CN109311666B - 将甲烷转化为丙醛的工艺 - Google Patents

将甲烷转化为丙醛的工艺 Download PDF

Info

Publication number
CN109311666B
CN109311666B CN201780039024.XA CN201780039024A CN109311666B CN 109311666 B CN109311666 B CN 109311666B CN 201780039024 A CN201780039024 A CN 201780039024A CN 109311666 B CN109311666 B CN 109311666B
Authority
CN
China
Prior art keywords
reactor
ethylene
stream
water
methane
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201780039024.XA
Other languages
English (en)
Chinese (zh)
Other versions
CN109311666A (zh
Inventor
S·L·F·康塔尔斯
T·达维迪安
G·布德罗尼
P·E·赫鲁嫩代克
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dow Global Technologies LLC
Original Assignee
Dow Global Technologies LLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Global Technologies LLC filed Critical Dow Global Technologies LLC
Publication of CN109311666A publication Critical patent/CN109311666A/zh
Application granted granted Critical
Publication of CN109311666B publication Critical patent/CN109311666B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • C07C45/505—Asymmetric hydroformylation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J6/00—Heat treatments such as Calcining; Fusing ; Pyrolysis
    • B01J6/008—Pyrolysis reactions
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
    • C01B3/02—Production of hydrogen; Production of gaseous mixtures containing hydrogen
    • C01B3/06—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen with inorganic reducing agents
    • C01B3/12—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen with inorganic reducing agents by reaction of water vapour with carbon monoxide
    • C01B3/16—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen with inorganic reducing agents by reaction of water vapour with carbon monoxide using catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
    • C01B3/02—Production of hydrogen; Production of gaseous mixtures containing hydrogen
    • C01B3/32—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air
    • C01B3/34—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents
    • C01B3/36—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents using oxygen; using mixtures containing oxygen as gasifying agents
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
    • C01B3/02—Production of hydrogen; Production of gaseous mixtures containing hydrogen
    • C01B3/32—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air
    • C01B3/34—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents
    • C01B3/48—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents followed by reaction of water vapour with carbon monoxide
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C11/00—Aliphatic unsaturated hydrocarbons
    • C07C11/02—Alkenes
    • C07C11/04—Ethene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/76—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation of hydrocarbons with partial elimination of hydrogen
    • C07C2/82—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation of hydrocarbons with partial elimination of hydrogen oxidative coupling
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/76—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation of hydrocarbons with partial elimination of hydrogen
    • C07C2/82—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation of hydrocarbons with partial elimination of hydrogen oxidative coupling
    • C07C2/84—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation of hydrocarbons with partial elimination of hydrogen oxidative coupling catalytic
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C47/00—Compounds having —CHO groups
    • C07C47/02—Saturated compounds having —CHO groups bound to acyclic carbon atoms or to hydrogen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/327—Formation of non-aromatic carbon-to-carbon double bonds only
    • C07C5/333—Catalytic processes
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0283—Processes for making hydrogen or synthesis gas containing a CO-shift step, i.e. a water gas shift step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/06—Integration with other chemical processes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CN201780039024.XA 2016-06-30 2017-06-13 将甲烷转化为丙醛的工艺 Active CN109311666B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201662356786P 2016-06-30 2016-06-30
US62/356786 2016-06-30
PCT/US2017/037159 WO2018005074A1 (en) 2016-06-30 2017-06-13 Process for the conversion of methane into propanal

Publications (2)

Publication Number Publication Date
CN109311666A CN109311666A (zh) 2019-02-05
CN109311666B true CN109311666B (zh) 2022-07-19

Family

ID=59216020

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201780039024.XA Active CN109311666B (zh) 2016-06-30 2017-06-13 将甲烷转化为丙醛的工艺

Country Status (11)

Country Link
US (1) US10519087B2 (https=)
EP (1) EP3478631B1 (https=)
JP (1) JP6920023B2 (https=)
KR (1) KR102379397B1 (https=)
CN (1) CN109311666B (https=)
BR (1) BR112018075821B1 (https=)
CA (1) CA3029396A1 (https=)
MX (1) MX2018015552A (https=)
SA (1) SA518400731B1 (https=)
SG (1) SG11201811444YA (https=)
WO (1) WO2018005074A1 (https=)

