CN109797055A - Multifunctional detergent added with amino acid surfactant and preparation method thereof - Google Patents
Multifunctional detergent added with amino acid surfactant and preparation method thereof Download PDFInfo
- Publication number
- CN109797055A CN109797055A CN201910216744.XA CN201910216744A CN109797055A CN 109797055 A CN109797055 A CN 109797055A CN 201910216744 A CN201910216744 A CN 201910216744A CN 109797055 A CN109797055 A CN 109797055A
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- China
- Prior art keywords
- amino acid
- sodium
- parts
- living
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 150000001413 amino acids Chemical class 0.000 title claims abstract description 95
- 239000003599 detergent Substances 0.000 title claims abstract description 59
- 239000004094 surface-active agent Substances 0.000 title claims abstract description 56
- 238000002360 preparation method Methods 0.000 title claims abstract description 21
- 239000003381 stabilizer Substances 0.000 claims abstract description 45
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 45
- 239000008367 deionised water Substances 0.000 claims abstract description 30
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 30
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 8
- 229940024606 amino acid Drugs 0.000 claims description 91
- 235000001014 amino acid Nutrition 0.000 claims description 91
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 51
- 235000002639 sodium chloride Nutrition 0.000 claims description 45
- 230000000855 fungicidal effect Effects 0.000 claims description 43
- 239000000417 fungicide Substances 0.000 claims description 43
- 239000004615 ingredient Substances 0.000 claims description 42
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 38
- 239000003002 pH adjusting agent Substances 0.000 claims description 38
- -1 skin conditioner Substances 0.000 claims description 38
- 239000011780 sodium chloride Substances 0.000 claims description 38
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 claims description 36
- 239000003513 alkali Substances 0.000 claims description 35
- 239000000047 product Substances 0.000 claims description 35
- 239000004354 Hydroxyethyl cellulose Substances 0.000 claims description 21
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 claims description 21
- 235000007164 Oryza sativa Nutrition 0.000 claims description 21
- 238000000855 fermentation Methods 0.000 claims description 21
- 230000004151 fermentation Effects 0.000 claims description 21
- 239000000706 filtrate Substances 0.000 claims description 21
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 claims description 21
- 235000009566 rice Nutrition 0.000 claims description 21
- 238000003756 stirring Methods 0.000 claims description 21
- 229920001661 Chitosan Polymers 0.000 claims description 20
- NVNLLIYOARQCIX-MSHCCFNRSA-N Nisin Chemical compound N1C(=O)[C@@H](CC(C)C)NC(=O)C(=C)NC(=O)[C@@H]([C@H](C)CC)NC(=O)[C@@H](NC(=O)C(=C/C)/NC(=O)[C@H](N)[C@H](C)CC)CSC[C@@H]1C(=O)N[C@@H]1C(=O)N2CCC[C@@H]2C(=O)NCC(=O)N[C@@H](C(=O)N[C@H](CCCCN)C(=O)N[C@@H]2C(NCC(=O)N[C@H](C)C(=O)N[C@H](CC(C)C)C(=O)N[C@H](CCSC)C(=O)NCC(=O)N[C@H](CS[C@@H]2C)C(=O)N[C@H](CC(N)=O)C(=O)N[C@H](CCSC)C(=O)N[C@H](CCCCN)C(=O)N[C@@H]2C(N[C@H](C)C(=O)N[C@@H]3C(=O)N[C@@H](C(N[C@H](CC=4NC=NC=4)C(=O)N[C@H](CS[C@@H]3C)C(=O)N[C@H](CO)C(=O)N[C@H]([C@H](C)CC)C(=O)N[C@H](CC=3NC=NC=3)C(=O)N[C@H](C(C)C)C(=O)NC(=C)C(=O)N[C@H](CCCCN)C(O)=O)=O)CS[C@@H]2C)=O)=O)CS[C@@H]1C NVNLLIYOARQCIX-MSHCCFNRSA-N 0.000 claims description 20
- 108010053775 Nisin Proteins 0.000 claims description 20
- 239000004309 nisin Substances 0.000 claims description 20
- 235000010297 nisin Nutrition 0.000 claims description 20
- WHUUTDBJXJRKMK-UHFFFAOYSA-N Glutamic acid Natural products OC(=O)C(N)CCC(O)=O WHUUTDBJXJRKMK-UHFFFAOYSA-N 0.000 claims description 19
- 235000013922 glutamic acid Nutrition 0.000 claims description 19
- 239000004220 glutamic acid Substances 0.000 claims description 19
- 229940045944 sodium lauroyl glutamate Drugs 0.000 claims description 19
- IWIUXJGIDSGWDN-UQKRIMTDSA-M sodium;(2s)-2-(dodecanoylamino)pentanedioate;hydron Chemical group [Na+].CCCCCCCCCCCC(=O)N[C@H](C([O-])=O)CCC(O)=O IWIUXJGIDSGWDN-UQKRIMTDSA-M 0.000 claims description 19
- 229940117986 sulfobetaine Drugs 0.000 claims description 19
- OPGYRRGJRBEUFK-UHFFFAOYSA-L disodium;diacetate Chemical compound [Na+].[Na+].CC([O-])=O.CC([O-])=O OPGYRRGJRBEUFK-UHFFFAOYSA-L 0.000 claims description 18
- 239000001632 sodium acetate Substances 0.000 claims description 18
- 235000017454 sodium diacetate Nutrition 0.000 claims description 18
- XHDJZIZDKIUZGM-UHFFFAOYSA-N CCCCCCCCCCCCC(=O)[Na] Chemical compound CCCCCCCCCCCCC(=O)[Na] XHDJZIZDKIUZGM-UHFFFAOYSA-N 0.000 claims description 16
- 239000006210 lotion Substances 0.000 claims description 8
- 150000003839 salts Chemical class 0.000 claims description 7
- GVJHHUAWPYXKBD-UHFFFAOYSA-N (±)-α-Tocopherol Chemical compound OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-UHFFFAOYSA-N 0.000 claims description 6
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 claims description 6
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 6
- 239000002253 acid Substances 0.000 claims description 6
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 claims description 6
- 230000003213 activating effect Effects 0.000 claims description 5
- 238000001514 detection method Methods 0.000 claims description 5
- ILRSCQWREDREME-UHFFFAOYSA-N dodecanamide Chemical compound CCCCCCCCCCCC(N)=O ILRSCQWREDREME-UHFFFAOYSA-N 0.000 claims description 5
- 238000002156 mixing Methods 0.000 claims description 5
- 238000003860 storage Methods 0.000 claims description 5
- 238000006243 chemical reaction Methods 0.000 claims description 4
- 238000007599 discharging Methods 0.000 claims description 4
- 238000011049 filling Methods 0.000 claims description 4
- 238000001914 filtration Methods 0.000 claims description 4
- WGYKZJWCGVVSQN-UHFFFAOYSA-N propylamine Chemical compound CCCN WGYKZJWCGVVSQN-UHFFFAOYSA-N 0.000 claims description 4
- 238000012797 qualification Methods 0.000 claims description 4
- 238000010792 warming Methods 0.000 claims description 4
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 claims description 3
- 102000008186 Collagen Human genes 0.000 claims description 3
- 108010035532 Collagen Proteins 0.000 claims description 3
- ZZZCUOFIHGPKAK-UHFFFAOYSA-N D-erythro-ascorbic acid Natural products OCC1OC(=O)C(O)=C1O ZZZCUOFIHGPKAK-UHFFFAOYSA-N 0.000 claims description 3
- 229930003268 Vitamin C Natural products 0.000 claims description 3
- 229930003427 Vitamin E Natural products 0.000 claims description 3
- 235000013871 bee wax Nutrition 0.000 claims description 3
- 239000012166 beeswax Substances 0.000 claims description 3
- 239000004202 carbamide Substances 0.000 claims description 3
- 229920001436 collagen Polymers 0.000 claims description 3
- WIGCFUFOHFEKBI-UHFFFAOYSA-N gamma-tocopherol Natural products CC(C)CCCC(C)CCCC(C)CCCC1CCC2C(C)C(O)C(C)C(C)C2O1 WIGCFUFOHFEKBI-UHFFFAOYSA-N 0.000 claims description 3
- 150000003949 imides Chemical class 0.000 claims description 3
- 235000013923 monosodium glutamate Nutrition 0.000 claims description 3
- 239000000661 sodium alginate Substances 0.000 claims description 3
- 235000010413 sodium alginate Nutrition 0.000 claims description 3
- 229940005550 sodium alginate Drugs 0.000 claims description 3
- 229940073490 sodium glutamate Drugs 0.000 claims description 3
- 235000019154 vitamin C Nutrition 0.000 claims description 3
- 239000011718 vitamin C Substances 0.000 claims description 3
- 235000019165 vitamin E Nutrition 0.000 claims description 3
- 229940046009 vitamin E Drugs 0.000 claims description 3
- 239000011709 vitamin E Substances 0.000 claims description 3
- 239000000230 xanthan gum Substances 0.000 claims description 2
- 235000010493 xanthan gum Nutrition 0.000 claims description 2
- 229920001285 xanthan gum Polymers 0.000 claims description 2
- 229940082509 xanthan gum Drugs 0.000 claims description 2
- 240000007594 Oryza sativa Species 0.000 claims 1
- 229940045110 chitosan Drugs 0.000 claims 1
- 229940071826 hydroxyethyl cellulose Drugs 0.000 claims 1
