CN103864512B - A kind of nano biological environment protection multifunctional organic bamboo vinegar medicine is fertile - Google Patents

A kind of nano biological environment protection multifunctional organic bamboo vinegar medicine is fertile Download PDF

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CN103864512B
CN103864512B CN201410051071.4A CN201410051071A CN103864512B CN 103864512 B CN103864512 B CN 103864512B CN 201410051071 A CN201410051071 A CN 201410051071A CN 103864512 B CN103864512 B CN 103864512B
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bamboo vinegar
radix
silicon dioxide
raw material
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CN103864512A (en
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李世平
刘嘉城
李代华
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Guilin Hongtian Biochemical Co., Ltd.
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GUILIN TANBAO BIOLOGICAL ENERGY SCIENCE & TECHNOLOGY Co Ltd
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Abstract

The invention discloses a kind of nano biological environment protection multifunctional organic bamboo vinegar medicine fertile, it contains following raw material: bamboo vinegar liquid 31 ~ 46 parts, nano silicon dioxide sol 2 ~ 16 parts, potassium primary phosphate 1 ~ 2 part, spraying conerete foliage fertilizer 0.2 ~ 0.3 part, Kuliansu 0.6 ~ 0.8 part, Radix Aconiti Kusnezoffii extract 0.6 ~ 0.8 part, Oxymatyine 0.6 ~ 0.8 part, sapindoside 0.3 ~ 0.6 part, Radix Et Rhizoma Rhei anthraquinone 0.2 ~ 0.6 part, natural pyrethrum essential oil 0.15 ~ 0.16 part, Radix et Caulis Opuntiae Dillenii extract 2 ~ 4 parts, water is appropriate, by each raw material mixed dissolution.Bamboo vinegar medicine fertilizer of the present invention can be used as soil redeposition, and the heavy metal in absorption soil, reduces the heavy metal content in farm crop, thus improves the quality of farm crop.

