CN108239444B - A kind of thermal insulation coat finishing technique of decorative substrate - Google Patents

A kind of thermal insulation coat finishing technique of decorative substrate Download PDF

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Publication number
CN108239444B
CN108239444B CN201810163821.5A CN201810163821A CN108239444B CN 108239444 B CN108239444 B CN 108239444B CN 201810163821 A CN201810163821 A CN 201810163821A CN 108239444 B CN108239444 B CN 108239444B
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Prior art keywords
parts
coating
thermal insulation
coating agent
agent
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CN201810163821.5A
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CN108239444A (en
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倪海霞
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Shandong Shian Chemical Co., Ltd.
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Shandong Shian Chemical Co Ltd
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    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
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    • D06M23/00—Treatment of fibres, threads, yarns, fabrics or fibrous goods made from such materials, characterised by the process
    • D06M23/04—Processes in which the treating agent is applied in the form of a foam
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D123/00—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers
    • C09D123/02—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
    • C09D123/04—Homopolymers or copolymers of ethene
    • C09D123/08—Copolymers of ethene
    • C09D123/0846—Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
    • C09D123/0853—Vinylacetate
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/004—Reflecting paints; Signal paints
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    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/44—Oxides or hydroxides of elements of Groups 2 or 12 of the Periodic System; Zincates; Cadmates
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    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/77—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
    • D06M11/79—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof with silicon dioxide, silicic acids or their salts
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    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
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    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/144—Alcohols; Metal alcoholates
    • D06M13/148—Polyalcohols, e.g. glycerol or glucose
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    • D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
    • D06M13/248—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur
    • D06M13/256—Sulfonated compounds esters thereof, e.g. sultones
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    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/325—Amines
    • D06M13/328—Amines the amino group being bound to an acyclic or cycloaliphatic carbon atom
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    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/35—Heterocyclic compounds
    • D06M13/355—Heterocyclic compounds having six-membered heterocyclic rings
    • D06M13/358—Triazines
    • D06M13/364—Cyanuric acid; Isocyanuric acid; Derivatives thereof
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    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
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    • D06M13/50—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with organometallic compounds; with organic compounds containing boron, silicon, selenium or tellurium atoms
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    • D06M13/51—Compounds with at least one carbon-metal or carbon-boron, carbon-silicon, carbon-selenium, or carbon-tellurium bond
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    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
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    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
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    • D06M15/327—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof
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    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
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    • C08K3/20—Oxides; Hydroxides
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    • D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Laminated Bodies (AREA)
  • Paints Or Removers (AREA)

Abstract

The present invention relates to a kind of thermal insulation coat finishing techniques of decorative substrate, coating agent is continuously applied in the form of foams to flat flexible parent metal, higher than 80 DEG C at a temperature of by the coating of application by infrared radiation device and/or use hot-air be dried, cold blocking is carried out to the coating later, the preparation method overcomes the shortcomings that existing thermal insulation decorative paint coatings, provides a kind of thermal-insulation, pollution-free, good decorative property elastic thin layer thermal insulation coat finishing technique.

