CN109181884B - Preparation method of anti-wrinkle effervescent detergent for cotton cloth - Google Patents
Preparation method of anti-wrinkle effervescent detergent for cotton cloth Download PDFInfo
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- CN109181884B CN109181884B CN201810778361.7A CN201810778361A CN109181884B CN 109181884 B CN109181884 B CN 109181884B CN 201810778361 A CN201810778361 A CN 201810778361A CN 109181884 B CN109181884 B CN 109181884B
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/10—Carbonates ; Bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
- C11D3/227—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin with nitrogen-containing groups
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/50—Perfumes
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Inorganic Chemistry (AREA)
- Emergency Medicine (AREA)
- Detergent Compositions (AREA)
- Cosmetics (AREA)
Abstract
The invention provides a preparation method of an anti-wrinkle effervescent detergent for cotton cloth, which comprises the following steps: freeze drying sesame seed meal; taking out, pulverizing, sieving, adding ethanol water solution, sealing, mixing, and extracting under pressure; filtering, collecting filtrate, distilling under reduced pressure, and oven drying to obtain powder A; mixing gelatin with distilled water, stirring and dissolving; cooling to room temperature, adding distilled water, shaking, and hydrolyzing with citric acid; adding the powder A, stirring, and freeze-drying to obtain a product B; fully and uniformly mixing the product B, alkyl glycoside and citric acid, sieving by a 10-mesh sieve to prepare particles, and drying to obtain particles C; uniformly mixing sodium bicarbonate, a sodium ion energy auxiliary agent, nano chitosan and anhydrous sodium sulfate, sieving with a 10-mesh sieve to prepare particles, and drying to obtain particles D; mixing the particles C, the particles D and the thyme essential oil microspheres, and sieving the mixture by a 16-mesh sieve to prepare particles. The anti-wrinkle effervescent detergent for the cotton cloth prepared by the method has a good decontamination effect, high hand washing cleaning rate and high machine washing cleaning rate, and has good anti-wrinkle performance after being washed.
Description
Technical Field
The invention relates to a preparation method of an anti-wrinkle effervescent detergent for cotton cloth.
Background
With the rapid development of detergent industry, various types of synthetic detergents appear in succession, wherein the development of laundry products is particularly rapid, and various forms of laundry cream, laundry powder, laundry detergent liquid and the like exist so far, wherein the laundry powder is widely accepted by consumers and becomes a preferred product for people to wash clothes, and the concentrated detergent also becomes a future development direction, and has the advantages of high density, small using amount, strong washing capacity, less foam, suitability for machine washing and the like, which are accepted by consumers. However, these detergents have the disadvantages of inconvenience in carrying and large dosage, and the detergents in the form of effervescent tablets have come into play. Meanwhile, for cotton fabrics, wrinkles are easy to occur after cleaning. Therefore, research and development aims at the cotton fabric, the washing tablet has the crease-resistance performance and the good decontamination effect, can greatly facilitate the life of people, and improves the quality of clothes.
Disclosure of Invention
The technical problem to be solved is as follows: the prepared anti-wrinkle effervescent detergent for the cotton cloth has a good decontamination effect, high hand washing cleaning rate and high machine washing cleaning rate, and has good anti-wrinkle performance after being washed.
The technical scheme is as follows: a preparation method of an anti-wrinkle effervescent detergent for cotton cloth comprises the following steps of:
(1) adding water into the sesame seed meal, and then freeze-drying;
(2) taking out, pulverizing, sieving with 40 mesh sieve, adding 50% ethanol water solution, sealing, mixing, pressurizing at 500 and 600MPa, and extracting for 2-3min at a solid-to-liquid ratio of 1: 70-80;
(3) filtering, collecting filtrate, distilling under reduced pressure, and oven drying to obtain powder A;
(4) mixing 10-15 parts of gelatin and 50-75 parts of distilled water, placing into a constant temperature water bath, and stirring at 70 deg.C for dissolving for 50-60 min;
(5) cooling to room temperature, adding 40-60 parts of distilled water, shaking, adding 1.2-2 parts of citric acid, and hydrolyzing at 40 deg.C for 60-70 min;
(6) adding 40-50 parts of the powder A, stirring for 10-20min, and freeze-drying to obtain a product B;
(7) fully and uniformly mixing 5-10 parts of the product B, 9-10 parts of alkyl glycoside and 5-7 parts of citric acid, sieving with a 10-mesh sieve to prepare particles, and drying to obtain particles C;
(8) uniformly mixing 5-7 parts of sodium bicarbonate, 2-3 parts of a sodion energy auxiliary agent, 1-2 parts of nano chitosan and 3-5 parts of anhydrous sodium sulfate, sieving with a 10-mesh sieve to prepare particles, and drying to obtain particles D;
(9) and mixing the particle C, the particle D and 1-2 parts of thyme essential oil microspheres, and sieving with a 16-mesh sieve to prepare particles, thereby obtaining the anti-wrinkle effervescent detergent for cotton cloth with the particle size of 1-3 mm.