- ZEZSZCSSTDPVDM-DKWTVANSSA-M sodium;(2s)-2-aminopropanoate Chemical compound [Na+].C[C@H](N)C([O-])=O ZEZSZCSSTDPVDM-DKWTVANSSA-M 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 14
- 239000007788 liquid Substances 0.000 abstract description 12
- 239000000126 substance Substances 0.000 abstract description 11
- 238000004140 cleaning Methods 0.000 abstract description 6
- 239000000447 pesticide residue Substances 0.000 abstract description 5
- 230000036541 health Effects 0.000 abstract description 4
- 230000006378 damage Effects 0.000 abstract description 3
- 239000000463 material Substances 0.000 abstract description 3
- 238000003911 water pollution Methods 0.000 abstract description 3
- 230000000844 anti-bacterial effect Effects 0.000 abstract 1
- 239000003899 bactericide agent Substances 0.000 abstract 1
- 239000002085 irritant Substances 0.000 abstract 1
- 231100000021 irritant Toxicity 0.000 abstract 1
- 239000002699 waste material Substances 0.000 abstract 1
- 230000000052 comparative effect Effects 0.000 description 27
- 235000013399 edible fruits Nutrition 0.000 description 25
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 21
- 239000011734 sodium Substances 0.000 description 21
- 229910052708 sodium Inorganic materials 0.000 description 21
- 241000209094 Oryza Species 0.000 description 20
- 239000011521 glass Substances 0.000 description 17
- WDJHALXBUFZDSR-UHFFFAOYSA-N acetoacetic acid Chemical compound CC(=O)CC(O)=O WDJHALXBUFZDSR-UHFFFAOYSA-N 0.000 description 16
- 239000001509 sodium citrate Substances 0.000 description 15
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 15
- JXKPEJDQGNYQSM-UHFFFAOYSA-M sodium propionate Chemical compound [Na+].CCC([O-])=O JXKPEJDQGNYQSM-UHFFFAOYSA-M 0.000 description 15
- 239000004324 sodium propionate Substances 0.000 description 15
- 235000010334 sodium propionate Nutrition 0.000 description 15
- 229960003212 sodium propionate Drugs 0.000 description 15
- 239000001993 wax Substances 0.000 description 14
- 239000003921 oil Substances 0.000 description 7
- 235000019198 oils Nutrition 0.000 description 7
- 238000010998 test method Methods 0.000 description 7
- 241000894006 Bacteria Species 0.000 description 6
- 235000013305 food Nutrition 0.000 description 6
- 235000012055 fruits and vegetables Nutrition 0.000 description 6
- 229910001385 heavy metal Inorganic materials 0.000 description 6
- 150000002500 ions Chemical class 0.000 description 6
- 241001465754 Metazoa Species 0.000 description 5
- 230000008859 change Effects 0.000 description 5
- 239000000575 pesticide Substances 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- 238000002242 deionisation method Methods 0.000 description 4
- 235000005979 Citrus limon Nutrition 0.000 description 3
- 244000131522 Citrus pyriformis Species 0.000 description 3
- 241000282326 Felis catus Species 0.000 description 3
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 3
- 244000269722 Thea sinensis Species 0.000 description 3
- 235000006468 Thea sinensis Nutrition 0.000 description 3
- 230000002378 acidificating effect Effects 0.000 description 3
- 238000003556 assay Methods 0.000 description 3
- 239000002585 base Substances 0.000 description 3
- 235000020279 black tea Nutrition 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 238000011109 contamination Methods 0.000 description 3
- 238000004851 dishwashing Methods 0.000 description 3
- 239000003814 drug Substances 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 230000007613 environmental effect Effects 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- 238000005303 weighing Methods 0.000 description 3
- GUBGYTABKSRVRQ-PICCSMPSSA-N D-Maltose Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@@H](CO)OC(O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-PICCSMPSSA-N 0.000 description 2
- 208000005374 Poisoning Diseases 0.000 description 2
- 235000010726 Vigna sinensis Nutrition 0.000 description 2
- 244000042314 Vigna unguiculata Species 0.000 description 2
- 230000005856 abnormality Effects 0.000 description 2
- 210000003484 anatomy Anatomy 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 230000003115 biocidal effect Effects 0.000 description 2
- 239000003139 biocide Substances 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 229930182470 glycoside Natural products 0.000 description 2
- 150000002338 glycosides Chemical class 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- 230000007774 longterm Effects 0.000 description 2
- 235000010755 mineral Nutrition 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 238000011056 performance test Methods 0.000 description 2
- 231100000572 poisoning Toxicity 0.000 description 2
- 230000000607 poisoning effect Effects 0.000 description 2
- 229940065859 sodium cocoyl glycinate Drugs 0.000 description 2
- IKGKWKGYFJBGQJ-UHFFFAOYSA-M sodium;2-(dodecanoylamino)acetate Chemical compound [Na+].CCCCCCCCCCCC(=O)NCC([O-])=O IKGKWKGYFJBGQJ-UHFFFAOYSA-M 0.000 description 2
- 239000002689 soil Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 208000024891 symptom Diseases 0.000 description 2
- 235000013311 vegetables Nutrition 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- 241000193830 Bacillus <bacterium> Species 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 206010008428 Chemical poisoning Diseases 0.000 description 1
- 244000060011 Cocos nucifera Species 0.000 description 1
- 235000013162 Cocos nucifera Nutrition 0.000 description 1
- 241000195493 Cryptophyta Species 0.000 description 1
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 1
- 206010013786 Dry skin Diseases 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- 241000233866 Fungi Species 0.000 description 1
- 208000018522 Gastrointestinal disease Diseases 0.000 description 1
- QNAYBMKLOCPYGJ-REOHCLBHSA-N L-alanine Chemical compound C[C@H](N)C(O)=O QNAYBMKLOCPYGJ-REOHCLBHSA-N 0.000 description 1
- 244000147568 Laurus nobilis Species 0.000 description 1
- 235000017858 Laurus nobilis Nutrition 0.000 description 1
- 235000011430 Malus pumila Nutrition 0.000 description 1
- 235000015103 Malus silvestris Nutrition 0.000 description 1
- 235000019082 Osmanthus Nutrition 0.000 description 1
- 241000333181 Osmanthus Species 0.000 description 1
- 229930182555 Penicillin Natural products 0.000 description 1
- JGSARLDLIJGVTE-MBNYWOFBSA-N Penicillin G Chemical compound N([C@H]1[C@H]2SC([C@@H](N2C1=O)C(O)=O)(C)C)C(=O)CC1=CC=CC=C1 JGSARLDLIJGVTE-MBNYWOFBSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- ISRUGXGCCGIOQO-UHFFFAOYSA-N Rhoden Chemical compound CNC(=O)OC1=CC=CC=C1OC(C)C ISRUGXGCCGIOQO-UHFFFAOYSA-N 0.000 description 1
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical class [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 1
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 1
- 235000005212 Terminalia tomentosa Nutrition 0.000 description 1
- 241001625808 Trona Species 0.000 description 1
- 241000607479 Yersinia pestis Species 0.000 description 1
- 235000010358 acesulfame potassium Nutrition 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 230000001154 acute effect Effects 0.000 description 1
- 231100000460 acute oral toxicity Toxicity 0.000 description 1
- 125000002252 acyl group Chemical group 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 238000007605 air drying Methods 0.000 description 1
- 235000004279 alanine Nutrition 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 238000010171 animal model Methods 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 230000003266 anti-allergic effect Effects 0.000 description 1
- 230000003064 anti-oxidating effect Effects 0.000 description 1
- 239000000022 bacteriostatic agent Substances 0.000 description 1
- 230000003542 behavioural effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 235000014121 butter Nutrition 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 235000015165 citric acid Nutrition 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 238000010668 complexation reaction Methods 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- KAATUXNTWXVJKI-UHFFFAOYSA-N cypermethrin Chemical group CC1(C)C(C=C(Cl)Cl)C1C(=O)OC(C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 KAATUXNTWXVJKI-UHFFFAOYSA-N 0.000 description 1