Families Citing this family (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109311666B (zh) 2016-06-30 2022-07-19 陶氏环球技术有限责任公司 将甲烷转化为丙醛的工艺
WO2020242924A1 (en) * 2019-05-24 2020-12-03 Eastman Chemical Company Recycle content propionaldehyde
CN113891928B (zh) 2019-05-24 2024-10-29 伊士曼化工公司 裂化热解油的c4-c7馏分
US11946000B2 (en) 2019-05-24 2024-04-02 Eastman Chemical Company Blend small amounts of pyoil into a liquid stream processed into a gas cracker
US12497467B2 (en) 2019-05-24 2025-12-16 Exxon Mobil Product Solutions Company Recycle content cellulose ester
US11365357B2 (en) 2019-05-24 2022-06-21 Eastman Chemical Company Cracking C8+ fraction of pyoil
US12031091B2 (en) 2019-05-24 2024-07-09 Eastman Chemical Company Recycle content cracked effluent
DE102019119543A1 (de) * 2019-07-18 2021-01-21 Linde Gmbh Verfahren und Anlage zur Herstellung einer Zielverbindung
DE102019119540A1 (de) * 2019-07-18 2021-01-21 Linde Gmbh Verfahren und Anlage zur Herstellung einer Zielverbindung
DE102019119562A1 (de) * 2019-07-18 2021-01-21 Linde Gmbh Verfahren und Anlage zur Herstellung einer Zielverbindung
US12338211B2 (en) 2019-07-29 2025-06-24 Eastman Chemical Company Recycle content (C4)alkanal
CN119912669A (zh) 2019-07-29 2025-05-02 伊士曼化工公司 回收成分环丁二醇聚酯
US12528995B2 (en) 2019-10-31 2026-01-20 ExxonMobil Product Solutions Company Pyrolysis method and system for recycled waste
US11945998B2 (en) 2019-10-31 2024-04-02 Eastman Chemical Company Processes and systems for making recycle content hydrocarbons
EP4051762A4 (en) 2019-10-31 2023-12-27 Eastman Chemical Company PYROLYSIS PROCESS AND SYSTEM FOR RECYCLED WASTE
US11319262B2 (en) 2019-10-31 2022-05-03 Eastman Chemical Company Processes and systems for making recycle content hydrocarbons
EP4055001A4 (en) 2019-11-07 2024-02-14 Eastman Chemical Company MIXED ESTERS AND SOLVENTS WITH RECYCLED CONTENTS
CN114728868B (zh) 2019-11-07 2024-09-03 伊士曼化工公司 回收成分羰基合成醇和羰基合成增塑剂
CN118851872A (zh) * 2019-11-07 2024-10-29 伊士曼化工公司 回收成分丙醇
US11939534B2 (en) 2019-11-07 2024-03-26 Eastman Chemical Company Recycle content alpha olefins and fatty alcohols
EP3922621B1 (de) 2020-06-10 2023-08-30 Linde GmbH Prozess zur herstellung von propylen
EP4015495A1 (de) * 2020-12-18 2022-06-22 Linde GmbH Verfahren und anlage zur herstellung einer zielverbindung
KR102536935B1 (ko) * 2020-12-31 2023-05-26 주식회사 카카오 사용자 프로필 관리 방법 및 장치
CN117999330A (zh) 2021-09-21 2024-05-07 伊士曼化工公司 用于回收成分烯烃生产商的低碳足迹集成方法
US12195674B2 (en) 2021-09-21 2025-01-14 Eastman Chemical Company Using spent caustic solution from pygas treatment to neutralize halogens from liquified waste plastic

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1997036848A1 (en) * 1996-04-01 1997-10-09 Union Carbide Chemicals & Plastics Technology Corporation Processes for the manufacture of methylmercaptopropanal
CN1298859A (zh) * 1999-12-09 2001-06-13 中国科学院成都有机化学研究所 一种天然气旋焰乙炔炉余热喷油产混合气的使用方法
CN1978409A (zh) * 2005-12-02 2007-06-13 四川大学 一种由甲烷氧化偶联和气相氧化耦合制取丙醛原料的方法
CN102438999A (zh) * 2009-05-20 2012-05-02 巴斯夫欧洲公司 从甲烷生产更高价值烃的系统和方法
CN102442894A (zh) * 2010-09-30 2012-05-09 中国石油化工股份有限公司 一种利用炼厂干气中乙烯制备丙醛的方法
CN102686546A (zh) * 2009-11-11 2012-09-19 陶氏环球技术有限责任公司 将链烯烃还原加氢甲酰化转化为链烷醇
CN105636928A (zh) * 2013-09-30 2016-06-01 陶氏环球技术有限责任公司 链烷酸烷基酯的气相生产

