CN108273088A - A kind of sterilizing method for pasture - Google Patents
A kind of sterilizing method for pasture Download PDFInfo
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- CN108273088A CN108273088A CN201810100976.4A CN201810100976A CN108273088A CN 108273088 A CN108273088 A CN 108273088A CN 201810100976 A CN201810100976 A CN 201810100976A CN 108273088 A CN108273088 A CN 108273088A
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- pasture
- sterilizing method
- disinfectant
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L2/00—Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor
- A61L2/16—Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor using chemical substances
- A61L2/18—Liquid substances or solutions comprising solids or dissolved gases
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/08—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing solids as carriers or diluents
- A01N25/10—Macromolecular compounds
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N33/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds
- A01N33/02—Amines; Quaternary ammonium compounds
- A01N33/12—Quaternary ammonium compounds
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/50—1,3-Diazoles; Hydrogenated 1,3-diazoles
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
- A01N65/40—Liliopsida [monocotyledons]
- A01N65/42—Aloeaceae [Aloe family] or Liliaceae [Lily family], e.g. aloe, veratrum, onion, garlic or chives
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L2202/00—Aspects relating to methods or apparatus for disinfecting or sterilising materials or objects
- A61L2202/20—Targets to be treated
- A61L2202/25—Rooms in buildings, passenger compartments
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- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Agronomy & Crop Science (AREA)
- Plant Pathology (AREA)
- Dentistry (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Biotechnology (AREA)
- Natural Medicines & Medicinal Plants (AREA)
- Microbiology (AREA)
- Mycology (AREA)
- Toxicology (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Epidemiology (AREA)
- Animal Behavior & Ethology (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention provides a kind of sterilizing method for pasture, which is:Spray disinfectant agent is given up to the field in pasture, the disinfectant is made by the following method:1)Chinese herbal medicine, ethyl alcohol and Peracetic acid are decocted, then filter to take filtrate so that extracting solution is made;2)Under ultrasound condition, extracting solution, nano-attapulgite, metronidazole, quaternary ammonium salt are subjected to adsorption treatment, then filtered so that modified nano concave good soil is made;3)Modified nano concave good soil, cyclodextrin and water are subjected to ultrasonic vibration so that disinfectant is made;Wherein, Chinese herbal medicine is the fruit of Rangoon creeper, betel nut, dandelion, radix paeoniae rubra, sweet wormwood, rheum officinale, wrinkled giant hyssop, garlic seed and peppermint.The sterilizing method for being used for pasture has excellent Disinfection Effect.
Description
Technical field
The present invention relates to disinfectants, and in particular, to a kind of sterilizing method for pasture.
Background technology
Animal husbandry refer to herd, stable breeding or the two combine mode, raising livestock and poultry to obtain animal product or the draught animal
Production division.It include livestock raise herd, home poultry raising, economic beasts are raised and train.Animal husbandry has important in national economy
Status and effect, predominantly:1. providing the animal foods such as meat, milk, eggs;2. for industry provide wool, cashmere, skin,
The raw materials such as hair on the neck, beast bone, casing;3. exporting acquisition of foreign currency by livestock products;4. the industry of animal husbandry input and livestock products is promoted to add
Industrial expansion increases labour employment chance;5. providing organic fertilizer for production estimation;6. increasing farmers' income;7. being agriculture
Industry and transportation provide animal power;8. promoting the economy and cultural development in vast pastoral area, strengthen the unity among nationalities.Thus
As it can be seen that the development of country is to be unable to do without the support of animal husbandry.
It during developing animal husbandry, often needs to sterilize, especially the disinfection to field house.Currently, field house disappears
Poison is carried out disinfection using chemically synthesized organic disinfectant, although certain Disinfection Effect can be obtained;But change
On the one hand the health of livestock can be adversely affected by learning the reagent of synthesis, and then affect the meat and hair cortex of livestock
Amount, the chemically synthesized reagent of another aspect can cause environmental pollution.