- 238000005238 degreasing Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 238000003306 harvesting Methods 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- 229940116335 lauramide Drugs 0.000 description 1
- 239000010410 layer Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000003641 microbiacidal effect Effects 0.000 description 1
- 229940124561 microbicide Drugs 0.000 description 1
- 239000002855 microbicide agent Substances 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 235000016709 nutrition Nutrition 0.000 description 1
- 239000003986 organophosphate insecticide Substances 0.000 description 1
- 229940049954 penicillin Drugs 0.000 description 1
- 230000008855 peristalsis Effects 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 229920000223 polyglycerol Polymers 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229960003975 potassium Drugs 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000001508 potassium citrate Substances 0.000 description 1
- 229960002635 potassium citrate Drugs 0.000 description 1
- QEEAPRPFLLJWCF-UHFFFAOYSA-K potassium citrate (anhydrous) Chemical compound [K+].[K+].[K+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O QEEAPRPFLLJWCF-UHFFFAOYSA-K 0.000 description 1
- 235000011082 potassium citrates Nutrition 0.000 description 1
- 230000001376 precipitating effect Effects 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000013535 sea water Substances 0.000 description 1
- 230000037307 sensitive skin Effects 0.000 description 1
- 210000000697 sensory organ Anatomy 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 238000004018 waxing Methods 0.000 description 1
- 230000003442 weekly effect Effects 0.000 description 1
Landscapes
- Detergent Compositions (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention relates to the technical field of daily chemical products, in particular to a multifunctional detergent added with amino acid surfactant and a preparation method thereof. A multifunctional detergent added with amino acid surfactant comprises the following components: the main material, amino acid surfactant, bactericide, stabilizer, skin care agent, deionized water and pH regulator. The multifunctional detergent added with the amino acid surfactant has strong oil stain removing capability and good cleaning effect on pesticide residues, and the detergent is not easy to remain on the surface of a material, so that the added value of the detergent is improved, the harm to human health during eating is reduced, the product is mild and non-irritant during use, the skin is protected and is not hurt to hands, the used waste liquid is easy to biodegrade, the water pollution is avoided, and the environment-friendly requirement is met.
Description
Technical field
The invention belongs to daily chemical product technical fields, more particularly it relates to which a kind of addition amino acid table is living
Multifunctional detergent and preparation method thereof.
Background technique
In actual life, due to accumulating over a long period in life process, so that the health in the kitchens such as family, hotel, restaurant
There are many dead angles in situation, and some dirts for being difficult to remove occurs in each corner, these long-term accumulative dirts, only
It is not strong by conventional detergent clean effect, it is difficult to realize and quickly, thoroughly clean.
It is indispensable food in human lives due to nutritional ingredients rich in such as commercially available water fruits and vegetables, dry fruits
Object.Currently, the fruit and vegetable varieties that people not only eat are more, but also a large amount of water fruits and vegetables, dry fruit, dry vegetalbe, food are all consumed daily
With bacterium etc..Therefore, it grows fruit, vegetables etc. can bring huge economic benefit to peasant.But due to the large area of water fruits and vegetables
Cultivation, in order to prevent and treat pest and disease damage, peasant is controlled usually using a large amount of pesticide, simultaneously because the lavishment of pesticide is indiscriminate
With and medicine after not up to safe period harvest water fruits and vegetables, cause fruit, vegetable surface to remain a large amount of pesticides.These residual agricultures
Aqueous solubility is small, with clear water generally can not washes clean, therefore when the phenomenon that edible such water fruits and vegetables causing pesticide poisoning
There is generation, social repercussion is very big.The Chinese government attaches great importance to problems, and since the 1970s, just makes successively
Determine and promulgated the regulations such as " major experiment standard ", " pesticide reasonable application ", " pesticide management rules ".
Meanwhile the fruit wax important link that is commercialized treatment after adopting and international market are to fruit commodity sense organ
Basic demand.The glossiness on fruit surface not only can be enhanced by waxing, improve exterior quality, improve commodity value, and
The stomata and hole skin that fruit surface can also be blocked, reduce the water loss of fruit, are conducive to the freshness for keeping fruit, to prolong
Long storage period and shelf life.In addition, wax liquor is alternatively arranged as the carrier of bacteriostatic agent, anti-corrosion guarantor can be played by being sprayed on fruit surface
Fresh effect.However most of fruit wax will use industrial wax instead of food wax to reduce cost now, and industrial wax usually contains
There are the harmful substances such as heavy metal, if fruit of the long-term consumption containing industrial wax, is easy to jeopardize people's health, therefore eating
Before fruit, removal fruit wax is seemed very necessary and important.But the removal of fruit wax, the moisture of pericarp accelerates to be lost, while fruit
The resistance that product treat the pollution sources such as extraneous bacterium can reduce very much.
Therefore this field needs to be developed a novel multifunctional detergent, is able to solve above-mentioned technical problem.
Summary of the invention
To solve the above-mentioned problems, first aspect of the present invention provides a kind of multi-functional washing that addition amino acid table is living
Agent, including following component: major ingredient, amino acid surfactant, fungicide, stabilizer, skin conditioner, deionized water, pH adjusting agent.
As a kind of perferred technical scheme, by weight, including following component: 15~32 parts of major ingredient, amino acid table
25~53 parts of face activating agent, 2~3 parts of fungicide, 8~13 parts of stabilizer, 3~4 parts of skin conditioner, 40~80 parts of deionized water, pH
0~1 part of regulator.
As a kind of perferred technical scheme, the major ingredient includes natural sea alkali, sodium bicarbonate, natural sea salt.
As a kind of perferred technical scheme, the natural sea alkali, sodium bicarbonate, natural sea salt weight ratio be (10~
18): (10~12): (12~16).
As a kind of perferred technical scheme, the amino acid surfactant is selected from sodium lauroyl glutamate, cocounut oil
Acylalaninies sodium, myristoyl sodium glutamate, sodium cocoyl glycinate, cocounut oil acyl Sodium L-alaninate, methyl lauroyl ox
One of sodium sulfonate, lauryl hydroxyl sulfo betaine, glutamic acid diacetic acid sodium salt are a variety of.
As a kind of perferred technical scheme, the fungicide is selected from salt acid imide urea, hexamethylene diamine, lauramide
One of propyl amine oxide, Na2Fe04, sodium Diacetate, nisin are a variety of.
As a kind of perferred technical scheme, the stabilizer be selected from polyglycoside surfactants, sodium alginate, xanthan gum,
One of chitosan, hydroxyethyl cellulose, oligoisomaltose are a variety of.
As a kind of perferred technical scheme, the polyglycoside surfactants be selected from APG0810, APG0814, APG0816,
One of APG1214, APG1216, APG1218 or a variety of.
As a kind of perferred technical scheme, the skin conditioner is selected from vitamin C, vitamin E, beeswax, collagen, sweet
One of oil, rice fermentation Product filtrate are a variety of.
