CN108402103A - Environmentally friendly pasture disinfectant and preparation method thereof - Google Patents

Environmentally friendly pasture disinfectant and preparation method thereof Download PDF

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Publication number
CN108402103A
CN108402103A CN201810100978.3A CN201810100978A CN108402103A CN 108402103 A CN108402103 A CN 108402103A CN 201810100978 A CN201810100978 A CN 201810100978A CN 108402103 A CN108402103 A CN 108402103A
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preparation
pasture
herbal medicine
chinese herbal
disinfectant
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Chinese (zh)
Inventor
彭常安
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Wuhu City Sanshan District Green Food Industry Association
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Wuhu City Sanshan District Green Food Industry Association
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Priority to CN201810100978.3A priority Critical patent/CN108402103A/en
Publication of CN108402103A publication Critical patent/CN108402103A/en
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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N33/00Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds
    • A01N33/02Amines; Quaternary ammonium compounds
    • A01N33/12Quaternary ammonium compounds
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/16Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group; Thio analogues thereof
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/02Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
    • A01N43/04Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
    • A01N43/14Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings
    • A01N43/16Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings with oxygen as the ring hetero atom
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/501,3-Diazoles; Hydrogenated 1,3-diazoles
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N59/00Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
    • A01N59/06Aluminium; Calcium; Magnesium; Compounds thereof
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N65/00Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N65/00Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
    • A01N65/08Magnoliopsida [dicotyledons]
    • A01N65/12Asteraceae or Compositae [Aster or Sunflower family], e.g. daisy, pyrethrum, artichoke, lettuce, sunflower, wormwood or tarragon
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N65/00Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
    • A01N65/08Magnoliopsida [dicotyledons]
    • A01N65/22Lamiaceae or Labiatae [Mint family], e.g. thyme, rosemary, skullcap, selfheal, lavender, perilla, pennyroyal, peppermint or spearmint
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N65/00Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
    • A01N65/08Magnoliopsida [dicotyledons]
    • A01N65/30Polygonaceae [Buckwheat family], e.g. red-knees or rhubarb
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N65/00Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
    • A01N65/08Magnoliopsida [dicotyledons]
    • A01N65/32Ranunculaceae [Buttercup family], e.g. hepatica, hydrastis or goldenseal
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N65/00Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
    • A01N65/40Liliopsida [monocotyledons]

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  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Environmental Sciences (AREA)
  • Dentistry (AREA)
  • Plant Pathology (AREA)
  • Agronomy & Crop Science (AREA)
  • Zoology (AREA)
  • Natural Medicines & Medicinal Plants (AREA)
  • Biotechnology (AREA)
  • Microbiology (AREA)
  • Mycology (AREA)
  • Pest Control & Pesticides (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Botany (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The invention discloses a kind of environmentally friendly pasture disinfectants and preparation method thereof, which includes:1)Chinese herbal medicine, ethyl alcohol and Peracetic acid are decocted, then filter to take filtrate so that extracting solution is made;2)Under ultrasound condition, extracting solution, nano-attapulgite, metronidazole, quaternary ammonium salt are subjected to adsorption treatment, then filtered so that modified nano concave good soil is made;3)Modified nano concave good soil, cyclodextrin and water are subjected to ultrasonic vibration so that environmentally friendly pasture disinfectant is made;Wherein, Chinese herbal medicine is the fruit of Rangoon creeper, betel nut, dandelion, radix paeoniae rubra, sweet wormwood, rheum officinale and wrinkled giant hyssop.The environmental protection pasture disinfectant has excellent Disinfection Effect for the body surface of livestock, and milder, nuisanceless to environment and livestock;The preparation method has the advantages that process is simple and raw material is easy to get simultaneously.

