CN108486887A - 一种纺织品去除荧光方法 - Google Patents

一种纺织品去除荧光方法 Download PDF

Info

Publication number
CN108486887A
CN108486887A CN201810254046.4A CN201810254046A CN108486887A CN 108486887 A CN108486887 A CN 108486887A CN 201810254046 A CN201810254046 A CN 201810254046A CN 108486887 A CN108486887 A CN 108486887A
Authority
CN
China
Prior art keywords
fluorescence
textile
parts
sodium
remover
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810254046.4A
Other languages
English (en)
Inventor
不公告发明人
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to CN201810254046.4A priority Critical patent/CN108486887A/zh
Publication of CN108486887A publication Critical patent/CN108486887A/zh
Pending legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/356—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of other unsaturated compounds containing nitrogen, sulfur, silicon or phosphorus atoms
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M10/00—Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M10/00—Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements
    • D06M10/04—Physical treatment combined with treatment with chemical compounds or elements
    • D06M10/08—Organic compounds
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/38—Oxides or hydroxides of elements of Groups 1 or 11 of the Periodic System
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/51—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof
    • D06M11/55—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof with sulfur trioxide; with sulfuric acid or thiosulfuric acid or their salts
    • D06M11/57—Sulfates or thiosulfates of elements of Groups 3 or 13 of the Periodic System, e.g. alums
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
    • D06M13/207—Substituted carboxylic acids, e.g. by hydroxy or keto groups; Anhydrides, halides or salts thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/285—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acid amides or imides
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/53—Polyethers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/61—Polyamines polyimines
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02—Natural fibres, other than mineral fibres
    • D06M2101/04—Vegetal fibres
    • D06M2101/06—Vegetal fibres cellulosic