The second aspect of the present invention provides a kind of preparation method of multifunctional detergent that addition amino acid table is living, step
Include:
S1: major ingredient, pH adjusting agent are added in reaction kettle, the deionized water of 1/4 parts by weight is slowly added to along kettle wall, is opened
50r/min is stirred, 10min is stirred to paste is melted, avoids acutely blistering, observation phenomenon is adjusted revolving speed；
S2: continuously adding 1/4 deionized water, and adjustment mixing speed is 100r/min, stirring 15min to uniform paste；
S3: amino acid surfactant, fungicide, stabilizer, skin conditioner are sequentially added and is warming up to 40~45 DEG C, adjustment is stirred
It mixes as 200r/min, it is uniform to lotion to stir 30min；
S4: being added the deionized water of remaining 1/2 parts by weight, and it is uniform to lotion to continue stirring 30min；
S5: sample detection pH, viscosity, adjustment pH be 6~9, viscosity 3000cps；
S6: being cooled to 32~38 DEG C, continues to stir 1h to uniform without obvious bubble；Add 120~200 mesh filter screen filtering and dischargings
It is sealed into storage tank, it is filling after qualification to be detected.
The utility model has the advantages that addition amino acid table multifunctional detergent ability of cleaning greasy dirt living prepared by the present invention is strong, to agriculture
The remaining cleaning effect of medicine is good, and detergent itself is not easy to remain in the surface of material, so that the added value of detergent is improved,
It endangers caused by human health when reducing edible product, and is not stimulated mildly when product use, skin care is not hurt hands, useless after use
Liquid is easily biodegradable, and not will cause water pollution, meets the demand of environmental protection.
Specific embodiment
It is further clear, complete that the technical characteristic work in technical solution is provided to the present invention With reference to embodiment
Description, not to the limitation of its protection scope.
Word " preferred ", " preferred " in the present invention etc. refer to, can provide in some cases certain beneficial to effect
The embodiment of the present invention of fruit.However, other embodiments are also likely to be preferred under identical circumstances or in the case of other
's.In addition, do not imply that other embodiments are unavailable to the statement of one or more preferred embodiments, be also not intended to by
Other embodiments exclude except the scope of the present invention.
When a numberical range disclosed herein, above range is considered as continuously, and the minimum value including the range and most
Big value and each value between this minimum value and maximum value.Further, when range refers to integer, including the model
Each integer between minimum value and maximum value enclosed.In addition, when providing multiple range Expressive Features or characteristic, Ke Yihe
And the range.In other words, unless otherwise specified, otherwise all ranges disclosed herein are understood to include and are wherein included into
Any and all subrange.For example, should be regarded as including between minimum value 1 and maximum value 10 from the specified range of " 1 to 10 "
Any and all subrange.The Exemplary range of range 1 to 10 include but is not limited to 1 to 6.1,3.5 to 7.8,5.5 to
10 etc..
To solve the above-mentioned problems, first aspect of the present invention provides a kind of multi-functional washing that addition amino acid table is living
Agent, including following component: major ingredient, amino acid surfactant, fungicide, stabilizer, skin conditioner, deionized water, pH adjusting agent.
In a preferred embodiment, by weight, including following component: 15~32 parts of major ingredient, amino acid table
25~53 parts of face activating agent, 2~3 parts of fungicide, 8~13 parts of stabilizer, 3~4 parts of skin conditioner, 40~80 parts of deionized water, pH
0~1 part of regulator.
Major ingredient
In a preferred embodiment, the major ingredient includes natural sea alkali, sodium bicarbonate, natural sea salt.
Natural sea alkali of the present invention refers to trona, the salt mine that the product in Saline Lake Deposits area is evaporated
Object is aqueous sodium bicarbonate, mainly from alkali lake and solid base mine；Its main chemical compositions is the one of sodium carbonate and sodium bicarbonate
Class mineral.It is in threadiness or column block, grey or yellow-white or colourless.
Natural sea salt of the present invention, which refers to, introduces salt pan for seawater, crystallizes by solar evaporation natural air drying；It
Potassium contained by right sea salt is more than common edible salt, but other content of mineral substances of natural sea salt, as sodium, phosphorus and calcium content difference not
It is more.
Preferably, natural sea salt of the present invention is bought from prosperous salt industry Co., Ltd, Laizhou City.
It is furthermore preferred that the weight ratio of natural sea alkali of the present invention, sodium bicarbonate, natural sea salt is (10~18): (10~
12): (12~16).
It is furthermore preferred that the weight ratio of natural sea alkali of the present invention, sodium bicarbonate, natural sea salt is 14:11:13.5.
Amino acid surfactant
Amino acid surfactant of the present invention is a kind of mild and degradable anionic surfactant, master
Wanting active constituent is compounded amino acid sodium-salt.Wherein, weakly acidic amino acid surfactant, pH value connect with human skin
Closely, so mild pro-skin, sensitive skin can also be safe to use.
Preferably, amino acid surfactant of the present invention is selected from sodium lauroyl glutamate, cocoyl alanine
Sodium, myristoyl sodium glutamate, sodium cocoyl glycinate, cocounut oil acyl Sodium L-alaninate, methyl lauroyl sodium taurocholate, laurel
One of base hydroxyl sulfo betaine, glutamic acid diacetic acid sodium salt are a variety of.
Preferably, the amino acid surfactant is sodium lauroyl glutamate, cocoamido sodium propionate, the methyl moon
Osmanthus acyl taurines sodium, lauryl hydroxyl sulfo betaine, four sodium of glutamic acid diacetic acid are by weight 1:(0.2~0.6): (0.1
~0.5): (0.1~0.5): the combination of (0.1~0.3).
It is furthermore preferred that the amino acid surfactant is sodium lauroyl glutamate, cocoamido sodium propionate, methyl
Lauroyl sodium taurocholate, lauryl hydroxyl sulfo betaine, four sodium of glutamic acid diacetic acid are by weight 1:0.5:0.2:0.2:
0.1 combination.
Sodium lauroyl glutamate of the present invention is bought from Guangzhou Sheng Xin Chemical Industry Science Co., Ltd；Coconut palm of the present invention
Oleoyl Sodium L-alaninate is bought from Suzhou Fu Lu Biotechnology Co., Ltd；Methyl lauroyl sodium taurocholate purchase of the present invention
It buys from Hubei and far successfully creates Science and Technology Ltd.；Lauryl hydroxyl sulfo betaine of the present invention is bought from the bright bright biology in Foshan
Science and Technology Ltd.；Four sodium of glutamic acid diacetic acid purchase of the present invention researches and develops Co., Ltd from Jiangsu Ai Kang biological medicine.
Fungicide
Fungicide of the present invention is also known as biocide, Biocidal algae-killing agent, microbicide etc., typically refers to effectively to control
Microorganism in system or kill water system, such as the chemicals of bacterium, fungi and algae.
Preferably, fungicide of the present invention is selected from salt acid imide urea, hexamethylene diamine, dodecanamide propyl oxidation
One of amine, Na2Fe04, sodium Diacetate, nisin are a variety of.
It is furthermore preferred that fungicide of the present invention is sodium Diacetate and nisin by weight 1:(1~2) group
It closes；It is further preferred that fungicide of the present invention is that sodium Diacetate and nisin are combined by weight 1:1.5.
Nisin of the present invention is bought from Hubei such as day biology Engineering Co., Ltd.
Applicants have unexpectedly found that excessive hydroxyethyl cellulose, oligoisomaltose, chitosan, nisin
It can be adsorbed on the surface of fruit, form layer protecting film, stop extraneous bacterium, pericarp internal moisture is lockked, to reach water conservation
The effect of, in addition, can effectively inhibit hay bacillus and penicillin.
Stabilizer
Stabilizer of the present invention refers to one substance of stability that can increase solution, colloid, solid, mixture.It is main
It will be according to the purpose of design of formula, using certain chemicals to achieve the purpose that product with stable quality.
In a preferred embodiment, stabilizer of the present invention is selected from polyglycoside surfactants, sodium alginate, Huang
One of virgin rubber, chitosan, hydroxyethyl cellulose, oligoisomaltose are a variety of.
Preferably, polyglycoside surfactants of the present invention be selected from APG0810, APG0814, APG0816, APG1214,
One of APG1216, APG1218 or a variety of.
Preferably, polyglycoside surfactants of the present invention are APG0814.
