CN108774889A - 一种户外服装用导湿聚酰胺面料的制备方法 - Google Patents

一种户外服装用导湿聚酰胺面料的制备方法 Download PDF

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CN108774889A
CN108774889A CN201810658984.0A CN201810658984A CN108774889A CN 108774889 A CN108774889 A CN 108774889A CN 201810658984 A CN201810658984 A CN 201810658984A CN 108774889 A CN108774889 A CN 108774889A
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polyamide fabric
outdoor wear
fabric
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王东营
杨子成
王东宝
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Anhui Hualida Outdoor Products Co Ltd
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Abstract

本发明公开一种导湿户外服装用聚酰胺纤维的制备方法，包括以下操作步骤：（1）将熔融纺丝后的聚酰胺纤维编织成面料，然后将得到的聚酰胺面料放入活化液中进行表面活化处理；（2）将聚乙二醇二丙烯酸酯、氧化石墨烯、晾感添加剂加入至水中，采用超声处理后，得到混合胶粒溶液，然后继续向混合胶粒溶液中加入甲基丙烯酸甲酯、丙烯酸烯丙酯、引发剂，保温反应，制得复合水凝胶；（3）然后将制得的复合水凝胶涂刷在聚酰胺面料的表面，烘干处理后，制得成品。本发明制得的聚酰胺面料，各项力学性能优异，耐磨性好，适合制备户外服装，尤其是具有优异的导湿性能，人体产生的汗液可快速的挥发掉，增加穿着的舒适度。

