CN101914415B - Effervescent detergent and preparation method thereof - Google Patents
Effervescent detergent and preparation method thereof Download PDFInfo
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- CN101914415B CN101914415B CN2010102643430A CN201010264343A CN101914415B CN 101914415 B CN101914415 B CN 101914415B CN 2010102643430 A CN2010102643430 A CN 2010102643430A CN 201010264343 A CN201010264343 A CN 201010264343A CN 101914415 B CN101914415 B CN 101914415B
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Abstract
The invention discloses an effervescent detergent. The effervescent detergent comprises the following components in part by weight: 14.0 to 16.0 parts of sodium lauryl sulfate, 1.0 to 5.0 parts of fatty acid polyoxyethylene ether, 5.0 to 10.0 parts of sodium ion energy auxiliary, 10 to 25 parts of anhydrous sodium sulfate, 25.0 to 35.0 parts of sodium bicarbonate, 30.0 to 40.0 parts of citric acid, 0.5 to 3.0 parts of biological complex enzyme, 0.2 to 1.0 part of ethylene diamine tetraacetic acid disodium and 0.0010 to 0.0030 part of brightening agent. The effervescent detergent of the invention is prepared by the following steps of: soft material preparation by taking an acid and an alkali as a disintegrating agent; grain preparation; drying; grain fixation; and finally extrusion or granulation. After the effervescent detergent is put into water, acidic materials and alkaline materials in the effervescent detergent are reacted to form carbon dioxide gas to effervesce and disintegrate tablets or grains. The detergent of the invention has high solubility and can also be quickly disintegrated and uniformly dispersed and dissolved even in cold water, which contributes to fully playing the washing performance well.
Description
Technical field
The present invention relates to a kind of effervescent detergent and preparation method thereof.
Background technology
At present, people's washing clothes is most to use washing powder, but there is following defective in washing powder: 1, washing effect is poor, and spots such as oil stain are difficult to remove, even use a large amount of washing powder; 2, often contain the material that can pollute environment in the washing powder, such as containing phosphorus or 4A zeolite; 3, the washing powder consumption is big, and detersive efficiency is low.
Summary of the invention
To above-mentioned prior art, the invention provides that a kind of washing effect is good, efficient is high, the effervescent detergent of environmentally safe, and its preparation method is provided.
The present invention realizes through following technical scheme:
A kind of effervescent detergent comprises the component of following weight part: 14.0～16.0 parts of sodium laurylsulfates, 1.0～5.0 parts of aliphatic acid polyethenoxy ethers; 5.0～10.0 parts of sodium ability auxiliary agents, 10～25 parts of SODIUM SULPHATE ANHYDROUS 99PCTs, 25.0～35.0 parts of sodium hydrogencarbonates; 30.0～40.0 parts of Citric Acids; 0.5～3.0 part of compound bio-enzyme, 0.2～1.0 part of EDTA Disodium, 0.0010～0.0030 part in whitening agent.
Said effervescent detergent also comprises essence, and the weight part of essence is 0.1～0.3 part.
Preferably, form: 16.0 parts of sodium laurylsulfates, 2.0 parts of aliphatic acid polyethenoxy ethers by the component of following weight part; 5.0 parts of sodium ability auxiliary agents, 12.5 parts of SODIUM SULPHATE ANHYDROUS 99PCTs, 30.0 parts of sodium hydrogencarbonates; 33.0 parts of Citric Acids, 1.0 parts of compound bio-enzymes, 0.5 part of EDTA Disodium; 0.0015 part in whitening agent, 0.2 part in essence.
The preferred AEO-7 model of said aliphatic acid polyethenoxy ether.
Said sodium can auxiliary agent be soap acid sodium (MR
2COONa), be the polynary mixed mineral fat that a kind of the Nature forms through long-time motion change repeatedly, this material contains a large amount of carbonate, silicon-dioxide mixed mineral fat, not phosphorous, aluminium, heavy metal; This material is soluble in water; It is strong to have wetting, infiltration, emulsification, dispersion, increase-volume, foaming, decontamination; Having good calcium exchange capacity and antiredeposition property simultaneously, is the active washing assistant of a kind of novel potent, and this auxiliary agent can industry and trade ltd be provided by smooth source, Weihui City, Xinxiang, Henan Province sodium; Is its article number YZ7750934SL? Trade name is: day sodium-sodium can the active strong auxiliary agent (this product is to buy from subordinate chemical department of former the Ministry of Chemical Industry, and the staple of product is a soap acid sodium, hence obtains one's name) of imitating.
