CN108530802A - 耐磨型木塑复合板材配方 - Google Patents

耐磨型木塑复合板材配方 Download PDF

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CN108530802A
CN108530802A CN201810486613.9A CN201810486613A CN108530802A CN 108530802 A CN108530802 A CN 108530802A CN 201810486613 A CN201810486613 A CN 201810486613A CN 108530802 A CN108530802 A CN 108530802A
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parts
wood
wear
powder
composite board
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郁华
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/06—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent
    • C08J9/10—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent developing nitrogen, the blowing agent being a compound containing a nitrogen-to-nitrogen bond
    • C08J9/102—Azo-compounds
    • C08J9/103—Azodicarbonamide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/06—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent
    • C08J9/08—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent developing carbon dioxide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00—Foams characterized by the expanding agent
    • C08J2203/02—CO2-releasing, e.g. NaHCO3 and citric acid
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00—Foams characterized by the expanding agent
    • C08J2203/04—N2 releasing, ex azodicarbonamide or nitroso compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00—Foams characterized by the expanding agent
    • C08J2203/18—Binary blends of expanding agents
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
    • C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
    • C08J2327/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08J2327/06—Homopolymers or copolymers of vinyl chloride
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    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2423/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2423/26—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers modified by chemical after-treatment
    • C08J2423/28—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers modified by chemical after-treatment by reaction with halogens or halogen-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2497/00—Characterised by the use of lignin-containing materials
    • C08J2497/02—Lignocellulosic material, e.g. wood, straw or bagasse
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
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    • C08K2201/011—Nanostructured additives
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    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/34—Silicon-containing compounds
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    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/10—Esters; Ether-esters
    • C08K5/101—Esters; Ether-esters of monocarboxylic acids
    • C08K5/103—Esters; Ether-esters of monocarboxylic acids with polyalcohols

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  • Polymers & Plastics (AREA)
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  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
  • Laminated Bodies (AREA)

Abstract

本发明公开了一种耐磨型木塑复合板材配方，包括木塑发泡层、花纹层、UV涂层，其中木塑发泡层配方质量份组成为：聚氯乙烯(PVC) 树脂100份、木粉20份、氯化聚乙烯(CPE)9份、SiC纳米粉末5份、钙锌复合稳定剂4份、聚酯增塑剂12份、乙二醇/偶联剂1份、AC发泡剂1.2份、碳酸氢钠0.7份、发泡调节剂8份、硬脂酸甘油脂0.6份、聚乙烯蜡0.7份；进一步改进在于：采用乙二醇/偶联剂对木粉进行表面处理。本发明耐磨，不易变形、开裂。

Description

耐磨型木塑复合板材配方
技术领域
本发明涉及一种高分子复合材料配方，特别是一种木塑复合板材配方。
背景技术
木塑复合板材具有较好的强度、硬度和韧性，但耐磨性能较差。
发明内容
本发明针对现有技术的不足，提出一种能显著提高耐磨性的耐磨型木塑复合板材配方。
本发明通过下述技术方案实现技术目标。
耐磨型木塑复合板材配方，包括木塑发泡层、花纹层、UV涂层，其改进之处在于：其中木塑发泡层配方质量份组成为：聚氯乙烯(PVC) 树脂100份、木粉20份、氯化聚乙烯(CPE)9份、SiC纳米粉末5份、钙锌复合稳定剂4份、聚酯增塑剂12份、乙二醇/偶联剂1份、AC发泡剂1.2份、碳酸氢钠0.7份、发泡调节剂8份、硬脂酸甘油脂0.6份、聚乙烯蜡0.7份。
进一步改进在于：采用乙二醇/偶联剂对木粉进行表面处理。
本发明与现有技术相比，具有以下积极效果：
1、加入SiC纳米粉末，大大增强了本发明的耐磨性和强度，地板不易变形、开裂。
2、采用乙二醇/偶联剂对木粉进行表面处理，改善了木粉与PVC基材间的相容性，在增加木粉填充量的同时，显著降低了复合板材的吸水率。
具体实施方式
下面结合实施例对本发明作进一步说明。
耐磨型木塑复合板材配方，包括木塑发泡层、花纹层、UV涂层，其中木塑发泡层配方质量份组成为：聚氯乙烯(PVC) 树脂100份、木粉20份、氯化聚乙烯(CPE)9份、SiC纳米粉末5份、钙锌复合稳定剂4份、聚酯增塑剂12份、乙二醇/偶联剂1份、AC发泡剂1.2份、碳酸氢钠0.7份、发泡调节剂8份、硬脂酸甘油脂0.6份、聚乙烯蜡0.7份。
本实施例中，采用乙二醇/偶联剂对木粉进行表面处理。

Claims (2)

1.一种耐磨型木塑复合板材配方，包括木塑发泡层、花纹层、UV涂层，其特征在于：其中木塑发泡层配方质量份组成为：聚氯乙烯(PVC) 树脂100份、木粉20份、氯化聚乙烯(CPE)9份、SiC纳米粉末5份、钙锌复合稳定剂4份、聚酯增塑剂12份、乙二醇/偶联剂1份、AC发泡剂1.2份、碳酸氢钠0.7份、发泡调节剂8份、硬脂酸甘油脂0.6份、聚乙烯蜡0.7份。
2.根据权利要求1所述的耐磨型木塑复合板材配方，其特征在于：采用乙二醇/偶联剂对木粉进行表面处理。
CN201810486613.9A 2018-05-21 2018-05-21 耐磨型木塑复合板材配方 Pending CN108530802A (zh)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109354800A (zh) * 2018-10-08 2019-02-19 蒋云忠 一种新型板材及其制备方法

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103450585A (zh) * 2012-05-29 2013-12-18 泰州市华丽塑料有限公司 高韧性、高耐磨、耐腐蚀纳米塑料地板
CN104072902A (zh) * 2014-06-06 2014-10-01 泰州市华丽塑料有限公司 一种抑菌抗静电木竹塑地板及其制造方法

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103450585A (zh) * 2012-05-29 2013-12-18 泰州市华丽塑料有限公司 高韧性、高耐磨、耐腐蚀纳米塑料地板
CN104072902A (zh) * 2014-06-06 2014-10-01 泰州市华丽塑料有限公司 一种抑菌抗静电木竹塑地板及其制造方法

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109354800A (zh) * 2018-10-08 2019-02-19 蒋云忠 一种新型板材及其制备方法

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