CN108865490A - The fruits and vegetables cleaning agent and preparation method thereof of microemulsion dosage removal pesticide residue - Google Patents
The fruits and vegetables cleaning agent and preparation method thereof of microemulsion dosage removal pesticide residue Download PDFInfo
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- CN108865490A CN108865490A CN201810792733.1A CN201810792733A CN108865490A CN 108865490 A CN108865490 A CN 108865490A CN 201810792733 A CN201810792733 A CN 201810792733A CN 108865490 A CN108865490 A CN 108865490A
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/201—Monohydric alcohols linear
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2041—Dihydric alcohols
- C11D3/2044—Dihydric alcohols linear
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2065—Polyhydric alcohols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
- C11D3/225—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin etherified, e.g. CMC
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/33—Amino carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/04—Carboxylic acids or salts thereof
- C11D1/10—Amino carboxylic acids; Imino carboxylic acids; Fatty acid condensates thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
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Abstract
The invention discloses a kind of fruits and vegetables cleaning agent of microemulsion dosage removal pesticide residue, each component including following parts by weight：5-30 parts of alkyl glycosides type surfactant, 5-25 parts of amino acid type surfactant, 0.1-10 parts of plants essential oil, 0-10 parts of cosolvent, 0-5 parts of rheology control agent, 0-2 parts of pH adjusting agent, surplus is that deionized water adds to 100 parts.The present invention overcomes existing technical barrier, so that cleaning agent other than having good removing pesticide residue ability, also has stable micro emulsion type structure by the way that the surfactant of appropriate ratio, auxiliary agent, oil to be mutually combined.And micro emulsion is made of the degradable surfactant of green, biology, oil mutually uses natural plant essential oils, and therefore, micro-emulsion type fruits and vegetables cleaning agent of the invention has many advantages, such as green, environmental protection, low stimulation.
Description
Technical field
The present invention relates to daily chemical product technical fields, and in particular to a kind of fruits and vegetables of microemulsion dosage removal pesticide residue
Cleaning agent and preparation method thereof.
Background technique
China's agricultural develops rapidly in recent years, and the scope of application of pesticide constantly expands, and usage amount is also continuously increased, in water
A large amount of uses in fruit vegetable production, necessarily will cause the pesticide residue in fruits and vegetables.The residual agriculture being adsorbed on fruit and vegetable
Medicine can constitute human body and seriously endanger, and therefore, whether the fruit and vegetable of daily consumption is that the majority of consumers are concerned about the most safely
One of problem.In order to guarantee edible fruit and vegetable safe and non-toxic, the cleaning to fruits and vegetables is essential step.For melon
There are many rinse product of fruit vegetable washing, but there are more limitation, such as the clean effect of rinse product are good, but go
It is ineffective except pesticide.In addition, synthetic surfactant contained by most of detergent easily remains on fruit and vegetable surfaces at present, from
And leading to secondary pollution, long-term intake may generate savings property to human body and poison.Therefore, be badly in need of exploitation it is environmentally protective, pollution-free,
Remove the good fruits and vegetables scavenger specially of agriculture residual effect fruit.
It is more to the development of fruits and vegetables cleaning agent at present.Such as：Chinese patent (publication number：CN104745328B) open
The preparation method of a kind of Fructus Schisandrae Sphenantherae extract and the fruits and vegetables cleaning agent of Oil-tea-cake extract compounding, can safely, effectively
Fruit and vegetable surfaces worm's ovum, microorganism, dirt and pesticide residue are removed, and does not change the nutritional ingredient and taste of fruits and vegetables.Chinese patent
(publication number：CN104130878B a kind of have both except fruit wax and except the fruits and vegetables cleaning agent of pesticide residue effect and its preparation) is disclosed
Method, can effectively remove the fruit wax of fruit surface, and can remove pesticide residue simultaneously.Chinese patent (publication number：
CN104450288B a kind of fruits and vegetables detergent and preparation method thereof based on strong brine) is disclosed, can be effectively removed on fruits and vegetables
The harmful substances such as remains of pesticide, waxing, and have antibiotic and sterilizing ability.
But above-mentioned development is the compound aqueous of surfactant, microstructure is that surfactant is compound
Micella, and micella is weaker to the pesticide solubilising power of fruit and vegetable surfaces in washing process.