Description

Environmentally friendly pasture disinfectant and preparation method thereof
Technical field
The present invention relates to disinfectants, and in particular, to a kind of environmental protection pasture disinfectant and preparation method thereof.
Background technology
Animal husbandry refer to herd, stable breeding or the two combine mode, raising livestock and poultry to obtain animal product or the draught animal Production division.It include livestock raise herd, home poultry raising, economic beasts are raised and train.Animal husbandry has important in national economy Status and effect, predominantly:1. providing the animal foods such as meat, milk, eggs;2. for industry provide wool, cashmere, skin, The raw materials such as hair on the neck, beast bone, casing;3. exporting acquisition of foreign currency by livestock products;4. the industry of animal husbandry input and livestock products is promoted to add Industrial expansion increases labour employment chance;5. providing organic fertilizer for production estimation;6. increasing farmers' income;7. being agriculture Industry and transportation provide animal power;8. promoting the economy and cultural development in vast pastoral area, strengthen the unity among nationalities.Thus As it can be seen that the development of country is to be unable to do without the support of animal husbandry.
It during developing animal husbandry, often needs to sterilize, especially the disinfection to field house.Currently, field house disappears Poison is carried out disinfection using chemically synthesized organic disinfectant, although certain Disinfection Effect can be obtained;But change On the one hand the health of livestock can be adversely affected by learning the reagent of synthesis, and then affect the meat and hair cortex of livestock Amount, the chemically synthesized reagent of another aspect can cause environmental pollution.
Invention content
The object of the present invention is to provide a kind of environmentally friendly pasture disinfectant and preparation method thereof, the environmental protection pasture disinfectant for The body surface of livestock has excellent Disinfection Effect, and milder, nuisanceless to environment and livestock;Preparation method tool simultaneously There is process simple and the advantages of raw material is easy to get.
To achieve the goals above, the present invention provides a kind of preparation methods of environmentally friendly pasture disinfectant, including:
1)Chinese herbal medicine, ethyl alcohol and Peracetic acid are decocted, then filter to take filtrate so that extracting solution is made;
2)Under ultrasound condition, by extracting solution, nano-attapulgite, metronidazole, quaternary ammonium salt carry out adsorption treatment, then filter with Modified nano concave good soil is made;
3)Modified nano concave good soil, cyclodextrin and water are subjected to ultrasonic vibration so that environmentally friendly pasture disinfectant is made;
Wherein, Chinese herbal medicine is the fruit of Rangoon creeper, betel nut, dandelion, radix paeoniae rubra, sweet wormwood, rheum officinale and wrinkled giant hyssop.
The present invention also provides a kind of environmentally friendly pasture disinfectant, which passes through above-mentioned preparation method system It is standby and obtain.
In the above-mentioned technical solutions, the present invention passes through first by the mixed liquor of ethyl alcohol and Peracetic acid composition to Chinese herbal medicine Decoct and then obtains extracting solution;Then, by nano-attapulgite to extracting solution, metronidazole, quaternary ammonium salt adsorbed into And modified nano concave good soil is made;Then, modified nano concave good soil is coated by cyclodextrin, while is pasted using ring The outer rim of essence is hydrophilic and characteristic that inner cavity is hydrophobic is so as to soluble in water and then obtained environmentally friendly pasture disinfectant.The disinfectant There is excellent Disinfection Effect not only for the body surface of livestock, while milder, nuisanceless to environment and livestock;Simultaneously should Preparation method has the advantages that process is simple and raw material is easy to get.
Other features and advantages of the present invention will be described in detail in subsequent specific embodiment part.
Specific implementation mode
The specific implementation mode of the present invention is described in detail below.It should be understood that described herein specific Embodiment is merely to illustrate and explain the present invention, and is not intended to restrict the invention.
The present invention provides a kind of preparation methods of environmentally friendly pasture disinfectant, including:
1)Chinese herbal medicine, ethyl alcohol and Peracetic acid are decocted, then filter to take filtrate so that extracting solution is made;
2)Under ultrasound condition, by extracting solution, nano-attapulgite, metronidazole, quaternary ammonium salt carry out adsorption treatment, then filter with Modified nano concave good soil is made;
3)Modified nano concave good soil, cyclodextrin and water are subjected to ultrasonic vibration so that environmentally friendly pasture disinfectant is made;
Wherein, Chinese herbal medicine is the fruit of Rangoon creeper, betel nut, dandelion, radix paeoniae rubra, sweet wormwood, rheum officinale and wrinkled giant hyssop.
In the step 1 of the present invention)In, the dosage of each material can select in a wide range, but in order to make the disinfection Agent has superior Disinfection Effect and mildness, it is preferable that in step 1)In, Chinese herbal medicine, ethyl alcohol and Peracetic acid weight Amount is than being 10:35-45:2-7;In Chinese herbal medicine, the fruit of Rangoon creeper, betel nut, dandelion, radix paeoniae rubra, sweet wormwood, rheum officinale and wrinkled giant hyssop weight ratio It is 20:11-15:6-10:15-20:5-10:8-12:9-16.
In the step 1 of the present invention)In, the condition of decoction can select in a wide range, but in order to make the disinfectant With superior Disinfection Effect and mildness, it is preferable that decoction meets the following conditions:It is 79-83 DEG C to decoct temperature, is decocted Time is 2-4h.
In the step 2 of the present invention)In, the dosage of each substance can select in a wide range, but in order to make the disinfection Agent has superior Disinfection Effect and mildness, it is preferable that in step 2)In, extracting solution, nano-attapulgite, first nitre Azoles, quaternary ammonium salt weight ratio be 100:30-40:1-3:0.2-0.9.