Abstract

一种纺织品去除荧光方法，其特征在于：使用荧光去除剂去除纺织品上荧光。

Description

一种纺织品去除荧光方法
本申请是申请号为2016101251025，发明名称为一种荧光去除剂及用其去除纺织品上荧光的方法，申请日为20160306的发明专利申请的分案申请。
技术领域
本发明属于纺织品荧光去除领域。
背景技术
经研究，荧光剂使用不当具有极大的危害，不像一般化学成分那样容易被分解，而是在人体内蓄积，产生许多有害的物质，大大消减人体免疫力。荧光剂与伤口外的蛋白质结合，还会阻碍伤口的愈合，使人体细胞出现变异性倾向，其毒性累积在肝脏或其它重要器官，会成为潜在的致癌因素。若是衣服没有清洗干净，还留有残余的荧光成分，身体一流汗，即会将衣服上残留的荧光剂溶解，而使皮肤接触到荧光物质，此时皮肤表面含有蛋白质的角质就会跟荧光剂结合对皮肤产生刺激，引发过敏及发痒，增加过敏性皮炎的发病机会。因此，纺织制品中，由于原料中混入荧光物质、或在加工中沾附荧光增白剂、或者不当添加荧光增白剂而带有荧光，或者由于应用场合限制存在荧光物质（如某些国家的婴儿用品等），经常需要加以去除。目前对荧光物质消除的方法的报道多见于纸张回收处理，对纺织品上荧光增白剂的消除方法尚无公开报道。
常规的荧光消去方法有两类，一类是采用氧化剂处理以破坏荧光增白剂的化学结构从而消除荧光，常用的有含氯氧化剂如次氯酸钠、二氧化氯，也有用含氧的氧化剂如过醋酸处理。如中国专利CN102230291A公开了一种消除废纸浆中荧光物质的方法，采用二氧化氯作为废纸浆的荧光消除剂，纸浆的漂白和去除荧光同时进行，因为荧光物质耐氯性很差，氯和次氯酸盐能够破坏大多数荧光结构，使其无荧光性质，但环境法规限制了氯和次氯酸盐的使用。另一类是添加荧光抑制剂来消除荧光，荧光抑制剂是典型的聚酰季胺类化合物结构。荧光增白剂本身大多是阴离子性的，且荧光增白剂有非常稳定的化学结构。因此，可利用荧光抑制剂本身带有的阳离子性来有效地中和系统中荧光增白剂的阴离子，使发色的活性阴离子基团变性，达到有效消除系统中荧光的目的。如中国专利CN103614943A公开了一种降低造纸系统中荧光增白剂含量的方法，采用阳离子聚丙烯酰胺、聚胺、二乙烯三胺五甲叉磷酸以1:5:2的比例混合物作为荧光消除剂，降低荧光增白剂在纸页上的留着，从而降低纸页的荧光含量。它不能破坏除去发荧光的分子，但能抑制它们发荧光的性质，掩盖了荧光特性，并未破坏荧光物质的分子结构和发色基团。一旦聚酰季胺类化合物被水解，则荧光增白剂又恢复了它的荧光性。上述强氧化型的荧光消除剂消除荧光后纸浆的白度下降，导致之前的漂白作用所增加的白度几乎完全被抵消，不仅造成化学品的浪费，而且还增加了流程，多耗费好多资源，增加环境的负担。而聚酰季胺类荧光抑制剂对抑制荧光有一定的作用，但是对于荧光较强的系统来说，其去除效果有限。
发明内容
本发明要解决的技术问题是克服现有技术的不足，提供一种能够去除纺织品上荧光增白剂产生荧光的方法，通过化学和物理两种消除方法相结合，既能够破坏纺织品生产中常见的荧光增白剂的发色体系，彻底消除荧光作用，也能够实现对纺织品的强力损伤最小化。
为解决上述问题，本发明采取如下技术方案：
一种纺织品荧光去除剂，其特征在于：含有以下质量份的组分：二甲基二烯丙基氯化铵120-150份、丙烯酰胺69-70份、硼氢化钠或亚硫酸钠3-8份、烯丙基磺酸钠或巯基乙醇0.7-0.8份、聚天冬氨酸0.2-0.5份、亚氯酸钠1-2份、铝盐2-3份、聚胺0.1-0.2份。
一种荧光去除剂的制备方法，在带有搅拌器、冷凝器、温度计及氮气接口的容器内加入二甲基二烯丙基氯化铵和丙烯酰胺，搅拌通入氮气，加入铝盐搅拌溶解，在70-90℃下加入硼氢化钠或亚硫酸钠，用无机酸调节pH值至4-5，保持15-30min，最后加入剩余组分。
得到的荧光去除剂，其固含量为40-50wt％，25℃下粘度为60-780cps。其中铝盐为硫酸铝或氯化铝。
一种使用上述荧光去除剂进行去除纺织品上荧光的方法，其特征在于：
1.用渗透剂JFC处理待处理织物表面，浸轧润湿；
2.在50-60℃下浸轧所述荧光去除剂，以2-3℃/min的温度升温至70℃，保温运转，加入纯碱，保温20-30min；
3.冷热水交替洗涤三次，然后借助经清洁的气体(经过滤的压缩空气、CO2、诸如半导体品质的氮气的惰性的气体或其混合物)以大于2m/s、优选大于10m/s、更优选大于100m/s的速度鼓吹至待处理纺织品表面上；
