CN107311796A - A kind of organic suspension liquid fertilizer of improved soil and preparation method thereof - Google Patents
A kind of organic suspension liquid fertilizer of improved soil and preparation method thereof Download PDFInfo
- Publication number
- CN107311796A CN107311796A CN201710478919.5A CN201710478919A CN107311796A CN 107311796 A CN107311796 A CN 107311796A CN 201710478919 A CN201710478919 A CN 201710478919A CN 107311796 A CN107311796 A CN 107311796A
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- Prior art keywords
- suspension liquid
- liquid fertilizer
- fertilizer
- improved soil
- organic
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- 239000007788 liquid Substances 0.000 title claims abstract description 111
- 239000002689 soil Substances 0.000 title claims abstract description 108
- 239000000725 suspension Substances 0.000 title claims abstract description 81
- 238000002360 preparation method Methods 0.000 title claims abstract description 16
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 13
- 239000000618 nitrogen fertilizer Substances 0.000 claims abstract description 13
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 12
- 239000002562 thickening agent Substances 0.000 claims abstract description 12
- 239000002270 dispersing agent Substances 0.000 claims abstract description 11
- 238000009736 wetting Methods 0.000 claims abstract description 11
- 239000000463 material Substances 0.000 claims description 38
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- 235000010755 mineral Nutrition 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 229940068041 phytic acid Drugs 0.000 description 1
- 235000002949 phytic acid Nutrition 0.000 description 1
- 239000000467 phytic acid Substances 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 229910052604 silicate mineral Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 238000004180 soil liming Methods 0.000 description 1
- 238000009331 sowing Methods 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-N sulfonic acid Chemical compound OS(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-N 0.000 description 1
- 239000010435 syenite Substances 0.000 description 1
- 208000024891 symptom Diseases 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05C—NITROGENOUS FERTILISERS
- C05C5/00—Fertilisers containing other nitrates
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/80—Soil conditioners
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G5/00—Fertilisers characterised by their form
- C05G5/20—Liquid fertilisers
- C05G5/27—Dispersions, e.g. suspensions or emulsions
Abstract
The invention discloses organic suspension liquid fertilizer of a kind of improved soil and preparation method thereof, the organic suspension liquid fertilizer of described improved soil includes 13.0~46.0 parts of calcareous fertilisers, 3.0~17.0 parts of fertiliser containing magnesiums, 40.0~55.0 parts of organic matters, 0 ~ 20 part of nitrogenous fertilizer, 0.1 ~ 2.0 wetting dispersing agent, 0.1 ~ 2.0 emulsifying agent, 0.1 ~ 2.0 thickener and 0.1 ~ 2.0 antifreezing agent.The number is parts by weight.The organic suspension liquid fertilizer of improved soil of the present invention is the organic-inorganic suspension liquid fertilizer containing moderate-element, total nutrient content is high, physics and chemical properties are stable, the phenomenon such as nodeless mesh, precipitation, layering under high temperature, low temperature and normal temperature condition, utilization rate of fertilizer can be significantly improved, the soil organism can be effectively increased simultaneously, increase quantity of useful microbe;Improved soil structure, adjusts soil acidity or alkalinity, recovers soil vitality.
Description
Technical field
The invention belongs to field of agricultural production technologies, further belong to technical field of fertilizer production, and in particular to Yi Zhonggai
Organic suspension liquid fertilizer of good soil and preparation method thereof.
Background technology
In characteristic of acid red soil, available phosphorus content is low, the active calcium ion content is not enough, the active high always limitation plant growth of aluminium ion
Key factor.The pH that China there are about 200,000 hectares of soil is less than 5.0.In order to reduce acid soil to Crops production and quality
Harmful effect, characteristic of acid red soil is often improved in production using alkaline modifying agent, aluminium poison and offer plant are provided needed for calcium from
Son, wherein liming are more effective and one of method of classics.But, a large amount of or chronic administration lime can not only cause soil
Earth is hardened and forms " the hardened field of lime ", and can cause soil calcium, potassium, the dysequilibrium of 3 kinds of elements of magnesium and cause the underproduction.
Acid soil liming is also possible to cause the activity of manganese ion and plant in the co-precipitation of magnesium and aluminum oxide, the reduction soil liquid
Thing validity.Therefore the amount of liming is suitable.But liming can go out new soil issues, therefore select its other party again
Method, which is matched somebody with somebody, to be applied(Such as water-fertilizer integral), to avoid the problem of single liming causes.