Micro emulsion is the Thermodynamically stable with oily phase kernel of the partial size that is made of surfactant in 100nm or so
System, lesser partial size are conducive to the wax layer through fruit and vegetable surfaces, and biggish oil phase kernel is then conducive to fruit and vegetable surfaces
Remaining pesticide carries out solubilising.But micro emulsion must be in the surfactant of appropriate ratio, auxiliary agent, oily phase composition condition
It is lower to constitute, there is certain technical difficulty.Therefore, how to develop with the micro-emulsion type fruits and vegetables cleaning agent except the residual ability of agriculture
It is that the field technical staff needs the technical problem solved at present.
Summary of the invention
Goal of the invention：The purpose of the invention is to make up the deficiency of existing investigative technique, a kind of main application is provided
In the washing of vegetables and fruit, and it can effectively remove the microemulsion dosage fruits and vegetables cleaning agent of fruit and vegetable surfaces pesticide residue.
Technical solution：A kind of fruits and vegetables cleaning agent of microemulsion dosage removal pesticide residue, each group including following parts by weight
Point：5-30 parts of alkyl glycosides type surfactant, 5-25 parts of amino acid type surfactant, 0.1-10 parts of plants essential oil, hydrotropy
0-10 parts of agent, 0-5 parts of rheology control agent, 0-2 parts of pH adjusting agent, surplus is that deionized water adds to 100 parts.
It further include 0.01-2 parts of chelating agent.
The alkyl chain length of the alkyl glycosides type surfactant is C8, C10, C12, C14, C16, C18, the alkane
Base glucoside type surfactant is used by the alkyl glycosides type surfactant compound of at least two different alkyl chain lengths
The amino acid classes of the amino acid type surfactant are glycine, glutamic acid, sarcosine；The amino acid pattern
The alkyl group of surfactant is lauroyl, in cocoyl, myristoyl, palmityl, stearyl, oleoyl
It is any.
The amino acid type surfactant is potassium amino acid, sodium-salt type, does not dissociate amino acid pattern.
The plants essential oil is at least one of cinnamon essential oil, tea tree ethereal oil, thyme linaloe oil, lemon oil, eucalyptus oil.
The cosolvent is at least one of ethyl alcohol, propylene glycol, butanediol, glycerine.
The rheology control agent is carboxymethyl cellulose, in hydroxyethyl cellulose, hydroxypropyl methyl cellulose, xanthan gum
It is at least one.
The cleaning agent be it is transparent or semitransparent, dosage form is micro emulsion.Dosage form construct in the present invention and wherein institute
The plants essential oil contained matches, so that cleaning agent has the good ability for removing pesticide residue.
The invention also discloses the preparation methods of above-mentioned fruits and vegetables cleaning agent, include the following steps：
1) alkyl glycosides type surfactant and amino acid type surfactant be heated to 50 DEG C of constant temperature and by above-mentioned ratio
Example is uniformly mixed, and is cooled to room temperature, is obtained mixed surfactant system；
2) it is added in the mixed surfactant system that step 1) obtains and stirs after mixing plants essential oil and cosolvent
Uniformly；
3) be added after being uniformly dissolved rheology control agent, chelating agent, pH adjusting agent in deionized water 2) obtained in mix
It closes object and stirs evenly.
Beneficial effect：The present invention is overcome existing by the way that the surfactant of appropriate ratio, auxiliary agent, oil to be mutually combined
Some technical barriers, so that cleaning agent other than having good removing pesticide residue ability, also has stable micro emulsion
Type structure.And micro emulsion is made of the degradable surfactant of green, biology, oil mutually uses natural plant essential oils, therefore,
Micro-emulsion type fruits and vegetables cleaning agent of the invention has many advantages, such as green, environmental protection, low stimulation.
Specific embodiment
In the present invention, pH adjusting agent is citric acid.Raw material is commercially available in the present invention.
Embodiment 1：
A kind of fruits and vegetables cleaning agent of microemulsion dosage removal pesticide residue, formula such as following table：
| Material name | Mass fraction |
| Alkyl glycosides C12-14 | 15 |
| Sodium lauroyl glutamate | 5 |
| Lemon oil | 1 |
| Citric acid | 0.4 |
| Deionized water | Surplus (adds to 100 parts) |
According to preparation method, by preparation method by alkyl glycosides C12-14, sodium lauroyl glutamate mixes equal at 50 DEG C
It is even and cooling, lemon oil is put into wherein and stirred 5-10 minutes, while citric acid being uniformly dissolved in deionized water, finally
It is stirred 10-15 minutes after the two is blended, product is canned after standing to basic non-foam.