或者借助经清洁的气体(经过滤的压缩空气、CO2、诸如半导体品质的氮气的惰性的气体或其混合物)在1至20巴、优选3至10巴的压力下将干冰颗粒在喷嘴中进行加速，并以大于2m/s、优选大于10m/s、更优选大于100m/s的速度由此鼓吹至待处理纺织品表面上；
4.经过步骤3后的纺织品浸入纯碱溶液，室温下浸渍2-5min，加入柠檬酸1-2g/L，随后清水洗涤，可以消除纺织品上的荧光。
作为压缩空气可以使用空气、二氧化碳或者其他惰性的气体，如氮气或氩气。还可以考虑任意的气体混合物，或者具有额外的化学清洁作用的气体添加剂，如臭氧。优选以1至20巴、更优选5至10巴的气体压力进行干冰颗粒的喷嘴加速。或者以至少2m/s、优选大于10m/s、更优选大于100m/s的气体速度对纺织品的表面进行吹气。气体射流在纺织品表面上的作用可以是小于1秒的一个或多个短脉冲，也可以是几秒或几分钟的持续射流。 优选用干燥(露点小于40℃)的、不含油和油脂的、经清洁的气体，特别优选用半导体品质的气体进行操作，
通过鼓吹所制备的干冰颗粒形式的CO2通过高速喷嘴，通过将干冰的动能、热冲击作用和升华作用相结合，使荧光成分脱离。优选将塑料衬里(例如PU、PP或PE)用于干冰储存容器。若用干冰的块运行设备，则优选将由耐磨的陶瓷或硬质金属制成的加工工具用于制造温度约为-80℃的冷冰颗粒。使用例如基于食品品质的二氧化碳气体的超纯干冰，因而不会被外来颗粒污染。在此，干冰的消耗根据喷嘴构型和压力范围而改变。
另一个优选的实施方案在于，将利用压缩空气的方法与利用干冰的方法相结合。
本发明的优点在于通过物理和化学手段的结合彻底去除纤维素纤维纺织制品上的荧光物质，且对纺织品的强度、伸长、柔软性和表面光泽度等性能损伤小。
具体实施方式
实施例1 荧光去除剂的制备
在带有搅拌器、冷凝器、温度计及氮气接口的容器内加入二甲基二烯丙基氯化铵123份和丙烯酰胺69份，搅拌通入氮气，加入铝盐2.3份搅拌溶解，在75℃下加入硼氢化钠或亚硫酸钠3.8份，用无机酸调节pH值至4.5，保持16min，最后加入烯丙基磺酸钠或巯基乙醇0.7-0.8份、聚天冬氨酸0.2-0.5份、亚氯酸钠1.2份，聚胺0.12份，得到的荧光去除剂，其固含量为45wt％，25℃下粘度为678cps，其中铝盐为硫酸铝。
实施例2 荧光去除剂处理纺织品
用渗透剂JFC处理待处理含有荧光增白剂的棉织物表面，浸轧润湿；在50-60℃下浸轧所述荧光去除剂，以2-3℃/min的温度升温至70℃，保温运转，加入纯碱，保温20-30min；冷热水交替洗涤三次，然后借助经清洁的气体(经过滤的压缩空气、CO2、诸如半导体品质的氮气的惰性的气体或其混合物)在12巴的压力下将干冰颗粒在喷嘴中进行加速，并以15m/s的速度由此鼓吹至待处理纺织品表面上；再将纺织品浸入纯碱溶液，室温下浸渍2.5min，加入柠檬酸1.2g/L，随后清水洗涤，可以消除纺织品上的荧光。
对比例1
将需处理的含荧光增白剂的棉织物按下列条件进行处理：
浸轧(室温，轧余率80～85％)→汽蒸(102℃，120～180分钟)→水洗→脱氯(60℃)→水洗。 浸轧液组成：
荧光消除剂(按二氧化氯/亚氯酸钠法中制备方法) 60g/L
HAc 4.5g/L
脱氯液组成：
硫代硫酸钠： 20g/L
纯碱： 15g/L
去除荧光测试：
利用荧光白度一非荧光白度差值法来评价实施例和对比例所制备的荧光去除效果，利用白度仪来测试纺织品荧光白度和非荧光白度，两者差值与非荧光白度之比越小，则纺织品中残留荧光剂相对含量越少。荧光去除效果的评价是比较加有荧光去除剂前后两块纺织品的荧光白度和非荧光白度的差值之比，即相对荧光(％)＝(ARF/ARM)/100％。比值越小，荧光去除效果越好(若荧光白度小于非荧光白度，则AR以0计)。
表1 去除荧光测试情况
样品编号 相对荧光％ 强度保持率（％） 布面光洁度（级） 伸长保持率（％）
实施例2 1.08 98 5 96
比较例1 5.65 87 4 80
从表1中可以发现，本发明的荧光去除效果以及强度等纺织品使用性能的保持均优于采用其它荧光去除剂和荧光去除方法制得的纺织品。
上面所述的实施例仅是对本发明优选实施方式进行描述，并非对本发明的范围进行限定，在不脱离本发明设计精神前提下，本领域普通技术人员对本发明技术方案作出的各种变形和改进，均落入本发明的权利要求书限定的范围内。

Claims (4)

1.一种纺织品去除荧光方法，其特征在于：使用荧光去除剂去除纺织品上荧光。
2.如权利要求1所述的纺织品去除荧光方法，其特征在于：所述荧光去除剂含有以下质量份的组分：二甲基二烯丙基氯化铵120-150份、丙烯酰胺69-70份、硼氢化钠或亚硫酸钠3-8份、烯丙基磺酸钠或巯基乙醇0.7-0.8份、聚天冬氨酸0.2-0.5份、亚氯酸钠1-2份、铝盐2-3份、聚胺0.1-0.2份。
3.如权利要求1所述的纺织品去除荧光方法，其特征在于：其荧光去除剂制备方法步骤如下：在带有搅拌器、冷凝器、温度计及氮气接口的容器内加入二甲基二烯丙基氯化铵和丙烯酰胺，搅拌通入氮气，加入铝盐搅拌溶解，在70-90℃下加入硼氢化钠或亚硫酸钠，用无机酸调节pH值至4-5，保持15-30min，最后加入剩余组分，得到的荧光去除剂，其固含量为40-50wt％，25℃下粘度为60-780cps。
4.如权利要求2所述的纺织品荧光去除剂，其特征在于：其中铝盐为硫酸铝或氯化铝。
CN201810254046.4A 2016-03-06 2016-03-06 一种纺织品去除荧光方法 Pending CN108486887A (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810254046.4A CN108486887A (zh) 2016-03-06 2016-03-06 一种纺织品去除荧光方法

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN201610125102.5A CN105671961B (zh) 2016-03-06 2016-03-06 一种荧光去除剂及用其去除纺织品上荧光的方法
CN201810254046.4A CN108486887A (zh) 2016-03-06 2016-03-06 一种纺织品去除荧光方法

Related Parent Applications (1)

Application Number Title Priority Date Filing Date
CN201610125102.5A Division CN105671961B (zh) 2016-03-06 2016-03-06 一种荧光去除剂及用其去除纺织品上荧光的方法

Publications (1)

Publication Number Publication Date
CN108486887A true CN108486887A (zh) 2018-09-04

Family

ID=56306760

Family Applications (3)

Application Number Title Priority Date Filing Date
CN201810254837.7A Expired - Fee Related CN108330689B (zh) 2016-03-06 2016-03-06 一种纺织品荧光去除剂
CN201610125102.5A Active CN105671961B (zh) 2016-03-06 2016-03-06 一种荧光去除剂及用其去除纺织品上荧光的方法
CN201810254046.4A Pending CN108486887A (zh) 2016-03-06 2016-03-06 一种纺织品去除荧光方法

Family Applications Before (2)

Application Number Title Priority Date Filing Date
CN201810254837.7A Expired - Fee Related CN108330689B (zh) 2016-03-06 2016-03-06 一种纺织品荧光去除剂
CN201610125102.5A Active CN105671961B (zh) 2016-03-06 2016-03-06 一种荧光去除剂及用其去除纺织品上荧光的方法

Country Status (1)

Country Link
CN (3) CN108330689B (zh)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114960086A (zh) * 2021-12-08 2022-08-30 中山市卓益服饰有限公司 一种用于婴童家居服的不含荧光剂面料的生产工艺

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106317952B (zh) * 2016-08-19 2018-03-09 福建中烟工业有限责任公司 一种增白组合物、其制备方法及用途
CN113005763B (zh) * 2021-02-25 2022-10-18 广东溢达纺织有限公司 织物荧光去除方法以及织物的加工方法

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2006188788A (ja) * 2005-01-06 2006-07-20 Daio Paper Corp 無蛍光板紙
CN101187150A (zh) * 2007-12-07 2008-05-28 东华大学 抑制和消除纺织制品上荧光消除剂产生荧光的方法
CN102383194A (zh) * 2010-08-25 2012-03-21 瓦克化学股份公司 多晶硅及其制造方法
CN103614943A (zh) * 2013-12-04 2014-03-05 天津科技大学 降低造纸系统中荧光增白剂含量的方法
CN104098747A (zh) * 2014-07-10 2014-10-15 浙江九本生物化学有限公司 一种荧光消除剂的制备方法
CN104711897A (zh) * 2015-04-02 2015-06-17 天津科技大学 荧光消减剂