Further, the product B, the alkyl glycoside, the citric acid, the sodium bicarbonate, the sodium ion assistant and the anhydrous sodium sulfate are all crushed before use and are sieved by a sieve of 80 meshes for later use.
Further, the preparation method of the thyme essential oil microspheres comprises the following steps:
the first step is as follows: taking 2-5 parts of ethyl cellulose, adding 40-60 parts of 80% ethanol, and stirring for dissolving;
the second step is that: adding 5-10 parts of thyme essential oil and 2% of glycerol, and stirring completely;
the third step: then adding 1wt% of talcum powder and stirring uniformly;
the fourth step: spray drying at feeding speed of 3mL/min, air inlet temperature of 100 deg.C, and atomization pressure of 100 kPa.
Has the advantages that:
1. the anti-wrinkle effervescent detergent for cotton cloth prepared by the invention has a good decontamination effect, the highest hand washing cleaning rate can reach 49.32%, the machine washing cleaning rate can reach 43.31%, which is far higher than that of the commercial detergents 1 and 2, and after the detergent is washed, the wrinkle recovery angle can reach 148 degrees, so that the anti-wrinkle detergent has good anti-wrinkle performance.
2. Each step is simple to operate and is suitable for industrial production.
Detailed Description
Example 1
A preparation method of an anti-wrinkle effervescent detergent for cotton cloth comprises the following steps of:
(1) adding water into the sesame seed meal, and then freeze-drying;
(2) taking out, pulverizing, sieving with 40 mesh sieve, adding 50% ethanol water solution, sealing, mixing, pressurizing to 500MPa, and extracting for 2min, wherein the solid-to-liquid ratio is 1: 70;
(3) filtering, collecting filtrate, distilling under reduced pressure, and oven drying to obtain powder A;
(4) mixing 10 parts of gelatin and 50 parts of distilled water, placing into a constant-temperature water bath, and stirring at 70 ℃ for dissolving for 50 min;
(5) cooling to room temperature, adding 40 parts of distilled water, shaking, adding 1.2 parts of citric acid, and hydrolyzing at 40 deg.C for 60 min;
(6) adding 40 parts of the powder A, stirring for 10min, and freeze-drying to obtain a product B;
(7) fully and uniformly mixing 5 parts of the product B, 9 parts of alkyl glycoside and 5 parts of citric acid, sieving by a 10-mesh sieve to prepare particles, and drying to obtain particles C;
(8) uniformly mixing 5 parts of sodium bicarbonate, 2 parts of a sodion energy assistant, 1 part of nano chitosan and 3 parts of anhydrous sodium sulfate, sieving with a 10-mesh sieve to prepare particles, and drying to obtain particles D;
(9) and mixing the granules C and D with 1 part of thyme essential oil microspheres, and sieving with a 16-mesh sieve to prepare granules, thereby obtaining the anti-wrinkle effervescent detergent for cotton cloth with the particle size of 1-3 mm.