Embodiment 2：
A kind of fruits and vegetables cleaning agent of microemulsion dosage removal pesticide residue, formula such as following table：
| Material name | Mass fraction |
| Alkyl glycosides C12-14 | 15 |
| Sodium lauroyl sarcosine | 5 |
| Lemon oil | 1 |
| Citric acid | 0.4 |
| Deionized water | Surplus (adds to 100 parts) |
By preparation method by alkyl glycosides C12-14, sodium lauroyl sarcosine is uniformly mixed and cooling, by lemon at 50 DEG C
Lemon oil puts into wherein and stirs 5-10 minutes, while citric acid being uniformly dissolved in deionized water, after finally the two is blended
Stirring 10-15 minutes.Product is canned after standing to basic non-foam.
Embodiment 3：
A kind of fruits and vegetables cleaning agent of microemulsion dosage removal pesticide residue, formula such as following table：
| Material name | Mass fraction |
| Alkyl glycosides C8-14 | 15 |
| Sodium cocoyl glutamate | 5 |
| Lauroyl glycine potassium | 1 |
| Xanthan gum | 0.2 |
| Lemon oil | 1 |
| Disodium ethylene diamine tetraacetate | 0.1 |
| Citric acid | 0.4 |
| Deionized water | Surplus (adds to 100 parts) |
By preparation method by alkyl glycosides C8-14, sodium cocoyl glutamate, lauroyl glycine potassium mixes at 50 DEG C
It is even and cooling, lemon oil investment wherein and is stirred 5-10 minutes, while by xanthan gum, disodium ethylene diamine tetraacetate, citric acid
It is uniformly dissolved, is stirred 10-15 minutes after finally the two is blended in deionized water.Tank after product is stood to basic non-foam
Dress.
Embodiment 4：
A kind of fruits and vegetables cleaning agent of microemulsion dosage removal pesticide residue, formula such as following table：
| Material name | Mass fraction |
| Alkyl glycosides C8-14 | 16 |
| Sodium lauroyl sarcosine | 4 |
| Ethyl alcohol | 5 |
| Butanediol | 2 |
| Lemon oil | 1.5 |
| Tea tree ethereal oil | 1 |
| Hydroxyethyl cellulose | 0.4 |
| Disodium ethylene diamine tetraacetate | 0.1 |
| Citric acid | 0.5 |
| Deionized water | Surplus (adds to 100 parts) |
By preparation method by alkyl glycosides C8-14, sodium lauroyl sarcosine is uniformly mixed at 50 DEG C and cooling, by second
Alcohol, butanediol, lemon oil, tea tree ethereal oil investment wherein and stir 10 minutes, while by hydroxyethyl cellulose, ethylenediamine tetra-acetic acid
Disodium, citric acid are uniformly dissolved in deionized water, are stirred 10-15 minutes after finally the two is blended.Product is stood to basic
It is canned after non-foam.
Embodiment 5：
A kind of fruits and vegetables cleaning agent of microemulsion dosage removal pesticide residue, formula such as following table：
| Material name | Mass fraction |
| Alkyl glycosides C12-14 | 16 |
| Oleoyl sodium glutamate | 4 |
| Ethyl alcohol | 5 |
| Tea tree ethereal oil | 0.5 |
| Eucalyptus leaf essential oil | 0.5 |
| Hydroxypropyl methyl cellulose | 0.6 |
| Disodium ethylene diamine tetraacetate | 0.1 |
| Citric acid | 0.5 |
| Deionized water | Surplus (adds to 100 parts) |
By preparation method by alkyl glycosides C12-14, oleoyl sodium glutamate is uniformly mixed and cooling at 50 DEG C, by ethyl alcohol,
Tea tree ethereal oil, eucalyptus leaf essential oil investment wherein and stir 5-10 minutes, while by hydroxypropyl methyl cellulose, ethylenediamine tetra-acetic acid two
Sodium, citric acid are uniformly dissolved in deionized water, are stirred 10-15 minutes after finally the two is blended.Product stand to substantially without
It is canned after foam.