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3118087B2 (ja) * 1992-07-16 2000-12-18 三菱製紙株式会社 古紙パルプの蛍光消去法
US6117190A (en) * 1999-08-12 2000-09-12 Raytheon Company Removing soil from fabric using an ionized flow of pressurized gas
CN104713412A (zh) * 2013-12-13 2015-06-17 琳德股份公司 在线清洁方法
CN104674431A (zh) * 2015-03-19 2015-06-03 苏州陈恒织造有限公司 一种二氧化碳退浆粘胶/铜氨纤维混纺面料的制作方法

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2006188788A (ja) * 2005-01-06 2006-07-20 Daio Paper Corp 無蛍光板紙
CN101187150A (zh) * 2007-12-07 2008-05-28 东华大学 抑制和消除纺织制品上荧光消除剂产生荧光的方法
CN102383194A (zh) * 2010-08-25 2012-03-21 瓦克化学股份公司 多晶硅及其制造方法
CN103614943A (zh) * 2013-12-04 2014-03-05 天津科技大学 降低造纸系统中荧光增白剂含量的方法
CN104098747A (zh) * 2014-07-10 2014-10-15 浙江九本生物化学有限公司 一种荧光消除剂的制备方法
CN104711897A (zh) * 2015-04-02 2015-06-17 天津科技大学 荧光消减剂

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
杨士林: "《聚天冬氨酸合成与阻垢技术》", 30 November 2009, 黑龙江大学出版社 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114960086A (zh) * 2021-12-08 2022-08-30 中山市卓益服饰有限公司 一种用于婴童家居服的不含荧光剂面料的生产工艺
CN114960086B (zh) * 2021-12-08 2022-12-16 中山市卓益服饰有限公司 一种用于婴童家居服的不含荧光剂面料的生产工艺

Also Published As

Publication number Publication date
CN105671961B (zh) 2018-06-05
CN108330689B (zh) 2021-12-03
CN108330689A (zh) 2018-07-27
CN105671961A (zh) 2016-06-15

Similar Documents

Publication Publication Date Title
CN105671961B (zh) 一种荧光去除剂及用其去除纺织品上荧光的方法
BRPI0710499A2 (pt) método e formulação para a limpeza de substrato sujo
WO2003089699A1 (fr) Fibre de bambou et sa fabrication
CN101245556B (zh) 抑制和消除纺织制品上荧光的方法
CN109722837B (zh) 纺织品的损伤方法
CN113047038B (zh) 一种纺织前处理用复合茶皂素助剂及其制备方法
CN108468219A (zh) 一种建筑用室内壁纸无害化处理工艺
CN107268298A (zh) 一种棉面料的新型染色工艺
US4961749A (en) Process for removing permanganate stains from articles
Fatma et al. An eco-friendly approach towards bleaching process for whitening of Kydia calycina fibres instead of hydrogen peroxide
CN109112832A (zh) 一种胶原蛋白-复合酸改性棉织物的方法
CN105803783A (zh) 一种医疗用无污染病床
JP2015083729A (ja) 綿繊維の精練方法
CN103643330B (zh) 一种芦荟维生素护肤面料的制作工艺
KR102243538B1 (ko) 타월의 정련방법.
CN106590944A (zh) 一种清除棉麻上血渍的清洁剂及其清洁方法
US1564433A (en) Gas-purifying composition
CN107217473A (zh) 一种棉面料的砂洗工艺
KR102412143B1 (ko) 극피동물 유래 다공성 물질을 포함하는 항염소 스판덱스 및 그 제조방법
CN1466640A (zh) 纺织品处理方法和产品
JP2005350785A (ja) アロフェン系物質含有レーヨンおよびその製造方法
Sharma et al. A novel method for scouring textile cotton
JP2009144270A (ja) 漂白方法および該方法によって加工されたインジゴ染色生地
CN106087180A (zh) 一种用于洁净室的耐高温擦拭布的生产工艺
JP4032295B2 (ja) ユニフォーム

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20180904

WD01 Invention patent application deemed withdrawn after publication