Invention content
The object of the present invention is to provide a kind of sterilizing methods for pasture, this is used for the sterilizing method in pasture
With excellent Disinfection Effect, and it is milder, nuisanceless to environment and livestock.
The technical solution adopted in the present invention is:
A kind of sterilizing method for pasture, which is characterized in that the sterilizing method is:It gives up and sprays to the field in pasture
Disinfectant is spilt, the disinfectant is made by the following method:1)Chinese herbal medicine, ethyl alcohol and Peracetic acid are decocted, then mistake
Leaching filtrate is to be made extracting solution;2)Under ultrasound condition, by the extracting solution, nano-attapulgite, metronidazole, quaternary ammonium salt into
Then row adsorption treatment is filtered so that modified nano concave good soil is made;3)By the modified nano concave good soil, cyclodextrin and water
Ultrasonic vibration is carried out so that the disinfectant is made;Wherein, the Chinese herbal medicine be the fruit of Rangoon creeper, it is betel nut, dandelion, radix paeoniae rubra, sweet wormwood, big
Yellow and wrinkled giant hyssop;Wherein, in step 1)In, the weight ratio of the Chinese herbal medicine, ethyl alcohol and Peracetic acid is 15:40-45:3-8;Institute
State in Chinese herbal medicine, the fruit of Rangoon creeper, betel nut, dandelion, radix paeoniae rubra, sweet wormwood, rheum officinale, wrinkled giant hyssop, peppermint, garlic seed weight ratio be 20:
11-12:6-8:15-18:5-8:8-10:10-12:3-6:5-8.
Further, the decoction meets the following conditions:It is 80-85 DEG C to decoct temperature, decocting time 5-6h.
Wherein, in step 2)In, the extracting solution, nano-attapulgite, metronidazole, quaternary ammonium salt weight ratio be 100:
25-35:3-5:0.5-1.2.
Wherein, in step 2)In, the adsorption treatment meets the following conditions:Treatment temperature is 50-68 DEG C, and processing time is
9-10h, supersonic frequency 40-46KHz.
Wherein, in step 3)In, the weight ratio of the modified nano concave good soil, cyclodextrin and water is 10:4-6:260-
300。
Wherein, in step 3)In, the ultrasonic vibration meets the following conditions:Shake temperature be 35-45 DEG C, concussion the time be
6h, supersonic frequency 55KHz.
Further, the average grain diameter of the nano-attapulgite is 35-40nm.
Further, the sprinkling frequency of the liquid medicine is 3 times/day.
Further, each fountain height of the liquid medicine is 55-60mL/m2。
In the above-mentioned technical solutions, the present invention passes through first by the mixed liquor of ethyl alcohol and Peracetic acid composition to Chinese herbal medicine
Decoct and then obtains extracting solution;Then, by nano-attapulgite to extracting solution, metronidazole, quaternary ammonium salt adsorbed into
And modified nano concave good soil is made;Then, modified nano concave good soil is coated by cyclodextrin, while is pasted using ring
The outer rim of essence is hydrophilic and characteristic that inner cavity is hydrophobic is so as to soluble in water and then obtained disinfectant.By the disinfectant to field
House carries out disinfection and can obtain excellent Disinfection Effect, while milder, nuisanceless to environment and livestock.
Other features and advantages of the present invention will be described in detail in subsequent specific embodiment part.
Specific implementation mode
The specific implementation mode of the present invention is described in detail below.It should be understood that described herein specific
Embodiment is merely to illustrate and explain the present invention, and is not intended to restrict the invention.
The present invention provides a kind of sterilizing methods for pasture to be:Spray disinfectant agent is given up to the field in pasture, it is described
Disinfectant is made by the following method:
1)Chinese herbal medicine, ethyl alcohol and Peracetic acid are decocted, then filter to take filtrate so that extracting solution is made;
2)Under ultrasound condition, by extracting solution, nano-attapulgite, metronidazole, quaternary ammonium salt carry out adsorption treatment, then filter with
Modified nano concave good soil is made;
3)Modified nano concave good soil, cyclodextrin and water are subjected to ultrasonic vibration so that disinfectant is made;
Wherein, Chinese herbal medicine is the fruit of Rangoon creeper, betel nut, dandelion, radix paeoniae rubra, sweet wormwood, rheum officinale, wrinkled giant hyssop, garlic seed and peppermint.