Description

A kind of nano biological environment protection multifunctional organic bamboo vinegar medicine is fertile
Technical field
The present invention relates to a kind of nano biological environment protection multifunctional organic bamboo vinegar medicine fertilizer and application thereof.
Background technology
Due to developing rapidly of industry-by-industry in recent years, cause severe contamination to environment, the physiological disease of the farm crop such as fruit tree, vegetables occurs again and again, and checking have impact on the yield and quality of farm crop.Medicine fertilizer is the new technology agriculturally adopted in recent years, refer to one or more the function having and kill and press down in diseases and pests of agronomic crop or plant growth adjustment, and nutrition can be provided for farm crop or there is the multi-Functional Fertilizers providing nutrition and improve fertilizer and agricultural chemicals utilization ratio simultaneously.
The fertile bag of the medicine adopted both at home and abroad is at present all add chemical pesticide in fertilizer, although enhance diseases prevention worm effect, unfriendly to environment.Along with development in science and technology progress, reduce and use chemical pesticide, the cry of protection environment for human survival grows to even greater heights, and researchs and develops the important topic that a kind of environmentally friendly biological medicine fertilizer becomes this area.
Summary of the invention
For deficiency existing in prior art, the object of the present invention is to provide a kind of nano biological environment protection multifunctional organic bamboo vinegar medicine fertilizer and application thereof.
The technical solution used in the present invention is:
A kind of nano biological environment protection multifunctional organic bamboo vinegar medicine is fertile, containing following raw material: bamboo vinegar liquid 31 ~ 46 parts, nano silicon dioxide sol 2 ~ 16 parts, potassium primary phosphate 1 ~ 2 part, spraying conerete foliage fertilizer 0.2 ~ 0.3 part, Kuliansu 0.6 ~ 0.8 part, Radix Aconiti Kusnezoffii extract 0.6 ~ 0.8 part, Oxymatyine 0.6 ~ 0.8 part, sapindoside 0.3 ~ 0.6 part, Radix Et Rhizoma Rhei anthraquinone 0.2 ~ 0.6 part, natural pyrethrum essential oil 0.15 ~ 0.16 part, Radix et Caulis Opuntiae Dillenii extract 2 ~ 4 parts, water is appropriate, by each raw material mixed dissolution.
As preferably, described bamboo vinegar medicine fertilizer is made up of following raw material: bamboo vinegar liquid 46 parts, nano silicon dioxide sol 10 parts, potassium primary phosphate 2 parts, spraying conerete foliage fertilizer 0.2 part, Kuliansu 0.8 part, Radix Aconiti Kusnezoffii extract 0.6 part, Oxymatyine 0.6 part, sapindoside 0.5 part, Radix Et Rhizoma Rhei anthraquinone 0.5 part, natural pyrethrum essential oil 0.15 part, Radix et Caulis Opuntiae Dillenii extract 2 parts, 36.65 parts, water, by each raw material mixed dissolution.
The preparation method of described nano silicon dioxide sol is as follows:
1) take metasilicic acid as raw material, add alkaline solution, more than 50 DEG C, continuous heating makes concentration for more than 5 hours is 5% to saturated metasilicate solution, then carries out acidification and obtain the active silicic acid solution of pH value between 2 ~ 4;
2) be added drop-wise in the alkaline solution of concentration 0.1 ~ 5.0M by above-mentioned active silicic acid solution and mix, solution is until pH is 8 ~ 11, and stirring reaction 2 ~ 24 hours at 30 DEG C ~ 90 DEG C, obtains high concentration basic silicon dioxide gel;
3) in above-mentioned alkaline silicon dioxide colloidal sol, add artificial sequestrant or natural chelators, less than 30 ~ 60 DEG C heated and stirred react more than 30 minutes, dialysis, repeat this step till the heavy metal content of silicon dioxide gel is less than 0.05mg/kg.
The fertile application as soil improvement agent, plant-growth regulator of above-described nano biological environment protection multifunctional organic bamboo vinegar medicine.
The invention has the beneficial effects as follows:
1) bamboo vinegar medicine fertilizer of the present invention can be used as soil redeposition, and the heavy metal in absorption soil, reduces the heavy metal content in farm crop, thus improves the quality of farm crop.
2) bamboo vinegar medicine fertilizer of the present invention can improve the undesirable property such as acid, alkali, sticky, husky and easy flood, easily drought of soil; promote pellet, to improve soil water conservation and permeability; and the micro-fixed nitrogen such as solvable phosphorus decomposing, potassium, magnesium, zinc, selenium, calcium; can direct Promoting plant growth; can also remain by decomposing pesticide; without weedicide, can suppress and elimination weeds.
3) the fertile heavy metal contamination for all kinds of farm crop such as vegetables, melon and fruit, paddy rice, soil, sewage disposal of bamboo vinegar medicine of the present invention has remarkable restraining effect, all kinds of refuse treatment, plant's night soil-treatment suppression, suppresses mosquito pupa, maggot hatching and the breeding of various insect, reduces disease and pest.
4) bamboo vinegar medicine fertilizer of the present invention can suppress the various bacteria-treating Be very effective such as die back disease, Powdery Mildew, leaf spot of the bacterium of various farm crop, improves the quality of agricultural-food.
5) the technology of the present invention conforms with environmental protection and hygienic requirements.Preparation technology of the present invention is easy, production cost is lower, the production cycle is shorter, and product performance are superior, and particle diameter is little, and stability is strong, is easy to store and use.
Embodiment