Said whitening agent is fluorescent brightener CBS-X, and its chemical name is 4 '-two (2-sulfonic benzo vinyl)-1,1 '-biphenyl.
Said compound bio-enzyme is the binary prozyme 4.8/20T that Novozymes Company provides, and can buy from market, and its trade name is: the Sai Wei/compound detersive enzyme 4.8/20T of beautiful ripple binary, English name: T-BLEND SAVINASE/LIPOLASE 4.8/20T; Its article number is: Novozymes Company provides three kinds of this product to be respectively: IUB numbering: 3.4.21.62/3.1.1.3, CAS compiles 9014-01-1/9001-62-1, EINECS numbering: 232-752-2/232-619-9.
A kind of preparation method of effervescent detergent, step is following:
(1) with sodium laurylsulfate, aliphatic acid polyethenoxy ether, Citric Acid, sodium hydrogencarbonate, SODIUM SULPHATE ANHYDROUS 99PCT and sodium ability auxiliary agent pulverize separately are crossed 80 mesh sieves, and be subsequent use;
(2) with sodium laurylsulfate, aliphatic acid polyethenoxy ether, Citric Acid and whitening agent (tensio-active agent is sodium laurylsulfate and aliphatic acid polyethenoxy ether) mixing, process softwood, system particle, drying;
(3) with sodium hydrogencarbonate, SODIUM SULPHATE ANHYDROUS 99PCT and sodium ability auxiliary agent mixing, process softwood, system particle, drying;
(4) particle that step (2) and (3) is obtained mixed the whole grain of 16 mesh sieves, added essence and compound bio-enzyme, carried out always mixing granulating or compressing tablet, promptly got effervescent detergent.
In the said step (5), total granula particle diameter that mixes after granulating is 0.5～3 millimeter, and the tablet diameters that obtains behind the compressing tablet is 15 millimeters～20 millimeters, and thickness is 2 millimeters～5 millimeters; The quality of granula or tablet is 1.5～2.5g.
Effervescent detergent of the present invention is to utilize bronsted lowry acids and bases bronsted lowry to cook disintegrating agent, through the preparation softwood; Process particle again, through oven dry, whole grain, after extruding or granulation process; Wherein acid and alkaloid substance attack after the entry produces dioxide gas and causes tablet or the disintegration of granule effervesce.Washing composition of the present invention has splendid solvability, even the dissolving of also disintegration rapidly in cold water, homodisperse more helps bringing into play scourability in all directions, is a kind of cleaning product that technology advanced person, environmental protection, development potentiality have good prospects that has.
Preparation technology of the present invention compares with technology of the prior art, and method scale of investment of the present invention is little, the no three wastes; Production technique investment of the prior art is big, energy consumption is high, dust is arranged.Raw material ratio is right: the present invention has adopted the very high starting material of biological degradability, environmentally safe; And contain phosphorus or 4A zeolite in the like product of the prior art mostly, and and because country prohibits phosphorus and pollutes, the 4A zeolite is water insoluble can to pollute at the bottom of the connate water, institute and is prone to cause environmental pollution so that its application is restricted.
The present invention has following beneficial effect:
1. consumption is few, soil removability is strong; Prescription of the present invention is for concentrating formulating of recipe, and density is the nearly twice of concentrated detergent powder, has greatly saved storage space, trucking costs and wrapping material; It adopts high-tech multi-element biologic prozyme and efficient pure white dose of CBS-X; Can go deep into clothes fiber inside, thoroughly remove multiple special spots such as stain that common washing powder and washing liquid be difficult to remove and bloodstain, milk stain, sweat stain, oil stain, fruit juice stain, make clothing beautiful as new.
2. the technology of employing new technology is made; It through mixing of materials, system softwood, the wet grain of system, dry, whole grain, always mix, extruding is granulated or pressed disc technique forms; Be different from common washing powder production technique fully; Spread, form uniform washing soln through the rapid disintegration of effect capillaceous after the product entry; So that its in use the snap-out release of active ingredient make washing composition can thoroughly give full play to its performance with making full use of, solved common washing powder entry and sunk to the bottom and do not dissolve, cause the bad problem of washing effect.