Embodiment 6：
A kind of fruits and vegetables cleaning agent of microemulsion dosage removal pesticide residue, formula such as following table：
| Material name | Mass fraction |
| Alkyl glycosides C12-14 | 30 |
| Oleoyl sodium glutamate | 25 |
| Ethyl alcohol | 10 |
| Tea tree ethereal oil | 5 |
| Eucalyptus leaf essential oil | 5 |
| Hydroxypropyl methyl cellulose | 5 |
| Disodium ethylene diamine tetraacetate | 2 |
| Citric acid | 0.5 |
| Deionized water | Surplus (adds to 100 parts) |
By preparation method by alkyl glycosides C12-14, oleoyl sodium glutamate is uniformly mixed and cooling at 50 DEG C, by ethyl alcohol,
Tea tree ethereal oil, eucalyptus leaf essential oil investment wherein and stir 5-10 minutes, while by hydroxypropyl methyl cellulose, ethylenediamine tetra-acetic acid two
Sodium, citric acid are uniformly dissolved in deionized water, are stirred 10-15 minutes after finally the two is blended.Product stand to substantially without
It is canned after foam.
Embodiment 7：
A kind of fruits and vegetables cleaning agent of microemulsion dosage removal pesticide residue, formula such as following table：
| Material name | Mass fraction |
| Alkyl glycosides C12-14 | 5 |
| Oleoyl sodium glutamate | 5 |
| Propylene glycol | 10 |
| Tea tree ethereal oil | 5 |
| Hundred inner essential oils | 5 |
| Hydroxypropyl methyl cellulose | 5 |
| Disodium ethylene diamine tetraacetate | 2 |
| Citric acid | 0.5 |
| Deionized water | Surplus (adds to 100 parts) |
By preparation method by alkyl glycosides C12-14, oleoyl sodium glutamate is uniformly mixed and cooling at 50 DEG C, by the third two
Alcohol, tea tree ethereal oil, eucalyptus leaf essential oil investment wherein and stir 5-10 minutes, while by hydroxypropyl methyl cellulose, ethylenediamine tetrem
Acid disodium, citric acid are uniformly dissolved in deionized water, are stirred 10-15 minutes after finally the two is blended.Product is stood to base
It is canned after this non-foam.
Microemulsion dosage fruits and vegetables cleaning agent of the invention removes pesticide residue performance using in 24691 fruits and vegetables cleaning agent of GB/T
The verification method that remains of pesticide removes effect in appendix A is measured.To be formulated simplest embodiment --- Examples 1 and 2
Four kinds of different pesticides are detected in the residual clearance rate of agriculture of vegetable surface, and the knot with clear water and commercially available common fruits and vegetables cleaning agent
Fruit compares, shown in test result following table：
Micro-emulsion type fruits and vegetables cleaning agent removes the residual the performance test results of agriculture to vegetables：
By in above-mentioned table, content shown in embodiment 1-2 is it is found that of the invention has the micro emulsion for removing pesticide residue ability
Dosage form fruits and vegetables cleaning agent shows the residual ability of good removal agriculture, is a fruits and vegetables cleaning agent having a vast market foreground
Product.
Claims (10)
1. a kind of fruits and vegetables cleaning agent of microemulsion dosage removal pesticide residue, it is characterised in that：Each group including following parts by weight
Point：5-30 parts of alkyl glycosides type surfactant, 5-25 parts of amino acid type surfactant, 0.1-10 parts of plants essential oil, hydrotropy
0-10 parts of agent, 0-5 parts of rheology control agent, 0-2 parts of pH adjusting agent, surplus is that deionized water adds to 100 parts.
2. the fruits and vegetables cleaning agent of microemulsion dosage removal pesticide residue as described in claim 1, it is characterised in that：It further include chelating
0.01-2 parts of agent.
3. the fruits and vegetables cleaning agent of microemulsion dosage removal pesticide residue as described in claim 1, it is characterised in that：The alkyl
The alkyl chain length of glucoside type surfactant is C8, C10, C12, C14, C16, C18, the alkyl glycosides type surfactant
It is used by the alkyl glycosides type surfactant compound of at least two different alkyl chain lengths.
4. the fruits and vegetables cleaning agent of microemulsion dosage removal pesticide residue as described in claim 1, it is characterised in that：The amino acid
The amino acid classes of type surfactant are glycine, glutamic acid, sarcosine；The alkyl base of the amino acid type surfactant
Group is lauroyl, cocoyl, myristoyl, palmityl, stearyl, oleoyl.
5. the fruits and vegetables cleaning agent of microemulsion dosage removal pesticide residue as claimed in claim 4, it is characterised in that：The amino acid
Type surfactant is potassium amino acid, sodium-salt type, does not dissociate amino acid pattern.