In the step 2 of the present invention)In, the condition of adsorption treatment can select in a wide range, but in order to make this disappear Toxic agent has superior Disinfection Effect and mildness, it is preferable that in step 2)In, adsorption treatment meets the following conditions:Place It is 55-65 DEG C, processing time 6-8h, supersonic frequency 34-38KHz to manage temperature.
In the step 3 of the present invention)In, the dosage of each substance can select in a wide range, but in order to make the disinfection Agent has superior Disinfection Effect and mildness, it is preferable that in step 3)In, modified nano concave good soil, cyclodextrin and The weight ratio of water is 10:4-6:225-250.
In the step 3 of the present invention)In, the condition of ultrasonic vibration can select in a wide range, but in order to make this disappear Toxic agent has superior Disinfection Effect and mildness, it is preferable that in step 3)In, ultrasonic vibration meets the following conditions:Shake It is 15-35 DEG C to swing temperature, and the concussion time is 3-5h, supersonic frequency 45-50KHz.
In the present invention, the average grain diameter of nano-attapulgite can select in a wide range, but in order to make this disappear Toxic agent has superior Disinfection Effect and mildness, it is preferable that the average grain diameter of nano-attapulgite is 15-30nm.
The present invention also provides a kind of environmentally friendly pasture disinfectant, which passes through above-mentioned preparation method system It is standby and obtain.
The present invention will be described in detail by way of examples below.
Embodiment 1
1)By Chinese herbal medicine(The fruit of Rangoon creeper, betel nut, dandelion, radix paeoniae rubra, sweet wormwood, rheum officinale and wrinkled giant hyssop weight ratio be 20:13:8:18:7: 10:13), ethyl alcohol and Peracetic acid be according to 10:40:6 weight ratio is decocted(It is 80 DEG C to decoct temperature, and decocting time is 3h), filtrate is then filtered to take so that extracting solution is made;
2)Under ultrasound condition, by extracting solution, nano-attapulgite(Average grain diameter is 20nm), metronidazole, quaternary ammonium salt according to 100:35:2:0.6 weight ratio carries out adsorption treatment(Treatment temperature is 60 DEG C, processing time 7h, and supersonic frequency is 36KHz), then filter so that modified nano concave good soil is made;
3)By modified nano concave good soil, cyclodextrin and water according to 10:5:225 weight ratio carries out ultrasonic vibration(Shake temperature It it is 25 DEG C, the concussion time is 4h, supersonic frequency 48KHz)Environmental protection pasture disinfectant A1 is made.
Embodiment 2
1)By Chinese herbal medicine(The fruit of Rangoon creeper, betel nut, dandelion, radix paeoniae rubra, sweet wormwood, rheum officinale and wrinkled giant hyssop weight ratio be 20:11:6:15:5: 8:9), ethyl alcohol and Peracetic acid be according to 10:35:2 weight ratio is decocted(It is 79 DEG C to decoct temperature, decocting time 2h), Then filtrate is filtered to take so that extracting solution is made;
2)Under ultrasound condition, by extracting solution, nano-attapulgite(Average grain diameter is 15nm), metronidazole, quaternary ammonium salt according to 100:30:1:0.2 weight ratio carries out adsorption treatment(Treatment temperature is 55 DEG C, processing time 6h, and supersonic frequency is 34KHz), then filter so that modified nano concave good soil is made;
3)By modified nano concave good soil, cyclodextrin and water according to 10:4:240 weight ratio carries out ultrasonic vibration(Shake temperature It it is 15 DEG C, the concussion time is 3h, supersonic frequency 45KHz)Environmental protection pasture disinfectant A2 is made.
Embodiment 3
1)By Chinese herbal medicine(The fruit of Rangoon creeper, betel nut, dandelion, radix paeoniae rubra, sweet wormwood, rheum officinale and wrinkled giant hyssop weight ratio be 20:15:10:20: 10:12:16), ethyl alcohol and Peracetic acid be according to 10:45:7 weight ratio is decocted(It is 83 DEG C to decoct temperature, and decocting time is 4h), filtrate is then filtered to take so that extracting solution is made;
2)Under ultrasound condition, by extracting solution, nano-attapulgite(Average grain diameter is 30nm), metronidazole, quaternary ammonium salt according to 100:40:3:0.9 weight ratio carries out adsorption treatment(Treatment temperature is 65 DEG C, processing time 8h, and supersonic frequency is 38KHz), then filter so that modified nano concave good soil is made;
3)By modified nano concave good soil, cyclodextrin and water according to 10:6:250 weight ratio carries out ultrasonic vibration(Shake temperature It it is 35 DEG C, the concussion time is 5h, supersonic frequency 50KHz)Environmental protection pasture disinfectant A3 is made.
Comparative example 1
It carries out that disinfectant B1 is made according to the method for embodiment 1, unlike, step 2)Extracting solution is not used.
Comparative example 2
It carries out that disinfectant B2 is made according to the method for embodiment 1, unlike, step 3)Cyclodextrin is not used.
Detect example 1
It is given up using Farm as sterilization objects in this test example;6 pieces of cowshed are taken respectively while detecting the bacterium colony of bacterium in cowshed Density 1;Then above-mentioned disinfectant is periodically sprinkled, daily sprinkling 3 times, each fountain height is 30mL/m2, continuous sprinkling 3 days, so The colony density 2 of bacterium in cowshed is detected afterwards;Wherein blank control group spray water;Concrete outcome is shown in Table 1.
Table 1
The substance of sprinkling Colony density 1(CFU/dm2 Colony density 2(CFU/dm2
A1 45 2
A2 38 1
A3 42 3
B1 40 35
B2 39 26
Water 37 54
The preferred embodiment of the present invention has been described above in detail, still, the tool during present invention is not limited to the embodiments described above Body details can carry out a variety of simple variants, these letters to technical scheme of the present invention within the scope of the technical concept of the present invention Monotropic type all belongs to the scope of protection of the present invention.
It is further to note that specific technical features described in the above specific embodiments, in not lance In the case of shield, can be combined by any suitable means, in order to avoid unnecessary repetition, the present invention to it is various can The combination of energy no longer separately illustrates.
In addition, various embodiments of the present invention can be combined randomly, as long as it is without prejudice to originally The thought of invention, it should also be regarded as the disclosure of the present invention.