3. the biological degradation rate of the raw material that the present invention selected for use is high, and not phosphorous, 4A zeolite uses the back not have deposition; Neutral instant washings etc. are adopted the compound preparation of natural promoter material, environmentally safe; Portably use convenience, do not touch with one's hand; Unrestrained, disintegration rapidly, be easy to rinsing: disintegration in the disintegration in the effervescent granule 15 seconds, 15 millimeters in tablet 4 minutes.
Prospect analysis of market: from the listing in succession of the New-type detergent of several big detergent manufacturer of the quick growth and the world of external novel disintegration washing granule agent in recent years, tablet share of market on Europe, the U.S., Japan and other places; Development along with society; Improving constantly of people's living standard; The popularity rate of washing machine improves greatly, and along with social development and people's idea is brought in constant renewal in, the disintegration washing composition will be that a clothing that has the market competitiveness is used cleaning product.
In a word, effervescent detergent of the present invention has advantages such as soil removability is strong, detersive efficiency is high, environmentally safe.
Embodiment
Below in conjunction with embodiment the present invention is further described.
A kind of effervescent detergent of embodiment 1 preparation
Prescription is: 16.0 kilograms of sodium laurylsulfates, 2.0 kilograms of AEO AEO-7,5.0 kilograms of sodium ability auxiliary agents; 12.5 kilograms of SODIUM SULPHATE ANHYDROUS 99PCTs, 30.0 kilograms of sodium hydrogencarbonates, 33.0 kilograms of Citric Acids; 1.0 kilograms of compound bio-enzymes; 0.5 kilogram of EDTA Disodium, 0.0015 kilogram in whitening agent, 0.2 kilogram in essence.
Preparation technology is:
(1) with sodium laurylsulfate, AEO, Citric Acid, sodium hydrogencarbonate, SODIUM SULPHATE ANHYDROUS 99PCT and sodium ability auxiliary agent pulverize separately are crossed 80 mesh sieves, and be subsequent use;
(2) with sodium laurylsulfate, AEO, Citric Acid and whitening agent mixing, process softwood, system particle, drying;
(3) with sodium hydrogencarbonate, SODIUM SULPHATE ANHYDROUS 99PCT and sodium ability auxiliary agent mixing, process softwood, system particle, drying;
(4) particle that step (2) and (3) is obtained mixes, and crosses the whole grain of 16 mesh sieves, adds essence and compound bio-enzyme, carries out always mixing granulating, and makes particle diameter and be 0.5 millimeter granule, is effervescent detergent.
A kind of effervescent detergent of embodiment 2 preparations
Prescription is: 14.0 kilograms of sodium laurylsulfates, 5.0 kilograms of AEO AEO-7,10.0 kilograms of sodium ability auxiliary agents; 10 kilograms of SODIUM SULPHATE ANHYDROUS 99PCTs, 35.0 kilograms of sodium hydrogencarbonates, 30.0 kilograms of Citric Acids; 3.0 kilograms of compound bio-enzymes; 1.0 kilograms of EDTA Disodiums, 0.0010 kilogram in whitening agent, 0.1 kilogram in essence.
Preparation technology is:
(1) with sodium laurylsulfate, AEO, Citric Acid, sodium hydrogencarbonate, SODIUM SULPHATE ANHYDROUS 99PCT and sodium ability auxiliary agent pulverize separately are crossed 80 mesh sieves, and be subsequent use;
(2) with sodium laurylsulfate, AEO, Citric Acid and whitening agent mixing, process softwood, system particle, drying;
(3) with sodium hydrogencarbonate, SODIUM SULPHATE ANHYDROUS 99PCT and sodium ability auxiliary agent mixing, process softwood, system particle, drying;
(4) particle that step (2) and (3) is obtained mixes, and crosses the whole grain of 16 mesh sieves, adds essence and compound bio-enzyme, carries out always mixing granulating, and makes particle diameter and be 3 millimeters granule, is effervescent detergent.