Preferably, stabilizer of the present invention is APG0814, chitosan, hydroxyethyl cellulose, oligoisomaltose are by weight
Amount is than (5~10): (1~3): (1~2): 1 combination；It is further preferred that stabilizer of the present invention is APG0814, shell is poly-
Sugar, hydroxyethyl cellulose, oligoisomaltose by weight 7.5:2:1.5:1 combination.
It has been found that when selecting rice fermentation Product filtrate, amino acid surfactant, glycoside surfactant
When with sodium bicarbonate, the fruit wax and pesticide residue on fruit surface layer can be effectively removed.Possible reason is these types of substance
Under the action of mutual collaboration, a variety of groups can have an effect rapidly with fruit wax and pesticide residue, destroy fruit wax and go forward side by side
One step destroys the structure of pesticide residue, to achieve the purpose that cleaning.And when control major ingredient: stabilizer: skin conditioner=(5~
8): (2~4): when 1, though at 0 DEG C, also can rapid cleanup fall fruit wax, it is residual to organophosphorus insecticide in addition, with this condition
Stay object that there is optimal effect.
Skin conditioner
Skin conditioner of the present invention has certain lubricious, water conservation, antiallergic, oxidation resistant effect, to improve skin
Dry condition also has protective effect when by environmental stimuli, and can promote the reparation of damaged skin.
In a preferred embodiment, skin conditioner of the present invention is selected from vitamin C, vitamin E, beeswax, collagen
One of albumen, glycerol, rice fermentation Product filtrate are a variety of.
Preferably, skin conditioner of the present invention is that glycerol and rice fermentation Product filtrate press (2~3): 1 combination.
It is furthermore preferred that skin conditioner of the present invention is that glycerol and rice fermentation Product filtrate are combined by 2.5:1.
Rice fermentation Product filtrate purchase of the present invention reaches Biotechnology Co., Ltd from Dezhou Onlly.
The application uses weakly acidic amino acid surfactant and weakly alkaline sodium bicarbonate, and is aided with rice fermentation production
Object filtrate and glycoside surfactant, not only strong cleaning force, can decompose rapidly in greasy dirt, while whole system can be made to connect
Weakly acidic pH, it is similar with human body pH, it does not stimulate mildly, does not hurt hands, in addition, multiple-microorganism and the amino acid side being wherein rich in
Dead skin and the bacterium for helping removal manpower surface, improve the state on hand skin surface, thus the effect of reaching handguard.
PH adjusting agent
PH adjusting agent, that is, acid-base modifier of the present invention is the substance to maintain or change food pH value, has
Certain enhancement antioxidation, prevents food rancid, with complex, has and prevents oxidation or take off change react, is steady
Determine color, reduce the effects of turbidity, enhancing gelling characteristic.
In a preferred embodiment, pH adjusting agent of the present invention is selected from citric acid, lactic acid, tartaric acid, apple
One of acid, sodium citrate, potassium citrate are a variety of.
Preferably, pH adjusting agent of the present invention is sodium citrate.
After having used the cleaned fruit of detergent described herein, it is not required to peel, it is directly edible, into internal, energy
Enough a variety of enzymes by human body decompose, and the hydroxyethyl cellulose of the multi cellulose and the application in pericarp, oligomeric different malt
Sugar, chitosan collective effect can promote enterogastric peristalsis, to promote gastrointestinal disturbances.
It is found by the applicant that can effectively destroy out industrial wax and pesticide residue when all components are had an effect jointly
In heavy metal ion and other ions, and by hydroxyethyl cellulose, the collective effect of oligoisomaltose and chitosan
Complexation heavy metal ion and other ions, on the one hand, the harm that heavy metal ion enters human body with food can be excluded, make to eat
Object is safe and healthy；On the other hand, sewer will not be entered after heavy metal ion is complexed, pipeline etc. will not be corroded,
Water pollution will not be caused, also all components of the present invention are all easily biodegradable, and meet the demand of environmental protection.
The second aspect of the present invention provides a kind of preparation method of multifunctional detergent that addition amino acid table is living, step
Include:
S1: major ingredient, pH adjusting agent are added in reaction kettle, the deionized water of 1/4 parts by weight is slowly added to along kettle wall, is opened
50r/min is stirred, 10min is stirred to paste is melted, avoids acutely blistering, observation phenomenon is adjusted revolving speed；
S2: continuously adding 1/4 deionized water, and adjustment mixing speed is 100r/min, stirring 15min to uniform paste；
S3: amino acid surfactant, fungicide, stabilizer, skin conditioner are sequentially added and is warming up to 40~45 DEG C, adjustment is stirred
It mixes as 200r/min, it is uniform to lotion to stir 30min；
S4: being added the deionized water of remaining 1/2 parts by weight, and it is uniform to lotion to continue stirring 30min；
S5: sample detection pH, viscosity, adjustment pH be 6~9, viscosity 3000cps；
S6: being cooled to 32~38 DEG C, continues to stir 1h to uniform without obvious bubble；Add 120~200 mesh filter screen filtering and dischargings
It is sealed into storage tank, it is filling after qualification to be detected.
The present invention is specifically described below by embodiment, in addition, if without other explanations, it is raw materials used to be all
It is commercially available.
Embodiment
Embodiment 1
Embodiment 1 provides a kind of multifunctional detergent that addition amino acid table is living, by weight, including such as the following group
Point: 21 parts of major ingredient, 35 parts of amino acid surfactant, 2.5 parts of fungicide, 10.5 parts of stabilizer, 3.5 parts of skin conditioner, deionization
60 parts of water, 0.6 part of pH adjusting agent.
The major ingredient includes natural sea alkali, sodium bicarbonate, natural sea salt；The natural sea alkali, sodium bicarbonate, natural sea salt
Weight ratio be 14:11:13.5.
The amino acid surfactant is sodium lauroyl glutamate, cocoamido sodium propionate, methyl lauroyl
Sodium taurocholate, lauryl hydroxyl sulfo betaine, four sodium of glutamic acid diacetic acid by weight 1:0.5:0.2:0.2:0.1 group
It closes.
The fungicide is that sodium Diacetate and nisin are combined by weight 1:1.5.
The stabilizer is APG0814, chitosan, hydroxyethyl cellulose, oligoisomaltose by weight 7.5:2:
The combination of 1.5:1.
The skin conditioner is that glycerol and rice fermentation Product filtrate are combined by 2.5:1.
The pH adjusting agent is sodium citrate.
A kind of preparation method for the multifunctional detergent that addition amino acid table is living, step include:
S1: major ingredient, pH adjusting agent are added in reaction kettle, the deionized water of 1/4 parts by weight is slowly added to along kettle wall, is opened
50r/min is stirred, 10min is stirred to paste is melted, avoids acutely blistering, observation phenomenon is adjusted revolving speed；
S2: continuously adding 1/4 deionized water, and adjustment mixing speed is 100r/min, stirring 15min to uniform paste；
S3: amino acid surfactant, fungicide, stabilizer, skin conditioner are sequentially added and is warming up to 40~45 DEG C, adjustment is stirred
It mixes as 200r/min, it is uniform to lotion to stir 30min；
S4: being added the deionized water of remaining 1/2 parts by weight, and it is uniform to lotion to continue stirring 30min；
S5: sample detection pH, viscosity, adjustment pH be 6~9, viscosity 3000cps；
S6: being cooled to 32~38 DEG C, continues to stir 1h to uniform without obvious bubble；Add 120~200 mesh filter screen filtering and dischargings
It is sealed into storage tank, it is filling after qualification to be detected.
Embodiment 2
Embodiment 2 provides a kind of multifunctional detergent that addition amino acid table is living, by weight, including such as the following group
Point: 15 parts of major ingredient, 25 parts of amino acid surfactant, 2 parts of fungicide, 8 parts of stabilizer, 3 parts of skin conditioner, 40 parts of deionized water,
0.2 part of pH adjusting agent.
The major ingredient includes natural sea alkali, sodium bicarbonate, natural sea salt；The natural sea alkali, sodium bicarbonate, natural sea salt
Weight ratio be 10:10:12.
The amino acid surfactant is sodium lauroyl glutamate, cocoamido sodium propionate, methyl lauroyl
Sodium taurocholate, lauryl hydroxyl sulfo betaine, four sodium of glutamic acid diacetic acid by weight 1:0.5:0.2:0.2:0.1 group
It closes.
