CN108530165A - Quick-acting, the long-acting new foliar fertilizer having both and preparation method and purposes - Google Patents

Quick-acting, the long-acting new foliar fertilizer having both and preparation method and purposes Download PDF

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Publication number
CN108530165A
CN108530165A CN201810389004.1A CN201810389004A CN108530165A CN 108530165 A CN108530165 A CN 108530165A CN 201810389004 A CN201810389004 A CN 201810389004A CN 108530165 A CN108530165 A CN 108530165A
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acting
parts
fertilizer
quick
long
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Inventor
庄胜加
彭小明
蔡典贤
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Agricultural Technology Co Ltd Zhuhai Run
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Agricultural Technology Co Ltd Zhuhai Run
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Priority to CN201810389004.1A priority Critical patent/CN108530165A/en
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    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01CPLANTING; SOWING; FERTILISING
    • A01C21/00Methods of fertilising, sowing or planting
    • A01C21/005Following a specific plan, e.g. pattern
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05CNITROGENOUS FERTILISERS
    • C05C11/00Other nitrogenous fertilisers
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05FORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
    • C05F11/00Other organic fertilisers

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  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Soil Sciences (AREA)
  • Environmental Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Fertilizers (AREA)

Abstract

The present invention provides a kind of quick-acting, long-acting new foliar fertilizers having both, composed of the following components:Water soluble fertilizer, higher aliphatic, emulsifier, emulsion adjuvant, thickener, water.Using quick-acting, the long-acting new foliar fertilizers having both provided by the invention, when the Foliar Spraying is in plant leaf surface and blade back, plant will absorb part nutrient, and after moisture evaporation, remaining nutrient will form one layer of nutrient film and be covered in blade surface.

