CN108383793B - 在溶液中制备卡宾的方法、尤其通过该方法获得的卡宾的新的稳定形式及其在催化中的应用 - Google Patents

在溶液中制备卡宾的方法、尤其通过该方法获得的卡宾的新的稳定形式及其在催化中的应用 Download PDF

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CN108383793B
CN108383793B CN201711439210.0A CN201711439210A CN108383793B CN 108383793 B CN108383793 B CN 108383793B CN 201711439210 A CN201711439210 A CN 201711439210A CN 108383793 B CN108383793 B CN 108383793B
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carbene
alkyl
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CN108383793A (zh
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C·马利维尔尼
L·圣-雅尔姆斯
S·戈容
T·卡托
A·J·巴塞拉杜
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Elkem Silicones France SAS
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/72—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from metals not provided for in group C08F4/44
    • C08F4/80—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from metals not provided for in group C08F4/44 selected from iron group metals or platinum group metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D233/00—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings
    • C07D233/04—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member
    • C07D233/06—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member with only hydrogen atoms or radicals containing only hydrogen and carbon atoms, directly attached to ring carbon atoms
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D233/00—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings
    • C07D233/54—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members
    • C07D233/56—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members with only hydrogen atoms or radicals containing only hydrogen and carbon atoms, attached to ring carbon atoms
    • C07D233/58—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members with only hydrogen atoms or radicals containing only hydrogen and carbon atoms, attached to ring carbon atoms with only hydrogen atoms or radicals containing only hydrogen and carbon atoms, attached to ring nitrogen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04—Polysiloxanes
    • C08G77/06—Preparatory processes
    • C08G77/08—Preparatory processes characterised by the catalysts used

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  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Silicon Polymers (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CN201711439210.0A 2010-01-08 2011-01-07 在溶液中制备卡宾的方法、尤其通过该方法获得的卡宾的新的稳定形式及其在催化中的应用 Active CN108383793B (zh)

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Application Number Priority Date Filing Date Title
FR1050108 2010-01-08
FR1050108 2010-01-08
PCT/EP2011/050175 WO2011083146A1 (fr) 2010-01-08 2011-01-07 Procede de preparation de carbene en solution, nouvelle forme stable de carbene obtenu notamment par ce procede et applications de celle-ci en catalyse.
CN2011800106123A CN102985409A (zh) 2010-01-08 2011-01-07 在溶液中制备卡宾的方法、尤其通过该方法获得的卡宾的新的稳定形式及其在催化中的应用

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CN108383793B true CN108383793B (zh) 2022-04-05

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CN2011800106123A Pending CN102985409A (zh) 2010-01-08 2011-01-07 在溶液中制备卡宾的方法、尤其通过该方法获得的卡宾的新的稳定形式及其在催化中的应用

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EP (1) EP2542532B8 (enExample)
JP (2) JP5702403B2 (enExample)
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WO2008103769A1 (en) 2007-02-20 2008-08-28 Haiyun Tang High dynamic range transceiver for cognitive radio
KR101653068B1 (ko) * 2011-07-07 2016-08-31 블루스타 실리콘즈 프랑스 에스에이에스 카르벤-유형 촉매의 존재 하에서 탈수소 축합 반응에 의해 가교될 수 있는 실리콘 조성물
CN107922621B (zh) * 2015-07-27 2021-05-14 美国道康宁公司 具有基于金属的n-杂环碳烯缩合反应催化剂的聚有机硅氧烷组合物及其制备方法
PL238806B1 (pl) 2015-09-30 2021-10-04 Apeiron Synthesis Spolka Akcyjna Kompleks rutenu i sposób jego wytwarzania, związek pośredni stosowany w tym sposobie oraz zastosowanie kompleksu rutenu i związku pośredniego w metatezie olefin
KR102313503B1 (ko) * 2018-05-23 2021-10-15 국방과학연구소 N-헤테로고리 카벤 착화합물의 제조 방법, 이의 제조 방법으로 제조된 n-헤테로고리 카벤 착화합물 및 이를 이용한 폴리우레탄의 중합 지연 방법
KR102081916B1 (ko) * 2018-07-17 2020-02-26 전남대학교산학협력단 폴리우레탄 중합지연촉매 및 이를 이용한 폴리우레탄 중합지연방법
EP3901135A1 (en) * 2020-04-22 2021-10-27 Universität Heidelberg Sulfur extrusion from disulfides by carbenes
US11319613B2 (en) 2020-08-18 2022-05-03 Enviro Metals, LLC Metal refinement