Calcium is one of content most abundant element in soil, but be due to soil parent material, leaching, cultivated land utilization mode etc. from
Calcium content difference in the influence of right and human factor, different soils is but very big.As characteristic of acid red soil calcium content is relatively low.Characteristic of acid red soil
In, low soil the active calcium ion content is the key factor for restricting plant growth.The sub- heat in the torrid zone in south China high temperature and humidity profit area
Band acid soil, mainly including red earth, laterite, red soil, because weathering and eluviation are strong, the silicate mineral of calcic
By intensive decomposition, alkali is also by leaching loss, therefore its calcium content is relatively low, and exchangeable calcium average content is only 10 ~ 20mg/
kg.In addition, south some by granite, syenite develop soil and siliceous sandstone development soil, its Calcium nutrient some
It is also very low, extracts the effective calcium of soil as index with 1mol/L NH4OAC, acid red soil of south China exchangeable calcium is less than
56mg/kg, it is seen then that Ca supply amount is than relatively low in characteristic of acid red soil soil.Need the crop that calcium is more(Such as banana, citrus
Deng)Easy calcium deficiency, it is necessary to apply External Calcium.
Domestic complex fertilizer chronic administration easily causes the serious problems such as soil hardening, acidifying and salinization of soil.A kind of conditioned soil
The organic suspension liquid fertilizer of earth be using green, environmental protection plant source organic matter do raw material, with reference to needed for plant growth in
Secondary element calcium, magnesium etc..Nucleus is using ultramicro grinding and scattered waits suspension patented technology will natural organic active material
It is suspended in Deng nutrient particle in liquid dispersed system, so as to substantially increase the nutrient content in liquid fertilizer.This fertilizer has
Multiple biological activities and function, the content of organic matter are high, can not only be promoted soil fertility with improved soil structure, can also be improved
Utilization rate of fertilizer, promotes crop root more preferably to grow, and improves the yield and quality of crop.
With the popularization and application of the Integration of Water into Fertilizer, liquid fertilizer starts gradually to use in China.But current China
Liquid fertilizer also in Primary Study stage, particularly high concentration, the research of high compound liquid fertilizer, be substantially at home
Blank.In actual production, peasant largely uses chemical fertilizer, and high yield, fertilizer caused by irrational fertigation mode are pursued merely
This season utilization rate is low, the wasting of resources, decline in benefits, environmental pollution the problems such as, and these problems are threaten the health of the mankind
And ecological environment security.Improved soil organic suspension liquid fertilizer is as a kind of highly enriched liquid fertilizer, and nutrient content is high, contains
The multi-functional fertilizer for having improved soil is increasingly welcome by vast farmerses.The research and development and popularization of the present invention help to alleviate me
State's agricultural fertilizer make soil hardening, acid-base value imbalance the problem of.
The content of the invention
The first object of the present invention is the organic suspension liquid fertilizer for providing a kind of improved soil;Second purpose is to provide
The preparation method of the organic suspension liquid fertilizer of described improved soil.
The first object of the present invention is achieved in that the organic suspension liquid fertilizer of described improved soil includes parts by weight
40.0 ~ 55.0 parts of 13.0 ~ 46.0 parts of calcareous fertilisers, 3.0 ~ 17.0 parts of fertiliser containing magnesium, 0 ~ 20 part of nitrogenous fertilizer and organic matter.
The second object of the present invention, which is achieved in that, to be comprised the following steps:
A, the nitrogenous fertilizer of the organic matter of formulation ratio 2/3 and formulation ratio 2/3 obtained into mother liquor;The calcareous fertilisers of formulation ratio were crushed
It is standby that 100 ~ 200 mesh sieves obtain material a;
B, material a is added in the mother liquor of step A preparation, it is stirring while adding, in stirring reaction 30 at 50 ~ 65 DEG C of temperature ~
40min obtains material b;
C, the fertiliser containing magnesium of formulation ratio is added in material b, it is stirring while adding, obtained in 30 ~ 45min of stirring reaction at 50 ~ 65 DEG C
To material c;
D, by the organic matter of the wetting dispersing agent of formulation ratio, emulsifying agent, thickener, antifreezing agent and formulation ratio 1/3, match somebody with somebody
Nitrogenous fertilizer than 1/3, which is homogenously mixed together, obtains slurry d;
E, material c and slurry d are uniformly mixed to get to Materialien, Materialien obtains material through the levigate mesh sieve of mistake 100 ~ 200 of colloid mill
f;Material f grinds the suspending agent for obtaining good fluidity through sand mill again, and adjustment pH value obtains having for object improved soil for 6 ~ 8
Machine suspension body fertilizer.
The present invention can make the nutrients such as calcium, magnesium, organic matter by the control of particular order and the technique of special reaction condition
Organically, stably it is dissolved in suspension liquid.Instant invention overcomes the utilization rate of fertilizer for improving calcium, magnesium in the prior art.