A kind of nano biological environment protection multifunctional organic bamboo vinegar medicine is fertile, containing following raw material: bamboo vinegar liquid 31 ~ 46 parts, nano silicon dioxide sol 2 ~ 16 parts, potassium primary phosphate 1 ~ 2 part, spraying conerete foliage fertilizer 0.2 ~ 0.3 part, Kuliansu 0.6 ~ 0.8 part, Radix Aconiti Kusnezoffii extract 0.6 ~ 0.8 part, Oxymatyine 0.6 ~ 0.8 part, sapindoside 0.3 ~ 0.6 part, Radix Et Rhizoma Rhei anthraquinone 0.2 ~ 0.6 part, natural pyrethrum essential oil 0.15 ~ 0.16 part, Radix et Caulis Opuntiae Dillenii extract 2 ~ 4 parts, water is appropriate, by each raw material mixed dissolution.
The preparation method of described nano silicon dioxide sol is as follows:
1) take metasilicic acid as raw material, add alkaline solution, more than 50 DEG C, continuous heating makes concentration for more than 5 hours is 5% to saturated metasilicate solution, then carries out acidification and obtain the active silicic acid solution of pH value between 2 ~ 4;
2) be added drop-wise in the alkaline solution of concentration 0.1 ~ 5.0M by above-mentioned active silicic acid solution and mix, solution is until pH is 8 ~ 11, and stirring reaction 2 ~ 24 hours at 30 DEG C ~ 90 DEG C, obtains high concentration basic silicon dioxide gel;
3) in above-mentioned high concentration basic silicon dioxide gel, artificial sequestrant or natural chelators is added, its add-on exceedes it and heavy metal chelating reacts 120% of aequum, less than 30 ~ 60 DEG C heated and stirred react more than 30 minutes, carry out more than 2 times dialysis again, till the various heavy metal content of silicon dioxide gel are less than 0.05mg/kg.
Below in conjunction with embodiment, the present invention is further illustrated, but be not limited thereto.
Nano silicon dioxide sol used in following examples is prepared by following methods:
1) take metasilicic acid as raw material, add alkaline solution, within 5 hours, making concentration at 50 DEG C ~ 60 DEG C continuous heatings is 5% to saturated metasilicate solution, then carries out acidification and obtain the active silicic acid solution of pH value between 2 ~ 4;
2) be added drop-wise in the alkaline solution of concentration 2.0M by above-mentioned active silicic acid solution and mix, solution is until pH is 10, and stirring reaction 2 hours at 50 DEG C ~ 60 DEG C, obtains alkaline silicon dioxide colloidal sol;
3) in above-mentioned alkaline silicon dioxide colloidal sol, add artificial sequestrant or natural chelators, less than 50 ~ 60 DEG C heated and stirred react 30 minutes, then dialysis, and fully this step is till the various heavy metal content of silicon dioxide gel are less than 0.05mg/kg.
embodiment 1
A kind of nano biological environment protection multifunctional organic bamboo vinegar medicine is fertile, is made up of: bamboo vinegar liquid 31 parts, nano silicon dioxide sol 2 parts following raw material, potassium primary phosphate 2 parts, spraying conerete foliage fertilizer 0.3 part, Kuliansu 0.6 part, Radix Aconiti Kusnezoffii extract 0.8 part, Oxymatyine 0.8 part, sapindoside 0.3 part, Radix Et Rhizoma Rhei anthraquinone 0.2 part, natural pyrethrum essential oil 0.16 part, Radix et Caulis Opuntiae Dillenii extract 4 parts, 57.84 parts, water, by each raw material mixed dissolution.
embodiment 2
A kind of nano biological environment protection multifunctional organic bamboo vinegar medicine is fertile, is made up of: bamboo vinegar liquid 46 parts, nano silicon dioxide sol 10 parts following raw material, potassium primary phosphate 2 parts, spraying conerete foliage fertilizer 0.2 part, Kuliansu 0.8 part, Radix Aconiti Kusnezoffii extract 0.6 part, Oxymatyine 0.6 part, sapindoside 0.5 part, Radix Et Rhizoma Rhei anthraquinone 0.5 part, natural pyrethrum essential oil 0.15 part, Radix et Caulis Opuntiae Dillenii extract 2 parts, 36.65 parts, water, by each raw material mixed dissolution.
embodiment 3
A kind of nano biological environment protection multifunctional organic bamboo vinegar medicine is fertile, is made up of: bamboo vinegar liquid 35 parts, nano silicon dioxide sol 16 parts following raw material, potassium primary phosphate 1.5 parts, spraying conerete foliage fertilizer 0.2 part, Kuliansu 0.6 part, Radix Aconiti Kusnezoffii extract 0.7 part, Oxymatyine 0.6 part, sapindoside 0.3 part, Radix Et Rhizoma Rhei anthraquinone 0.6 part, natural pyrethrum essential oil 0.16 part, Radix et Caulis Opuntiae Dillenii extract 3 parts, 41.34 parts, water, by each raw material mixed dissolution.
application example 1
Field test is carried out in the 9-10 month in 2011 at Guilin Xingan Cd-polluted farmland, and testing the vegetables planted is cabbage heart.The basic physical and chemical of soil is pH6.25, organic 9.6 grams/kilogram, 1.12 grams/kilogram, full nitrogen, 0.83 gram/kilogram, full phosphorus, 8.37 grams/kilogram, full potassium, full cadmium 0.95 mg/kg, cation exchange capacity 5.68cmol/ kilogram.After cabbage heart field planting after 15 days, nano biological environment protection multifunctional organic bamboo vinegar medicine fertilizer (diluting 100 times with clear water) of the foliage-spray embodiment of the present invention 1 ~ 4, squirts profit with plant blade face and is as the criterion, and sooner or later respectively sprays 1 time, contrast is clear water, the same Routine Management of all the other field management.Biomass is measured after results.Plot area 20 square metres, repeat for four times, random district group arranges.Experimental result shows, spray the experimental group of bamboo vinegar medicine fertilizer of the present invention, the overground part cadmium content of cabbage heart drops to 1.03 mgs/kg (calculating with dry weight) below by 1.56 mgs/kg of control treatment, at least have dropped 35.0%, especially the experimental group of embodiment 2 bamboo vinegar medicine fertilizer is used, the overground part cadmium content of cabbage heart is dropped to 1.00 mgs/kg (calculating with dry weight) by 1.56 mgs/kg of control treatment, and the limitation of national food hygienic standard (vegetables) is 0.2 mg/kg (calculating with fresh weight).Cabbage heart water content is approximately 85%, is converted into the limitation of national food hygienic standard.
Have this visible, nano biological environmental protection organic bamboo vinegar medicine fertilizer of the present invention effectively can improve planting soil, reduces the heavy metal content in farm crop.