6. the fruits and vegetables cleaning agent of microemulsion dosage removal pesticide residue as described in claim 1, it is characterised in that：The plant essence
Oil is at least one of cinnamon essential oil, tea tree ethereal oil, thyme linaloe oil, lemon oil, eucalyptus oil.
7. the fruits and vegetables cleaning agent of microemulsion dosage removal pesticide residue as described in claim 1, it is characterised in that：The cosolvent
For at least one of ethyl alcohol, propylene glycol, butanediol, glycerine.
8. the fruits and vegetables cleaning agent of microemulsion dosage removal pesticide residue as described in claim 1, it is characterised in that：The rheology tune
Section agent is at least one of carboxymethyl cellulose, hydroxyethyl cellulose, hydroxypropyl methyl cellulose, xanthan gum.
9. the fruits and vegetables cleaning agent of microemulsion dosage removal pesticide residue as described in claim 1, it is characterised in that：The cleaning
Agent be it is transparent or semitransparent, dosage form is micro emulsion.
10. the preparation method of the fruits and vegetables cleaning agent of microemulsion dosage removal pesticide residue as claimed in any one of claims 1-9 wherein,
It is characterized in that：Include the following steps：
1) alkyl glycosides type surfactant and amino acid type surfactant are heated to 50 DEG C of constant temperature and mixed according to the above ratio
It closes uniformly, is cooled to room temperature, obtains mixed surfactant system；
2) it is added in the mixed surfactant system that step 1) obtains and stirs evenly after mixing plants essential oil and cosolvent；
3) be added after being uniformly dissolved rheology control agent, chelating agent, pH adjusting agent in deionized water 2) obtained in mixture
And stir evenly, product is canned after standing to basic non-foam.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201810792733.1A CN108865490B (en) | 2018-07-18 | 2018-07-18 | Microemulsion type fruit and vegetable cleaning agent for removing pesticide residues and preparation method thereof |
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| CN201810792733.1A CN108865490B (en) | 2018-07-18 | 2018-07-18 | Microemulsion type fruit and vegetable cleaning agent for removing pesticide residues and preparation method thereof |
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| CN108865490B CN108865490B (en) | 2021-01-19 |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109797055A (en) * | 2019-03-21 | 2019-05-24 | 冠道（广州）科技有限公司 | A kind of multifunctional detergent and preparation method thereof that addition amino acid table is living |
| CN111778116A (en) * | 2020-07-10 | 2020-10-16 | 广州市加茜亚化妆品有限公司 | Fruit and vegetable tableware detergent and preparation method thereof |
| CN113278475A (en) * | 2021-05-06 | 2021-08-20 | 广州市加茜亚化妆品有限公司 | Thixotropic laundry bead body and preparation method thereof |
| CN114517133A (en) * | 2020-11-18 | 2022-05-20 | 中山火炬职业技术学院 | Micro-emulsion fruit and vegetable detergent |
| CN115477981A (en) * | 2022-09-23 | 2022-12-16 | 广西壮族自治区林业科学研究院 | Liquid green fruit and vegetable washing product and preparation method thereof |
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| CN109797055A (en) * | 2019-03-21 | 2019-05-24 | 冠道（广州）科技有限公司 | A kind of multifunctional detergent and preparation method thereof that addition amino acid table is living |
| CN109797055B (en) * | 2019-03-21 | 2021-06-08 | 广东站成研创科技有限公司 | Multifunctional detergent added with amino acid surfactant and preparation method thereof |
| CN111778116A (en) * | 2020-07-10 | 2020-10-16 | 广州市加茜亚化妆品有限公司 | Fruit and vegetable tableware detergent and preparation method thereof |
| CN114517133A (en) * | 2020-11-18 | 2022-05-20 | 中山火炬职业技术学院 | Micro-emulsion fruit and vegetable detergent |
| CN114517133B (en) * | 2020-11-18 | 2023-10-31 | 中山火炬职业技术学院 | Microemulsion fruit and vegetable detergent |
| CN113278475A (en) * | 2021-05-06 | 2021-08-20 | 广州市加茜亚化妆品有限公司 | Thixotropic laundry bead body and preparation method thereof |
| CN115477981A (en) * | 2022-09-23 | 2022-12-16 | 广西壮族自治区林业科学研究院 | Liquid green fruit and vegetable washing product and preparation method thereof |
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