A kind of effervescent detergent of embodiment 3 preparations
Prescription is: 15.0 kilograms of sodium laurylsulfates, 1.0 kilograms of AEO AEO-7,8.0 kilograms of sodium ability auxiliary agents; 25 kilograms of SODIUM SULPHATE ANHYDROUS 99PCTs, 25.0 kilograms of sodium hydrogencarbonates, 40.0 kilograms of Citric Acids; 0.5 kilogram of compound bio-enzyme; 0.2 kilogram of EDTA Disodium, 0.003 kilogram in whitening agent, 0.3 kilogram in essence.
Preparation technology is:
(1) with sodium laurylsulfate, AEO, Citric Acid, sodium hydrogencarbonate, SODIUM SULPHATE ANHYDROUS 99PCT and sodium ability auxiliary agent pulverize separately are crossed 80 mesh sieves, and be subsequent use;
(2) with sodium laurylsulfate, AEO, Citric Acid and whitening agent mixing, process softwood, system particle, drying;
(3) with sodium hydrogencarbonate, SODIUM SULPHATE ANHYDROUS 99PCT and sodium ability auxiliary agent mixing, process softwood, system particle, drying;
(4) particle that step (2) and (3) is obtained mixes, and crosses the whole grain of 16 mesh sieves, adds essence and compound bio-enzyme, carries out compressing tablet, and making diameter is 15 millimeters, and thickness is 5 millimeters, and quality is the tablet of 1.5g, is effervescent detergent.
A kind of effervescent detergent of embodiment 4 preparations
Prescription is: 16.0 kilograms of sodium laurylsulfates, 3.0 kilograms of AEO AEO-7,9.0 kilograms of sodium ability auxiliary agents; 20 kilograms of SODIUM SULPHATE ANHYDROUS 99PCTs, 32.0 kilograms of sodium hydrogencarbonates, 37.0 kilograms of Citric Acids; 2.0 kilograms of compound bio-enzymes; 0.8 kilogram of EDTA Disodium, 0.002 kilogram in whitening agent, 0.2 kilogram in essence.
Preparation technology is:
(1) with sodium laurylsulfate, AEO, Citric Acid, sodium hydrogencarbonate, SODIUM SULPHATE ANHYDROUS 99PCT and sodium ability auxiliary agent pulverize separately are crossed 80 mesh sieves, and be subsequent use;
(2) with sodium laurylsulfate, AEO, Citric Acid and whitening agent mixing, process softwood, system particle, drying;
(3) with sodium hydrogencarbonate, SODIUM SULPHATE ANHYDROUS 99PCT and sodium ability auxiliary agent mixing, process softwood, system particle, drying;
(4) particle that step (2) and (3) is obtained mixes, and crosses the whole grain of 16 mesh sieves, adds essence and compound bio-enzyme, carries out compressing tablet, and making diameter is 20 millimeters, and thickness is 2 millimeters, and quality is the tablet of 2.5g, promptly gets effervescent detergent.
Among the above embodiment, used sodium can be soap acid sodium by auxiliary agent, can industry and trade ltd provide by smooth source, Weihui City, Xinxiang, Henan Province sodium, and is its article number YZ7750934SL?, trade name is: day sodium-sodium can actively be imitated auxiliary agent by force;
Used whitening agent is fluorescent brightener CBS-X;
Used compound bio-enzyme is the binary prozyme 4.8/20T that Novozymes Company provides.
Experiment effervescent detergent recruitment evaluation
Department assesses by the solution of the Asia-Pacific client's scheme of Novi's letter (China) Investment Co., Ltd detergent industry, and is specific as follows:
Experiment condition, (clean ability sample is effervescent detergent of the present invention) as shown in table 1:
Table 1 experiment condition
Experimental result and discussion: the result is as shown in table 2
Table 2
Discuss:
All clean ability samples all reach GB A level product standard;
All clean ability samples have all surpassed the washing effect of GB powder;
Clean sample and the common GB powder of newly filling a prescription has notable difference.
* wash conditions: vertical spotter (Denmark)/wash temperature: the 30C/ water hardness: 250ppm (Ca/Mg 3/2)/washing time: 20 minutes.
Claims (3)
1. an effervescent detergent is characterized in that, comprises the component of following weight part: 14.0～16.0 parts of sodium laurylsulfates; 1.0～5.0 parts of aliphatic acid polyethenoxy ethers, 5.0～10.0 parts of sodium ability auxiliary agents, 10～25 parts of SODIUM SULPHATE ANHYDROUS 99PCTs; 25.0～35.0 parts of sodium hydrogencarbonates, 30.0～40.0 parts of Citric Acids, 0.5～3.0 part of compound bio-enzyme; 0.2～1.0 part of EDTA Disodium, 0.0010～0.0030 part in whitening agent, 0.1～0.3 part in essence;
Said sodium can auxiliary agent be soap acid sodium.