In the step 1 of the present invention)In, the dosage of each material can select in a wide range, but in order to make the disinfection
Method has superior Disinfection Effect and mildness, it is preferable that in step 1)In, Chinese herbal medicine, ethyl alcohol and Peracetic acid
Weight ratio is 10:35-45:2-7;In Chinese herbal medicine, the fruit of Rangoon creeper, betel nut, dandelion, radix paeoniae rubra, sweet wormwood, rheum officinale, wrinkled giant hyssop, garlic seed and
The weight ratio of peppermint is 18:10-12:6-8:15-20:5-6:8-10:5-8:5-10:3-6.
In the step 1 of the present invention)In, the condition of decoction can select in a wide range, but in order to make the disinfection side
Method has superior Disinfection Effect and mildness, it is preferable that decoction meets the following conditions:It is 79-83 DEG C to decoct temperature, is decocted
It is 2-4h to boil the time.
In the step 2 of the present invention)In, the dosage of each substance can select in a wide range, but in order to make the disinfection
Method has superior Disinfection Effect and mildness, it is preferable that in step 2)In, extracting solution, nano-attapulgite, first nitre
Azoles, quaternary ammonium salt weight ratio be 100:30-40:1-3:0.2-0.9.
In the step 2 of the present invention)In, the condition of adsorption treatment can select in a wide range, but in order to make this disappear
Malicious method has superior Disinfection Effect and mildness, it is preferable that in step 2)In, adsorption treatment meets the following conditions:
Treatment temperature is 55-65 DEG C, processing time 6-8h, supersonic frequency 34-38KHz.
In the step 3 of the present invention)In, the dosage of each substance can select in a wide range, but in order to make the disinfection
Method has superior Disinfection Effect and mildness, it is preferable that in step 3)In, modified nano concave good soil, cyclodextrin
Weight ratio with water is 10:4-6:225-250.
In the step 3 of the present invention)In, the condition of ultrasonic vibration can select in a wide range, but in order to make this disappear
Malicious method has superior Disinfection Effect and mildness, it is preferable that in step 3)In, ultrasonic vibration meets the following conditions:
It is 15-35 DEG C to shake temperature, and the concussion time is 3-5h, supersonic frequency 45-50KHz.
In the present invention, the average grain diameter of nano-attapulgite can select in a wide range, but in order to make this disappear
Malicious method has superior Disinfection Effect and mildness, it is preferable that the average grain diameter of nano-attapulgite is 15-30nm.
In the present invention, the sprinkling frequency of liquid medicine can select in a wide range, but in order to make the sterilization method have
There is superior Disinfection Effect, it is preferable that the sprinkling frequency of liquid medicine is 1-2 times/day.
In the present invention, the fountain height of liquid medicine can select in a wide range, but in order to make the sterilization method have
Superior Disinfection Effect, it is preferable that each fountain height is 30-50mL/m2。
The present invention will be described in detail by way of examples below.
Embodiment 1
1)By Chinese herbal medicine(The fruit of Rangoon creeper, betel nut, dandelion, radix paeoniae rubra, sweet wormwood, rheum officinale, wrinkled giant hyssop, peppermint and garlic seed weight ratio be 16:
13:8:18:7:10:13:3:10), ethyl alcohol and Peracetic acid be according to 10:40:6 weight ratio is decocted(It is 80 to decoct temperature
DEG C, decocting time 3h), filtrate is then filtered to take so that extracting solution is made;
2)Under ultrasound condition, by extracting solution, nano-attapulgite(Average grain diameter is 20nm), metronidazole, quaternary ammonium salt according to
100:35:2:0.6 weight ratio carries out adsorption treatment(Treatment temperature is 60 DEG C, processing time 7h, and supersonic frequency is
36KHz), then filter so that modified nano concave good soil is made;
3)By modified nano concave good soil, cyclodextrin and water according to 10:5:225 weight ratio carries out ultrasonic vibration(Shake temperature
It it is 25 DEG C, the concussion time is 4h, supersonic frequency 48KHz)Disinfectant A1 is made.
