CN108823604B - 一次电解制备5n高纯铟的方法 - Google Patents
一次电解制备5n高纯铟的方法 Download PDFInfo
- Publication number
- CN108823604B CN108823604B CN201810977839.9A CN201810977839A CN108823604B CN 108823604 B CN108823604 B CN 108823604B CN 201810977839 A CN201810977839 A CN 201810977839A CN 108823604 B CN108823604 B CN 108823604B
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- Prior art keywords
- indium
- mixed solution
- purity
- concentration
- metal
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- 229910052738 indium Inorganic materials 0.000 title claims abstract description 80
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 title claims abstract description 80
- 238000000034 method Methods 0.000 title claims abstract description 32
- 238000005868 electrolysis reaction Methods 0.000 title claims abstract description 17
- 229910052751 metal Inorganic materials 0.000 claims abstract description 37
- 239000002184 metal Substances 0.000 claims abstract description 35
- 238000007670 refining Methods 0.000 claims abstract description 19
- 239000003792 electrolyte Substances 0.000 claims abstract description 13
- 238000001914 filtration Methods 0.000 claims abstract description 7
- 239000002994 raw material Substances 0.000 claims abstract description 3
- 239000011259 mixed solution Substances 0.000 claims description 35
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 34
- UMGDCJDMYOKAJW-UHFFFAOYSA-N thiourea Chemical compound NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 claims description 34
- LUEWUZLMQUOBSB-FSKGGBMCSA-N (2s,3s,4s,5s,6r)-2-[(2r,3s,4r,5r,6s)-6-[(2r,3s,4r,5s,6s)-4,5-dihydroxy-2-(hydroxymethyl)-6-[(2r,4r,5s,6r)-4,5,6-trihydroxy-2-(hydroxymethyl)oxan-3-yl]oxyoxan-3-yl]oxy-4,5-dihydroxy-2-(hydroxymethyl)oxan-3-yl]oxy-6-(hydroxymethyl)oxane-3,4,5-triol Chemical compound O[C@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@H]1O[C@@H]1[C@@H](CO)O[C@@H](O[C@@H]2[C@H](O[C@@H](OC3[C@H](O[C@@H](O)[C@@H](O)[C@H]3O)CO)[C@@H](O)[C@H]2O)CO)[C@H](O)[C@H]1O LUEWUZLMQUOBSB-FSKGGBMCSA-N 0.000 claims description 18
- 241001312219 Amorphophallus konjac Species 0.000 claims description 18
- 235000001206 Amorphophallus rivieri Nutrition 0.000 claims description 18
- 229920002581 Glucomannan Polymers 0.000 claims description 18
- 229920002752 Konjac Polymers 0.000 claims description 18
- 229940046240 glucomannan Drugs 0.000 claims description 18
- 235000010485 konjac Nutrition 0.000 claims description 18
- 239000000252 konjac Substances 0.000 claims description 18
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Natural products NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 17
- 239000011780 sodium chloride Substances 0.000 claims description 17
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 16
- 239000000243 solution Substances 0.000 claims description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 10
- 238000001035 drying Methods 0.000 claims description 9
- 239000003365 glass fiber Substances 0.000 claims description 9
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 8
- 238000002156 mixing Methods 0.000 claims description 8
- 239000010936 titanium Substances 0.000 claims description 8
- 229910052719 titanium Inorganic materials 0.000 claims description 8
- 229910021642 ultra pure water Inorganic materials 0.000 claims description 8
- 239000012498 ultrapure water Substances 0.000 claims description 8
- 239000004744 fabric Substances 0.000 claims description 7
- 238000010438 heat treatment Methods 0.000 claims description 7
- 229920000728 polyester Polymers 0.000 claims description 7
- 238000005406 washing Methods 0.000 claims description 7
- 238000004140 cleaning Methods 0.000 claims description 2
- 150000002500 ions Chemical class 0.000 abstract description 2
- 238000004519 manufacturing process Methods 0.000 abstract description 2
- 239000012466 permeate Substances 0.000 abstract description 2
- 239000000047 product Substances 0.000 description 3
- 239000000654 additive Substances 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 230000000737 periodic effect Effects 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 229940088594 vitamin Drugs 0.000 description 2
- 229930003231 vitamin Natural products 0.000 description 2
- 235000013343 vitamin Nutrition 0.000 description 2
