CN109311666B - 将甲烷转化为丙醛的工艺 - Google Patents

将甲烷转化为丙醛的工艺 Download PDF

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CN109311666B
CN109311666B CN201780039024.XA CN201780039024A CN109311666B CN 109311666 B CN109311666 B CN 109311666B CN 201780039024 A CN201780039024 A CN 201780039024A CN 109311666 B CN109311666 B CN 109311666B
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reactor
ethylene
stream
water
methane
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CN109311666A (zh
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S·L·F·康塔尔斯
T·达维迪安
G·布德罗尼
P·E·赫鲁嫩代克
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Dow Global Technologies LLC
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • C07C45/505—Asymmetric hydroformylation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
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    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/06—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents
    • C01B3/12—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with carbon monoxide
    • C01B3/16—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with carbon monoxide using catalysts
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    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/36—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using oxygen or mixtures containing oxygen as gasifying agents
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    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/48—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents followed by reaction of water vapour with carbon monoxide
    • C—CHEMISTRY; METALLURGY
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    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C11/00—Aliphatic unsaturated hydrocarbons
    • C07C11/02—Alkenes
    • C07C11/04—Ethylene
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    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/76—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation of hydrocarbons with partial elimination of hydrogen
    • C07C2/82—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation of hydrocarbons with partial elimination of hydrogen oxidative coupling
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/76—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation of hydrocarbons with partial elimination of hydrogen
    • C07C2/82—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation of hydrocarbons with partial elimination of hydrogen oxidative coupling
    • C07C2/84—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation of hydrocarbons with partial elimination of hydrogen oxidative coupling catalytic
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C47/00—Compounds having —CHO groups
    • C07C47/02—Saturated compounds having —CHO groups bound to acyclic carbon atoms or to hydrogen
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    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
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    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/327—Formation of non-aromatic carbon-to-carbon double bonds only
    • C07C5/333—Catalytic processes
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    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0283—Processes for making hydrogen or synthesis gas containing a CO-shift step, i.e. a water gas shift step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/06—Integration with other chemical processes

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CN201780039024.XA 2016-06-30 2017-06-13 将甲烷转化为丙醛的工艺 Active CN109311666B (zh)

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US201662356786P 2016-06-30 2016-06-30
US62/356786 2016-06-30
PCT/US2017/037159 WO2018005074A1 (en) 2016-06-30 2017-06-13 Process for the conversion of methane into propanal

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CN109311666B true CN109311666B (zh) 2022-07-19

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EP (1) EP3478631B1 (enExample)
JP (1) JP6920023B2 (enExample)
KR (1) KR102379397B1 (enExample)
CN (1) CN109311666B (enExample)
BR (1) BR112018075821B1 (enExample)
CA (1) CA3029396A1 (enExample)
MX (1) MX2018015552A (enExample)
SA (1) SA518400731B1 (enExample)
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US10519087B2 (en) 2016-06-30 2019-12-31 Dow Global Technologies Llc Process for the conversion of methane into propanal
US12031091B2 (en) 2019-05-24 2024-07-09 Eastman Chemical Company Recycle content cracked effluent
WO2020242924A1 (en) * 2019-05-24 2020-12-03 Eastman Chemical Company Recycle content propionaldehyde
CN113993977B (zh) 2019-05-24 2024-09-13 伊士曼化工公司 进入气体裂化器中加工的液体流中混入少量热解油
US11365357B2 (en) 2019-05-24 2022-06-21 Eastman Chemical Company Cracking C8+ fraction of pyoil
DE102019119562A1 (de) * 2019-07-18 2021-01-21 Linde Gmbh Verfahren und Anlage zur Herstellung einer Zielverbindung
DE102019119540A1 (de) * 2019-07-18 2021-01-21 Linde Gmbh Verfahren und Anlage zur Herstellung einer Zielverbindung
DE102019119543A1 (de) * 2019-07-18 2021-01-21 Linde Gmbh Verfahren und Anlage zur Herstellung einer Zielverbindung
CN114206820B (zh) 2019-07-29 2024-05-10 伊士曼化工公司 回收成分(c4)烷醛
US11945998B2 (en) 2019-10-31 2024-04-02 Eastman Chemical Company Processes and systems for making recycle content hydrocarbons
US11319262B2 (en) 2019-10-31 2022-05-03 Eastman Chemical Company Processes and systems for making recycle content hydrocarbons
EP4051762A4 (en) 2019-10-31 2023-12-27 Eastman Chemical Company PYROLYSIS PROCESS AND SYSTEM FOR RECYCLED WASTE
WO2021092306A1 (en) 2019-11-07 2021-05-14 Eastman Chemical Company Recycle content alpha olefins and fatty alcohols
WO2021092305A1 (en) 2019-11-07 2021-05-14 Eastman Chemical Company Recycle content mixed esters and solvents
WO2021092309A1 (en) * 2019-11-07 2021-05-14 Eastman Chemical Company Recycle content propanol
EP3922621B1 (de) 2020-06-10 2023-08-30 Linde GmbH Prozess zur herstellung von propylen
EP4015495A1 (de) 2020-12-18 2022-06-22 Linde GmbH Verfahren und anlage zur herstellung einer zielverbindung
KR102536935B1 (ko) * 2020-12-31 2023-05-26 주식회사 카카오 사용자 프로필 관리 방법 및 장치
US12195674B2 (en) 2021-09-21 2025-01-14 Eastman Chemical Company Using spent caustic solution from pygas treatment to neutralize halogens from liquified waste plastic

