CN103525056A - Composite polycarbonate material for water cup shell and preparation method of composite polycarbonate material - Google Patents
Composite polycarbonate material for water cup shell and preparation method of composite polycarbonate material Download PDFInfo
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- CN103525056A CN103525056A CN201310510108.0A CN201310510108A CN103525056A CN 103525056 A CN103525056 A CN 103525056A CN 201310510108 A CN201310510108 A CN 201310510108A CN 103525056 A CN103525056 A CN 103525056A
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Abstract
The invention discloses a composite polycarbonate material for a water cup shell. The composite polycarbonate material is characterized by being prepared from the following raw materials in parts by weight: 500-520 parts of polycarbonate, 20-24 parts of ABS (acrylonitrile-butadiene-styrene), 12-14 parts of PET (polyethylene glycol terephthalate), 2-3 parts of polyethylene wax, 12-15 parts of triethyl citrate, 2-3 parts of a silane coupling agent KH550, 8-12 parts of chlorinated paraffin, 3-4 parts of zinc stearate, 2-3 parts of magnesium oxide, 20-24 parts of precipitation method white carbon black and 10-12 parts of auxiliary agents. The composite polycarbonate material has good wear resistance and crack resistance, strong impact ductility, high surface finish and a wide usage temperature range, the production process is simple, the cost is low, the quality is stable, and the material is safe and nontoxic, accords with sanitary safety, and is suitable for manufacturing the water cup shells.
Description
Technical field
The present invention relates to plastics field, particularly a kind of water tumbler compound polycarbonate material and preparation method thereof for housing.
Background technology
Polycarbonate (being called for short PC) is the high molecular polymer that contains carbonate group in molecular chain, due to the singularity on polycarbonate structure, has now become the fastest general engineering plastic of rate of growth in five large-engineering plastics.Due to polycarbonate article, to have quality light, and shock resistance and the transparency are good, and indeformable and keep transparent advantage during by hot water and caustic soln carrying out washing treatment, some field PC bottles replace vial completely.It is predicted, along with people are to the improving constantly of drinking water quality attention degree, polycarbonate consumption rate of growth in this respect will remain on more than 10%, and the water tumbler housing of therefore researching and developing a kind of polycarbonate material is trend of the times.
Summary of the invention
The object of this invention is to provide a kind of water tumbler compound polycarbonate material and preparation method thereof for housing.
In order to realize object of the present invention, the present invention passes through following scheme implementation:
The compound polycarbonate material of housing, is made by the raw material of following weight part: polycarbonate 500-520, ABS 20-24, PET 12-14, polyethylene wax 2-3, triethyl citrate 12-15, Silane coupling agent KH550 2-3, clorafin 8-12, Zinc Stearate 3-4, magnesium oxide 2-3, precipitated silica 20-24, auxiliary agent 10-12;
Described auxiliary agent is made by the raw material of following weight part: diatomite 40-45, vinylformic acid dimethylamino ethyl ester 2-3, ethoxylated trimethylolpropane triacrylate 3-4, jade 1-2, nano titanium oxide 3-4, Union carbide A-162 1-2, linking agent TAC1-2, aluminium hydroxide 8-10, oxidation inhibitor 1035 1-2; Preparation method puts into diatomite, jade mixing calcining furnace and calcine 3-4 hour at 700-720 ℃, cooling, put into 10-12% hydrochloric acid soln and soak 1-2 hour, filter and take out, with clear water, clean and dry, be ground into 200-400 order powder, mix with other remaining component, grinding distribution is even, obtains.
The compound polycarbonate material of water tumbler housing of the present invention, by following concrete steps, made:
(1) ABS, polyethylene wax are heated to molten state, add triethyl citrate, Silane coupling agent KH550, clorafin, magnesium oxide, auxiliary agent, stir and mediate 15-25 minute, send into twin screw extruder granulation, obtain A material;
(2) dried polycarbonate is heated to 245-280 ℃, adds other remaining component, stir 7-10 minute, send on twin screw extruder and melt extrude granulation, obtain B material;
(3) after A, B material is mixed, on twin screw extruder, melt extrude granulation, obtain.