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1511064A (zh) * 2001-03-23 2004-07-07 ����ʯ��ѧԺ 采用热活化n-杂环卡宾前体制备的高活性金属卡宾易位催化剂
CN1564795A (zh) * 2001-10-06 2005-01-12 奥克森诺奥勒芬化学股份有限公司 使用钯卡宾化合物制备1－烯烃的方法

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5077414A (en) 1990-03-29 1991-12-31 E. I. Du Pont De Nemours And Company Preparation of 1,3-disubstituted imidazolium salts
WO1998039346A1 (en) 1997-03-06 1998-09-11 Ciba Specialty Chemicals Holding Inc. New catalysts
GB0008707D0 (en) 2000-04-07 2000-05-31 Bp Chem Int Ltd Imidazole carbenes
FR2825709B1 (fr) 2001-06-07 2005-07-01 Rhodia Chimie Sa Composition silicone reticulable en elastomere par hydrosilylation, en presence de catalyseurs metalliques a base de carbenes, et catalyseurs de ce type
FR2864543B1 (fr) * 2003-12-30 2006-03-03 Rhodia Chimie Sa Procede de preparation de polyorganosiloxanes (pos) par polymerisation par ouverture de cycle(s) et/ou redistribution de pos, en presence de carbene(s) et compositions de pos mises en oeuvre dans ce procede
JP4538603B2 (ja) * 2004-07-08 2010-09-08 独立行政法人産業技術総合研究所 カルバミン酸エステルの製造方法
FR2900153B1 (fr) 2006-04-21 2008-07-18 Rhodia Recherches & Tech Procede de condensation de motifs silyles a l'aide d'un catalyseur de type carbene

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1511064A (zh) * 2001-03-23 2004-07-07 ����ʯ��ѧԺ 采用热活化n-杂环卡宾前体制备的高活性金属卡宾易位催化剂
CN1564795A (zh) * 2001-10-06 2005-01-12 奥克森诺奥勒芬化学股份有限公司 使用钯卡宾化合物制备1－烯烃的方法

Non-Patent Citations (4)

* Cited by examiner, † Cited by third party
Title
Copper(I) halide complexes of the new 4,40-bridged heteroaromatic biscarbenes of the 1,2,4-triazole series;Arthur V. Knishevitsky et al.;《Journal of Organometallic Chemistry》;20070823;第693卷;第1405-1411页 *
Proton Affinities of N-Heterocyclic Carbene Super Bases;Hao Chen et al.;《ORGANIC LETTERS》;20050804;第7卷(第18期);第3949-3952页 *
Synthesis and Activity of a New Generation of Ruthenium-Based Olefin Metathesis Catalysts Coordinated with 1,3-Dimesityl-4,5-dihydroimidazol-2-ylidene Ligands;Matthias Scholl et al.;《Org. Lett.》;19991231;第1卷(第6期);第953-956页 *
Synthesis and Activity of Ruthenium Alkylidene Complexes Coordinated with Phosphine and N-Heterocyclic Carbene Ligands;Tina M. Trnka et al.;《J. AM. CHEM. SOC.》;20031231;第125卷;第2546-2558页 *

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Publication number Publication date
US9499643B2 (en) 2016-11-22
JP2015096531A (ja) 2015-05-21
WO2011083146A1 (fr) 2011-07-14
KR20180077335A (ko) 2018-07-06
EP2542532B8 (fr) 2018-02-14
JP2013532117A (ja) 2013-08-15
CN102985409A (zh) 2013-03-20
KR102004586B1 (ko) 2019-07-26
KR20120104624A (ko) 2012-09-21
US20130158274A1 (en) 2013-06-20
CN108383793A (zh) 2018-08-10
KR20150091539A (ko) 2015-08-11
JP5702403B2 (ja) 2015-04-15
EP2542532A1 (fr) 2013-01-09
EP2542532B1 (fr) 2018-01-03

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