CN103525061A - Polycarbonate cup shell material with high impact resistance and preparation method for polycarbonate cup shell material - Google Patents
Polycarbonate cup shell material with high impact resistance and preparation method for polycarbonate cup shell material Download PDFInfo
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- CN103525061A CN103525061A CN201310510358.4A CN201310510358A CN103525061A CN 103525061 A CN103525061 A CN 103525061A CN 201310510358 A CN201310510358 A CN 201310510358A CN 103525061 A CN103525061 A CN 103525061A
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Abstract
The invention discloses a polycarbonate cup shell material with high impact resistance. The material is characterized by being prepared from the following raw materials in parts by weight: 500 to 520 parts of polycarbonate, 30 to 35 parts of styrene-butadiene rubber, 30 to 35 parts of polystyrene, 20 to 23 parts of polyvinyl alcohol, 2 to 3 parts of polyethylene glycol octylphenol ether, 12 to 14 parts of talc powder, 12 to 15 parts of oxidic polyethylene, 3 to 4 parts of octaphenyl polyoxyethyiene and 10 to 12 parts of an accessory. The material has high impact resistance, good processing flowability and good thermal resistance, is wide in application temperature range, stable in product quality, low in molding shrinkage and stable in size, and a process is simple.
Description
Technical field
The present invention relates to plastics field, particularly good polycarbonate water tumbler case material of a kind of shock resistance and preparation method thereof.
Background technology
Polycarbonate (being called for short PC) is the high molecular polymer that contains carbonate group in molecular chain, due to the singularity on polycarbonate structure, has now become the fastest general engineering plastic of rate of growth in five large-engineering plastics.Due to polycarbonate article, to have quality light, and shock resistance and the transparency are good, and indeformable and keep transparent advantage during by hot water and caustic soln carrying out washing treatment, some field PC bottles replace vial completely.It is predicted, along with people are to the improving constantly of drinking water quality attention degree, polycarbonate consumption rate of growth in this respect will remain on more than 10%, and the water tumbler housing of therefore researching and developing a kind of polycarbonate material is trend of the times.
Summary of the invention
The object of this invention is to provide good polycarbonate water tumbler case material of a kind of shock resistance and preparation method thereof.
In order to realize object of the present invention, the present invention passes through following scheme implementation:
A good polycarbonate water tumbler case material, is made by the raw material of following weight part: polycarbonate 500-520, styrene-butadiene rubber(SBR) 30-35, polystyrene 30-35, polyvinyl alcohol 20-23, Triton X-100 2-3, talcum powder 12-14, oxidic polyethylene 12-15, polyoxyethylene octylphenol ether 3-4, auxiliary agent 10-12;
Described auxiliary agent is made by the raw material of following weight part: diatomite 40-45, vinylformic acid dimethylamino ethyl ester 4-5, tri (propylene glycol) diacrylate 2-3, zinc oxide 5-6, jade 4-5,3-aminopropyl trimethoxysilane 2-3, linking agent TAC1-2, Zinc Gluconate 1-2, Zinic stearas 1-2, Flos Rosae Rugosae quintessence oil 0.1-0.2; Preparation method puts into diatomite, jade mixing calcining furnace and calcine 3-4 hour at 710-740 ℃, cooling, put into 10-12% hydrochloric acid soln and soak 1-2 hour, filter and take out, with clear water, clean and dry, be ground into 200-400 order powder, mix with other remaining component, grinding distribution is even, obtains.
The polycarbonate water tumbler case material that shock resistance of the present invention is good, by following concrete steps, made:
(1) polystyrene is heated to molten state, adds polyvinyl alcohol, Triton X-100, talcum powder, auxiliary agent, stir and mediate 15-25 minute, send into twin screw extruder granulation, obtain A material;
(2) dried polycarbonate is heated to 240-285 ℃, adds other remaining component, stir 6-10 minute, send on twin screw extruder and melt extrude granulation, obtain B material;
(3) after A, B material is mixed, on twin screw extruder, melt extrude granulation, obtain.