The present invention has the following advantages: the compound polycarbonate material of the present invention has good wear resistance and splitting resistance, impelling strength is strong, surface smoothness is high, use temperature scope is wide, and production technique is simple, with low cost, steady quality, safety non-toxic, meet hygienic safety, be applicable to making water tumbler housing.
Embodiment
Below by specific examples, the present invention is described in detail.
The compound polycarbonate material of housing, by following weight part (kilogram) raw material make: polycarbonate 500, ABS 20, PET 12, polyethylene wax 2, triethyl citrate 12, Silane coupling agent KH550 2, clorafin 8, Zinc Stearate 3, magnesium oxide 2, precipitated silica 20, auxiliary agent 10;
Described auxiliary agent by following weight part (kilogram) raw material make: diatomite 40, vinylformic acid dimethylamino ethyl ester 3, ethoxylated trimethylolpropane triacrylate 4, jade 1, nano titanium oxide 3, Union carbide A-162 1, linking agent TAC2, aluminium hydroxide 8, oxidation inhibitor 1,035 1; Preparation method puts into diatomite, jade mixing calcining furnace and calcine 3-4 hour at 700-720 ℃, cooling, put into 10-12% hydrochloric acid soln and soak 1-2 hour, filter and take out, with clear water, clean and dry, be ground into 200-400 order powder, mix with other remaining component, grinding distribution is even, obtains.
The compound polycarbonate material of water tumbler housing of the present invention, by following concrete steps, made:
(1) ABS, polyethylene wax are heated to molten state, add triethyl citrate, Silane coupling agent KH550, clorafin, magnesium oxide, auxiliary agent, stir and mediate 15-25 minute, send into twin screw extruder granulation, obtain A material;
(2) dried polycarbonate is heated to 245-280 ℃, adds other remaining component, stir 7-10 minute, send on twin screw extruder and melt extrude granulation, obtain B material;
(3) after A, B material is mixed, on twin screw extruder, melt extrude granulation, obtain.
Tensile strength of material of the present invention is 50-55MPa, elongation 10-15%, flexural strength 70-80MPA, notched Izod impact strength 370J/M.
Claims (2)
1. the compound polycarbonate material of water tumbler housing, it is characterized in that, by the raw material of following weight part, made: polycarbonate 500-520, ABS 20-24, PET 12-14, polyethylene wax 2-3, triethyl citrate 12-15, Silane coupling agent KH550 2-3, clorafin 8-12, Zinc Stearate 3-4, magnesium oxide 2-3, precipitated silica 20-24, auxiliary agent 10-12;
Described auxiliary agent is made by the raw material of following weight part: diatomite 40-45, vinylformic acid dimethylamino ethyl ester 2-3, ethoxylated trimethylolpropane triacrylate 3-4, jade 1-2, nano titanium oxide 3-4, Union carbide A-162 1-2, linking agent TAC1-2, aluminium hydroxide 8-10, oxidation inhibitor 1035 1-2; Preparation method puts into diatomite, jade mixing calcining furnace and calcine 3-4 hour at 700-720 ℃, cooling, put into 10-12% hydrochloric acid soln and soak 1-2 hour, filter and take out, with clear water, clean and dry, be ground into 200-400 order powder, mix with other remaining component, grinding distribution is even, obtains.