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE69602717T2 (de) 1995-01-18 2000-01-13 Exxon Chemical Ltd., Fareham Hydroformylierungsverfahren
DE102010030209A1 (de) * 2010-06-17 2011-12-22 Evonik Oxeno Gmbh Energieeffiziente Synthese von aliphatischen Adelhyden aus Alkanen und Kohlendioxid
US9676695B2 (en) 2011-03-02 2017-06-13 Aither Chemical LLC Methods for integrated natural gas purification and products produced therefrom
US9012694B2 (en) 2011-12-27 2015-04-21 Shell Oil Company Process for the production of alcohols
WO2014089479A1 (en) 2012-12-07 2014-06-12 Siluria Technologies, Inc. Integrated processes and systems for conversion of methane to multiple higher hydrocarbon products
CA2902192C (en) 2013-03-15 2021-12-07 Siluria Technologies, Inc. Catalysts for petrochemical catalysis
WO2015057753A1 (en) * 2013-10-16 2015-04-23 Saudi Basic Industries Corporation Method for converting methane to ethylene
WO2015080218A1 (ja) 2013-11-29 2015-06-04 Dic株式会社 重合性化合物、組成物、重合体、光学異方体、液晶表示素子及び有機ｅｌ素子
CN109311666B (zh) 2016-06-30 2022-07-19 陶氏环球技术有限责任公司 将甲烷转化为丙醛的工艺

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1997036848A1 (en) * 1996-04-01 1997-10-09 Union Carbide Chemicals & Plastics Technology Corporation Processes for the manufacture of methylmercaptopropanal
CN1298859A (zh) * 1999-12-09 2001-06-13 中国科学院成都有机化学研究所 一种天然气旋焰乙炔炉余热喷油产混合气的使用方法
CN1978409A (zh) * 2005-12-02 2007-06-13 四川大学 一种由甲烷氧化偶联和气相氧化耦合制取丙醛原料的方法
CN102438999A (zh) * 2009-05-20 2012-05-02 巴斯夫欧洲公司 从甲烷生产更高价值烃的系统和方法
CN102686546A (zh) * 2009-11-11 2012-09-19 陶氏环球技术有限责任公司 将链烯烃还原加氢甲酰化转化为链烷醇
CN102442894A (zh) * 2010-09-30 2012-05-09 中国石油化工股份有限公司 一种利用炼厂干气中乙烯制备丙醛的方法
CN105636928A (zh) * 2013-09-30 2016-06-01 陶氏环球技术有限责任公司 链烷酸烷基酯的气相生产

Also Published As

Publication number Publication date
JP6920023B2 (ja) 2021-08-18
BR112018075821A2 (pt) 2019-03-26
CN109311666A (zh) 2019-02-05
WO2018005074A1 (en) 2018-01-04
SA518400731B1 (ar) 2021-12-12
BR112018075821B1 (pt) 2022-11-16
MX2018015552A (es) 2019-06-06
US20190292122A1 (en) 2019-09-26
US10519087B2 (en) 2019-12-31
SG11201811444YA (en) 2019-01-30
KR102379397B1 (ko) 2022-03-28
CA3029396A1 (en) 2018-01-04
EP3478631A1 (en) 2019-05-08
JP2019519547A (ja) 2019-07-11
KR20190024967A (ko) 2019-03-08
EP3478631B1 (en) 2020-04-22

Similar Documents

Publication Publication Date Title
CN109311666B (zh) 将甲烷转化为丙醛的工艺
CN108368037B (zh) 生产甲醛稳定的脲的整合方法
US11148985B2 (en) Process for oxidative conversion of methane to ethylene
US5714657A (en) Natural gas conversion to higher hydrocarbons
JP2019519547A5 (https=)
JP5633980B2 (ja) メタノールおよびアンモニアの同時製造のためのプロセス
JP6352929B2 (ja) メタン源からの酸化性の双改質を介した効率的で自己充足的なメタノールの製造
CN104471037A (zh) 形成合成气混合物的方法
WO2010067077A1 (en) Integrated gas refinery
CN101213143A (zh) 合成气的生产和应用
CN104024149A (zh) 甲醇和脲的联合生产
EP3230238A1 (en) Method for converting methane to ethylene and in situ transfer of exothermic heat
CN106715367A (zh) 烷烃脱氢成烯烃
CN121800608A (zh) 合成气和甲醇的生产
EP4355686A1 (en) A method for producing syngas using catalytic reverse water gas shift
CN112292200A (zh) 生产甲醇的方法和设置
CN105980341A (zh) 由合成气生产二甲醚的方法和设备
CN105593160A (zh) 在绝热金属反应器中氢化co2的方法
US20090264543A1 (en) Integrated Process for the Co-Production of Methanol and Demethyl Ether From Syngas Containing Nitrogen
JP2018512392A (ja) エチレンオキサイド、エチレングリコール、及び／またはエタノールアミンの生成に関するシステム及び方法
CN113710613A (zh) 具有提高的能效的甲醇生产方法
CA2933279A1 (en) Process for the production of synthesis gas for use in the production of chemical compounds from a hydrocarbon feed stock
CN104150441A (zh) 一种费托合成尾气转化为费托合成原料气的方法
RU2782258C2 (ru) Способ получения метанола и аммиака
AU2020211925B2 (en) Methanol production process

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant