CN108486860A - 一种抗菌防静电针织服装制造方法 - Google Patents
一种抗菌防静电针织服装制造方法 Download PDFInfo
- Publication number
- CN108486860A CN108486860A CN201810387776.1A CN201810387776A CN108486860A CN 108486860 A CN108486860 A CN 108486860A CN 201810387776 A CN201810387776 A CN 201810387776A CN 108486860 A CN108486860 A CN 108486860A
- Authority
- CN
- China
- Prior art keywords
- added
- warp thread
- knitted dress
- antibiotic antistatic
- antistatic knitted
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 230000003115 biocidal effect Effects 0.000 title claims abstract description 31
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 18
- 239000000835 fiber Substances 0.000 claims abstract description 77
- 239000002131 composite material Substances 0.000 claims abstract description 43
- 238000002360 preparation method Methods 0.000 claims abstract description 29
- 230000000844 anti-bacterial effect Effects 0.000 claims abstract description 27
- 238000009955 starching Methods 0.000 claims abstract description 21
- 239000002002 slurry Substances 0.000 claims abstract description 19
- 239000000126 substance Substances 0.000 claims abstract description 13
- 238000012545 processing Methods 0.000 claims abstract description 9
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims abstract description 8
- 238000000034 method Methods 0.000 claims abstract 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 20
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 18
- 229920002994 synthetic fiber Polymers 0.000 claims description 18
- 239000012209 synthetic fiber Substances 0.000 claims description 18
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 16
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims description 10
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 claims description 10
- 239000002202 Polyethylene glycol Substances 0.000 claims description 9
- 229920001223 polyethylene glycol Polymers 0.000 claims description 9
- 229920001661 Chitosan Polymers 0.000 claims description 8
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 8
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 8
- 235000019441 ethanol Nutrition 0.000 claims description 8
- 238000003756 stirring Methods 0.000 claims description 8
- UMGDCJDMYOKAJW-UHFFFAOYSA-N thiourea Chemical compound NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 claims description 8
- 238000010792 warming Methods 0.000 claims description 7
- 229910001961 silver nitrate Inorganic materials 0.000 claims description 5
- XYHKNCXZYYTLRG-UHFFFAOYSA-N 1h-imidazole-2-carbaldehyde Chemical compound O=CC1=NC=CN1 XYHKNCXZYYTLRG-UHFFFAOYSA-N 0.000 claims description 4
- GWYFCOCPABKNJV-UHFFFAOYSA-M 3-Methylbutanoic acid Natural products CC(C)CC([O-])=O GWYFCOCPABKNJV-UHFFFAOYSA-M 0.000 claims description 4
- GWYFCOCPABKNJV-UHFFFAOYSA-N beta-methyl-butyric acid Natural products CC(C)CC(O)=O GWYFCOCPABKNJV-UHFFFAOYSA-N 0.000 claims description 4
- 125000004185 ester group Chemical group 0.000 claims description 4
- 238000010438 heat treatment Methods 0.000 claims description 4
- 238000007654 immersion Methods 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 3
- 229910052708 sodium Inorganic materials 0.000 claims description 3
- 239000011734 sodium Substances 0.000 claims description 3
- UEBARDWJXBGYEJ-UHFFFAOYSA-N 2-bromo-3-methylbutanoic acid Chemical compound CC(C)C(Br)C(O)=O UEBARDWJXBGYEJ-UHFFFAOYSA-N 0.000 claims description 2
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims description 2
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims description 2
- 125000002057 carboxymethyl group Chemical group [H]OC(=O)C([H])([H])[*] 0.000 claims 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 claims 1
- FOIXSVOLVBLSDH-UHFFFAOYSA-N Silver ion Chemical compound [Ag+] FOIXSVOLVBLSDH-UHFFFAOYSA-N 0.000 abstract description 19
- 230000000845 anti-microbial effect Effects 0.000 abstract description 10
- 238000005406 washing Methods 0.000 abstract description 9
- 230000007423 decrease Effects 0.000 abstract description 7
- 238000006243 chemical reaction Methods 0.000 abstract description 6
- 238000003795 desorption Methods 0.000 abstract description 6
- 238000005341 cation exchange Methods 0.000 abstract description 2
- 238000004513 sizing Methods 0.000 description 14
- 230000000052 comparative effect Effects 0.000 description 8
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 description 7
- 239000004744 fabric Substances 0.000 description 7
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 7
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 description 7
- MKYBYDHXWVHEJW-UHFFFAOYSA-N N-[1-oxo-1-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propan-2-yl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(C(C)NC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 MKYBYDHXWVHEJW-UHFFFAOYSA-N 0.000 description 4
- 239000002216 antistatic agent Substances 0.000 description 4
- 230000007547 defect Effects 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 229910052709 silver Inorganic materials 0.000 description 4
- 239000004332 silver Substances 0.000 description 4
- 230000004048 modification Effects 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 238000011056 performance test Methods 0.000 description 3
- -1 silver ions Chemical class 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- 230000008034 disappearance Effects 0.000 description 2
- 230000032050 esterification Effects 0.000 description 2
- 238000005886 esterification reaction Methods 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 238000013508 migration Methods 0.000 description 2
- 230000005012 migration Effects 0.000 description 2
- 239000002052 molecular layer Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 239000004753 textile Substances 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 1
- 229920003043 Cellulose fiber Polymers 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 238000009940 knitting Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/58—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with nitrogen or compounds thereof, e.g. with nitrides
- D06M11/64—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with nitrogen or compounds thereof, e.g. with nitrides with nitrogen oxides; with oxyacids of nitrogen or their salts
- D06M11/65—Salts of oxyacids of nitrogen
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D1/00—Garments
- A41D1/04—Vests, jerseys, sweaters or the like
-
- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
- D02G3/44—Yarns or threads characterised by the purpose for which they are designed
- D02G3/441—Yarns or threads with antistatic, conductive or radiation-shielding properties
-
- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
- D02G3/44—Yarns or threads characterised by the purpose for which they are designed
- D02G3/449—Yarns or threads with antibacterial properties
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/38—Oxides or hydroxides of elements of Groups 1 or 11 of the Periodic Table
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/12—Aldehydes; Ketones
- D06M13/127—Mono-aldehydes, e.g. formaldehyde; Monoketones
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
- D06M13/207—Substituted carboxylic acids, e.g. by hydroxy or keto groups; Anhydrides, halides or salts thereof
- D06M13/21—Halogenated carboxylic acids; Anhydrides, halides or salts thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/402—Amides imides, sulfamic acids
- D06M13/432—Urea, thiourea or derivatives thereof, e.g. biurets; Urea-inclusion compounds; Dicyanamides; Carbodiimides; Guanidines, e.g. dicyandiamides
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/03—Polysaccharides or derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/03—Polysaccharides or derivatives thereof
- D06M15/05—Cellulose or derivatives thereof
- D06M15/09—Cellulose ethers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/53—Polyethers
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D2500/00—Materials for garments
- A41D2500/10—Knitted
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D31/00—Materials specially adapted for outerwear
- A41D31/04—Materials specially adapted for outerwear characterised by special function or use
- A41D31/30—Antimicrobial, e.g. antibacterial
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Mechanical Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
本发明公开了一种抗菌防静电针织服装制造方法，具体方法如下：制备导电抗菌复合纤维；将制备的导电抗菌复合纤维与普通的化纤进行混纺，制成经纱；将第二步中得到的经纱通过功能性上浆液进行上浆处理；将上浆后的经纱进行纺织得到抗菌防静电针织服装。本发明制备的复合纤维上具有大量的氨基和巯基，氨基和巯基通过阳离子交换反应将银离子直接吸附在复合纤维上，使得制备的导电抗菌复合纤维表面含有丰富的银离子，并且银离子与复合纤维之间的作用力较强，后期在衣物清洗过程中不会出现银离子的解吸导致服装导电和抗菌性能的减弱。
Description
技术领域
本发明属于针织服装制造领域，涉及一种抗菌防静电针织服装制造方法。
背景技术
针织服装由于其舒适保暖性能得到大家的广泛青睐，但是在天气较干燥的情况下针织服装容易起静电，同时在潮湿的环境的中放置一段时间后针织衫由于霉菌的滋生会有霉味，需要重新清洗，为消费者带来了很大的困扰，申请号为CN201610143544.2的发明专利公布了一种防静电针织面料及其制备方法，通过三层合适的织物纤维进行复合，再进行纱织而成，增强了面料内外层的导电性，降低摩擦而产生的静电现象的发生；此外在制备过程中对各种原料纤维以及纱线采用整理溶液浸泡后进行整理后进行制备，进一步增强了面料的质感舒适度和抗静电性能，但是该采用的纤维素纤维、锦纶纤维、羊毛混纺纤维三层纤维在摩擦时仍会起一定的静电，并且直接通过将原料纤维在整理溶液中浸泡，虽然会起到一定的抗静电作用的，但是随着时间的推移和清洗次数的增大，原料表面的整理溶液会慢慢变少，进而造成抗静电性能的减弱甚至消失。
发明内容
本发明的目的在于提供一种抗菌防静电针织服装制造方法，在制备过程中中通过吸附银离子的导电抗菌复合纤维与化纤进行混纺得到的轻纱具有一定的抗菌导静电性能，同时在轻纱的表面通过上浆包裹一层功能性上浆液，上浆液中自身具有较强的导电抗菌性能，粘附包裹在经纱的表面能够有效的对经纱中吸附的银离子有一定的制约作用，能够进一步限制银离子的解吸，使得整条经纱都具有较强的导电性能和抗菌性能，不会受服装摩擦和洗涤的影响。
本发明的目的可以通过以下技术方案实现：
一种抗菌防静电针织服装制造方法，具体制备过程如下：
第一步，制备导电抗菌复合纤维，具体制备过程如下：
(1)将合成纤维浸泡于质量分数为20％的氢氧化钠溶液中，常温搅拌反应4-5h，除去合成纤维表面的酯基；1L氢氧化钠溶液中加入300g合成纤维；
(2)在搅拌罐中加入乙醚溶液，向其中加入一定量的2-溴代异戊酸充分溶解后，升温至60℃，将步骤1中处理得到的合成纤维在搅拌罐中恒温浸泡5-7h后取出，然后取出合成纤维在乙醇溶液中浸泡12h后晾干得到复合纤维；1kg合成纤维中加入2-溴代异戊酸的量为120-130g；
(3)将硫脲和水按照一定比例加入搅拌罐中，充分溶解后加入甲醛溶液，搅拌均匀后迅速放入步骤2中得到的复合纤维，然后缓慢升温至60-70℃后保持温度不变浸泡10h，捞出复合纤维后用乙醇冲洗并在40℃下烘干，得到吸附纤维，此时吸附纤维上含有大量的氨基和巯基；1kg复合纤维中加入甲醛38-47g，加入硫脲103-112g；
(4)将吸附纤维在硝酸银溶液中浸泡5h后取出晾干得到导电抗菌复合纤维，复合纤维上的氨基和巯基通过阳离子交换反应将银离子直接吸附在复合纤维上，使得制备的导电抗菌复合纤维表面含有丰富的银离子，并且银离子与复合纤维之间的作用力较强，后期在衣物清洗过程中不会出现银离子的解吸导致服装导电和抗菌性能的减弱；
第二步，将制备的导电抗菌复合纤维与普通的化纤进行混纺，制成经纱；
第三步，将第二步中得到的经纱通过功能性上浆液进行上浆处理，不仅能够增强经纱的强度，并且对经纱中阴离子进一步固定，同时该功能性上浆液同样具有导电抗菌的性能，使得上浆后的经纱由内到外均具有导电抗菌性能，不会由于后期衣物磨损清洗造成导电抗菌性能的减弱；其中功能性上浆液的具体制备过程为：配置浓度为0.2mol/L的盐酸溶液，向其中加入羧甲基纤维素钠，升温至50℃后搅拌反应2h，继续升温至60℃后保持温度不变，然后同时向其中加入一定量的聚乙二醇和壳聚糖的混合物，恒温搅拌反应5-7h，得到功能性上浆液；其中羧甲基纤维素钠、聚乙二醇和壳聚糖的质量比为12-14:1:1，该功能性上浆液中复合有聚乙二醇，由于聚乙二醇含有醚基和羟基，具有一定的亲水性能，在上浆液粘合在经纱上后，亲水基都朝向空气一侧排列,形成一个单分子导电层，在服装经过摩擦和洗涤后会总成材料表面抗静电剂分子层的缺损，抗静电性能也随之下降，但经过一段时间之后，材料内部的抗静电剂分子又会不断向表面迁移，使缺损部位得以恢复，重新显示出抗静电效果，并且上浆液中的壳聚糖通过酯化反应复合在羧甲基纤维素钠上，可以均匀的在经纱的表面形成一层致密的抗菌薄膜，并能起到永久的抗菌作用，不会由于摩擦和洗涤造成抗菌性能的消失；并且上浆液粘附包裹在经纱的表面能够有效的对经纱中吸附的银离子有一定的制约作用，能够进一步限制银离子的解吸，使得整条经纱都具有较强的导电性能和抗菌性能，不会受湿度和温度的限制；
第四步，将上浆后的经纱进行纺织得到抗菌防静电针织服装。
本发明的有益效果：
本发明制备的复合纤维上具有大量的氨基和巯基，氨基和巯基通过阳离子交换反应将银离子直接吸附在复合纤维上，使得制备的导电抗菌复合纤维表面含有丰富的银离子，并且银离子与复合纤维之间的作用力较强，后期在衣物清洗过程中不会出现银离子的解吸导致服装导电和抗菌性能的减弱。
本发明在经纱表面上浆时使用功能性上浆液，该上浆液自身很强的导电和抗菌性能，在上浆液过程中粘附包裹在经纱的表面能够有效的对经纱中吸附的银离子有一定的制约作用，能够进一步限制银离子的解吸，使得整条经纱都具有较强的导电性能和抗菌性能，不会受服装摩擦和洗涤的影响。
本发明的上浆液中复合有聚乙二醇，由于聚乙二醇含有醚基和羟基，具有一定的亲水性能，在上浆液粘合在经纱上后，亲水基都朝向空气一侧排列,形成一个单分子导电层，在服装经过摩擦和洗涤后会总成材料表面抗静电剂分子层的缺损，抗静电性能也随之下降，但经过一段时间之后，材料内部的抗静电剂分子又会不断向表面迁移，使缺损部位得以恢复，重新显示出抗静电效果。
本发明上浆液中的壳聚糖通过酯化反应复合在羧甲基纤维素钠上，可以均匀的在经纱的表面形成一层致密的抗菌薄膜，并能起到永久的抗菌作用，不会由于摩擦和洗涤造成抗菌性能的消失。
附图说明
为了便于本领域技术人员理解，下面结合附图对本发明作进一步的说明。
图1为本发明导电抗菌复合纤维的制备反应结构式。
具体实施方式
实施例1：
一种抗菌防静电针织服装制造方法，具体制备过程如下：
第一步，制备导电抗菌复合纤维，具体制备过程如下：
(1)将1.2kg合成纤维浸泡于4L质量分数为20％的氢氧化钠溶液中，常温搅拌反应4-5h，除去合成纤维表面的酯基；
(2)在搅拌罐中加入1.5L乙醚溶液，向其中加入144g的2-溴代异戊酸充分溶解后，升温至60℃，将步骤1中处理得到的合成纤维在搅拌罐中恒温浸泡5-7h后取出，然后取出合成纤维在乙醇溶液中浸泡12h后晾干得到复合纤维；
(3)将148g硫脲和4.44kg水加入搅拌罐中，充分溶解后加入57.6g甲醛溶液，搅拌均匀后迅速放入步骤2中得到的复合纤维，然后缓慢升温至60-70℃后保持温度不变浸泡10h，捞出复合纤维后用乙醇冲洗并在40℃下烘干，得到吸附纤维，此时吸附纤维上含有大量的氨基和巯基；
(4)将吸附纤维在银离子浓度为100mg/L的硝酸银溶液中浸泡5h后取出晾干得到导电抗菌复合纤维，该导电抗菌复合纤维的反应结构式如图1所示；
第二步，将制备的导电抗菌复合纤维与普通的化纤进行混纺，制成经纱；
第三步，将第二步中得到的经纱通过功能性上浆液进行上浆处理，其中功能性上浆液的具体制备过程为：配置浓度为0.2mol/L的盐酸溶液1L，向其中加入240g羧甲基纤维素钠，升温至50℃后搅拌反应2h，继续升温至60℃后保持温度不变，然后同时向其中加入20g聚乙二醇和20g壳聚糖的混合物，恒温搅拌反应5-7h，得到功能性上浆液；
第四步，将上浆后的经纱进行纺织得到抗菌防静电针织服装。
实施例2：
一种抗菌防静电针织服装制造方法，具体制备过程如下：
第一步，制备导电抗菌复合纤维，具体制备过程如下：
(1)将1.2kg合成纤维浸泡于4L质量分数为20％的氢氧化钠溶液中，常温搅拌反应4-5h，除去合成纤维表面的酯基；
(2)在搅拌罐中加入1.4L乙醚溶液，向其中加入156g 2-溴代异戊酸充分溶解后，升温至60℃，将步骤1中处理得到的合成纤维在搅拌罐中恒温浸泡5-7h后取出，然后取出合成纤维在乙醇溶液中浸泡12h后晾干得到复合纤维；
(3)将134.4g硫脲和4.02kg水加入搅拌罐中，充分溶解后加入56.4g甲醛溶液，搅拌均匀后迅速放入步骤2中得到的复合纤维，然后缓慢升温至60-70℃后保持温度不变浸泡10h，捞出复合纤维后用乙醇冲洗并在40℃下烘干，得到吸附纤维，此时吸附纤维上含有大量的氨基和巯基；
(4)将吸附纤维在银离子浓度为100mg/L的硝酸银溶液中浸泡5h后取出晾干得到导电抗菌复合纤维；
第二步，将制备的导电抗菌复合纤维与普通的化纤进行混纺，制成经纱；
第三步，将第二步中得到的经纱通过功能性上浆液进行上浆处理；其中功能性上浆液的具体制备过程为：配置1L浓度为0.2mol/L的盐酸溶液，向其中加入羧甲基纤维素钠，升温至50℃后搅拌反应2h，继续升温至60℃后保持温度不变，然后同时向其中加入20g聚乙二醇和20g壳聚糖的混合物，恒温搅拌反应5-7h，得到功能性上浆液；
第四步，将上浆后的经纱进行纺织得到抗菌防静电针织服装。
对比例1：
一种抗菌防静电针织服装制造方法，具体制备过程如下：
第一步，制备导电抗菌复合纤维，具体制备过程与实施例1相同；
第二步，将制备的导电抗菌复合纤维与普通的化纤进行混纺，制成经纱；
第三步，将第二步中得到的经纱通过羧甲基纤维素钠上浆液进行上浆处理；
第四步，将上浆后的经纱进行纺织得到抗菌防静电针织服装。
对比例2：
一种抗菌防静电针织服装制造方法，具体制备过程如下：
第一步，将普通的化纤直接在银离子浓度为100mg/L的硝酸银溶液中浸泡5h后取出晾干得到改性化纤；
第二步，将制备的改性化纤与普通的化纤进行混纺，制成经纱；
第三步，将第二步中得到的经纱通过功能性上浆液进行上浆处理，功能性上浆液的制备方法同实施例1；
第四步，将上浆后的经纱进行纺织得到抗菌防静电针织服装。
对比例3：
第一步，将普通的化纤纺织成经纱；
第二步，将第一步中得到的经纱通过功能性上浆液进行上浆处理，功能性上浆液的制备方法同实施例1；
第三步，将上浆后的经纱进行纺织得到抗菌防静电针织服装。
对比例4：
第一步，将普通的化纤纺织成经纱；
第二步，将第一步中得到的经纱通过羧甲基纤维素钠上浆液进行上浆处理；
第三步，将上浆后的经纱进行纺织得到抗菌防静电针织服装。
性能测试：
将实施例1-2和对比例1-4中制备的抗菌防静电针织服装的一块面料直接进行导电性测试；然后将实施例1-2和对比例1-4中制备的抗菌防静电针织服装的一块面料分别清洗9次后进行导电性能测试；将实施例1-2和对比例1-4中制备的抗菌防静电针织服装的一块面料的两表面分别在粗糙的桌面摩擦30天后进行导电性能测试，测试结构如表1所示：
表1：实施例1-2和对比例1-4中制备的抗菌防静电针织服装的导电参数
由表1可知，经过氨基和巯基功能化后的合成纤维，在吸附银离子后制备的服装的电阻达到2.135，并且电阻率为0.316，大大增加了导电能力，同时与不经过改性直接吸附银离子的合成纤维、没有经过改性的上浆液相比，在经过10次洗涤或者经过30天的粗糙摩擦后该服装仍然具有较高的导电能力。
以上公开的本发明优选实施例只是用于帮助阐述本发明。优选实施例并没有详尽叙述所有的细节，也不限制该发明仅为所述的具体实施方式。显然，根据本说明书的内容，可作很多的修改和变化。本说明书选取并具体描述这些实施例，是为了更好地解释本发明的原理和实际应用，从而使所属技术领域技术人员能很好地理解和利用本发明。本发明仅受权利要求书及其全部范围和等效物的限制。
Claims (6)
1.一种抗菌防静电针织服装制造方法，其特征在于，具体方法如下：
第一步，制备导电抗菌复合纤维，具体制备过程为：
(1)将合成纤维浸泡于质量分数为20％的氢氧化钠溶液中，常温搅拌反应4-5h，除去合成纤维表面的酯基；
(2)在搅拌罐中加入乙醚溶液，向其中加入一定量的2-溴代异戊酸充分溶解后，升温至60℃，将步骤1中处理得到的合成纤维在搅拌罐中恒温浸泡5-7h后取出，然后取出合成纤维在乙醇溶液中浸泡12h后晾干得到复合纤维；
(3)将硫脲和水按照一定比例加入搅拌罐中，充分溶解后加入甲醛溶液，搅拌均匀后迅速放入步骤2中得到的复合纤维，然后缓慢升温至60-70℃后保持温度不变浸泡10h，捞出复合纤维后用乙醇冲洗并在40℃下烘干，得到吸附纤维，此时吸附纤维上含有大量的氨基和巯基；
(4)将吸附纤维在硝酸银溶液中浸泡5h后取出晾干得到导电抗菌复合纤维；
第二步，将制备的导电抗菌复合纤维与普通的化纤进行混纺，制成经纱；
第三步，将第二步中得到的经纱通过功能性上浆液进行上浆处理；
第四步，将上浆后的经纱进行纺织得到抗菌防静电针织服装。
2.根据权利要求1所述的一种抗菌防静电针织服装制造方法，其特征在于，所述第一步步骤1中1L氢氧化钠溶液中加入300g合成纤维。
3.根据权利要求1所述的一种抗菌防静电针织服装制造方法，其特征在于，所述第一步步骤2中1kg合成纤维中加入2-溴代异戊酸的量为120-130g。
4.根据权利要求1所述的一种抗菌防静电针织服装制造方法，其特征在于，所述第一步步骤3中1kg复合纤维中加入甲醛38-47g，加入硫脲103-112g。
5.根据权利要求1所述的一种抗菌防静电针织服装制造方法，其特征在于，所述第三步中功能性上浆液的具体制备过程为：配置浓度为0.2mol/L的盐酸溶液，向其中加入羧甲基纤维素钠，升温至50℃后搅拌反应2h，继续升温至60℃后保持温度不变，然后同时向其中加入一定量的聚乙二醇和壳聚糖的混合物，恒温搅拌反应5-7h，得到功能性上浆液。
6.根据权利要求5所述的一种抗菌防静电针织服装制造方法，其特征在于，羧甲基纤维素钠、聚乙二醇和壳聚糖的质量比为12-14:1:1。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810387776.1A CN108486860B (zh) | 2018-04-26 | 2018-04-26 | 一种抗菌防静电针织服装制造方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810387776.1A CN108486860B (zh) | 2018-04-26 | 2018-04-26 | 一种抗菌防静电针织服装制造方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN108486860A true CN108486860A (zh) | 2018-09-04 |
| CN108486860B CN108486860B (zh) | 2019-03-01 |
Family
ID=63313243
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810387776.1A Expired - Fee Related CN108486860B (zh) | 2018-04-26 | 2018-04-26 | 一种抗菌防静电针织服装制造方法 |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108486860B (zh) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113290967A (zh) * | 2021-02-24 | 2021-08-24 | 湖州师范学院 | 一种抗菌童装面料及其加工方法和应用 |
| CN114395912A (zh) * | 2021-06-29 | 2022-04-26 | 台湾塑胶工业股份有限公司 | 抗菌纤维的制造方法 |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101586310A (zh) * | 2009-06-18 | 2009-11-25 | 浙江理工大学 | 一种导电纤维及其制备方法 |