The present invention has the following advantages: the present invention has higher shock resistance, and technique is simple, and processing flowability is good, and use temperature scope is wide, constant product quality, and molding shrinkage is low, dimensional stabilizing, resistance toheat is good.
Embodiment
Below by specific examples, the present invention is described in detail.
A good polycarbonate water tumbler case material, by following weight part (kilogram) raw material make: polycarbonate 500, styrene-butadiene rubber(SBR) 30, polystyrene 30, polyvinyl alcohol 20, Triton X-100 2, talcum powder 12, oxidic polyethylene 12, polyoxyethylene octylphenol ether 3, auxiliary agent 10;
Described auxiliary agent by following weight part (kilogram) raw material make: diatomite 40, vinylformic acid dimethylamino ethyl ester 5, tri (propylene glycol) diacrylate 3, zinc oxide 5, jade 4,3-aminopropyl trimethoxysilane 2, linking agent TAC2, Zinc Gluconate 2, Zinic stearas 2, Flos Rosae Rugosae quintessence oil 0.1; Preparation method puts into diatomite, jade mixing calcining furnace and calcine 3-4 hour at 710-740 ℃, cooling, put into 10-12% hydrochloric acid soln and soak 1-2 hour, filter and take out, with clear water, clean and dry, be ground into 200-400 order powder, mix with other remaining component, grinding distribution is even, obtains.
The polycarbonate water tumbler case material that shock resistance of the present invention is good, by following concrete steps, made:
(1) polystyrene is heated to molten state, adds polyvinyl alcohol, Triton X-100, talcum powder, auxiliary agent, stir and mediate 15-25 minute, send into twin screw extruder granulation, obtain A material;
(2) dried polycarbonate is heated to 240-285 ℃, adds other remaining component, stir 6-10 minute, send on twin screw extruder and melt extrude granulation, obtain B material;
(3) after A, B material is mixed, on twin screw extruder, melt extrude granulation, obtain.
Tensile strength of material of the present invention is 50-55MPa, elongation 10-15%, flexural strength 70-80MPA, notched Izod impact strength 370J/M.
Claims (2)
1. the polycarbonate water tumbler case material that shock resistance is good, it is characterized in that, by the raw material of following weight part, made: polycarbonate 500-520, styrene-butadiene rubber(SBR) 30-35, polystyrene 30-35, polyvinyl alcohol 20-23, Triton X-100 2-3, talcum powder 12-14, oxidic polyethylene 12-15, polyoxyethylene octylphenol ether 3-4, auxiliary agent 10-12;
Described auxiliary agent is made by the raw material of following weight part: diatomite 40-45, vinylformic acid dimethylamino ethyl ester 4-5, tri (propylene glycol) diacrylate 2-3, zinc oxide 5-6, jade 4-5,3-aminopropyl trimethoxysilane 2-3, linking agent TAC1-2, Zinc Gluconate 1-2, Zinic stearas 1-2, Flos Rosae Rugosae quintessence oil 0.1-0.2; Preparation method puts into diatomite, jade mixing calcining furnace and calcine 3-4 hour at 710-740 ℃, cooling, put into 10-12% hydrochloric acid soln and soak 1-2 hour, filter and take out, with clear water, clean and dry, be ground into 200-400 order powder, mix with other remaining component, grinding distribution is even, obtains.