Embodiment 2
1)By Chinese herbal medicine(The fruit of Rangoon creeper, betel nut, dandelion, radix paeoniae rubra, sweet wormwood, rheum officinale, wrinkled giant hyssop, peppermint and garlic seed weight ratio be 18:
8:6:12:5:8:7:2:6), ethyl alcohol and Peracetic acid be according to 10:35:2 weight ratio is decocted(It is 79 DEG C to decoct temperature, is decocted
It is 2h to boil the time), filtrate is then filtered to take so that extracting solution is made;
2)Under ultrasound condition, by extracting solution, nano-attapulgite(Average grain diameter is 15nm), metronidazole, quaternary ammonium salt according to
100:30:1:0.2 weight ratio carries out adsorption treatment(Treatment temperature is 55 DEG C, processing time 6h, and supersonic frequency is
34KHz), then filter so that modified nano concave good soil is made;
3)By modified nano concave good soil, cyclodextrin and water according to 10:4:240 weight ratio carries out ultrasonic vibration(Shake temperature
It it is 15 DEG C, the concussion time is 3h, supersonic frequency 45KHz)Disinfectant A2 is made.
Embodiment 3
1)By Chinese herbal medicine(The fruit of Rangoon creeper, betel nut, dandelion, radix paeoniae rubra, sweet wormwood, rheum officinale, wrinkled giant hyssop, peppermint and garlic seed weight ratio be 15:
12:10:18:10:12:16:3:12), ethyl alcohol and Peracetic acid be according to 10:45:7 weight ratio is decocted(Decocting temperature is
83 DEG C, decocting time 4h), filtrate is then filtered to take so that extracting solution is made;
2)Under ultrasound condition, by extracting solution, nano-attapulgite(Average grain diameter is 30nm), metronidazole, quaternary ammonium salt according to
100:40:3:0.9 weight ratio carries out adsorption treatment(Treatment temperature is 65 DEG C, processing time 8h, and supersonic frequency is
38KHz), then filter so that modified nano concave good soil is made;
3)By modified nano concave good soil, cyclodextrin and water according to 10:6:250 weight ratio carries out ultrasonic vibration(Shake temperature
It it is 35 DEG C, the concussion time is 5h, supersonic frequency 50KHz)Disinfectant A3 is made.
Comparative example 1
It carries out that disinfectant B1 is made according to the method for embodiment 1, unlike, step 2)Extracting solution is not used.
Comparative example 2
It carries out that disinfectant B2 is made according to the method for embodiment 1, unlike, step 3)Cyclodextrin is not used.
Application examples 1
It is given up using Farm as sterilization objects in this test example;6 pieces of cowshed are taken respectively while detecting the bacterium colony of bacterium in cowshed
Density 1;Then above-mentioned disinfectant is periodically sprinkled, daily sprinkling 3 times, each fountain height is 30mL/m2, continuous sprinkling 3 days, so
The colony density 2 of bacterium in cowshed is detected afterwards;Wherein blank control group spray water;Concrete outcome is shown in Table 1.
Table 1
The substance of sprinkling | Colony density 1(CFU/dm2) | Colony density 2(CFU/dm2) |
A1 | 40 | 1 |
A2 | 35 | 1 |
A3 | 42 | 2 |
B1 | 41 | 34 |
B2 | 38 | 23 |
Water | 35 | 50 |
The preferred embodiment of the present invention has been described above in detail, still, the tool during present invention is not limited to the embodiments described above
Body details can carry out a variety of simple variants, these letters to technical scheme of the present invention within the scope of the technical concept of the present invention
Monotropic type all belongs to the scope of protection of the present invention.