The organic suspension liquid fertilizer of improved soil of the present invention can add according to the need for crop different growing
Plus the growth regulator of different type and concentration, the organic suspension liquid fertilizer of the improved soil can also be with fulvic acid, black
The Organic Ingredients such as rotten acid or ulmic acid are used in mixed way, and improve the utilization rate of fertilizer nutrient.
The application method of the organic suspension liquid fertilizer of improved soil of the present invention is:When pouring is applied, crops seedling stage is dilute
200~300 times are released, other time dilutes 100~200 times, directly drenches in crop root, determines that pouring is applied according to the breeding time of crop
Number of times, time interval is 10~15 days, and vegetables can suitably increase application times, and fruit tree can suitably increase amount of application;When spraying, vegetable
Dish and field crop dilute 800~1000 times, and fruit tree dilutes 500~800 times, is sprayed on blade surface, positive and negative will spray
Apply, be sprayed onto untill blade just drips;When being applied by drip irrigation, seedling stage concentration is 200~300 times, and the middle and later periods is 100~200
Times, general can drip for every 7~10 days is applied once, during drip irrigation, must get hold of fertilization time, the shallower crop of root system, during fertilising
Between must control within 30 minutes, the deep crop of root system, fertilization time was controlled at 1~1.5 hour.
Compared with prior art, the present invention has the advantages that:
(1)The organic suspension liquid fertilizer total nutrient content of improved soil of the present invention is high, and physics and chemical properties are stable, in height
The phenomenon such as nodeless mesh, precipitation, layering under temperature, low temperature and normal temperature condition.
(2)The organic and inorganic suspension liquid fertilizer of improved soil of the present invention belongs to suspension type liquid fertilizer, can be sprayed with blade face
Apply, drench and apply, can be used for sprinkling irrigation and drip irrigation system, it is easy to use, have the advantages that time saving, saving of labor, province's fertilizer, fertilizer efficiency are fast.
(3)Effective content in the organic suspension liquid fertilizer of improved soil of the present invention is high, contains calcium, magnesium, organic matter, corruption
These nutrients organically, are stably dissolved in suspension liquid by the nutrients such as phytic acid, the present invention well, improve the utilization of nutrient
Rate.
(4)The good fluidity of the present invention, and nutrient is highly enriched, it is adaptable to the larger automation fertilising operation of area, can be bright
It is aobvious to improve fertilising efficiency.
(5)The invention provides containing organic and inorganic suspension liquid compound fertilizer, soil physico-chemical property is can adjust, is promoted
Crop root more preferably grows, and the yield and quality of crop is improved, while the nutritional deficiency symptom of crop can be prevented effectively.
(6)Organic matter >=150g/L in the organic suspension liquid fertilizer that the present invention is provided, CaO+MgO >=100g/L, N >=
85g/L, nutrient content therein both can reach People's Republic of China's agricultural industry criteria(NY 2266-2012)" moderate-element
Water-soluble fertilizer " liquid product mass index, also complies with company standard " organic water-soluble fertilizer " liquid product mass index, is fertilizer
Expect that output enterprise provides splendid convenience in the flexible production and selling of liquid fertilizer.
Embodiment
With reference to embodiment, the present invention is further illustrated, but the present invention is not any limitation as in any way,
Based on present invention teach that any conversion or replacement made, belong to protection scope of the present invention.
Calcareous fertilisers 13.0 ~ 46.0 part of the organic suspension liquid fertilizer including parts by weight of improved soil of the present invention, fertiliser containing magnesium
40.0 ~ 55.0 parts of 3.0 ~ 17.0 parts, 0 ~ 20 part of nitrogenous fertilizer and organic matter.
The organic suspension liquid fertilizer of described improved soil also includes auxiliary material.
Described auxiliary material includes wetting dispersing agent, emulsifying agent, thickener and antifreezing agent.
0.1 ~ 2.0 part of 0.1 ~ 2.0 part of wetting dispersing agent, the emulsifying agent of described auxiliary material including parts by weight, thickener 0.1 ~
2.0 parts and 0.1 ~ 2.0 part of antifreezing agent.
Described calcareous fertilisers are one kind in calcium nitrate, nitric acid calcium and magnesium, calcium oxide, calcium ammonium nitrate and calcio-disodium edetate
Or it is several.
Described fertiliser containing magnesium is one kind or several in magnesium nitrate, magnesium sulfate, magnesium chloride, magnesia and ethylenediamine tetra-acetic acid magnesium sodium
Kind.
Described nitrogenous fertilizer is the one or more in urea, ammonium nitrate and urea ammonium nitrate.
Described organic matter is one kind in molasses, alcohol effluent, yeast factory waste liquid and the Gourmet Powder Factory's leftover bits and pieces of sugarcane factory
Or it is several.