Claims (4)

1. a nano biological environment protection multifunctional organic bamboo vinegar medicine is fertile, it is characterized in that, described medicine fertilizer is containing following raw material: bamboo vinegar liquid 31 ~ 46 parts, nano silicon dioxide sol 2 ~ 16 parts, potassium primary phosphate 1 ~ 2 part, spraying conerete foliage fertilizer 0.2 ~ 0.3 part, Kuliansu 0.6 ~ 0.8 part, Radix Aconiti Kusnezoffii extract 0.6 ~ 0.8 part, Oxymatyine 0.6 ~ 0.8 part, sapindoside 0.3 ~ 0.6 part, Radix Et Rhizoma Rhei anthraquinone 0.2 ~ 0.6 part, natural pyrethrum essential oil 0.15 ~ 0.16 part, Radix et Caulis Opuntiae Dillenii extract 2 ~ 4 parts, water is appropriate, by each raw material mixed dissolution;
The preparation method of described nano silicon dioxide sol is as follows:
1) take metasilicic acid as raw material, add alkaline solution, more than 50 DEG C, continuous heating makes concentration for more than 5 hours is 5% to saturated metasilicate solution, then carries out acidification and obtain the active silicic acid solution of pH value between 2 ~ 4;
2) be added drop-wise in the alkaline solution of concentration 0.1 ~ 5.0M by above-mentioned active silicic acid solution and mix, solution is until pH is 8 ~ 11, and stirring reaction 2 ~ 24 hours at 30 DEG C ~ 90 DEG C, obtains alkaline silicon dioxide colloidal sol;
3) in above-mentioned alkaline silicon dioxide colloidal sol, add artificial sequestrant or natural chelators, less than 30 ~ 60 DEG C heated and stirred react more than 30 minutes, dialysis, repeat this step till the heavy metal content of silicon dioxide gel is less than 0.05mg/kg.
2. bamboo vinegar medicine according to claim 1 is fertile, it is characterized in that, described bamboo vinegar medicine fertilizer is made up of following raw material: bamboo vinegar liquid 46 parts, nano silicon dioxide sol 10 parts, potassium primary phosphate 2 parts, spraying conerete foliage fertilizer 0.2 part, Kuliansu 0.8 part, Radix Aconiti Kusnezoffii extract 0.6 part, Oxymatyine 0.6 part, sapindoside 0.5 part, Radix Et Rhizoma Rhei anthraquinone 0.5 part, natural pyrethrum essential oil 0.15 part, Radix et Caulis Opuntiae Dillenii extract 2 parts, 36.65 parts, water, by each raw material mixed dissolution.
3. the fertile application as soil improvement agent of the bamboo vinegar medicine described in any one of claim 1 ~ 2.
4. the fertile application as plant-growth regulator of the bamboo vinegar medicine described in any one of claim 1 ~ 2.
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CN104311357A (en) * 2014-10-21 2015-01-28 赵连祺 Soil remediation agent with insecticidal effect and preparation process of soil remediation agent
CN104355918B (en) * 2014-12-09 2016-05-18 徐同珊 A kind of manufacture method of the sustained and controlled release chemical fertilizer based on cactus with globular thorn
CN105330485B (en) * 2015-11-25 2018-08-28 深圳市铁汉生态环境股份有限公司 A kind of barrier crops absorb foliar fertilizer and its application of cadmium
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