Meanwhile it should be noted that:Specific technical features described in the above specific embodiments,
It in the case of reconcilable, can be combined by any suitable means, in order to avoid unnecessary repetition, the present invention is to each
The possible combination of kind no longer separately illustrates.In addition, can also be appointed between a variety of different embodiments of the present invention
Meaning combination, as long as it does not violate the idea of the present invention, it should also be regarded as the disclosure of the present invention.
Claims (9)
1. a kind of sterilizing method for pasture, which is characterized in that the sterilizing method is:It is given up to the field in pasture
Spray disinfectant agent, the disinfectant are made by the following method:1)Chinese herbal medicine, ethyl alcohol and Peracetic acid are decocted, then
Filtrate is filtered to take so that extracting solution is made;2)Under ultrasound condition, by the extracting solution, nano-attapulgite, metronidazole, quaternary ammonium salt
Adsorption treatment is carried out, is then filtered so that modified nano concave good soil is made;3)By the modified nano concave good soil, cyclodextrin and
Water carries out ultrasonic vibration so that the disinfectant is made;Wherein, the Chinese herbal medicine be the fruit of Rangoon creeper, betel nut, dandelion, radix paeoniae rubra, sweet wormwood,
Rheum officinale and wrinkled giant hyssop;Wherein, in step 1)In, the weight ratio of the Chinese herbal medicine, ethyl alcohol and Peracetic acid is 15:40-45:3-8;
In the Chinese herbal medicine, the fruit of Rangoon creeper, betel nut, dandelion, radix paeoniae rubra, sweet wormwood, rheum officinale, wrinkled giant hyssop, peppermint, garlic seed weight ratio be
20:11-12:6-8:15-18:5-8:8-10:10-12:3-6:5-8.
2. the sterilizing method according to claim 1 for pasture, wherein the decoction meets the following conditions:It decocts
It is 80-85 DEG C to boil temperature, decocting time 5-6h.
3. the sterilizing method for pasture according to any one of claim 1-2, wherein in step 2)In,
The extracting solution, nano-attapulgite, metronidazole, quaternary ammonium salt weight ratio be 100:25-35:3-5:0.5-1.2.
4. the sterilizing method according to claim 3 for pasture, wherein in step 2)In, the adsorption treatment
Meet the following conditions:Treatment temperature is 50-68 DEG C, processing time 9-10h, supersonic frequency 40-46KHz.
5. the sterilizing method for pasture according to claim 1-2, any one of 4, wherein in step 3)
In, the weight ratio of the modified nano concave good soil, cyclodextrin and water is 10:4-6:260-300.
6. the sterilizing method for pasture according to claim 1-2, any one of 4, wherein in step 3)
In, the ultrasonic vibration meets the following conditions:It is 35-45 DEG C to shake temperature, and the concussion time is 6h, supersonic frequency 55KHz.
7. the sterilizing method for pasture according to claim 1-2, any one of 4, wherein the nanometer is recessed
The average grain diameter of convex stick soil is 35-40nm.
8. the sterilizing method for pasture according to claim 1-2, any one of 4, wherein the liquid medicine
It is 3 times/day to spray frequency.
9. the sterilizing method according to claim 8 for pasture, wherein each fountain height is 55-60mL/m2。
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CN201810100976.4A CN108273088A (en) | 2018-02-01 | 2018-02-01 | A kind of sterilizing method for pasture |
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Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106234458A (en) * | 2016-08-20 | 2016-12-21 | 裕龙农牧科技股份有限公司 | A kind of pig farm compound Chinese herb disinfectant |
CN106823678A (en) * | 2017-04-14 | 2017-06-13 | 明光市安盛非金属材料厂 | A kind of attapulgite sterilization deodorant and preparation method |
-
2018
- 2018-02-01 CN CN201810100976.4A patent/CN108273088A/en not_active Withdrawn
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106234458A (en) * | 2016-08-20 | 2016-12-21 | 裕龙农牧科技股份有限公司 | A kind of pig farm compound Chinese herb disinfectant |
CN106823678A (en) * | 2017-04-14 | 2017-06-13 | 明光市安盛非金属材料厂 | A kind of attapulgite sterilization deodorant and preparation method |
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