magnesium soil 5%, black mud 10%, bentonite 9%, edging slag 8% and polishing slag 2%.The formula has optimal oxidisability
Can, so that the properties of ceramic wafer are optimal.
Further, in step (1), green body has used toner material to carry out cloth with multitube distributing mode, makes to be pressed into
Green body texture match with inkjet printing pattern texture;The charity ground coat enamel on green body;
In step (2), the charity transparent protective layer on the green body with inkjet printing pattern.
May be implemented the preparation of all-body tile with existing multitube distributing mode, adobe has an entire body texture, picture on surface with
Adobe entire body texture matches, and improves the decorative effect of ceramic big plate.It is realized by the way that protective layer is arranged on green body to bottom
The protection of pattern texture, the transparent protective layer by drench in a manner of glaze or charity dry granular in the way of formed.
A kind of big plate of ceramics, the big plate of ceramics are obtained using above-mentioned preparation method, the pattern texture decoration of the big plate of the ceramics
The edge that big plate can be extended to carries out edging by the small figure after printing extension and after being burnt into, realizes pattern line after big plate split
Manage the effect to fit like a glove.
Below by way of specific embodiment, the present invention is further explained.
Embodiment 1
A kind of preparation method of the big plate of stone multi-panel ceramics, comprising the following steps:
(1), the green body of the big plate of preparation ceramics, green body is using compression moulding after existing distributing mode completion cloth;
(2), it is decorated in the form of inkjet printing on green body: being divided into the big figure of a width in the input terminal of ink-jet printer
The small figure of muti-piece, input ink-jet printer prints on green body after the pattern edge of small figure is extended, and every piece small figure is corresponding
The pattern extension edge of one piece of green body, small figure is directed towards what the pattern that the small figure connects was extended;Inkjet printing pattern it is big
Small in the same size with green body, the pattern extension edge of small figure forms pattern extension by inkjet printing on the edge of green body
Side;The default stock removal of one side length of ceramic wafer is ⊿ L, and the pattern extension hem width degree on green body is L1, the contraction after green body firing
Rate is A, A=2 × ⊿ L/L1;
(3), kiln-firing obtains the big plate of ceramics that there is pattern texture to decorate;
(4), the big plate of the ceramics being fired into is subjected to edging processing, for making the pattern kissing of the big plate of adjacent two pieces of ceramics
It closes.When edging processing, the pattern extension side on ceramic big plate is ground off, makes the corresponding big plate of muti-piece ceramics of the big figure of a width in split
When, the texture joining place of the big plate of adjacent two pieces of ceramics matches.
Embodiment 2
A kind of preparation method of the big plate of stone multi-panel ceramics, comprising the following steps:
(1), the green body of the big plate of preparation ceramics, green body is using compression moulding after existing distributing mode completion cloth;In base
Charity ground coat enamel on body;
(2), it is decorated in the form of inkjet printing on green body: being divided into the big figure of a width in the input terminal of ink-jet printer
The small figure of muti-piece, input ink-jet printer prints on green body after the pattern edge of small figure is extended, and every piece small figure is corresponding
The pattern extension edge of one piece of green body, small figure is directed towards what the pattern that the small figure connects was extended;Inkjet printing pattern it is big
Small in the same size with green body, the pattern extension edge of small figure forms pattern extension by inkjet printing on the edge of green body
Side;The default stock removal of one side length of ceramic wafer is ⊿ L, and the pattern extension hem width degree on green body is L1, the contraction after green body firing
Rate is A, A=2 × ⊿ L/L1;
After the completion of inkjet printing, glaze is protected in charity on green body;
(3), kiln-firing obtains the big plate of ceramics that there is pattern texture to decorate;
(4), the big plate of the ceramics being fired into is subjected to edging processing, for making the pattern kissing of the big plate of adjacent two pieces of ceramics
It closes.When edging processing, the pattern extension side on ceramic big plate is ground off, makes the corresponding big plate of muti-piece ceramics of the big figure of a width in split
When, the texture joining place of the big plate of adjacent two pieces of ceramics matches.
In the present embodiment, by the big figure of a width by inkjet printing in this group ceramics on one group of green body, after firing through polishing
Big plate capable assembling is the pattern of big figure;The big plate of multiple groups ceramics, which is laid with, is presented duplicate pattern texture.
Embodiment 3
The preparation method of the one big plate of stone multi-panel ceramics of the present embodiment is substantially the same manner as Example 2, the difference is that,
In step (1), green body has used toner material to carry out cloth with multitube distributing mode, makes the green body texture being pressed into and inkjet printing
Pattern texture matches.