Description

A kind of thermal insulation coat finishing technique of decorative substrate
Technical field
The present invention relates to a kind of ornament materials finishing technique, in particular to a kind of thermal insulation coat of decorative substrate is whole Science and engineering skill.
Background technique
The material for being used as insulation at present is broadly divided into two kinds: low thermal conductivity light material, heat reflection material Material.Low thermal conductivity light material relies primarily on the structure of material itself and chemical property achievees the purpose that heat-insulated, main material Have: porous light-weight material, hollow (or filling gas) material of closed pore, specialty fibers class material etc..Heat-reflecting material then relies on it Can reflection wavelength infrared region electromagnetic wave and achieve the purpose that it is heat-insulated, main material be some high IR heat reflectivities Metal, alloy and compound, such as ferroso-ferric oxide, metallic nickel, aluminium foil, titanium dioxide etc..
It is applied to the heat-insulation and heat-preservation of chemical engineering industry field, especially high temperature storage tank, the pump housing, pipeline outer heat insulation at present Material is essentially all with mineral wool class, mineral wool class winding tank body, additional galvanized iron sheet or aluminium-foil paper cladding.This material Material only has function of heat insulation, does not have anti-corrosion and waterproof function, is unfavorable for southern wet area and is imbedded in setting for underground It is standby；And these materials on skin have very big irritation, easy incoming call respiratory tract, and material contains carcinogen, cause construction with after Phase maintenance difficulties are big；This material category highly energy-consuming trade is produced simultaneously, has been used at present by limitation in most cities.Cause This finds a kind of energy conservation and environmental protection, service life long heat insulating material and has very important significance.
Summary of the invention
The technical problem to be solved by the present invention is to overcome existing thermal insulation decorative paint coatings, one kind is provided Thermal-insulation, pollution-free, good decorative property elastic thin layer thermal insulation coat finishing technique.
To achieve the goals above, the present invention adopts the following technical scheme: a kind of thermal insulation coat of decorative substrate Finishing technique continuously applies coating agent to flat flexible parent metal in the form of foams, higher than 80 DEG C at a temperature of The coating of application is dried by infrared radiation device and/or using hot-air, cold blocking is carried out to the coating later；Institute The layer of coating is stated with a thickness of 4-6mm；Wherein apply the coating agent in the form of foams, and by into the coating agent Introduce air, nitrogen, CO2Or their mixture is as gas, to form the foams；The coating agent includes following The component of parts by weight:
100 parts of matrix lotion of ethene-vinyl acetate copolymer resins composition,
Three 10-23 parts of fulminuric acid ester of (2,3- dibromopropyl),
1-3 parts of association type aqueous polyurethane emulsion,
5-10 parts of polyacrylate dispersion,
2-4 parts of fumed silica,
1-1.5 parts of sulfosuccinate,
0.3-0.8 parts of sulfosuccinamide,
6-16 parts of silicon-nitrogen compound,
5-13 parts of ethylene oxide/propylene oxide block copolymer,
12-20 parts of modifying agent；
20-35 parts of wood fiber powder；
1-10 parts of Aluminate；
The modifying agent is made from the following raw materials in parts by weight: diatomite 40-45, acrylate 4-5, Tri (propylene glycol) diacrylate 2-3, zinc oxide 5-6, jade 4-5,3- aminopropyl trimethoxysilane 2-3, crosslinking agent TAC1-2, zinc gluconate 1-2, zinc stearate 1-2, Rosa Damascana 0.1-0.2.
Further, the solid content of the coating agent is 30-50%, viscosity 1000-5000mpas.
Further, the blowing ratio control is between 1: 1.2-10.
Further, the substrate is selected from the hydrophilic polymer that polyester fiber, cellulose fibre or lignin fibre are constituted Object is constituted.
Coating of the present invention has the beneficial effect that: it is insufficient for prior art and provide a kind of collection elasticity, thin layer, it is heat-insulated, The advantages that heat preservation in one Multifunctional partition hot coating, meanwhile, decoration of the invention with coating in addition to heat preservation and insulation, Also there is very strong weather resistance, to guarantee that coating is still able to maintain in the case where relatively thin (overall thickness is less than or equal to 0.6 millimeter) Good heat insulation property；By configuring special elastic resin lotion, make the coating of composition that there is good elasticity, and very There is in a wide range of spectrum reflecting effect, paint film elongation percentage may be up to 370%, to cracking caused by wall have it is stronger oneself Dynamic closed performance；And surface modifying agent protection technique is used, extend the heat preservation property of coating.
Specific embodiment
Below by embodiment, the technical solutions of the present invention will be further described.
Embodiment one:
A kind of thermal insulation coat finishing technique of decorative substrate, coating agent is continuously applied in the form of foams to On flat flexible parent metal, 85 DEG C at a temperature of by the coating of application by infrared radiation device and/or using hot-air carry out It is dry, cold blocking is carried out to the coating later；The layer of the coating is with a thickness of 4mm；Wherein apply institute in the form of foams Coating agent is stated, and by introducing air, nitrogen, CO into the coating agent2Or their mixture carrys out shape as gas At the foams；The coating agent includes the component of following parts by weight:
100 parts of matrix lotion of ethene-vinyl acetate copolymer resins composition,
Three 10 parts of fulminuric acid ester of (2,3- dibromopropyl),
1 part of association type aqueous polyurethane emulsion,
5 parts of polyacrylate dispersion,
2 parts of fumed silica,
1 part of sulfosuccinate,
0.3 part of sulfosuccinamide,
6 parts of silicon-nitrogen compound,
5 parts of ethylene oxide/propylene oxide block copolymer,
12 parts of modifying agent；
20 parts of wood fiber powder；
1 part of Aluminate；
The modifying agent is made from the following raw materials in parts by weight: diatomite 40, acrylate 4, two contract Tripropylene glycol diacrylate 2, zinc oxide 5, jade 4,3- aminopropyl trimethoxysilane 2, crosslinking agent TAC 1, gluconic acid Zinc 1, zinc stearate 1, Rosa Damascana 0.1.The solid content of the coating agent is 30-50%, viscosity 1000-5000mpas. Blowing ratio controls between 1: 1.2-10.The substrate is selected from the hydrophilic polymer structure that polyester fiber and cellulose fibre are constituted At.
Embodiment two:
A kind of thermal insulation coat finishing technique of decorative substrate, coating agent is continuously applied in the form of foams to On flat flexible parent metal, 98 DEG C at a temperature of by the coating of application by infrared radiation device and/or using hot-air carry out It is dry, cold blocking is carried out to the coating later；The layer of the coating is with a thickness of 6mm；Wherein apply institute in the form of foams Coating agent is stated, and by introducing air, nitrogen, CO into the coating agent2Or their mixture carrys out shape as gas At the foams；The coating agent includes the component of following parts by weight:
100 parts of matrix lotion of ethene-vinyl acetate copolymer resins composition,
Three 23 parts of fulminuric acid ester of (2,3- dibromopropyl),
3 parts of association type aqueous polyurethane emulsion,
10 parts of polyacrylate dispersion,
4 parts of fumed silica,
1.5 parts of sulfosuccinate,
0.8 part of sulfosuccinamide,
16 parts of silicon-nitrogen compound,
13 parts of ethylene oxide/propylene oxide block copolymer,
20 parts of modifying agent；
35 parts of wood fiber powder；
10 parts of Aluminate；
The modifying agent is made from the following raw materials in parts by weight: diatomite 45, acrylate 5, two contract Tripropylene glycol diacrylate 3, zinc oxide 6, jade 5,3- aminopropyl trimethoxysilane 3, crosslinking agent TAC 2, gluconic acid Zinc 2, zinc stearate 2, Rosa Damascana 0.2.The solid content of the coating agent is 30-50%, viscosity 1000-5000mpas. Blowing ratio controls between 1: 1.2-10.The substrate is selected from the hydrophilic polymer structure that polyester fiber and lignin fibre are constituted At.
The above description is merely a specific embodiment, but scope of protection of the present invention is not limited thereto, any Those skilled in the art within the technical scope disclosed by the invention, can without the variation that creative work is expected or Replacement, should be covered by the protection scope of the present invention.Therefore, protection scope of the present invention should be limited with claims Subject to fixed protection scope.