Description

一种户外服装用导湿聚酰胺面料的制备方法
技术领域
本发明属于户外服装技术领域，具体涉及一种户外服装用导湿聚酰胺面料的制备方法。
背景技术
户外环境复杂多变，为抵御恶劣环境对人体的伤害，保护身体热量不被散失以及快速排出运动时所产生的汗水，在登山、攀岩及其他户外运动时，应该穿戴专业的户外服装。现有技术中的户外服装，为了增加其强度，常常采用聚酰胺纤维编织，但是聚酰胺纤维存在着导湿性能差，人体产生的汗液不易快速挥发，导致其舒适感较差。
发明内容
为了解决上述技术问题，本发明提供一种户外服装用导湿聚酰胺面料的制备方法。
本发明是通过以下技术方案实现的。
一种户外服装用导湿聚酰胺面料的制备方法，包括以下操作步骤：
（1）将熔融纺丝后的聚酰胺纤维编织成面料，然后将得到的聚酰胺面料放入活化液中进行表面活化处理，其中活化液由以下重量份的组分制成：甲基丙烯磺酸钠13-16份、过氧化钠4-9份、三聚磷酸钾10-15份、水190-200份；
（2）按重量份计，将36-40份聚乙二醇二丙烯酸酯、13-20份氧化石墨烯、10-14份晾感添加剂加入至140-160份水中，采用超声处理后，得到混合胶粒溶液，然后继续向混合胶粒溶液中加入60-70份甲基丙烯酸甲酯、46-50份丙烯酸烯丙酯、0.5-0.9份引发剂，混合搅拌均匀后，55-60℃保温反应3-4小时后，制得复合水凝胶，其中凉感添加剂由以下重量份的组分制成：钽粉5-10份、氧化钆13-16份、氧硅磷灰石29-35份；
（3）然后将制得的复合水凝胶涂刷在聚酰胺面料的表面，烘干处理后，制得成品。
具体地，上述步骤（2）中，氧化石墨烯的纯度为99%，平均粒径大小为2-3μm。
具体地，上述步骤（2）中，引发剂为过氧化苯甲酰、过氧化月桂酰中的任意一种。
具体地，上述步骤（3）中，烘干处理的温度为70-80℃。
由以上的技术方案可知，本发明的有益效果是：
本发明提供的一种户外服装用导湿聚酰胺面料的制备方法，成本较低，可实现大规模的工业化生产，制得的聚酰胺面料，各项力学性能优异，耐磨性好，适合制备户外服装，尤其是具有优异的导湿性能，人体产生的汗液可快速的挥发掉，增加穿着的舒适度。其中，步骤（1）中的活化液，可在面料表面形成较多的羧基、羰基、磺酸基等活性基团，提升了其表面活性，增加了复合水凝胶在其表面的粘结力；本发明制得的复合水凝胶，在聚酰胺面料表面干燥后，可形成一层致密的膜层，增强聚酰胺面料的耐磨性能，但是膜层内部由于含有氧化石墨烯以及凉感添加剂，两者协同作用后，具有优异的吸湿能力和导湿能力，其能吸收聚酰胺面料内侧的气态水，并向聚酰胺面料内部传递，传到聚酰胺面料的另一面，可使的聚酰胺面料长久的保持干燥的状况。
具体实施方式
下面通过具体的实施例对本发明进行详细说明，但这些举例性实施方式的用途和目的仅用来例举本发明，并非对本发明的实际保护范围构成任何形式的任何限定，更非将本发明的保护范围局限于此。
实施例1
一种户外服装用导湿聚酰胺面料的制备方法，包括以下操作步骤：
（1）将熔融纺丝后的聚酰胺纤维编织成面料，然后将得到的聚酰胺面料放入活化液中进行表面活化处理，其中活化液由以下重量份的组分制成：甲基丙烯磺酸钠13份、过氧化钠4份、三聚磷酸钾10份、水190份；
（2）按重量份计，将36份聚乙二醇二丙烯酸酯、13份氧化石墨烯、10份晾感添加剂加入至140份水中，采用超声处理后，得到混合胶粒溶液，然后继续向混合胶粒溶液中加入60份甲基丙烯酸甲酯、46份丙烯酸烯丙酯、0.5份引发剂，混合搅拌均匀后，55℃保温反应3小时后，制得复合水凝胶，其中凉感添加剂由以下重量份的组分制成：钽粉5份、氧化钆13份、氧硅磷灰石29份；
（3）然后将制得的复合水凝胶涂刷在聚酰胺面料的表面，烘干处理后，制得成品。
其中，上述步骤（2）中，氧化石墨烯的纯度为99%，平均粒径大小为2μm。
具体地，上述步骤（2）中，引发剂为过氧化苯甲酰。
具体地，上述步骤（3）中，烘干处理的温度为70℃。
实施例2
一种户外服装用导湿聚酰胺面料的制备方法，包括以下操作步骤：
（1）将熔融纺丝后的聚酰胺纤维编织成面料，然后将得到的聚酰胺面料放入活化液中进行表面活化处理，其中活化液由以下重量份的组分制成：甲基丙烯磺酸钠15份、过氧化钠7份、三聚磷酸钾13份、水195份；
（2）按重量份计，将38份聚乙二醇二丙烯酸酯、16份氧化石墨烯、12份晾感添加剂加入至150份水中，采用超声处理后，得到混合胶粒溶液，然后继续向混合胶粒溶液中加入65份甲基丙烯酸甲酯、48份丙烯酸烯丙酯、0.7份引发剂，混合搅拌均匀后，58℃保温反应3.5小时后，制得复合水凝胶，其中凉感添加剂由以下重量份的组分制成：钽粉8份、氧化钆15份、氧硅磷灰石33份；
（3）然后将制得的复合水凝胶涂刷在聚酰胺面料的表面，烘干处理后，制得成品。
其中，上述步骤（2）中，氧化石墨烯的纯度为99%，平均粒径大小为3μm。
具体地，上述步骤（2）中，引发剂为过氧化月桂酰。
具体地，上述步骤（3）中，烘干处理的温度为75℃。
实施例3
一种户外服装用导湿聚酰胺面料的制备方法，包括以下操作步骤：
（1）将熔融纺丝后的聚酰胺纤维编织成面料，然后将得到的聚酰胺面料放入活化液中进行表面活化处理，其中活化液由以下重量份的组分制成：甲基丙烯磺酸钠16份、过氧化钠9份、三聚磷酸钾15份、水200份；
（2）按重量份计，将40份聚乙二醇二丙烯酸酯、20份氧化石墨烯、14份晾感添加剂加入至160份水中，采用超声处理后，得到混合胶粒溶液，然后继续向混合胶粒溶液中加入70份甲基丙烯酸甲酯、50份丙烯酸烯丙酯、0.9份引发剂，混合搅拌均匀后，60℃保温反应4小时后，制得复合水凝胶，其中凉感添加剂由以下重量份的组分制成：钽粉10份、氧化钆16份、氧硅磷灰石35份；
（3）然后将制得的复合水凝胶涂刷在聚酰胺面料的表面，烘干处理后，制得成品。
其中，上述步骤（2）中，氧化石墨烯的纯度为99%，平均粒径大小为3μm。
具体地，上述步骤（2）中，引发剂为过氧化月桂酰。
具体地，上述步骤（3）中，烘干处理的温度为80℃。
对比例1
步骤（2）中不添加氧化石墨烯和晾感添加剂，其余操作步骤与实施例1完全相同。
分别用各实施例和对比例的方法制得户外服装用导湿聚酰胺面料，然后按照GB/T12704.2-2009 《纺织品 织物透湿性试验方法 第2部分：蒸发法》测试其导湿性能，试验结果如表1所示：
表1 聚酰胺面料的导湿性能
项目 聚酰胺面料的导湿性能，g/（m2·h）
实施例1 328
对比例1 102
实施例2 341
实施例3 352
由表1可知，本实施例制得的聚酰胺面料，具有优异的导湿性能，可快速的排净人体产生的汗液。
需要说明的是，以上实施例仅用以说明本发明的技术方案而非限制。尽管参照较佳实施例对本发明进行了详细说明，本领域的普通技术人员应当理解，可以对发明的技术方案进行修改或者等同替换，而不脱离本发明技术方案的范围，其均应涵盖在本发明的权利要求范围中。