Example 2
A preparation method of an anti-wrinkle effervescent detergent for cotton cloth comprises the following steps of:
(1) adding water into the sesame seed meal, and then freeze-drying;
(2) taking out, pulverizing, sieving with 40 mesh sieve, adding 50% ethanol water solution, sealing, mixing, pressurizing at 550MPa, and extracting for 2.5min, wherein the solid-to-liquid ratio is 1: 75;
(3) filtering, collecting filtrate, distilling under reduced pressure, and oven drying to obtain powder A;
(4) mixing 13 parts of gelatin and 63 parts of distilled water, putting into a constant-temperature water bath kettle, and stirring and dissolving at 70 ℃ for 50-60 min;
(5) cooling to room temperature, adding 50 parts of distilled water, shaking, adding 1.6 parts of citric acid, and hydrolyzing at 40 deg.C for 65 min;
(6) adding 45 parts of the powder A, stirring for 15min, and carrying out freeze drying to obtain a product B;
(7) fully and uniformly mixing 8 parts of the product B, 9.5 parts of alkyl glycoside and 6 parts of citric acid, sieving by a 10-mesh sieve to prepare particles, and drying to obtain particles C;
(8) uniformly mixing 6 parts of sodium bicarbonate, 2.5 parts of a sodion energy auxiliary agent, 1.5 parts of nano chitosan and 4 parts of anhydrous sodium sulfate, sieving with a 10-mesh sieve to prepare particles, and drying to obtain particles D;
(9) and mixing the granule C, the granule D and 1.5 parts of thyme essential oil microspheres, and sieving with a 16-mesh sieve to prepare granules, thereby obtaining the anti-wrinkle effervescent detergent for cotton cloth with the particle size of 1-3 mm.
Example 3
A preparation method of an anti-wrinkle effervescent detergent for cotton cloth comprises the following steps of:
(1) adding water into the sesame seed meal, and then freeze-drying;
(2) taking out, pulverizing, sieving with 40 mesh sieve, adding 50% ethanol water solution, sealing, mixing, pressurizing at 600MPa, and extracting for 3min, wherein the solid-to-liquid ratio is 1: 80;
(3) filtering, collecting filtrate, distilling under reduced pressure, and oven drying to obtain powder A;
(4) mixing 15 parts of gelatin and 75 parts of distilled water, putting into a constant-temperature water bath kettle, and stirring and dissolving at 70 ℃ for 60 min;
(5) cooling to room temperature, adding 60 parts of distilled water, shaking, adding 2 parts of citric acid, and hydrolyzing at 40 deg.C for 70 min;
(6) adding 50 parts of the powder A, stirring for 20min, and freeze-drying to obtain a product B;
(7) fully and uniformly mixing 10 parts of the product B, 10 parts of alkyl glycoside and 7 parts of citric acid, sieving by a 10-mesh sieve to prepare particles, and drying to obtain particles C;
(8) mixing 7 parts of sodium bicarbonate, 3 parts of a sodion energy assistant, 2 parts of nano chitosan and 5 parts of anhydrous sodium sulfate uniformly, sieving with a 10-mesh sieve to prepare particles, and drying to obtain particles D;
(9) and mixing the particle C, the particle D and 2 parts of thyme essential oil microspheres, and sieving with a 16-mesh sieve to prepare particles, thereby obtaining the anti-wrinkle effervescent detergent for cotton cloth with the particle size of 1-3 mm.
And (3) hand washing: under normal temperature and normal pressure and at a natural pH value, 200.00m L hard water (250 mg/kg) (prepared according to GB/T6367) is added into a beaker, JB-01 carbon black greasy dirt cloth strips (6 cm multiplied by 6 cm) and prepared detergents 1 and 2 in the invention and the detergents on the market are added, after the detergent is stirred to be completely dissolved, the detergent is soaked for 30min, the dirty cloth strips are taken out, the same person wears rubber gloves to carry out centralized scrubbing for 20min, the scrubbing frequency is 70 times per minute, 3 parallel experiments are respectively carried out to take average values, the detergent is washed for 5min by tap water, then the detergent is dried and flattened, and the reflectivity of the detergent is measured by a whiteness meter.
Machine washing simulation: JB-01 carbon black greasy cloth strips (6 cm × 6 cm) are immersed in a beaker containing 200.00m L prepared detergent of the present invention or commercially available detergents 1 and 2, stirred electrically at 25 deg.C for 40 min, and stirred and cleaned in 60.00 mL of tap water at 25 deg.C for 5min, taken out, dried, flattened, and its reflectance is measured with a whiteness meter.
And measuring the polluted cloth before and after the test, measuring and calculating the average value for multiple times, and recording data. Calculated using the following formula:
in the formula: dr-cleaning efficiency
Rw-the reflectance of the soiled cloth after washing%
Rs-reflectance before washing of contaminated cloth%
Ro-reflectance of original cloth,%.