Description

Quick-acting, the long-acting new foliar fertilizer having both and preparation method and purposes
Technical field
The present invention relates to a kind of foliar fertilizers, more particularly to a kind of quick-acting, long-acting new foliar fertilizers having both and preparation Method and purposes.
Background technology
Water soluble fertilizer (Water Soluble Fertilizer, abbreviation WSF), be it is a kind of can be completely soluble it is more Element compound fertilizer, it can promptly be dissolved in the water, it is easier to be absorbed by crops, and its absorption rate is relatively high, more For crucially it can be applied to be sprayed and the industrialized agricultures such as fill, realize water-fertilizer integral, reach the efficiency that water-saving saves fertile saving of labor. Compared with the kinds such as traditional calcium superphosphate, granulated compound fertilizer, water soluble fertilizer has apparent advantage.It is mainly characterized by using Amount is few, and easy to use, use cost is low, and crop absorbs soon, and nutritional ingredient utilization rate is high.In view of above-mentioned advantage, water-soluble fertilizer Material becomes the new-type fertilizer that the Ministry of Agriculture encourages development.
For the water soluble fertilizer of foliage-spray, being commonly called as foliar fertilizer, (such as Patent No. CN201110087081.X's has Machine Water-solubility foliar fertilizer).Since foliar fertilizer in the prior art is directly sprayed on blade face, plant is absorbed by the stomata on blade Nutrient, nutrient go directly plant, and effect is particularly rapid.Therefore, dosage is few, easy to use, and crop absorbs fast, quick, nutrition It is the outstanding advantages of foliar fertilizer that components utilising rate is high, and still, fertilizer efficiency is short, need to repeatedly spray, time-consuming, is foliar fertilizer Major defect, this seriously affects foliar fertilizer and promotes and applies on a large scale.
Invention content
The present invention, which is intended to provide, provides a kind of preparation method of quick-acting, the long-acting new foliar fertilizers having both, and solves existing The fertilizer efficiency of foliar fertilizer in technology is short, need to repeatedly spray, time-consuming technical problem.
The present invention provides a kind of quick-acting, long-acting new foliar fertilizers having both, composed of the following components:Water soluble fertilizer, height Grade fatty alcohol, emulsifier, emulsion adjuvant, thickener, water.
Further, the new foliar fertilizer is by weight composed of the following components:400-600 parts of water soluble fertilizer, height 180-270 parts of fatty alcohol of grade, 30-60 parts of emulsifier, 4-6 parts of emulsion adjuvant, 40 parts of thickener, 700-800 parts of water.
Further, the water soluble fertilizer is water soluble fertilizer containing amino acid.
Further, the water soluble fertilizer is fertilizer containing humic acid water-soluble.
Further, the higher aliphatic is one or more mixing in 12 carbon alcohol, 14 carbon alcohol, 16 carbon alcohol.
Further, the emulsifier be the Tea Saponin of nonionic surface active agent, high-carbon fatty alcohol polyoxyethylene ether, One or more mixing in polyoxyethylene carboxylate, sorbitan ester.
Further, the emulsion adjuvant is short carbon chain alcohol.
Further, the thickener is Arabic gum, methylcellulose, xanthans, White Carbon black, attapulgite and swelling One or more mixing in soil.
The present invention also provides a kind of preparation methods of quick-acting, the long-acting new foliar fertilizers having both, and include the following steps:
A1:400 parts of water intaking is heated to 60 degree, 400-600 parts of water soluble fertilizers is poured into reaction kettle and are stirred in reaction kettle It is for use to mix uniform dissolution;
A2:Higher aliphatic is put into high shear homogenizer for 180-270 parts, 60 degree of thawings are heated to, then at high shear 4-6 parts of 30-60 parts of emulsifier and emulsion adjuvant are added in homogenizer, is handled by high shear homogenizer, 1000 revs/min of rotating speed, Rotation 5 minutes, is then added 300-400 parts of the water that temperature is 60 degree, and 10000 revs/min of rotating speed is rotated 20 minutes, is eventually adding Prepare 40 parts of for use solution and thickener in step A1, continue with 10000 revs/min, rotation 30 minutes to get.
The present invention also provides a kind of purposes of quick-acting, the long-acting new foliar fertilizers having both, by the new foliar fertilizer of the present invention After being diluted with water 300 times, plant leaf surface is directly sprayed.