The fungicide is that sodium Diacetate and nisin are combined by weight 1:1.5.
The stabilizer is APG0814, chitosan, hydroxyethyl cellulose, oligoisomaltose by weight 5:1:1:1's
Combination.
The skin conditioner is that glycerol and rice fermentation Product filtrate are combined by 2:1.
The pH adjusting agent is sodium citrate.
A kind of preparation method for the multifunctional detergent that addition amino acid table is living, step is the same as embodiment 1.
Embodiment 3
Embodiment 3 provides a kind of multifunctional detergent that addition amino acid table is living, by weight, including such as the following group
Point: 32 parts of major ingredient, 53 parts of amino acid surfactant, 3 parts of fungicide, 13 parts of stabilizer, 4 parts of skin conditioner, 80 parts of deionized water,
0.8 part of pH adjusting agent.
The major ingredient includes natural sea alkali, sodium bicarbonate, natural sea salt；The natural sea alkali, sodium bicarbonate, natural sea salt
Weight ratio be 18:12:16.
The amino acid surfactant is sodium lauroyl glutamate, cocoamido sodium propionate, methyl lauroyl
Sodium taurocholate, lauryl hydroxyl sulfo betaine, four sodium of glutamic acid diacetic acid by weight 1:0.5:0.2:0.2:0.1 group
It closes.
The fungicide is that sodium Diacetate and nisin are combined by weight 1:2.
The stabilizer is APG0814, chitosan, hydroxyethyl cellulose, oligoisomaltose by weight 10:3:2:1
Combination.
The skin conditioner is that glycerol and rice fermentation Product filtrate are combined by 2.5:1.
The pH adjusting agent is sodium citrate.
A kind of preparation method for the multifunctional detergent that addition amino acid table is living, step is the same as embodiment 1.
Embodiment 4
Embodiment 4 provides a kind of multifunctional detergent that addition amino acid table is living, by weight, including such as the following group
Point: 18 parts of major ingredient, 30 parts of amino acid surfactant, 2.5 parts of fungicide, 9 parts of stabilizer, 3.5 parts of skin conditioner, deionized water 50
Part, 0.5 part of pH adjusting agent.
The major ingredient includes natural sea alkali, sodium bicarbonate, natural sea salt；The natural sea alkali, sodium bicarbonate, natural sea salt
Weight ratio be 12:10:13.
The amino acid surfactant is sodium lauroyl glutamate, cocoamido sodium propionate, methyl lauroyl
Sodium taurocholate, lauryl hydroxyl sulfo betaine, four sodium of glutamic acid diacetic acid by weight 1:0.5:0.2:0.2:0.1 group
It closes.
The fungicide is that sodium Diacetate and nisin are combined by weight 1:1.5.
The stabilizer is APG0814, chitosan, hydroxyethyl cellulose, oligoisomaltose by weight 6:2:2:1's
Combination.
The skin conditioner is that glycerol and rice fermentation Product filtrate are combined by 2.5:1.
The pH adjusting agent is sodium citrate.
A kind of preparation method for the multifunctional detergent that addition amino acid table is living, step is the same as embodiment 1.
Embodiment 5
Embodiment 5 provides a kind of multifunctional detergent that addition amino acid table is living, by weight, including such as the following group
Point: 25 parts of major ingredient, 42 parts of amino acid surfactant, 3 parts of fungicide, 12 parts of stabilizer, 4 parts of skin conditioner, 70 parts of deionized water,
0.8 part of pH adjusting agent.
The major ingredient includes natural sea alkali, sodium bicarbonate, natural sea salt；The natural sea alkali, sodium bicarbonate, natural sea salt
Weight ratio be 16:12:15.
The amino acid surfactant is sodium lauroyl glutamate, cocoamido sodium propionate, methyl lauroyl
Sodium taurocholate, lauryl hydroxyl sulfo betaine, four sodium of glutamic acid diacetic acid by weight 1:0.5:0.2:0.2:0.1 group
It closes.
The fungicide is that sodium Diacetate and nisin are combined by weight 1:1.5.
The stabilizer is APG0814, chitosan, hydroxyethyl cellulose, oligoisomaltose by weight 9:2:2:1's
Combination.
The skin conditioner is that glycerol and rice fermentation Product filtrate are combined by 2.5:1.
The pH adjusting agent is sodium citrate.
A kind of preparation method for the multifunctional detergent that addition amino acid table is living, step is the same as embodiment 1.
Comparative example 1
Comparative example 1 provides a kind of multifunctional detergent that addition amino acid table is living, by weight, including such as the following group
Point: 5 parts of major ingredient, 35 parts of amino acid surfactant, 2.5 parts of fungicide, 10.5 parts of stabilizer, 3.5 parts of skin conditioner, deionized water
60 parts, 0.6 part of pH adjusting agent.
The major ingredient includes natural sea alkali, sodium bicarbonate, natural sea salt；The natural sea alkali, sodium bicarbonate, natural sea salt
Weight ratio be 14:11:13.5.
The amino acid surfactant is sodium lauroyl glutamate, cocoamido sodium propionate, methyl lauroyl
Sodium taurocholate, lauryl hydroxyl sulfo betaine, four sodium of glutamic acid diacetic acid by weight 1:0.5:0.2:0.2:0.1 group
It closes.
The fungicide is that sodium Diacetate and nisin are combined by weight 1:1.5.
The stabilizer is APG0814, chitosan, hydroxyethyl cellulose, oligoisomaltose by weight 7.5:2:
The combination of 1.5:1.
The skin conditioner is that glycerol and rice fermentation Product filtrate are combined by 2.5:1.
The pH adjusting agent is sodium citrate.
A kind of preparation method for the multifunctional detergent that addition amino acid table is living, step is the same as embodiment 1.
Comparative example 2
Comparative example 2 provides a kind of multifunctional detergent that addition amino acid table is living, by weight, including such as the following group
Point: 60 parts of major ingredient, 35 parts of amino acid surfactant, 2.5 parts of fungicide, 10.5 parts of stabilizer, 3.5 parts of skin conditioner, deionization
60 parts of water, 0.6 part of pH adjusting agent.
The major ingredient includes natural sea alkali, sodium bicarbonate, natural sea salt；The natural sea alkali, sodium bicarbonate, natural sea salt
Weight ratio be 14:11:13.5.
The amino acid surfactant is sodium lauroyl glutamate, cocoamido sodium propionate, methyl lauroyl
Sodium taurocholate, lauryl hydroxyl sulfo betaine, four sodium of glutamic acid diacetic acid by weight 1:0.5:0.2:0.2:0.1 group
It closes.
The fungicide is that sodium Diacetate and nisin are combined by weight 1:1.5.
The stabilizer is APG0814, chitosan, hydroxyethyl cellulose, oligoisomaltose by weight 7.5:2:
The combination of 1.5:1.
The skin conditioner is that glycerol and rice fermentation Product filtrate are combined by 2.5:1.
The pH adjusting agent is sodium citrate.
A kind of preparation method for the multifunctional detergent that addition amino acid table is living, step is the same as embodiment 1.
Comparative example 3
Comparative example 3 provides a kind of multifunctional detergent that addition amino acid table is living, by weight, including such as the following group
Point: 21 parts of major ingredient, 35 parts of amino acid surfactant, 2.5 parts of fungicide, 1 part of stabilizer, 3.5 parts of skin conditioner, deionized water 60
Part, 0.6 part of pH adjusting agent.
The major ingredient includes natural sea alkali, sodium bicarbonate, natural sea salt；The natural sea alkali, sodium bicarbonate, natural sea salt
Weight ratio be 14:11:13.5.
The amino acid surfactant is sodium lauroyl glutamate, cocoamido sodium propionate, methyl lauroyl
Sodium taurocholate, lauryl hydroxyl sulfo betaine, four sodium of glutamic acid diacetic acid by weight 1:0.5:0.2:0.2:0.1 group
It closes.
The fungicide is that sodium Diacetate and nisin are combined by weight 1:1.5.
The stabilizer is APG0814, chitosan, hydroxyethyl cellulose, oligoisomaltose by weight 7.5:2:
The combination of 1.5:1.
The skin conditioner is that glycerol and rice fermentation Product filtrate are combined by 2.5:1.