The crease recovery angle of the cotton was determined according to GB/T3819-1997 determination of the recovery angle for crease recovery of textile fabrics.
TABLE 1 stain removal and wrinkle resistance of high-performance detergent compositions
The anti-wrinkle effervescent detergent for cotton cloth prepared by the invention has a good decontamination effect, the highest hand washing cleaning rate can reach 49.32%, the machine washing cleaning rate can reach 43.31%, which is far higher than that of the commercial detergents 1 and 2, and after the detergent is washed, the wrinkle recovery angle can reach 148 degrees, so that the anti-wrinkle detergent has good anti-wrinkle performance.
Claims (3)
1. A preparation method of an anti-wrinkle effervescent detergent for cotton cloth is characterized by comprising the following steps: the components by weight portion comprise the following steps:
(1) adding water into the sesame seed meal, and then freeze-drying;
(2) taking out, pulverizing, sieving with 40 mesh sieve, adding 50% ethanol water solution, sealing, mixing, pressurizing at 500 and 600MPa, and extracting for 2-3min at a solid-to-liquid ratio of 1: 70-80;
(3) filtering, collecting filtrate, distilling under reduced pressure, and oven drying to obtain powder A;
(4) mixing 10-15 parts of gelatin and 50-75 parts of distilled water, placing into a constant temperature water bath, and stirring at 70 deg.C for dissolving for 50-60 min;
(5) cooling to room temperature, adding 40-60 parts of distilled water, shaking, adding 1.2-2 parts of citric acid, and hydrolyzing at 40 deg.C for 60-70 min;
(6) adding 40-50 parts of the powder A, stirring for 10-20min, and freeze-drying to obtain a product B;
(7) fully and uniformly mixing 5-10 parts of the product B, 9-10 parts of alkyl glycoside and 5-7 parts of citric acid, sieving with a 10-mesh sieve to prepare particles, and drying to obtain particles C;
(8) uniformly mixing 5-7 parts of sodium bicarbonate, 2-3 parts of a sodion energy auxiliary agent, 1-2 parts of nano chitosan and 3-5 parts of anhydrous sodium sulfate, sieving with a 10-mesh sieve to prepare particles, and drying to obtain particles D;
(9) and mixing the particle C, the particle D and 1-2 parts of thyme essential oil microspheres, and sieving with a 16-mesh sieve to prepare particles, thereby obtaining the anti-wrinkle effervescent detergent for cotton cloth with the particle size of 1-3 mm.
2. The preparation method of the anti-wrinkle effervescent detergent for the cotton cloth according to claim 1 is characterized in that: the product B, alkyl glycoside, citric acid, sodium bicarbonate, sodium ion assistant and anhydrous sodium sulfate are crushed before use and sieved by a 80-mesh sieve for later use.
3. The preparation method of the anti-wrinkle effervescent detergent for the cotton cloth according to claim 1 is characterized in that: the preparation method of the thyme essential oil microspheres comprises the following steps:
the first step is as follows: taking 2-5 parts of ethyl cellulose, adding 40-60 parts of 80% ethanol, and stirring for dissolving;
the second step is that: adding 5-10 parts of thyme essential oil and 2% of glycerol, and stirring completely;
the third step: then adding 1wt% of talcum powder and stirring uniformly;
the fourth step: spray drying at feeding speed of 3mL/min, air inlet temperature of 100 deg.C, and atomization pressure of 100 kPa.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201810778361.7A CN109181884B (en) | 2018-07-16 | 2018-07-16 | Preparation method of anti-wrinkle effervescent detergent for cotton cloth |
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| CN201810778361.7A CN109181884B (en) | 2018-07-16 | 2018-07-16 | Preparation method of anti-wrinkle effervescent detergent for cotton cloth |
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| CN109181884B true CN109181884B (en) | 2022-04-08 |
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| CN100382805C (en) * | 2006-01-11 | 2008-04-23 | 南京工业大学 | Azithromycin enteric casing microsphere and its preparing process |
| CN101914415B (en) * | 2010-08-27 | 2012-02-01 | 郭俊华 | Effervescent detergent and preparation method thereof |
| CN104177370B (en) * | 2014-09-04 | 2016-10-05 | 陕西源邦生物技术有限公司 | A kind of method preparing high-load sesamin from sesame seed meal |
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