2. the compound polycarbonate material of water tumbler housing according to claim 1, is characterized in that, by following concrete steps, is made:
(1) ABS, polyethylene wax are heated to molten state, add triethyl citrate, Silane coupling agent KH550, clorafin, magnesium oxide, auxiliary agent, stir and mediate 15-25 minute, send into twin screw extruder granulation, obtain A material;
(2) dried polycarbonate is heated to 245-280 ℃, adds other remaining component, stir 7-10 minute, send on twin screw extruder and melt extrude granulation, obtain B material;
(3) after A, B material is mixed, on twin screw extruder, melt extrude granulation, obtain.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310510108.0A CN103525056A (en) | 2013-10-25 | 2013-10-25 | Composite polycarbonate material for water cup shell and preparation method of composite polycarbonate material |
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| CN201310510108.0A CN103525056A (en) | 2013-10-25 | 2013-10-25 | Composite polycarbonate material for water cup shell and preparation method of composite polycarbonate material |
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| CN103525056A true CN103525056A (en) | 2014-01-22 |
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| CN201310510108.0A Pending CN103525056A (en) | 2013-10-25 | 2013-10-25 | Composite polycarbonate material for water cup shell and preparation method of composite polycarbonate material |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103865156A (en) * | 2014-03-26 | 2014-06-18 | 马鞍山市佳源环保科技有限公司 | Flexible cross-linked polyethylene insulated cable material and preparation method of cable material |
| CN103980672A (en) * | 2014-04-30 | 2014-08-13 | 中国科学院化学研究所 | 3D printing aromatic polyester material and preparation method thereof |
| CN103980675A (en) * | 2014-04-30 | 2014-08-13 | 中国科学院化学研究所 | 3D printing aromatic polyester material and preparation method |
| CN104559023A (en) * | 2014-12-09 | 2015-04-29 | 惠州市昌亿科技股份有限公司 | High-strength smooth ABS/PC (acrylonitrile-butadiene-styrene/polycarbonate) alloy material for 3D printing, and preparation method and application thereof |
| CN106317943A (en) * | 2016-08-19 | 2017-01-11 | 安徽金星包装有限公司 | Plastic cup production technology |
| CN108003592A (en) * | 2017-12-30 | 2018-05-08 | 珠海国能新材料股份有限公司 | A kind of PC plastic antenna house and its preparation process |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN1206655A (en) * | 1997-07-29 | 1999-02-03 | 胡学根 | Transparent polyester cup and making technology thereof |
| CN102051034A (en) * | 2009-10-30 | 2011-05-11 | 上海普利特复合材料股份有限公司 | Polycarbonate composite with low gloss and high heat resistance |
| CN103351520A (en) * | 2013-06-19 | 2013-10-16 | 安徽电缆股份有限公司 | High-cold-resistant insulated cable material and preparation method thereof |
-
2013
- 2013-10-25 CN CN201310510108.0A patent/CN103525056A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1206655A (en) * | 1997-07-29 | 1999-02-03 | 胡学根 | Transparent polyester cup and making technology thereof |
| CN102051034A (en) * | 2009-10-30 | 2011-05-11 | 上海普利特复合材料股份有限公司 | Polycarbonate composite with low gloss and high heat resistance |
| CN103351520A (en) * | 2013-06-19 | 2013-10-16 | 安徽电缆股份有限公司 | High-cold-resistant insulated cable material and preparation method thereof |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103865156A (en) * | 2014-03-26 | 2014-06-18 | 马鞍山市佳源环保科技有限公司 | Flexible cross-linked polyethylene insulated cable material and preparation method of cable material |
| CN103865156B (en) * | 2014-03-26 | 2016-03-16 | 马鞍山市佳源环保科技有限公司 | A kind of soft cross-linked polyethylene insulating CABLE MATERIALS and preparation method thereof |
| CN103980672A (en) * | 2014-04-30 | 2014-08-13 | 中国科学院化学研究所 | 3D printing aromatic polyester material and preparation method thereof |
| CN103980675A (en) * | 2014-04-30 | 2014-08-13 | 中国科学院化学研究所 | 3D printing aromatic polyester material and preparation method |
| CN103980675B (en) * | 2014-04-30 | 2016-08-24 | 中国科学院化学研究所 | A kind of 3D prints aromatic polyester material and preparation method thereof |
| CN104559023A (en) * | 2014-12-09 | 2015-04-29 | 惠州市昌亿科技股份有限公司 | High-strength smooth ABS/PC (acrylonitrile-butadiene-styrene/polycarbonate) alloy material for 3D printing, and preparation method and application thereof |
| CN104559023B (en) * | 2014-12-09 | 2018-07-24 | 惠州市昌亿科技股份有限公司 | Bright and clean type ABS/PC alloy materials of a kind of high intensity for 3D printing and its preparation method and application |
| CN106317943A (en) * | 2016-08-19 | 2017-01-11 | 安徽金星包装有限公司 | Plastic cup production technology |
| CN108003592A (en) * | 2017-12-30 | 2018-05-08 | 珠海国能新材料股份有限公司 | A kind of PC plastic antenna house and its preparation process |
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Application publication date: 20140122 |
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