Claims (9)

1. a kind of preparation method of environmental protection pasture disinfectant, which is characterized in that including:
1)Chinese herbal medicine, ethyl alcohol and Peracetic acid are decocted, then filter to take filtrate so that extracting solution is made;
2)Under ultrasound condition, the extracting solution, nano-attapulgite, metronidazole, quaternary ammonium salt are subjected to adsorption treatment, then mistake Filter is to be made modified nano concave good soil;
3)The modified nano concave good soil, cyclodextrin and water are subjected to ultrasonic vibration so that the environmentally friendly pasture disinfectant is made;
Wherein, the Chinese herbal medicine is the fruit of Rangoon creeper, betel nut, dandelion, radix paeoniae rubra, sweet wormwood, rheum officinale and wrinkled giant hyssop.
2. preparation method according to claim 1, wherein in step 1)In, the Chinese herbal medicine, ethyl alcohol and Peracetic acid Weight ratio is 10:35-45:2-7;
In the Chinese herbal medicine, the fruit of Rangoon creeper, betel nut, dandelion, radix paeoniae rubra, sweet wormwood, rheum officinale and wrinkled giant hyssop weight ratio be 20: 11-15:6-10:15-20:5-10:8-12:9-16.
3. preparation method according to claim 1, wherein the decoction meets the following conditions:Decoction temperature is 79-83 DEG C, decocting time 2-4h.
4. according to the preparation method described in any one of claim 1-3, wherein in step 2)In, the extracting solution, nanometer Attapulgite, metronidazole, quaternary ammonium salt weight ratio be 100:30-40:1-3:0.2-0.9.
5. preparation method according to claim 4, wherein in step 2)In, the adsorption treatment meets the following conditions:Place It is 55-65 DEG C, processing time 6-8h, supersonic frequency 34-38KHz to manage temperature.
6. according to the preparation method described in claim 1-3, any one of 5, wherein in step 3)In, the modified Nano The weight ratio of attapulgite, cyclodextrin and water is 10:4-6:225-250.
7. according to the preparation method described in claim 1-3, any one of 5, wherein in step 3)In, the ultrasonic vibration Meet the following conditions:It is 15-35 DEG C to shake temperature, and the concussion time is 3-5h, supersonic frequency 45-50KHz.
8. according to the preparation method described in claim 1-3, any one of 5, wherein the average grain of the nano-attapulgite Diameter is 15-30nm.
9. a kind of environmental protection pasture disinfectant, which is characterized in that the environmental protection pasture disinfectant passes through any one in claim 1-8 Preparation method described in is prepared.
CN201810100978.3A 2018-02-01 2018-02-01 Environmentally friendly pasture disinfectant and preparation method thereof Withdrawn CN108402103A (en)

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CN201810100978.3A CN108402103A (en) 2018-02-01 2018-02-01 Environmentally friendly pasture disinfectant and preparation method thereof

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Application Number Priority Date Filing Date Title
CN201810100978.3A CN108402103A (en) 2018-02-01 2018-02-01 Environmentally friendly pasture disinfectant and preparation method thereof

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