2. the good polycarbonate water tumbler case material of shock resistance according to claim 1, is characterized in that, by following concrete steps, is made:
(1) polystyrene is heated to molten state, adds polyvinyl alcohol, Triton X-100, talcum powder, auxiliary agent, stir and mediate 15-25 minute, send into twin screw extruder granulation, obtain A material;
(2) dried polycarbonate is heated to 240-285 ℃, adds other remaining component, stir 6-10 minute, send on twin screw extruder and melt extrude granulation, obtain B material;
(3) after A, B material is mixed, on twin screw extruder, melt extrude granulation, obtain.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310510358.4A CN103525061A (en) | 2013-10-26 | 2013-10-26 | Polycarbonate cup shell material with high impact resistance and preparation method for polycarbonate cup shell material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310510358.4A CN103525061A (en) | 2013-10-26 | 2013-10-26 | Polycarbonate cup shell material with high impact resistance and preparation method for polycarbonate cup shell material |
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| CN103525061A true CN103525061A (en) | 2014-01-22 |
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| CN201310510358.4A Pending CN103525061A (en) | 2013-10-26 | 2013-10-26 | Polycarbonate cup shell material with high impact resistance and preparation method for polycarbonate cup shell material |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104559049A (en) * | 2014-12-11 | 2015-04-29 | 柳州市麦可思塑胶科技有限公司 | Injection molding raw material of plastic cup |
| CN105506956A (en) * | 2016-02-25 | 2016-04-20 | 倪海霞 | Heat-insulation coating agent of decorative base material |
| CN105544229A (en) * | 2016-02-25 | 2016-05-04 | 倪海霞 | Finishing process for heat-insulation coating of decorative substrate |
| CN113214612A (en) * | 2021-04-13 | 2021-08-06 | 中北大学 | PBSeT/Zinc gluconate puncture-resistant biodegradable material and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1203246A (en) * | 1997-05-14 | 1998-12-30 | 大赛璐化学工业株式会社 | Thermoplastic resin composition |
| CN1377911A (en) * | 2001-04-04 | 2002-11-06 | 中国石油化工股份有限公司 | Syndiotactic polyphenlethylene/polycarbonate composite material |
| CN101210105A (en) * | 2006-12-30 | 2008-07-02 | 上海普利特复合材料有限公司 | Illumination aging resisting polycarbonate/styryl resin composition and preparing method thereof |
-
2013
- 2013-10-26 CN CN201310510358.4A patent/CN103525061A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1203246A (en) * | 1997-05-14 | 1998-12-30 | 大赛璐化学工业株式会社 | Thermoplastic resin composition |
| CN1377911A (en) * | 2001-04-04 | 2002-11-06 | 中国石油化工股份有限公司 | Syndiotactic polyphenlethylene/polycarbonate composite material |
| CN101210105A (en) * | 2006-12-30 | 2008-07-02 | 上海普利特复合材料有限公司 | Illumination aging resisting polycarbonate/styryl resin composition and preparing method thereof |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104559049A (en) * | 2014-12-11 | 2015-04-29 | 柳州市麦可思塑胶科技有限公司 | Injection molding raw material of plastic cup |
| CN105506956A (en) * | 2016-02-25 | 2016-04-20 | 倪海霞 | Heat-insulation coating agent of decorative base material |
| CN105544229A (en) * | 2016-02-25 | 2016-05-04 | 倪海霞 | Finishing process for heat-insulation coating of decorative substrate |
| CN105544229B (en) * | 2016-02-25 | 2018-04-13 | 王敏晓 | A kind of thermal insulation coat finishing technique of decorative substrate |
| CN108239444A (en) * | 2016-02-25 | 2018-07-03 | 倪海霞 | A kind of thermal insulation coat finishing technique of decorative substrate |
| CN108265521A (en) * | 2016-02-25 | 2018-07-10 | 倪海霞 | A kind of thermal insulation coat finishing technique of decorative substrate |
| CN108265521B (en) * | 2016-02-25 | 2018-12-07 | 杭州曼京科技有限公司 | A kind of thermal insulation coat finishing technique of decorative substrate |
| CN108239444B (en) * | 2016-02-25 | 2019-11-19 | 山东世安化工有限公司 | A kind of thermal insulation coat finishing technique of decorative substrate |
| CN113214612A (en) * | 2021-04-13 | 2021-08-06 | 中北大学 | PBSeT/Zinc gluconate puncture-resistant biodegradable material and preparation method thereof |
| CN113214612B (en) * | 2021-04-13 | 2022-12-30 | 中北大学 | PBSeT/Zinc gluconate puncture-resistant biodegradable material and preparation method thereof |
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Application publication date: 20140122 |
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