Using quick-acting, the long-acting new foliar fertilizers having both provided by the invention, when the Foliar Spraying in plant leaf surface and When blade back, plant will absorb part nutrient, and after moisture evaporation, remaining nutrient will form one layer of nutrient film and be covered in blade surface. When meeting water or having dew, nutrient film can re-dissolve, and plant can absorb part nutrient by the stomata on blade again.The sun goes out After coming, moisture evaporation, and form nutrient film.In cycles, about 7 to the 10 days existing time of this layer of nutrient film, quite It is sprayed in once, in 7 to 10 days, all applies a foliar fertilizer to plant automatically daily, it is time saving and energy saving to save money, ideally solve leaf The great difficult problem of leaven application
Water soluble fertilizer and higher aliphatic are really prepared into a kind of containing full water-soluble by the present invention by certain technique The fatty alcohol aqueous emulsion of fertilizer, the foliar fertilizer are a nutritional emulsions, and plant leaf surface and blade back, part are sprayed on after 300 times of dilution Nutrient moisture is absorbed by plants by blade face stomata, and after moisture absorption, evaporation, other nutrients and fatty alcohol are together on blade face Form one layer of nutrient film containing nutrient.When coming at night, dew is there has been on blade face, these dew keep nutrient film again molten Solution forms nutrient solution, and such plant can absorb part nutrient by stomata again, and the sun comes out moisture evaporation, and forms new one Layer nutrient film (this phenomenon can be obtained by microscope mock inspection).In cycles, which can probably exist ten days, It is equivalent in this ten days, time foliar fertilizer of plant-spraying is all given daily, to achieve the effect that rapid long-acting has both.This layer of nutrition Film is also equipped with water conservation drought resisting, adjusts temperature, promote the effect of plant photosynthesis efficiency in addition to there is slow releasing function.Therefore, the invention pair Agricultural production is of great significance.
Specific implementation mode
Embodiment 1
The embodiment of the present invention provides a kind of quick-acting, long-acting new foliar fertilizers having both, by weight composed of the following components: 500 parts of water soluble fertilizer, 230 parts of higher aliphatic, 50 parts of emulsifier, 5 parts of emulsion adjuvant, 40 parts of thickener, 800 parts of water.
In the present embodiment, the water soluble fertilizer is water soluble fertilizer containing amino acid, the amino acid water soluble fertilizer At least containing 10% free amino acid.The higher aliphatic be 12 carbon alcohol.The emulsifier is high-carbon fatty alcohol polyoxy Vinethene.The emulsion adjuvant is short carbon chain alcohol.The thickener is Arabic gum.
The present embodiment also provides the preparation method of above-mentioned new foliar fertilizer, includes the following steps:
A1:400 parts of water intaking is heated to 60 degree in reaction kettle, and 500 parts of water soluble fertilizers are poured into reaction kettle and are stirred Even dissolving is for use;
A2:Higher aliphatic is put into high shear homogenizer for 180-270 parts, 60 degree of thawings are heated to, then at high shear 5 parts of 50 parts of emulsifier and emulsion adjuvant are added in homogenizer, is handled by high shear homogenizer, 1000 revs/min of rotating speed, rotation 5 Minute, 400 parts of the water that temperature is 60 degree is then added, 10000 revs/min of rotating speed rotates 20 minutes, is eventually adding in step A1 and makes Standby for use 40 parts of solution and thickener continue with 10000 revs/min, rotation 30 minutes to get.
Embodiment 2
The present embodiment provides a kind of quick-acting, long-acting new foliar fertilizers having both, by weight composed of the following components:It is water-soluble 400 parts of fertilizer of property, 180 parts of higher aliphatic, 30 parts of emulsifier, 4 parts of emulsion adjuvant, 40 parts of thickener, 700 parts of water.
In the present embodiment, the water soluble fertilizer is fertilizer containing humic acid water-soluble.The higher aliphatic is 12 carbon Alcohol, 16 carbon alcohol, two kinds of mixing.The emulsifier is three kinds of polyoxyethylene carboxylate, sorbitan ester mixing.The emulsification Auxiliary agent is short carbon chain alcohol.The thickener is two kinds of methylcellulose, xanthans mixing.
The present embodiment also provides the preparation method of above-mentioned new foliar fertilizer, includes the following steps:
A1:400 parts of water intaking is heated to 60 degree in reaction kettle, and 400 parts of water soluble fertilizers are poured into reaction kettle and are stirred Even dissolving is for use;
A2:Higher aliphatic is put into high shear homogenizer for 180 parts, 60 degree of thawings are heated to, then at high shear homogeneous 4 parts of 30 parts of emulsifier and emulsion adjuvant are added in machine, is handled by high shear homogenizer, 1000 revs/min of rotating speed, rotates 5 minutes, Then 300 parts of the water that temperature is 60 degree is added, 10000 revs/min of rotating speed rotates 20 minutes, is eventually adding to prepare in step A1 and wait for 40 parts of solution and thickener, continue with 10000 revs/min, rotation 30 minutes to get.
Embodiment 3
The present embodiment provides a kind of quick-acting, long-acting new foliar fertilizers having both, by weight composed of the following components:It is water-soluble 600 parts of fertilizer of property, 270 parts of higher aliphatic, 60 parts of emulsifier, 6 parts of emulsion adjuvant, 40 parts of thickener, 800 parts of water.
In the present embodiment, the water soluble fertilizer is water soluble fertilizer containing amino acid, the amino acid water soluble fertilizer At least containing 10% free amino acid.The higher aliphatic is 12 carbon alcohol, 14 carbon alcohol, 16 carbon alcohol, three kinds of mixing.The breast Agent is two kinds of polyoxyethylene carboxylate, sorbitan ester mixing.The emulsion adjuvant is short carbon chain alcohol.The thickener It is four kinds of xanthans, White Carbon black, attapulgite and bentonite mixing.
The present embodiment also provides the preparation method of above-mentioned new foliar fertilizer, includes the following steps:
A1:400 parts of water intaking is heated to 60 degree, 400-600 parts of water soluble fertilizers is poured into reaction kettle and are stirred in reaction kettle It is for use to mix uniform dissolution;
A2:Higher aliphatic is put into high shear homogenizer for 270 parts, 60 degree of thawings are heated to, then at high shear homogeneous 4-6 parts of 60 parts of emulsifier and emulsion adjuvant are added in machine, is handled by high shear homogenizer, 1000 revs/min of rotating speed, rotates 5 points Clock, is then added 400 parts of the water that temperature is 60 degree, and 10000 revs/min of rotating speed rotates 20 minutes, is eventually adding in step A1 and prepares 40 parts for use of solution and thickener, continue with 10000 revs/min, rotation 30 minutes to get.
Embodiment 4
The present embodiment provides a kind of purposes of quick-acting, the long-acting new foliar fertilizers having both, when the use embodiment of the present invention 1,2 Or 3 prepare new foliar fertilizer when, after the new foliar fertilizer is diluted with water 300 times, directly spray plant leaf surface.
Embodiment 5
The new foliar fertilizer for taking a small amount of embodiment 1,2 or 3 to prepare, is put into centrifuge and runs at high speed 2 minutes, see whether formed Homogeneous solution is then qualified, is not then unqualified.
Embodiment 6
The new foliar fertilizer for taking a small amount of embodiment 1 to prepare, (i.e. the new foliar fertilizer sprays plant leaf surface for 300 times of dilution Concentration) after, it drips on slide, after moisture evaporation, one layer of nutrient film is left on slide, with micro- sem observation, with knife in film On scratch a few road slight cracks after, drop it is upper one drip water, slight crack just can be repaired quickly, and amino acid gradually dissolves and absorbs.
Embodiment 7
The practice case explanation of new foliar fertilizer prepared by the present embodiment 1
1, romaine lettuce plantation in the villages Yingde City Xi Niu Zhen Jiangxia luminous energy nutrient film planting experiment base is real
The romaine lettuce of same period plantation is separated two groups, sprays prepared by suitable the present embodiment 1 to first group in its Seedling Stage New foliar fertilizer, second group sprays equivalent clear water.After seven days, laboratory technician has found to have sprayed the more healthy and strong kingfisher of amino acid foliage fertilizer It is green, do not spray group romaine lettuce dish leaf yellowing wither it is weak.
2, Shaoguan Shixing County black clouds mausoleum radish planting is tested
At radish planting initial stage, laboratory technician will be divided into two groups and the one group of spray thereto of same time with batch radish of plantation The new foliar fertilizer of the preparation of appropriate the present embodiment 1 is applied, another set sprays equivalent clear water.After a period of time, laboratory technician has found real The Turnip Sprouts leaf par of group is tested obviously than control group pair, the color of seedling is also more dark green.
In radish planting mid-term, radish and the not used same period radish of the new foliar fertilizer prepared using the present embodiment 1 always It is obviously more sturdy tender white to compare fruit shape, the leaf of fruit upper end is also more emerald green, and Ye Jing is more sturdy.