The pH adjusting agent is sodium citrate.
A kind of preparation method for the multifunctional detergent that addition amino acid table is living, step is the same as embodiment 1.
Comparative example 4
Comparative example 4 provides a kind of multifunctional detergent that addition amino acid table is living, by weight, including such as the following group
Point: 21 parts of major ingredient, 35 parts of amino acid surfactant, 2.5 parts of fungicide, 40 parts of stabilizer, 3.5 parts of skin conditioner, deionized water
60 parts, 0.6 part of pH adjusting agent.
The major ingredient includes natural sea alkali, sodium bicarbonate, natural sea salt；The natural sea alkali, sodium bicarbonate, natural sea salt
Weight ratio be 14:11:13.5.
The amino acid surfactant is sodium lauroyl glutamate, cocoamido sodium propionate, methyl lauroyl
Sodium taurocholate, lauryl hydroxyl sulfo betaine, four sodium of glutamic acid diacetic acid by weight 1:0.5:0.2:0.2:0.1 group
It closes.
The fungicide is that sodium Diacetate and nisin are combined by weight 1:1.5.
The stabilizer is APG0814, chitosan, hydroxyethyl cellulose, oligoisomaltose by weight 7.5:2:
The combination of 1.5:1.
The skin conditioner is that glycerol and rice fermentation Product filtrate are combined by 2.5:1.
The pH adjusting agent is sodium citrate.
A kind of preparation method for the multifunctional detergent that addition amino acid table is living, step is the same as embodiment 1.
Comparative example 5
Comparative example 5 provides a kind of multifunctional detergent that addition amino acid table is living, by weight, including such as the following group
Point: 21 parts of major ingredient, 35 parts of amino acid surfactant, 2.5 parts of fungicide, 10.5 parts of stabilizer, 0.1 part of skin conditioner, deionization
60 parts of water, 0.6 part of pH adjusting agent.
The major ingredient includes natural sea alkali, sodium bicarbonate, natural sea salt；The natural sea alkali, sodium bicarbonate, natural sea salt
Weight ratio be 14:11:13.5.
The amino acid surfactant is sodium lauroyl glutamate, cocoamido sodium propionate, methyl lauroyl
Sodium taurocholate, lauryl hydroxyl sulfo betaine, four sodium of glutamic acid diacetic acid by weight 1:0.5:0.2:0.2:0.1 group
It closes.
The fungicide is that sodium Diacetate and nisin are combined by weight 1:1.5.
The stabilizer is APG0814, chitosan, hydroxyethyl cellulose, oligoisomaltose by weight 7.5:2:
The combination of 1.5:1.
The skin conditioner is that glycerol and rice fermentation Product filtrate are combined by 2.5:1.
The pH adjusting agent is sodium citrate.
A kind of preparation method for the multifunctional detergent that addition amino acid table is living, step is the same as embodiment 1.
Comparative example 6
Comparative example 6 provides a kind of multifunctional detergent that addition amino acid table is living, by weight, including such as the following group
Point: 21 parts of major ingredient, 35 parts of amino acid surfactant, 2.5 parts of fungicide, 10.5 parts of stabilizer, 20 parts of skin conditioner, deionized water
60 parts, 0.6 part of pH adjusting agent.
The major ingredient includes natural sea alkali, sodium bicarbonate, natural sea salt；The natural sea alkali, sodium bicarbonate, natural sea salt
Weight ratio be 14:11:13.5.
The amino acid surfactant is sodium lauroyl glutamate, cocoamido sodium propionate, methyl lauroyl
Sodium taurocholate, lauryl hydroxyl sulfo betaine, four sodium of glutamic acid diacetic acid by weight 1:0.5:0.2:0.2:0.1 group
It closes.
The fungicide is that sodium Diacetate and nisin are combined by weight 1:1.5.
The stabilizer is APG0814, chitosan, hydroxyethyl cellulose, oligoisomaltose by weight 7.5:2:
The combination of 1.5:1.
The skin conditioner is that glycerol and rice fermentation Product filtrate are combined by 2.5:1.
The pH adjusting agent is sodium citrate.
A kind of preparation method for the multifunctional detergent that addition amino acid table is living, step is the same as embodiment 1.
Comparative example 7
Comparative example 7 provides a kind of multifunctional detergent that addition amino acid table is living, by weight, including such as the following group
Point: 21 parts of major ingredient, 35 parts of amino acid surfactant, 0.1 part of fungicide, 10.5 parts of stabilizer, 3.5 parts of skin conditioner, deionization
60 parts of water, 0.6 part of pH adjusting agent.
The major ingredient includes natural sea alkali, sodium bicarbonate, natural sea salt；The natural sea alkali, sodium bicarbonate, natural sea salt
Weight ratio be 14:11:13.5.
The amino acid surfactant is sodium lauroyl glutamate, cocoamido sodium propionate, methyl lauroyl
Sodium taurocholate, lauryl hydroxyl sulfo betaine, four sodium of glutamic acid diacetic acid by weight 1:0.5:0.2:0.2:0.1 group
It closes.
The fungicide is that sodium Diacetate and nisin are combined by weight 1:1.5.
The stabilizer is APG0814, chitosan, hydroxyethyl cellulose, oligoisomaltose by weight 7.5:2:
The combination of 1.5:1.
The skin conditioner is that glycerol and rice fermentation Product filtrate are combined by 2.5:1.
The pH adjusting agent is sodium citrate.
A kind of preparation method for the multifunctional detergent that addition amino acid table is living, step is the same as embodiment 1.
Comparative example 8
Comparative example 8 provides a kind of multifunctional detergent that addition amino acid table is living, by weight, including such as the following group
Point: 21 parts of major ingredient, 35 parts of amino acid surfactant, 15 parts of fungicide, 10.5 parts of stabilizer, 3.5 parts of skin conditioner, deionized water
60 parts, 0.6 part of pH adjusting agent.
The major ingredient includes natural sea alkali, sodium bicarbonate, natural sea salt；The natural sea alkali, sodium bicarbonate, natural sea salt
Weight ratio be 14:11:13.5.
The amino acid surfactant is sodium lauroyl glutamate, cocoamido sodium propionate, methyl lauroyl
Sodium taurocholate, lauryl hydroxyl sulfo betaine, four sodium of glutamic acid diacetic acid by weight 1:0.5:0.2:0.2:0.1 group
It closes.
The fungicide is that sodium Diacetate and nisin are combined by weight 1:1.5.
The stabilizer is APG0814, chitosan, hydroxyethyl cellulose, oligoisomaltose by weight 7.5:2:
The combination of 1.5:1.
The skin conditioner is that glycerol and rice fermentation Product filtrate are combined by 2.5:1.
The pH adjusting agent is sodium citrate.
A kind of preparation method for the multifunctional detergent that addition amino acid table is living, step is the same as embodiment 1.
Performance evaluation
1. acute oral toxicity is tested
Test method: disinfection technology standard (version in 2002) takes 100 to mouse, half male and half female, is classified as five groups, right
Five groups of embodiments are answered, 5.0756g sample is weighed in beaker, is settled in the volumetric flask of 20mL, using once real to greatest extent
It tests, given low 5075.6mg/kg, animal is forbidden overnight before contaminating.Continue fasting 3 hours after contamination, daily observation poisoning
Symptom or Behavioral change, weighing is primary weekly.Gross anatomy observation is made to 14 days surviving animals after be poisoned to death animal and contamination.
As the result is shown: the product of Examples 1 to 5 does not have any impact to experimental animal, and contamination had no any poisoning symptom in 14 days
Be poisoned to death, the weight of animals no abnormality seen, after experiment, gross anatomy carried out to animal subject and checks that also no abnormality seen becomes
Change, according to standard, acute oral LD of the sample to ICR mouse50> 5000mg/kg belongs to practical nontoxic grade.
2. smell and pH test
Test method: the preparation-obtained environment protection multifunctional detergent of Examples 1 to 5 is marked according to GB/T24691-2009
Standard is tested, as the result is shown: the uniform free from admixture of the product appearance of Examples 1 to 5 does not agglomerate, is not stratified, meets the requirements；It is real
The equal free from extraneous odour of product for applying example 1~5, meets the requirements；The product pH of Examples 1 to 5 is 8~9.7, is met the requirements.