Described wetting dispersing agent is sodium lignin sulfonate, naphthalenesulfonic acid-formaldehyde condensate, AEO fat
Fat alcohol, triethyl group hexyl phosphoric acid, methyl anyl alcohol, polyacrylamide, aliphatic acid Macrogol Ester, polyethylene glycol and vinyl are double hard
One or more in acyl amine;Described emulsifying agent is neopelex, calcium dodecyl benzene sulfonate, alkylaryl
Sodium sulfonate, dialkyl benzene sulfonic acids are received, hydroxy alkyl sulfonic acid sodium, styryl APEO, thousand base phenol polyethenoxy ethers, octyl group
Phenol polyethenoxy ether, secondary octyl phenol polyethenoxy ether, double, tributyl phenol APEO, APES polyoxy third
Alkene ether, benzyl dimethyl phenol polyethenoxy ether, dibenzyl xenol polyoxyethylene polyoxypropylene ether, ethoxylated dodecyl alcohol and
One or more in octadecane alcohol radical APEO;Described thickener is xanthans, carboxymethyl cellulose, carboxymethyl fibre
The plain sodium of dimension, diatomite, attapulgite, Silica hydrogel, gum arabic, Artemisia Glue, trigonella bean gum, polyacrylamide and polyvinyl alcohol
In one or more;Described antifreezing agent is methanol, ethanol, isopropanol, ethylene glycol, propane diols, diethylene glycol (DEG), ethylene glycol fourth
Ether, propandiol butyl ether, 2-Butoxyethyl acetate, dichloromethane, 1,1- dichloroethanes, 1,2- dichloroethanes, dimethyl sulfoxide (DMSO),
One or more in formamide, calcium chloride, sodium acetate and magnesium chloride.
The preparation method of the organic suspension liquid fertilizer of improved soil of the present invention, comprises the following steps:
A, the nitrogenous fertilizer of the organic matter of formulation ratio 2/3 and formulation ratio 2/3 obtained into mother liquor;The calcareous fertilisers of formulation ratio were crushed
It is standby that 100 ~ 200 mesh sieves obtain material a;
B, material a is added in the mother liquor of step A preparation, it is stirring while adding, in stirring reaction 30 at 50 ~ 65 DEG C of temperature ~
40min obtains material b;
C, the fertiliser containing magnesium of formulation ratio is added in material b, it is stirring while adding, obtained in 30 ~ 45min of stirring reaction at 50 ~ 65 DEG C
To material c;
D, by the organic matter of the wetting dispersing agent of formulation ratio, emulsifying agent, thickener, antifreezing agent and formulation ratio 1/3, match somebody with somebody
Nitrogenous fertilizer than 1/3, which is homogenously mixed together, obtains slurry d;
E, material c and slurry d are uniformly mixed to get to Materialien, Materialien obtains material through the levigate mesh sieve of mistake 100 ~ 200 of colloid mill
f;Material f grinds the suspending agent for obtaining good fluidity through sand mill again, and adjustment pH value obtains having for object improved soil for 6 ~ 8
Machine suspension body fertilizer.
Above-mentioned preparation method concrete operations are as follows:
S1. compound fertilizer formula, by organic matter, the nitrogenous fertilizer of 2/3 organic matter, or 2/3, is put into reaction as described in claim 1
In kettle, mother liquor is obtained;
S2. calcareous fertilisers are obtained into the powder below micron by airslide disintegrating mill respectively;
S3. calcareous fertilisers are added into mother liquor, stirring while adding to black liquor is formed, stirring while adding, it is 50 to keep reaction temperature
~65℃;
S4. fertiliser containing magnesium is respectively added slowly into S3, it is stirring while adding;
S5. wetting dispersing agent, emulsifying agent, thickener, antifreezing agent are homogenously mixed together with 1/3 organic matter, form slurry;
S6. S4, S5 are homogenously mixed together, form thick slurry, homogenized through colloid mill levigate;
S7. S6 is then passed through into the secondary grinding of sand mill, obtains good fluidity, the suspending agent of modest viscosity;
S8. most backward S7 liquid agitations are uniform, adjustment pH value etc., through quality examination it is qualified after produce suspension liquid compound fertilizer;
Mixing time is preferably 10 ~ 20min described in step S1;Grinding time is preferably 30~45min described in step S2;Step
Mixing time is 30~40min described in rapid S3;Step S4 mixing time is 30~45min;Step S5 mixing time is
10~20min;Step S6 milling time is 30~45min;Milling time described in step S7 is 30~50min;Step S8
Mixing time be 5~10min.
So that case is embodied, the present invention will be further described below:
Embodiment 1
The organic suspension liquid fertilizer of improved soil described in the present embodiment contains each component of following parts by weight:
The specific preparation method of the organic suspension liquid fertilizer of the improved soil comprises the following steps:
S1. yeast liquid molasses are put into reactor by compound fertilizer formula as described in claim 1, obtain mother liquor;
S2. nitric acid calcium and magnesium is obtained into powder below micron by airslide disintegrating mill, grinding time is 40min;
S3. nitric acid calcium and magnesium is added into mother liquor, it is stirring while adding to black liquor is formed, it is stirring while adding, keep reaction temperature
For 60 DEG C;
S4. magnesium nitrate is respectively added slowly into S3, it is stirring while adding;
S5. methyl pentanal, sodium acetate, secondary octyl phenol polyethenoxy ether, Silica hydrogel are evenly mixed in 1/3 yeast liquid molasses
Together, slurry is formed;
S6. S4, S5 are homogenously mixed together, form thick slurry, homogenized through colloid mill levigate;
S7. S6 is then passed through into the secondary grinding of sand mill, obtains good fluidity, the suspending agent of modest viscosity;
S8. uniform probably 8min or so of most backward S7 liquid agitations, adjustment pH value etc., through quality examination it is qualified after, finished product is close
In encapsulation to 30L liquid storing barrel, suspension liquid compound fertilizer is produced;
Using People's Republic of China's agricultural industry criteria(NY 2266-2012)The synthesis content's index of fertilizer is determined, 1 is shown in Table
It is shown.
Embodiment 2
The organic suspension liquid fertilizer of improved soil described in the present embodiment contains each component of following parts by weight:
The specific preparation method of the organic suspension liquid fertilizer of the improved soil comprises the following steps:
S1. 2/3 cane molasses liquid, urea are put into reactor by compound fertilizer formula as described in claim 1, obtain mother
Liquid;
S2. calcium nitrate is obtained into powder below micron by airslide disintegrating mill, grinding time is 40min;
S3. calcium nitrate is added into mother liquor, stirring while adding to black liquor is formed, stirring while adding, holding reaction temperature is
65℃;
S4. magnesium nitrate, magnesium chloride are respectively added slowly into S3, it is stirring while adding;
S5. naphthalenesulfonic acid-formaldehyde condensate, ethylene glycol, calcium dodecyl benzene sulfonate, xanthans with 1/3 cane molasses liquid it is equal
It is even to mix, form slurry;
S6. S4, S5 are homogenously mixed together, form thick slurry, homogenized through colloid mill levigate;
S7. S6 is then passed through into the secondary grinding of sand mill, obtains good fluidity, the suspending agent of modest viscosity;
S8. uniform probably 8min or so of most backward S7 liquid agitations, adjustment pH value etc., through quality examination it is qualified after, by finished product
Sealing is filled in 30L liquid storing barrel, produces suspension liquid compound fertilizer;
Using People's Republic of China's agricultural industry criteria(NY 2266-2012)The synthesis content's index of fertilizer is determined, 1 is shown in Table
It is shown.
Embodiment 3
The organic suspension liquid fertilizer of improved soil described in the present embodiment contains each component of following parts by weight:
The specific preparation method of the organic suspension liquid fertilizer of the improved soil comprises the following steps:
S1. 2/3 alcohol effluent, urea are put into reactor by compound fertilizer formula as described in claim 1, obtain mother liquor;
S2. calcium chloride is obtained into powder below micron by airslide disintegrating mill, grinding time is 45min;
S3. calcium chloride is added into mother liquor, stirring while adding to black liquor is formed, stirring while adding, holding reaction temperature is
50℃;
S4. magnesium nitrate, magnesium chloride are respectively added slowly into S3, it is stirring while adding;
S5. sodium lignin sulfonate, formamide, benzyl dimethyl phenol polyethenoxy ether, carboxymethyl cellulose and 1/3 alcohol are useless
Liquid is homogenously mixed together, and forms slurry;
S6. S4, S5 are homogenously mixed together, form thick slurry, homogenized through colloid mill levigate;
S7. S6 is then passed through into the secondary grinding of sand mill, obtains good fluidity, the suspending agent of modest viscosity;
S8. uniform probably 8min or so of most backward S7 liquid agitations, adjustment pH value etc., through quality examination it is qualified after, finished product is close
In encapsulation to 30L liquid storing barrel, suspension liquid compound fertilizer is produced;
Using People's Republic of China's agricultural industry criteria(NY 2266-2012)The synthesis content's index of fertilizer is determined, 1 is shown in Table
It is shown.
Embodiment 4
The organic suspension liquid fertilizer of improved soil described in the present embodiment contains each component of following parts by weight:
The specific preparation method of the organic suspension liquid fertilizer of the improved soil comprises the following steps:
S1. 2/3 monosodium glutamate leftover bits and pieces, urea are put into reactor by compound fertilizer formula as described in claim 1, obtain mother
Liquid;
S2. calcium chloride is obtained into powder below micron by airslide disintegrating mill, grinding time is 40min;
S3. calcium chloride is added into mother liquor, stirring while adding to black liquor is formed, stirring while adding, holding reaction temperature is
65℃;
S4. magnesium chloride is respectively added slowly into S3, it is stirring while adding;
S5. polyacrylamide, propane diols, alkyl aryl sulphonic acid are received, polyvinyl alcohol is evenly mixed in 1/3 monosodium glutamate leftover bits and pieces
Together, slurry is formed;
S6. S4, S5 are homogenously mixed together, form thick slurry, homogenized through colloid mill levigate;
S7. S6 is then passed through into the secondary grinding of sand mill, obtains good fluidity, the suspending agent of modest viscosity;
S8. uniform probably 8min or so of most backward S7 liquid agitations, adjustment pH value etc., through quality examination it is qualified after, finished product is close
In encapsulation to 30L liquid storing barrel, suspension liquid compound fertilizer is produced;
Using People's Republic of China's agricultural industry criteria(NY 2266-2012)The synthesis content's index of fertilizer is determined, 1 is shown in Table
It is shown.
Embodiment 5
The organic suspension liquid fertilizer of improved soil described in the present embodiment contains each component of following parts by weight:
The specific preparation method of the organic suspension liquid fertilizer of the improved soil comprises the following steps:
S1. 2/3 yeast liquid molasses, ammonium nitrate are put into reactor by compound fertilizer formula as described in claim 1, are obtained
Mother liquor;
S2. calcium chloride is obtained into powder below micron by airslide disintegrating mill, grinding time is 45min;
S3. calcium chloride is added into mother liquor, stirring while adding to black liquor is formed, stirring while adding, holding reaction temperature is
50℃;
S4. magnesium nitrate, magnesium chloride are respectively added slowly into S3, it is stirring while adding;
S5. methyl anyl alcohol, ethanol, styryl phenyl APEO, attapulgite are uniformly mixed with 1/3 yeast liquid molasses
It is combined, forms slurry;
S6. S4, S5 are homogenously mixed together, form thick slurry, homogenized through colloid mill levigate;
S7. S6 is then passed through into the secondary grinding of sand mill, obtains good fluidity, the suspending agent of modest viscosity;
S8. uniform probably 8min or so of most backward S7 liquid agitations, adjustment pH value etc., through quality examination it is qualified after, finished product is close
In encapsulation to 30L liquid storing barrel, suspension liquid compound fertilizer is produced;
Using People's Republic of China's agricultural industry criteria(NY 2266-2012)The synthesis content's index of fertilizer is determined, 1 is shown in Table
It is shown.
Embodiment 6
The performance test of the organic suspension liquid fertilizer of improved soil of the present invention
Effective content in the organic suspension liquid fertilizer for the improved soil that the method for the invention is prepared is high, containing calcium,
These nutrients organically, are stably dissolved in suspension liquid by the nutrients such as magnesium, organic matter, nitrogen, the present invention well, form total support
Point content is high, moderate-element is complete, good fluidity organic and inorganic suspension liquid fertilizer.Using People's Republic of China's agricultural
Professional standard(NY 2266-2012)The content's index for measuring fertilizer is shown in Table 1.
The fertile quality index of suspension liquid that the present invention of table 1 is prepared
As seen from the results in Table 1, the present invention is made into suspending agent by using wetting dispersing agent, emulsifying agent, thickener, antifreezing agent etc.,
, can be effectively by calcium, magnesium, organic matter, nitrogen by strictly controlling the temperature of the granule size of insoluble matter, addition sequence and reaction
Organically, stably it is incorporated into suspension liquid Deng nutrient, forms total nutrient content height, moderate-element complete, good fluidity
Organic and inorganic suspension liquid fertilizer, effectively improves the utilization rate of fertilizer of calcium and magnesium.
Embodiment 7
The application test of the organic suspension liquid fertilizer of improved soil of the present invention
(1)Experiment is applied in pouring
Test site:Zhanjiang, Guangdong Province Xuwen County advance farm
Test period:In October, -2016 in May, 2016
Trial crops:Corn
Test soil:Laterite
Testing program:Two processing of organic suspension liquid fertilizer sample and comparative example of improved soil of the present invention are chosen in this experiment.It is right
Ratio uses the Liquid Fertilizer (moderate-element water-soluble fertilizer) that Guangdong Lv Xing bio tech ltd is produced, Ca+Mg >=100g/L.