| CN106436288A (zh) * | 2016-09-30 | 2017-02-22 | 天津工业大学 | 一种导电氨纶丝或棉织物的制备方法 |
| CN106917267A (zh) * | 2017-04-20 | 2017-07-04 | 河南工程学院 | 一种抗菌高效过滤无纺布的制备方法 |
-
2018
- 2018-04-26 CN CN201810387776.1A patent/CN108486860B/zh not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101586310A (zh) * | 2009-06-18 | 2009-11-25 | 浙江理工大学 | 一种导电纤维及其制备方法 |
| CN106436288A (zh) * | 2016-09-30 | 2017-02-22 | 天津工业大学 | 一种导电氨纶丝或棉织物的制备方法 |
| CN106917267A (zh) * | 2017-04-20 | 2017-07-04 | 河南工程学院 | 一种抗菌高效过滤无纺布的制备方法 |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113290967A (zh) * | 2021-02-24 | 2021-08-24 | 湖州师范学院 | 一种抗菌童装面料及其加工方法和应用 |
| CN113290967B (zh) * | 2021-02-24 | 2022-04-22 | 湖州师范学院 | 一种抗菌童装面料及其加工方法和应用 |
| CN114395912A (zh) * | 2021-06-29 | 2022-04-26 | 台湾塑胶工业股份有限公司 | 抗菌纤维的制造方法 |
| CN114395912B (zh) * | 2021-06-29 | 2024-04-16 | 台湾塑胶工业股份有限公司 | 抗菌纤维的制造方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| CN108486860B (zh) | 2019-03-01 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105200773B (zh) | 壳聚糖改性织物的纳米银涂层制备方法 | |
| CN108486860B (zh) | 一种抗菌防静电针织服装制造方法 | |
| WO2016165649A1 (zh) | 一种耐盐、耐洗涤剂海藻纤维的制备方法 | |
| CN113403835B (zh) | 一种超薄超弹排汗面料的制备方法 | |
| CN115323577A (zh) | 一种耐磨抗菌面料及其制备方法 | |
| CN108950807A (zh) | 抗皱面料及其制备方法 | |
| CN102430435A (zh) | 多功能螯合离子交换纤维及其制备方法和应用 | |
| JP2006508276A5 (zh) | ||
| CN113152074B (zh) | 一种氨纶包覆丝及其制备方法及应用该包覆丝的内衣面料 | |
| CN109972279A (zh) | 一种宽幅凉爽混纺面料的制备方法 | |
| CN113897782A (zh) | 一种抗菌面料的制备方法 | |
| CN113564791A (zh) | 一种玄武岩纤维针织布的制备工艺 | |
| CN103046385A (zh) | 一种粗纺可机洗纯羊毛面料的制造工艺 | |
| TWI670403B (zh) | 紡紗用麻纖維之製造方法及紡紗用麻纖維 | |
| CN105951268A (zh) | 一种棉麻复合功能面料 | |
| CN107653533A (zh) | 一种抗菌、防臭夏季衬衫面料的制备方法 | |
| CN110219172A (zh) | 一种高挂干外观免烫面料及其制备方法 | |
| CN115110198A (zh) | 具有凉感功能的面料及其制备方法 | |
| CN111519436B (zh) | 一种添加有石墨烯的服装面料生产工艺 | |
| CN102500432A (zh) | 超级螯合离子交换纤维 | |
| CN108951176A (zh) | 一种改善涤纶织物亲水性的处理工艺 | |
| CN111826946A (zh) | 一种羊毛石墨烯混纺纱及面料的生产方法 | |
| CN117818189B (zh) | 一种耐磨抗菌防水pu复合面料 | |
| CN112080834A (zh) | 一种超疏水棉麻纺织面料的制备方法 | |
| CN115352138B (zh) | 一种抗静电寝具面料及制备工艺 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20191125 Address after: 523000 No.1, xinhongchang Road, Changping village, Daojiao Town, Dongguan City, Guangdong Province Patentee after: Dongguan souyute Design Co.,Ltd. Address before: 510145 Room 309, long Jin Xi Road, Liwan District, Guangzhou, Guangdong, 309 Patentee before: GUANGZHOU CHAOXUAN CLOTHES CO.,LTD. |
|
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20190301 |