When harvest, we it is apparent it can be seen that the radish of new foliar fertilizer prepared by the present embodiment 1 used always with do not make Radish compares, and has used the radish fruit average length of nutrient film longer than not used, and fruit average diameter is also than being not used It is big, i.e., shape is cashed to have used the radish fruit of nutrient film more healthy and strong very large.
Embodiment 8
Control experiment
The foliar fertilizer that experimental group uses:The present embodiment 1 or the new foliar fertilizer of 2 or 3 preparations
The foliar fertilizer that control group uses:The organic water-soluble foliar fertilizer of Patent No. CN201110087081.X
(1) in 20 mu of Zhuhai modern agricultural development center flat sand base corn demonstration contrast test, 19 mu of corns are made For experimental group, the new foliar fertilizer of the preparation of the present embodiment 1 is sprayed, stays one mu to set control group, sprays Patent No. The organic water-soluble foliar fertilizer of CN201110087081.X.Entire growth period sprays four times, 19 mu of corn growths of experimental group Stem is obviously sturdy compared with one mu of control group in the process, and blade is big and green, and consistency is good, and setting percentage is high, and stick is big and corn It is full, be not in the bald phenomenon in top, finally compare yield average output value and increase by 12%, volume increase difference reaches the pole level of signifiance.
(2) in two mu of cabbage mustards of Zhuhai City modern agricultural development center demonstration plant, one mu is used as experimental group, sprays this New foliar fertilizer prepared by embodiment 2, another mu as a control group, spray the organic water of Patent No. CN201110087081.X Dissolubility foliar fertilizer, entire growth period spray 3 times, and experimental group is obviously more sturdy than control group growing way, finally compare yield, experimental group ratio Control group yield increases by 18%, and volume increase difference reaches the pole level of signifiance.
(3) is arranged in the field trial on cabbage heart by fertilizer association of Guangdong Province, respectively by the institute of agricultural sciences of Zhaoqing Guangdong city and The institute of agricultural sciences of Huidong County of Guangdong Huizhou city accepts.If experimental group, control group and conventional group, experimental group growth period spray the present embodiment 3 The new foliar fertilizer of preparation, control group spray the organic water-soluble foliar fertilizer of Patent No. CN201110087081.X, conventional group Any fertilizer is not sprayed, under conditions of 1,2 month low temperature, as a result, experimental group averagely increases production 10.5% than control group in Zhaoqing, Huizhou averagely increases production 11%, and experimental group averagely increases production 15.5% than conventional group in Zhaoqing, averagely increases production 16% in Huizhou.It is specifically shown in Following table one, table two:
Conclusion:The new foliar fertilizer that the Growth of Brassica Parachinensis phase sprays the preparation of 3 the present embodiment 3 altogether does not spray any fertilizer than the same period Routine control group be averaged mu volume increase 17.5%, spray the organic water of 3 Patent No. CN201110087081.X altogether than the same period The control group of dissolubility foliar fertilizer be averaged mu volume increase 11.0%, volume increase difference reach the pole level of signifiance.
(4) in the field trial of the Huang Tian Cunliu mus of winter kind ternip in Guangdong Province Shixing County Horse market town, three mu of ground are experiment Group sprays the new foliar fertilizer of the preparation of the present embodiment 1, and three mu of ground are control group, spray Patent No. CN201110087081.X Organic water-soluble foliar fertilizer, as a result the radish of experimental group, which than control group shifts to an earlier date 15 days and reaches maturation, receives, and appearance is more good-looking, mouth Sense is more preferable, reaches the quality that " fruit " grade is eaten it raw, and the average product of experimental group compares volume increase 33% with control group.
The foregoing is only a preferred embodiment of the present invention, is not intended to restrict the invention, for the skill of this field For art personnel, the invention may be variously modified and varied.All within the spirits and principles of the present invention, any made by repair Change, equivalent replacement, improvement etc., should all be included in the protection scope of the present invention.