The organic suspension liquid fertilizer of improved soil of the present invention designs 1 processing, and numbering is processing 1(Prepared using the embodiment of the present invention 1
The organic suspension liquid fertilizer of obtained improved soil)., processing 2(The improved soil prepared using the embodiment of the present invention 2
Organic suspension liquid fertilizer), processing 3(The organic suspension liquid fertilizer of the improved soil prepared using the embodiment of the present invention 3
Material), processing 4(The organic suspension liquid fertilizer of the improved soil prepared using the embodiment of the present invention 4), processing 5(Using this
The organic suspension liquid fertilizer for the improved soil that inventive embodiments 5 are prepared).In sowing on May 2nd, 2016,2016 6
The moon 3 was transplanted, and mu plants 4500 plants.Each processing liquid fertilizer is respectively on June 25th, 2016, on July 5th, 2016, in July, 2016
20 days, August in 2016 1 day, each drench on the 16th of August in 2016 apply once, pouring applies concentration for 200 times.Comparative example is applied with same pouring
Concentration and time carry out pouring and applied.Result of the test is as shown in table 2.
The fluid present invention fertilizer of table 2 and the fertile comparative result of commercial liquid
The result of table 2 shows, is compared with comparative example, drenches the organic suspension liquid fertilizer for applying improved soil of the present invention to a certain degree
On add the yield of corn.The wherein obvious effect of increasing production of embodiment 1, single plant yield increases 102.1kg compared with comparative example,
Rate of growth is 20.0%.Meanwhile, drench and apply the organic suspension liquid fertilizer of the improved soil of the present invention and also significantly improve the list of corn
Corn ear weight, the single corn ear of embodiment 1 is again higher than comparative example by 16.7% respectively.The plant height of embodiment 1,2,3,4,5 compares ratio respectively
Example it is high by 16.70%, 14.57%, 12.90%, 14.99%, 12.56%.It can be seen that, the organic suspension liquid for the improved soil that the present invention is provided
Body fertilizer promotes corn kernel growth and the absorption of mineral nutrient, improves the setting percentage and single corn ear weight of corn, effectively
The nutritional deficiency phenomenon such as calcium deficiency magnesium deficiency is prevented, so as to improve the yield and quality of corn.
In recent years, composite fertilizer and agricultural chemicals is excessively used in peasant household, adds industrial pollution, and various regions soil acidification is serious, causes to make
Thing absorbs nutrient efficiency lowly, and soil-borne disease increases, crop yield and quality degradation, and the plantation for directly affecting peasant household is received
Benefit.It is reported that, the soil of Zhanjiang region is characteristic of acid red soil, and growing area generally faces the problems such as soil acidification, phosphorus are fixed, and seriously
Lack the moderate-elements such as calcium, magnesium.The shortage of soil souring and moderate-element has turned into that crop yield is constantly improve and quality changes
Good important limitation silver.Microbe colony abundance refers to the kind number of species in a group;Microbe colony abundance, which can embody, to be changed
Native characteristic.
The fluid present invention fertilizer of table 3 and comparative result of the commercial liquid fertilizer to reclamation result
The result of table 3 shows, is compared with comparative example, and the organic suspension liquid fertilizer of the improved soil provided using the present invention is one
Determine to improve soil organic matter content in degree, wherein the content of organic matter highest of embodiment 1, compared with comparative example, organic matter
Content increase by 0.47%, growth rate is 47.30%.Microbiologic population's abundance also has growth to a certain extent, the microorganism of embodiment 1
Group's abundance is higher than comparative example by 180.0%% respectively.Meanwhile, the organic suspension liquid fertilizer for drenching the improved soil of the present invention is also notable
Microbiologic population's abundance is improved, microbiologic population's abundance that embodiment 1,2,3,4,5 is compared respectively is higher than comparative example respectively
180.0%、160.0%、140.0%、160.0%、150.0%.The organic suspension liquid fertilizer of the improved soil provided using the present invention
Afterwards, the pH value of soil increases to a certain extent, the soil pH value of embodiment 1,2,3,4,5 is higher than comparative example by 1.3 respectively,
1.1st, 1.0,1.2,1.1 points.The organic suspension liquid fertilizer for the improved soil that the present invention is provided can not only improve the production of crop
Amount and quality, can also significantly improve the pH value of soil, increase microbial bacteria planting number, improve soil organic matter content, so that
Reach the purpose of the physicochemical property of improved soil.The organic suspension liquid fertilizer for the improved soil that the present invention is provided can improve work
Thing soil root environment, allows crop preferably to grow.
Claims (10)
1. a kind of organic suspension liquid fertilizer of improved soil, it is characterised in that the organic suspension liquid fertilizer bag of described improved soil
Include 0 ~ 20 part of 13.0 ~ 46.0 parts of calcareous fertilisers, 3.0 ~ 17.0 parts of fertiliser containing magnesium, the nitrogenous fertilizer and 40.0 ~ 55.0 parts of organic matter of parts by weight.
2. the organic suspension liquid fertilizer of improved soil according to claim 1, it is characterised in that described improved soil
Organic suspension liquid fertilizer also includes auxiliary material.