- 239000011782 vitamin Substances 0.000 description 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 229910001361 White metal Inorganic materials 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- RKTYLMNFRDHKIL-UHFFFAOYSA-N copper;5,10,15,20-tetraphenylporphyrin-22,24-diide Chemical group [Cu+2].C1=CC(C(=C2C=CC([N-]2)=C(C=2C=CC=CC=2)C=2C=CC(N=2)=C(C=2C=CC=CC=2)C2=CC=C3[N-]2)C=2C=CC=CC=2)=NC1=C3C1=CC=CC=C1 RKTYLMNFRDHKIL-UHFFFAOYSA-N 0.000 description 1
- 230000007123 defense Effects 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 229910052745 lead Inorganic materials 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000002105 nanoparticle Substances 0.000 description 1
- 230000005622 photoelectricity Effects 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 239000010802 sludge Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229910052716 thallium Inorganic materials 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 238000005292 vacuum distillation Methods 0.000 description 1
- 150000003722 vitamin derivatives Chemical class 0.000 description 1
- 239000010969 white metal Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C1/00—Electrolytic production, recovery or refining of metals by electrolysis of solutions
- C25C1/22—Electrolytic production, recovery or refining of metals by electrolysis of solutions of metals not provided for in groups C25C1/02 - C25C1/20
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C7/00—Constructional parts, or assemblies thereof, of cells; Servicing or operating of cells
- C25C7/06—Operating or servicing
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Electrolytic Production Of Metals (AREA)
Abstract
Description
Claims (4)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN201810977839.9A CN108823604B (zh) | 2018-08-27 | 2018-08-27 | 一次电解制备5n高纯铟的方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
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CN201810977839.9A CN108823604B (zh) | 2018-08-27 | 2018-08-27 | 一次电解制备5n高纯铟的方法 |
Publications (2)
Publication Number | Publication Date |
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CN108823604A CN108823604A (zh) | 2018-11-16 |
CN108823604B true CN108823604B (zh) | 2020-09-29 |
Family
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Family Applications (1)
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CN201810977839.9A Active CN108823604B (zh) | 2018-08-27 | 2018-08-27 | 一次电解制备5n高纯铟的方法 |
Country Status (1)
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CN (1) | CN108823604B (zh) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
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CN111286755A (zh) * | 2020-04-10 | 2020-06-16 | 云南锡业集团(控股)有限责任公司研发中心 | 一种电解-区域法制备高纯铟的方法 |
CN113802151B (zh) * | 2021-10-27 | 2023-01-20 | 上海大学 | 一种高纯铟电解精炼的多通道电解装置及机器学习工艺优化方法 |
CN114561670A (zh) * | 2022-03-28 | 2022-05-31 | 云南锡业集团(控股)有限责任公司研发中心 | 一种高纯铟电解装置及其电解方法 |
CN115044941A (zh) * | 2022-06-21 | 2022-09-13 | 成都中建材光电材料有限公司 | 一种粗铟一次电解制备高纯铟的工艺 |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
SU222104A1 (ru) * | 1967-04-11 | 1969-10-07 | М. А. Лошкарев , А. А. Казаров Днепропетровский химико технологический институт | Способ электролитического осаждения индия |
US4287030A (en) * | 1980-05-19 | 1981-09-01 | Belsky Arkady A | Process for producing high-purity indium |
CN1267583C (zh) * | 2002-10-16 | 2006-08-02 | 沈奕林 | 一种制备高纯铟的方法 |
CN101892495B (zh) * | 2010-06-29 | 2012-02-22 | 葫芦岛锌业股份有限公司 | 高杂质粗铟一次电解生产4n5精铟的方法 |
CN102943284A (zh) * | 2012-12-07 | 2013-02-27 | 株洲科能新材料有限责任公司 | 一种铟电解液的配制方法 |
CN203904474U (zh) * | 2014-06-12 | 2014-10-29 | 广西德邦科技有限公司 | 电解阳极板 |
CN107513731A (zh) * | 2017-09-07 | 2017-12-26 | 韶关市欧莱高新材料有限公司 | 一种铟电解阳极板机构 |
CN107354485B (zh) * | 2017-09-12 | 2019-05-17 | 武汉峰则惠电子材料股份有限公司 | 一种电解精炼制备高纯铟的方法 |
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2018
- 2018-08-27 CN CN201810977839.9A patent/CN108823604B/zh active Active
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Effective date of registration: 20240407 Address after: No. 2 Yunjing Road, Information Industry Base, Luoyang Street Office, Economic Development Zone, Kunming Area, China (Yunnan) Pilot Free Trade Zone, Kunming City, Yunnan Province, 650501 Patentee after: YUNNAN TIN NEW MATERIAL Co.,Ltd. Country or region after: China Address before: No. 650000, Changyuan Road, Kunming, Yunnan Province Patentee before: R & D Center of Yunnan Tin Industry Group (Holdings) Co.,Ltd. Country or region before: China |