2. a kind of effervescent detergent according to claim 1 is characterized in that, is made up of the component of following weight part: 16.0 parts of sodium laurylsulfates; 2.0 parts of aliphatic acid polyethenoxy ethers, 5.0 parts of sodium ability auxiliary agents, 12.5 parts of SODIUM SULPHATE ANHYDROUS 99PCTs; 30.0 parts of sodium hydrogencarbonates, 33.0 parts of Citric Acids, 1.0 parts of compound bio-enzymes; 0.5 part of EDTA Disodium, 0.0015 part in whitening agent, 0.2 part in essence.
3. a kind of effervescent detergent according to claim 1 and 2 is characterized in that: said whitening agent is fluorescent brightener CBS-X.
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| Application Number | Priority Date | Filing Date | Title |
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| CN2010102643430A CN101914415B (en) | 2010-08-27 | 2010-08-27 | Effervescent detergent and preparation method thereof |
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| CN2010102643430A CN101914415B (en) | 2010-08-27 | 2010-08-27 | Effervescent detergent and preparation method thereof |
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| CN101914415A CN101914415A (en) | 2010-12-15 |
| CN101914415B true CN101914415B (en) | 2012-02-01 |
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Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ES2443767B1 (en) * | 2012-07-20 | 2014-11-26 | Proeco Químicas, S.L. | Detergent composition in the form of effervescent tablet |
| CN102965222B (en) * | 2012-12-04 | 2014-06-18 | 新时代健康产业（集团）有限公司 | Low-foaming anti-crease soft laundry detergent and preparation method thereof |
| CN103897839A (en) * | 2012-12-26 | 2014-07-02 | 青岛锦涟鑫商贸有限公司 | An environmental-friendly detergent |
| CN103555431A (en) * | 2013-10-30 | 2014-02-05 | 合肥市华美光电科技有限公司 | Printed circuit board cleaning agent and preparation method thereof |
| CN105238604A (en) * | 2015-11-09 | 2016-01-13 | 云南健牛生物科技有限公司 | High-stability salt-containing clothes washing effervescent tablet and preparation method thereof |
| CN106350328A (en) * | 2016-08-22 | 2017-01-25 | 兰州泰坦生物科技有限责任公司 | Soap powder antibacterial cleaning effervescent tablet containing nano-silver |
| CN106635474A (en) * | 2016-10-12 | 2017-05-10 | 吉冠（上海）新材料科技有限公司 | Highly-concentrated neutral-washing zinc-ion antibacterial effervescent tablets and preparation method thereof |
| CN109181884B (en) * | 2018-07-16 | 2022-04-08 | 深圳市三浦天然化妆品有限公司 | Preparation method of anti-wrinkle effervescent detergent for cotton cloth |
| CN110025498A (en) * | 2019-04-28 | 2019-07-19 | 重庆第二师范学院 | A kind of portable effervesce soap of soapberry and preparation method |
| WO2021161059A1 (en) * | 2020-02-14 | 2021-08-19 | Wash To Go, Unipessoal, Lda | Detergent composition in effervescent tablet form |
| CN111494244A (en) * | 2020-04-27 | 2020-08-07 | 台州地听科技有限公司 | Hand-washing effervescent tablet and preparation method thereof |
| CN116035195A (en) * | 2022-12-26 | 2023-05-02 | 桑泽健康科技(上海)有限公司 | Compound enzyme of food enzyme preparation and preparation method thereof |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3516937A (en) * | 1967-05-15 | 1970-06-23 | Armour & Co | Sustained action detergent product containing encapsulated sodium tripolyphosphate |
| GB0115552D0 (en) * | 2001-05-16 | 2001-08-15 | Unilever Plc | Particulate laundry detergent composition containing zeolite |
| GB0221739D0 (en) * | 2002-09-19 | 2002-10-30 | Unilever Plc | Detergent compositions |
| CN100395324C (en) * | 2006-09-01 | 2008-06-18 | 王涛 | Synthetic detergent and its preparation method |
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