The processing step of embodiment 4 is same as Example 1, and the processing step of embodiment 5 is same as Example 2, embodiment
Body recipe in 1-5 is as shown in the table with the raw material of weight percent:
Raw material | Embodiment B1 | Embodiment B2 | Embodiment B3 | Embodiment B4 | Embodiment B5 |
Weathering aloxite | 33% | 39% | 36% | 38% | 35% |
Potassium sodium sand | 35% | 26% | 30% | 28% | 32% |
Magnesium soil | 7% | 3% | 5% | 6% | 4% |
Black mud | 8% | 12% | 10% | 9% | 11% |
Bentonite | 10% | 7% | 9% | 8% | 9% |
Edging slag | 6% | 10% | 8% | 10% | 7% |
Polish slag | 1% | 3% | 2% | 1% | 2% |
Comparative example 1
The step of this comparative example provides a kind of preparation process of ceramic wafer, and step is with embodiment 3 is identical, and difference exists
In the raw material of the formula of green body by weight percentage is as shown in the table:
Weathering aloxite | Potassium sodium sand | Magnesium soil | Black mud | Bentonite | Edging slag | Polish slag |
36% | 35% | 5% | 10% | 9% | 4% | 1% |
Comparative example 2
The step of this comparative example provides a kind of preparation process of ceramic wafer, and step is with embodiment 3 is identical, and difference exists
In the raw material of the formula of green body by weight percentage is as shown in the table:
Weathering aloxite | Potassium sodium sand | Magnesium soil | Black mud | Bentonite | Edging slag | Polish slag |
36% | 35% | 6% | 10% | 10% | 10% | 4% |
Comparative example 3
The step of this comparative example provides a kind of preparation process of ceramic wafer, and step is with embodiment 3 is identical, and difference exists
In the raw material of the formula of green body by weight percentage is as shown in the table:
Weathering aloxite | Potassium sodium sand | Magnesium soil | Black mud | Bentonite | Edging slag | Polish slag |
33% | 30% | 6% | 10% | 8% | 8% | 4% |
Ceramic wafer made of embodiment 1-5, comparative example 1-3 is detected, testing result is as follows:
By the data of upper table it is found that when the dosage of edging slag and polishing slag is smaller, body crack defects are not influenced,
When edging slag and polishing slag dosage increase to a certain degree after, can to the performance of green body generate large effect.When edging slag
When dosage with polishing slag is 8% and 2%, the utilization of relatively large waste residue not only it had been able to achieve but also can have made ceramic wafer that there is preferable property
Energy.
The technical principle of the invention is described above in combination with a specific embodiment.These descriptions are intended merely to explain of the invention
Principle, and shall not be construed in any way as a limitation of the scope of protection of the invention.Based on the explanation herein, the technology of this field
Personnel can associate with other specific embodiments of the invention without creative labor, these modes are fallen within
Within protection scope of the present invention.
Claims (10)
1. the preparation method of the one big plate of stone multi-panel ceramics of one kind, which comprises the following steps:
(1), the green body of the big plate of preparation ceramics;
(2), it is decorated in the form of inkjet printing on green body: the big figure of one width being divided into muti-piece in the input terminal of ink-jet printer
Small figure, input ink-jet printer prints on green body after the pattern edge of small figure is extended, and every piece small figure is one piece corresponding
Green body;
(3), kiln-firing obtains the big plate of ceramics that there is pattern texture to decorate;
(4), the big plate of the ceramics being fired into is subjected to edging processing, for making the pattern of the big plate of adjacent two pieces of ceramics match.
2. the preparation method of the big plate of stone multi-panel ceramics according to claim 1, which is characterized in that in the step (2)
In, the size of inkjet printing pattern and green body it is in the same size, the pattern extension edge of the small figure is by inkjet printing in base
Pattern is formed on the edge of body extends side;
In the step (4), when edging is handled, the pattern extension side on ceramic big plate is ground off, keeps the big figure of a width corresponding
In split, the texture joining place of the big plate of adjacent two pieces of ceramics matches the big plate of muti-piece ceramics.
3. the preparation method of the big plate of stone multi-panel ceramics according to claim 1, which is characterized in that the pattern of the small figure
Extension edge is directed towards what the pattern that the small figure connects was extended.
4. the preparation method of the big plate of stone multi-panel ceramics according to claim 1, which is characterized in that in the step (2)
(4) in, the default stock removal of one side length of ceramic wafer is ⊿ L, and the pattern extension hem width degree on the green body is L1, the green body
Shrinking percentage after firing is A, A=2 × ⊿ L/L1.
5. the preparation method of the big plate of stone multi-panel ceramics according to claim 1, which is characterized in that in the step (2)
In, by the big figure of a width by inkjet printing on one group of green body, this big plate capable assembling of group ceramics after firing through polishing is described
The pattern of big figure;The big plate of ceramics described in multiple groups, which is laid with, is presented duplicate pattern texture.
6. the preparation method of the big plate of stone multi-panel ceramics according to claim 1, which is characterized in that in the step (1)
In, edging slag 6-10% and polishing slag 1-3% by weight percentage is included in the body recipe of the big plate of ceramics.
7. the preparation method of the big plate of stone multi-panel ceramics according to claim 6, which is characterized in that the big plate of ceramics
The raw material of body recipe by weight percentage further include: weathering aloxite 33-39%, potassium sodium sand 25-35%, magnesium soil 3-7%,
Black mud 8-12% and bentonite 7-10%.
8. the preparation method of the big plate of stone multi-panel ceramics according to claim 7, which is characterized in that the big plate of ceramics
The raw material of body recipe by weight percentage are as follows: weathering aloxite 36%, potassium sodium sand 30%, magnesium soil 5%, black mud 10%, swollen
Profit soil 9%, edging slag 8% and polishing slag 2%.
9. the preparation method of the big plate of stone multi-panel ceramics according to claim 1, which is characterized in that in the step (1)
In, the green body has used toner material to carry out cloth with multitube distributing mode, makes the green body texture being pressed into and inkjet printing figure
Case texture matches;The charity ground coat enamel on green body;
In the step (2), the charity transparent protective layer on the green body with inkjet printing pattern.
10. a kind of big plate of ceramics, the big plate of ceramics is obtained using preparation method described in claim 1-9.
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Cited By (1)
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