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CN1298859A (zh) * 1999-12-09 2001-06-13 中国科学院成都有机化学研究所 一种天然气旋焰乙炔炉余热喷油产混合气的使用方法
CN1978409A (zh) * 2005-12-02 2007-06-13 四川大学 一种由甲烷氧化偶联和气相氧化耦合制取丙醛原料的方法
CN102438999A (zh) * 2009-05-20 2012-05-02 巴斯夫欧洲公司 从甲烷生产更高价值烃的系统和方法
CN102442894A (zh) * 2010-09-30 2012-05-09 中国石油化工股份有限公司 一种利用炼厂干气中乙烯制备丙醛的方法
CN102686546A (zh) * 2009-11-11 2012-09-19 陶氏环球技术有限责任公司 将链烯烃还原加氢甲酰化转化为链烷醇
CN105636928A (zh) * 2013-09-30 2016-06-01 陶氏环球技术有限责任公司 链烷酸烷基酯的气相生产

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WO1997036848A1 (en) * 1996-04-01 1997-10-09 Union Carbide Chemicals & Plastics Technology Corporation Processes for the manufacture of methylmercaptopropanal
CN1298859A (zh) * 1999-12-09 2001-06-13 中国科学院成都有机化学研究所 一种天然气旋焰乙炔炉余热喷油产混合气的使用方法
CN1978409A (zh) * 2005-12-02 2007-06-13 四川大学 一种由甲烷氧化偶联和气相氧化耦合制取丙醛原料的方法
CN102438999A (zh) * 2009-05-20 2012-05-02 巴斯夫欧洲公司 从甲烷生产更高价值烃的系统和方法
CN102686546A (zh) * 2009-11-11 2012-09-19 陶氏环球技术有限责任公司 将链烯烃还原加氢甲酰化转化为链烷醇
CN102442894A (zh) * 2010-09-30 2012-05-09 中国石油化工股份有限公司 一种利用炼厂干气中乙烯制备丙醛的方法
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BR112018075821B1 (pt) 2022-11-16
WO2018005074A1 (en) 2018-01-04
EP3478631A1 (en) 2019-05-08
EP3478631B1 (en) 2020-04-22
KR102379397B1 (ko) 2022-03-28
SA518400731B1 (ar) 2021-12-12
JP2019519547A (ja) 2019-07-11
US10519087B2 (en) 2019-12-31
JP6920023B2 (ja) 2021-08-18
CA3029396A1 (en) 2018-01-04
SG11201811444YA (en) 2019-01-30
BR112018075821A2 (pt) 2019-03-26
CN109311666A (zh) 2019-02-05
US20190292122A1 (en) 2019-09-26
MX2018015552A (es) 2019-06-06
KR20190024967A (ko) 2019-03-08

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