Claims (1)

1. a kind of thermal insulation coat finishing technique of decorative substrate, it is characterised in that: by coating agent in the form of foams Continuously apply to flat flexible parent metal, higher than 80 DEG C at a temperature of by the coating of application by infrared radiation device and/or It is dried using hot-air, cold blocking is carried out to the coating later；The layer of the coating is with a thickness of 4-6mm；Wherein with bubble The form of foam body applies the coating agent, and by introducing air, nitrogen, CO into the coating agent2Or their mixing Object is as gas, to form the foams；The coating agent includes the component of following parts by weight:
100 parts of matrix lotion of ethene-vinyl acetate copolymer resins composition,
Three 10-23 parts of fulminuric acid ester of (2,3- dibromopropyl),
1-3 parts of association type aqueous polyurethane emulsion,
5-10 parts of polyacrylate dispersion,
2-4 parts of fumed silica,
1-1.5 parts of sulfosuccinate,
0.3-0.8 parts of sulfosuccinamide,
6-16 parts of silicon-nitrogen compound,
5-13 parts of ethylene oxide/propylene oxide block copolymer,
12-20 parts of modifying agent；
20-35 parts of wood fiber powder；
1-10 parts of Aluminate；
The modifying agent is made from the following raw materials in parts by weight: diatomite 40-45, acrylate 4-5, two Contracting tripropylene glycol diacrylate 2-3, zinc oxide 5-6, jade 4-5,3- aminopropyl trimethoxysilane 2-3, crosslinking agent TAC 1-2, zinc gluconate 1-2, zinc stearate 1-2, Rosa Damascana 0.1-0.2；
Wherein, for frostproof froth n than control between 1: 1.2-10, the substrate is selected from polyester fiber, cellulose fibre or lignin The hydrophilic polymer that fiber is constituted is constituted.
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CN105544229B (en) 2018-04-13

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