Claims (4)

1.一种户外服装用导湿聚酰胺面料的制备方法，其特征在于，包括以下操作步骤：
（1）将熔融纺丝后的聚酰胺纤维编织成面料，然后将得到的聚酰胺面料放入活化液中进行表面活化处理，其中活化液由以下重量份的组分制成：甲基丙烯磺酸钠13-16份、过氧化钠4-9份、三聚磷酸钾10-15份、水190-200份；
（2）按重量份计，将36-40份聚乙二醇二丙烯酸酯、13-20份氧化石墨烯、10-14份晾感添加剂加入至140-160份水中，采用超声处理后，得到混合胶粒溶液，然后继续向混合胶粒溶液中加入60-70份甲基丙烯酸甲酯、46-50份丙烯酸烯丙酯、0.5-0.9份引发剂，混合搅拌均匀后，55-60℃保温反应3-4小时后，制得复合水凝胶，其中凉感添加剂由以下重量份的组分制成：钽粉5-10份、氧化钆13-16份、氧硅磷灰石29-35份；
（3）然后将制得的复合水凝胶涂刷在聚酰胺面料的表面，烘干处理后，制得成品。
2.根据权利要求1所述的一种户外服装用导湿聚酰胺面料的制备方法，其特征在于，上述步骤（2）中，氧化石墨烯的纯度为99%，平均粒径大小为2-3μm。
3.根据权利要求1所述的一种户外服装用导湿聚酰胺面料的制备方法，其特征在于，上述步骤（2）中，引发剂为过氧化苯甲酰、过氧化月桂酰中的任意一种。
4.根据权利要求1所述的一种户外服装用导湿聚酰胺面料的制备方法，其特征在于，上述步骤（3）中，烘干处理的温度为70-80℃。
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