Claims (10)

1. quick-acting, the long-acting new foliar fertilizer having both, which is characterized in that composed of the following components:Water soluble fertilizer, higher aliphatic Alcohol, emulsifier, emulsion adjuvant, thickener, water.
2. quick-acting, the long-acting new foliar fertilizer having both as described in claim 1, which is characterized in that by weight by with the following group It is grouped as:400-600 parts of water soluble fertilizer, 30-60 parts of emulsifier, 4-6 parts of emulsion adjuvant, increases 180-270 parts of higher aliphatic Thick dose 40 parts, 700-800 parts of water.
3. the preparation method of quick-acting, the long-acting new foliar fertilizer having both as claimed in claim 1 or 2, which is characterized in that described Water soluble fertilizer is water soluble fertilizer containing amino acid.
4. the preparation method of quick-acting, the long-acting new foliar fertilizer having both as claimed in claim 1 or 2, which is characterized in that described Water soluble fertilizer is fertilizer containing humic acid water-soluble.
5. quick-acting, the long-acting new foliar fertilizer having both as claimed in claim 1 or 2, which is characterized in that the higher aliphatic For one or more mixing in 12 carbon alcohol, 14 carbon alcohol, 16 carbon alcohol.
6. quick-acting, the long-acting new foliar fertilizer having both as claimed in claim 1 or 2, which is characterized in that the emulsifier right and wrong In the Tea Saponin of ionic surfactant, high-carbon fatty alcohol polyoxyethylene ether, polyoxyethylene carboxylate, sorbitan ester One or more mixing.
7. quick-acting, the long-acting new foliar fertilizer having both as claimed in claim 1 or 2, which is characterized in that the emulsion adjuvant is Short carbon chain alcohol.
8. quick-acting, the long-acting new foliar fertilizer having both as claimed in claim 1 or 2, which is characterized in that the thickener be Ah Draw one or more mixing in primary glue, methylcellulose, xanthans, White Carbon black, attapulgite and bentonite.
9. the preparation method of quick-acting, the long-acting new foliar fertilizer having both as claimed in claim 2, which is characterized in that including with Lower step:
A1:400 parts of water intaking is heated to 60 degree in reaction kettle, and 400-600 parts of water soluble fertilizers are poured into reaction kettle and are stirred Even dissolving is for use;
A2:Higher aliphatic is put into high shear homogenizer for 180-270 parts, 60 degree of thawings are heated to, then at high shear homogeneous 4-6 parts of 30-60 parts of emulsifier and emulsion adjuvant are added in machine, is handled by high shear homogenizer, 1000 revs/min of rotating speed, rotation 5 Minute, 300-400 parts of the water that temperature is 60 degree is then added, 10000 revs/min of rotating speed rotates 20 minutes, is eventually adding step A1 It is middle to prepare 40 parts of for use solution and thickener, continue with 10000 revs/min, rotation 30 minutes to get.
10. the purposes of quick-acting, the long-acting new foliar fertilizer having both as claimed in claim 1 or 2, which is characterized in that will be described After new foliar fertilizer is diluted with water 300 times, plant leaf surface is directly sprayed.
CN201810389004.1A 2018-04-27 2018-04-27 Quick-acting, the long-acting new foliar fertilizer having both and preparation method and purposes Pending CN108530165A (en)

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Cited By (5)

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CN108840730A (en) * 2018-09-17 2018-11-20 山东宝瑞生物科技有限公司 A kind of organic fertilizer preventing apple bitter pit
CN109721420A (en) * 2018-12-26 2019-05-07 珠海市润农科技有限公司 The drip irrigation fertilizer and preparation method and purposes of high-efficiency sustained-release
WO2023077371A1 (en) * 2021-11-04 2023-05-11 珠海市润农科技有限公司 Application of higher fatty alcohol in aspects of disease and pest prevention and yield increasement of corn
WO2023077378A1 (en) * 2021-11-04 2023-05-11 珠海市润农科技有限公司 Use of higher aliphatic alcohol in promoting lignin synthesis and yield increase of rice and wheat
EP4144207A4 (en) * 2020-04-30 2024-05-01 Zhuhai Runnong Science And Tech Co Ltd Aqueous emulsion for preventing and treating huanglongbing of citrus fruit trees as well as preparation method and usage method

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