3. the organic suspension liquid fertilizer of improved soil according to claim 2, it is characterised in that described auxiliary material includes profit
Hygroscopic water powder, emulsifying agent, thickener and antifreezing agent.
4. the organic suspension liquid fertilizer of the improved soil according to Claims 2 or 3, it is characterised in that described auxiliary material includes
0.1 ~ 2.0 part of 0.1 ~ 2.0 part of 0.1 ~ 2.0 part of wetting dispersing agent, emulsifying agent, the thickener and 0.1 ~ 2.0 part of antifreezing agent of parts by weight.
5. the organic suspension liquid fertilizer of improved soil according to claim 1, it is characterised in that described calcareous fertilisers are nitric acid
One or more in calcium, nitric acid calcium and magnesium, calcium oxide, calcium ammonium nitrate and calcio-disodium edetate.
6. the organic suspension liquid fertilizer of improved soil according to claim 1, it is characterised in that described fertiliser containing magnesium is nitric acid
One or more in magnesium, magnesium sulfate, magnesium chloride, magnesia and ethylenediamine tetra-acetic acid magnesium sodium.
7. improved soil according to claim 1 organic suspension liquid fertilizer, it is characterised in that described nitrogenous fertilizer be urea,
One or more in ammonium nitrate and urea ammonium nitrate.
8. the organic suspension liquid fertilizer of improved soil according to claim 1, it is characterised in that described organic matter is sweet
One or more in molasses, alcohol effluent, yeast factory waste liquid and the Gourmet Powder Factory's leftover bits and pieces of sugarcane factory.
9. the organic suspension liquid fertilizer of improved soil according to claim 3, it is characterised in that described wetting dispersing agent
For sodium lignin sulfonate, naphthalenesulfonic acid-formaldehyde condensate, AEO fatty alcohol, triethyl group hexyl phosphoric acid, methyl
One or more in amylalcohol, polyacrylamide, aliphatic acid Macrogol Ester, polyethylene glycol and vinyl bis-stearamides;Institute
The emulsifying agent stated is neopelex, calcium dodecyl benzene sulfonate, sodium alklyarylsulfonate, dialkyl benzene sulfonic acids are received,
Hydroxy alkyl sulfonic acid sodium, styryl APEO, thousand base phenol polyethenoxy ethers, OPEO, secondary octyl phenol
APEO, double, tributyl phenol APEO, APES polyethenoxy ether, benzyl dimethyl phenol polyoxy
Vinethene, dibenzyl xenol polyoxyethylene polyoxypropylene ether, ethoxylated dodecyl alcohol and octadecane alcohol radical APEO
In one or more;Described thickener is xanthans, carboxymethyl cellulose, sodium carboxymethylcellulose, diatomite, concave convex rod
One or more in soil, Silica hydrogel, gum arabic, Artemisia Glue, trigonella bean gum, polyacrylamide and polyvinyl alcohol;It is described
Antifreezing agent be methanol, ethanol, isopropanol, ethylene glycol, propane diols, diethylene glycol (DEG), butyl glycol ether, propandiol butyl ether, ethylene glycol
Monobutyl ether acetate, dichloromethane, 1,1- dichloroethanes, 1,2- dichloroethanes, dimethyl sulfoxide (DMSO), formamide, calcium chloride, sodium acetate
With the one or more in magnesium chloride.
10. a kind of preparation method of the organic suspension liquid fertilizer of any described improved soil of claim 1 ~ 9, it is characterised in that
Comprise the following steps:
A, the nitrogenous fertilizer of the organic matter of formulation ratio 2/3 and formulation ratio 2/3 obtained into mother liquor;The calcareous fertilisers of formulation ratio were crushed
It is standby that 100 ~ 200 mesh sieves obtain material a;
B, material a is added in the mother liquor of step A preparation, it is stirring while adding, in stirring reaction 30 at 50 ~ 65 DEG C of temperature ~
40min obtains material b;
C, the fertiliser containing magnesium of formulation ratio is added in material b, it is stirring while adding, obtained in 30 ~ 45min of stirring reaction at 50 ~ 65 DEG C
To material c;
D, by the organic matter of the wetting dispersing agent of formulation ratio, emulsifying agent, thickener, antifreezing agent and formulation ratio 1/3, match somebody with somebody
Nitrogenous fertilizer than 1/3, which is homogenously mixed together, obtains slurry d;
E, material c and slurry d are uniformly mixed to get to Materialien, Materialien obtains material through the levigate mesh sieve of mistake 100 ~ 200 of colloid mill
f;Material f grinds the suspending agent for obtaining good fluidity through sand mill again, and adjustment pH value obtains having for object improved soil for 6 ~ 8
Machine suspension body fertilizer.
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