3. high-temperature stability
Test method: the preparation-obtained environment protection multifunctional detergent of Examples 1 to 5 is filled into glass tube, 40
Save 1d in DEG C thermostat, as the result is shown: the product of Examples 1 to 5 is not stratified, it is not muddy, do not change smell.
4. low-temperature stability
Test method: the preparation-obtained environment protection multifunctional detergent of Examples 1 to 5 is filled into glass tube, -3
Save 1d in~-10 DEG C of cryostat,s, after restoring to room temperature as the result is shown: the product nodeless mesh of Examples 1 to 5, without precipitating.
5. degreasing performance test
Test method is as follows:
(1) prepare before test: sample liquid prepares: embodiment and the preparation-obtained product of comparative example are matched using tap water
It is set to the sample liquid of 1:100 concentration；Greasy dirt prepares: with butter: lard: vegetable oil=1:1:2 proportional arrangement, and add its total matter
The polyglycerol ester fatty acid of amount 5%, obtains mixing artificial greasy dirt, refrigerates in -5 ± 0.5 DEG C stand-by；The preparation of greasy dirt slide glass:
Glass slide is boiled into 15min in deionized water, is placed in acid wash liquid again after cleaning and impregnates 1h, clear water is washed till nothing on glass slide
Acid solution residual after rinsed with deionized water, drying use, take glass slide from top to bottom 10mm place setting-out, by greasy dirt be limited in the line with
Under, it is spare；Wherein, the commercial detergent is white cat lemon black tea dish washing liquid of the purchase from supermarket.
(2) it defiles method: pretreated slide glass being precisely weighed with assay balance and (accurately to 0.001g), is denoted as m0,
After slide glass clip after weighing is fixed more than 10mm line, prepare to defile.(room temperature when greasy dirt is maintained at determining temperature
When being 20 ± 0.5 DEG C, oil temperature need to be heated to 80 DEG C.When room temperature is 25 ± 0.5 DEG C, oil temperature need to be heated to 45 DEG C.When room temperature is excessively high
Or when too low, test should not be carried out, and need room temperature being adjusted to preference temperature scope.) clip for fixing slide glass is held, by slide glass
It is immersed below upper 10mm line and keeps 1~2s in greasy dirt, after slowly taking out.After placing 4h at room temperature, it is (accurate to be weighed with assay balance
To 0.001g), it is denoted as m1, the greasy dirt amount of dirty on piece is 0.5 ± 0.05g at this time.
(3) soil removal efficiency measures: taking appropriate sample liquid, heats while stirring in 30 DEG C of water-baths, until stirring evenly and temperature
Rise to 30 DEG C.Slide glass is fixed on above sample liquid together with clip, guarantees to be immersed in sample below 10mm line on slide glass
In liquid, 1min is kept.After slide glass is fixed, opening magnetic agitation setting speed is 150r/min, continues 5min.After will carry
Original position is put back in piece and clip taking-up, slide glass is hung to being completely dried after 3h at room temperature, is m with assay balance weighing2It is (accurate
To 0.001g).
(4) result calculates
In formula: C-soil removal efficiency (%)；m0- defile before slide glass quality (g)；m1- defile after slide glass quality (g)；
m2The quality (g) of slide glass after the processing of-sample liquid.
Table 1
| Embodiment | Remove oil cut rate/% |
| Embodiment 1 | 95.6 |
| Embodiment 2 | 87.8 |
| Embodiment 3 | 90.5 |
| Embodiment 4 | 92.3 |
| Embodiment 5 | 93.3 |
| Comparative example 1 | 44.2 |
| Comparative example 2 | 87.3 |
| Comparative example 3 | 57.8 |
| Comparative example 4 | 74.6 |
| Comparative example 5 | 75.4 |
| Comparative example 6 | 81.5 |
| Comparative example 7 | 67.3 |
| Comparative example 8 | 83.4 |
| Commercial detergent | 25.7 |
6. bacteriostasis property is tested
Test method: standard GB/T/T24691- is pressed respectively using embodiment and the preparation-obtained product of comparative example
2009 detection cowpeas cleaned before and after Cypermethrin Residues rate, arprocarb residual rate and each bacterium on cowpea surface
Inhibition zone size (mm), wherein the commercial detergent is white cat lemon black tea dish washing liquid of the purchase from supermarket.
Table 2
7. heavy-metal residual performance test
Test method: by embodiment and the preparation-obtained product of comparative example according to GB9985-2000 annex G to a huge sum of money
Belonging to residual can be carried out test, wherein the commercial detergent is white cat lemon black tea dish washing liquid of the purchase from supermarket.
Table 3
Claims (10)
1. a kind of multifunctional detergent that addition amino acid table is living, which is characterized in that including following component: major ingredient, amino acid table
Face activating agent, fungicide, stabilizer, skin conditioner, deionized water, pH adjusting agent.
2. addition amino acid table according to claim 1 multifunctional detergent living, which is characterized in that by weight,
Including following component: 15~32 parts of major ingredient, 25~53 parts of amino acid surfactant, 2~3 parts of fungicide, stabilizer 8~13
Part, 3~4 parts of skin conditioner, 40~80 parts of deionized water, 0~1 part of pH adjusting agent.
3. addition amino acid table according to claim 2 multifunctional detergent living, which is characterized in that the major ingredient includes
Natural sea alkali, sodium bicarbonate, natural sea salt.
4. addition amino acid table according to claim 3 multifunctional detergent living, which is characterized in that the natural sea
Alkali, sodium bicarbonate, natural sea salt weight ratio be (10~18): (10~12): (12~16).
5. addition amino acid table according to claim 2 multifunctional detergent living, which is characterized in that the amino acid table
Face activating agent is selected from sodium lauroyl glutamate, cocoyl Sodium L-alaninate, myristoyl sodium glutamate, cocounut oil acyl glycine
Sodium, cocounut oil acyl Sodium L-alaninate, methyl lauroyl sodium taurocholate, lauryl hydroxyl sulfo betaine, glutamic acid diacetic acid sodium salt
One of or it is a variety of.
6. addition amino acid table according to claim 2 multifunctional detergent living, which is characterized in that the fungicide choosing
From in salt acid imide urea, hexamethylene diamine, dodecanamide propyl amine oxide, Na2Fe04, sodium Diacetate, nisin
It is one or more.
7. addition amino acid table according to claim 2 multifunctional detergent living, which is characterized in that the stabilizer choosing
From one of polyglycoside surfactants, sodium alginate, xanthan gum, chitosan, hydroxyethyl cellulose, oligoisomaltose or more
Kind.
8. addition amino acid table according to claim 7 multifunctional detergent living, which is characterized in that the polyglycoside surfactant
Activating agent is selected from one of APG0810, APG0814, APG0816, APG1214, APG1216, APG1218 or a variety of.
9. addition amino acid table according to claim 2 multifunctional detergent living, which is characterized in that the skin conditioner choosing
From one of vitamin C, vitamin E, beeswax, collagen, glycerol, rice fermentation Product filtrate or a variety of.
10. a kind of preparation method for the multifunctional detergent that addition amino acid table according to claim 1 is living, feature exist
In step includes:
S1: major ingredient, pH adjusting agent are added in reaction kettle, the deionized water of 1/4 parts by weight is slowly added to along kettle wall, opens stirring
50r/min stirs 10min to paste is melted, avoids acutely blistering, and observation phenomenon is adjusted revolving speed；
S2: continuously adding 1/4 deionized water, and adjustment mixing speed is 100r/min, stirring 15min to uniform paste；
S3: amino acid surfactant, fungicide, stabilizer, skin conditioner are sequentially added and is warming up to 40~45 DEG C, adjustment stirring is
200r/min, stirring 30min are uniform to lotion；
S4: being added the deionized water of remaining 1/2 parts by weight, and it is uniform to lotion to continue stirring 30min；
S5: sample detection pH, viscosity, adjustment pH be 6~9, viscosity 3000cps；
S6: being cooled to 32~38 DEG C, continues to stir 1h to uniform without obvious bubble；Add 120~200 mesh filter screen filtering and dischargings to storage
It is sealed in tank, it is filling after qualification to be detected.
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